Professional Documents
Culture Documents
materials
Compiled
By
pak de jongko
duraposita chem.
Table of content
In this chapter, we will study the assembly and the adhesive bonding of 2 kinds
of composites:
The primary composite materials are made by different techniques: lay out,
impregnation, molding, infusion, filament winding, pultrusion… All these methods
consist in impregnating fibers with a polymer resin ( epoxy, polyester, etc…), the
manufacturer may start with prepregs where the fibers are already impregnated
with resin, shaping the parts in various ways and then curing the polymer by heat
and pressure.
Co-curing
Adhesive bonding
EWhen the part is hollow, co-curing cannot be used, the 2 halves of the part
must be manufactured separately and then they have to be assembled, either by
mechanical fixtures or by using inserts, or by adhesive bonding. This chapter will
be devoted only to the adhesive bonding of composite materials and parts. Refer
to figure 2
Figure 2: Examples of composite bonded parts
Wet tabbing
We will also mention a technique which is frequently used in naval construction: this is
the "wet tabbing " (figure 3 ): in this technique, the cured composite parts are aligned
closely and then a prepreg ( reinforcing fibers impregnated with the raw, non cured resin
) is tabbed or laid onto the mating parts and then cured usually at room temperature.
Inserts
A last technique is the use of inserts ( figure 5 ) : here metal inserts such as
studs, plates… are placed into the premix in the mold before curing, and the cure
of the matrix will bl°Ck the insert into the hardened resin. Here we use the
adhesive properties of the polymer resin, and also the possibility of bolting,
screwing the parts together, and mechanical engineers, who are accustomed to
use mechanical fasteners, like and rely with confidence on this technique.
However we will not study this technique here because it is a mechanical
assembly.
Figure 5: The 3 steps of the use of metal inserts in the
final assembly on large GRP part
(Source: BIGHEAD bonding fasteners Ltd., UK)
In any case, the composite parts must be assembled onto a frame, and this
frame is very ofter made of metal. This is true for automotives, aircrafts or
construction panels. Therefore it is mandatory to have some kind of metal
fasteners, attached to the composite part, which is then attached to the frame.
Figure 6 shows how the speed breakes of the F15 aircraft fighter are molded,
including bonding of titanium ribs and actuators. Here both techniques are mixed:
co-curing of the graphite-epoxy skins over honeycomb core, bonding of titanium
ribs and then final positioning and curing of the graphite-epoxy skins.
• mechanical fasteners require drilling holes in the parts, and this weakens
the composites because it cuts through the reinforcing fibers and also
creates weak points. Figure 7 shows the many failure modes that may
occur in a bolted joint. Bonding improves tensile resistance ( figure 7 ).
• Bonded joints exhibit lower stresses concentrations than mechanical joints
when holes are needed, and thus provides increased static strength,
• Risks of cracks propagation are reduced,
• Bonded joints provide always 10 to 25 % weight savings in primary and
secondary structures,
• Bonded joints enable the design of smooth external structures,
• For large surfaces bonding costs less than mechanical assembly, because
it needs less manpower ( although there are now huge riveting machines
which may place automatically thousands of rivets on the fuselage of large
aircrafts in a short time, but these machines have of course a very high
cost ),
• Adhesive may join together all kinds of materials: metals, composites,
plastics, wood etc…
• Adhesives can join very thin materials which could not be riveted or
bolted,
• Adhesives can join dissimilar materials without the risk of galvanic
corrosion,
• Adhesives may be flexible or rigid according to their formulation,
• Adhesives have an excellent resistance to fatigue.
We will study a number of these factors and properties in the following sections
of this chapter.
Materials to be bonded
Composite materials are made with polymer matrixes and the surfaces to be
bonded are made of these polymers. Therefore the required surface preparation
is the same as it is used for the pure polymer or plastic.
Cleaning:
Prior to bonding, parts must be cleaned, the demolding release agents used
during curing must be completely eliminated by washing with detergents or
solvents. Washing must be followed by a perfect rinse and drying with clean air.
Abrasion:
In order to eliminate pollution, mold release agents and obtain a slightly rough
surface for a better wetting, the surface may be gently abraded, for instance with
abrasive pad, but the abrasion must be very light so that it never goes down to
the reinforcing fibers, because these fibers must always be protected by a layer
of the polymer and embedded in the polymer. After abrasion, dust and pollution
must be eliminated by cleaning and rinsing thoroughly.
Tear plies:
This is the best technique to get a clean surface on which the adhesive will bond
readily. Refer to figure 8. During the manufacture of the composite part, a special
textile ( such as Dacron or other ) is applied on the surface of the polymer before
curing. Immediately before bonding, this peel ply or tear ply is peeled away, and
it leaves underneath a perfectly clean resin surface.
There are several chemical surface preparations which are specifically adapted
to the various polymers. Table 1 lists these surface preparations.
Cleaning Chemical and Physical surface preparation
with Light Plasma
Polymers None detergent Toluene
abrasion Atmospheric Low Flame Other
or Silination Sulfochromic sulfonic
treatment treatments
solvent Pressure pressure acid
Acrylonitrile - butadiene -
styrene (ABS)
Peel
Epoxy resins
ply
Melamine and Urea- Peel
Formaldehyde resins ply
Peel
Phenolic resins
ply
Polyacetal
Polybutyleneterephthalate
(PBT)
Polycarbonate (PC)
(Alcohol)
Polyester (Thermosetting)
(Ketone)
Titanate
PET: Polyester
primer,
(Thermoplastic)
NaOH
Polyetherether Ketone
PEEK
Corona
Polyolefins: PE, PP
(Ketone) treatment
Polyimide NaOH
(Ketone)
Polysulfone (PS)
(Alcohol)
Polyurethane (PU)
thermosetting
Table 1: Chemicals and Physical surface preparation for plastics, polymers and composites
1. When bonding with epoxy adhesives, the part may be up to 80°C and the adhesive is then affected while parts are still hot.
2. Laser may be also used now on thermosetting reinforced plastics.
In the next sections, we will introduce the different chemical types of adhesives
used for structural bonding of composites and their technical characteristics.
And after that we will study the main end uses of adhesives bonding in many
industries such as Automotive, Aircraft industry, transportation, shipbuilding and
others
Part 2
The various chemical types of Adhesives for composites,
epoxy adhesives
Introduction
In this section, we will study the adhesives which are used for bonding the most
important composite materials:
As we will see, when choosing an adhesive for a given composite material, the
first idea that comes to our mind is to select a chemical type which is the same
as the resin used as the matrix. Epoxy adhesives are of course totally compatible
with epoxy matrixes, therefore they are frequently used because they are the
best choice for carbon-epoxy and Kevlar-epoxy composites.
We will now review the different types of epoxy adhesives which may be used for
composite bonding
Co curing:
In the aircraft construction, these adhesives can be cured at the same time that
the composite part itself (prepregs ) . This is called cocure. In this technique, the
parts prepregs are stacked together with the film epoxy adhesive, between the
mold and a vacuum bag for instance ( refer to figure 3 ), the whole system is
loaded into an autoclave where the prepregs and the adhesive are cured
simultaneously. This means that the curing conditions ( temperature, time and
pressure ) must be the same.One component, heat curing adhesives may have
different forms:
Let us mention that recently 2 components epoxy paste adhesive have been
developed for cold curing in aircraft construction: this is for instance the
EPIBOND 1590 A/B of Vantico now HUNTSMAN.
Toughened epoxies
There are several ways to flexibilise epoxy adhesives systems. One way is to
use HYCAR carboxyl terminated reactive liquid polymers at 10 to 25 parts of this
rubber for 100 parts of epoxy resin. This increases impact strength, peel strength
and fracture surface energy with little loss of modulus and heat resistance.
HYCAR polymers are acrylonitrile-butadiene copolymers ( CTBN ) bearing free
carboxyl groups at the polymer end of the chain or distributed along the chain.
Their structure is shown on figure 5. They react with epoxy rings as indicated on
figure 6 and this gives flexible links.
These alloys are formulated with epoxy resins modified by the addition and co-
reaction of other polymers:
All are one component heat curing adhesives that require high temperature for
the cure.
In the next section we will study the other types of adhesives for composites,
namely the structural acrylics, polyurethanes, polyesters, heat stable adhesives
and related products such as Syntactics.
In following sections later we will describe all the main applications / end uses of
adhesives in the various industries that use large amounts of composites, such
as Aerospace, Automotive and Transportation equipment, windmills and naval
construction.
Part 3
Various types of adhesives for composites: Acrylics,
urethanes-acrylates and Polyesters.
Introduction
In this section, we will study several types of structural adhesives which are used
for the assembly of composites: Acrylics, Polyesters, and others.
There are several types but all are based on the same chemistry:
This is the main family of structural acrylics. They display very interesting
properties for the assembly of composites:
Mix
Working Fixture Tensile1 Tensile Shear2
Description/ Ratio
Adhesive Viscosity (cps) Time Time Strength Elongation Strength
Substrates (By
(min) (min) (psi) (%) (psi)
Volume)
A:
High strength, all- 40,000~60,000
MA300 1:1 4~6 12~15 3000~3500 15~25 3000~3500
purpose adhesive B:
40,000~60,000
A:
High strength
40,000~60,000
MA310 adhesive for difficult- 1:1 15~18 30~35 4000~4500 5~15 3000~3500
B:
to-bond plastics
40,000~60,000
A:
Gray version of
40,000~60,000
MA330 MA310 for difficult- 1:1 15~18 30~35 4000~4500 5~15 3000~3500
B:
to-bond plastics
40,000~60,000
A:
Excellent to low-
135,000~175,000
MA320 temp and toughness 10:1 8~12 25~30 2000~2500 100~140 1500~2000
B:
properties
40,000~70,000
A:
All-purpose
100,000~125,000
AO420 adhesive; Fast 10:1 4~6 15~18 2700~3000 100~125 1750~2250
B:
curing
50,000~70,000
A:
All-purpose
100,000~125,000
MA422 adhesive; Medium 10:1 17~24 35~40 2000~2500 75~100 1500~1800
B:
open time
40,000~60,000
A:
All-purpose
100,000~125,000
MA425 adhesive; Long open 10:1 30~35 80~90 2000~2500 120~140 1500~1800
B:
time
40,000~60,000
A:
Excellent marine 130,000~160,000
MA550 10:1 40~45 70~75 1750~2000 30~45 1300~1800
adhesive; UV Stable B:
40,000~60,000
For boat-building; A:
Low exotherm 190,000~220,000
MA556 10:1 40~45 110~120 2500~3000 140~160 1250~1500
adhesive for bond B:
line to 1" thick 40,000~60,000
A:
Low exotherm
180,000~220,000
MA557 adhesive for bond 10:1 80~90 180~220 2000~2500 120~160 1250~1550
B:
line to 1.5" thick
40,000~60,000
A:
Primerless adhesive
80,000~110,000
MA820 for metal bonding; 10:1 4~6 15~18 3300~3700 75~100 2000~2400
B:
Fast cure
50,000~70,000
A:
Low-odor; all-
100,000~125,000
MA920 purpose adhesive; 10:1 4~6 15~18 2700~3000 80~100 1500~2000
B:
Fast cure
50,000~70,000
A:
Low-odor; all-
100,000~125,000
MA922 purpose adhesive; 10:1 17~24 35~40 1800~2200 75~100 1400~1700
B:
Medium open time
40,000~60,000
A:
Low-odor; all-
100,000~125,000
MA925 purpose adhesive; 10:1 30~35 80~90 1700~2200 100~120 1400~1700
B:
Long open time
40,000~60,000
A:
Low-shrink/odor;
100,000~125,000
MA1020 Fast cure, Multi 10:1 4~6 15~20 1750~2000 90~110 1250~1600
B:
purpose
50,000~70,000
Low- A:
shrink/odor/exotherm 180,000~220,000
MA1025 10:1 20~25 40~45 1750~2000 90~110 850~1200
for bond lines to 1" B:
thick 40,000~60,000
Table 1: Typical characteristics of structural, 2 component engineering acrylic adhesives
Source: (ITW- PLEXUS USA)
1: Tensile strength of coat adhesive
2: shera strengthon git blasted sheet
Applications:
• Naval construction, for all bonding jobs of deck to hull, partitions to hull,
stiffeners to hulls.
Figure 2 shows the many composites parts which may be bonded in a modern
bus. Here all the excellent properties of the structural acrylics mentioned above
are very interesting, mostly the adhesion to these composites, the high fatigue
and shocks resistances, the gap filling properties, the ease of application in the
plants where there are no large manufacturing series for buses, and the room
temperature cure.
Figure 2: Schematic of a bus showing composite parts that may
be bonded with adhesives
These structural acrylics may also be used in automotive body jobs, for instance
to bond composite parts such as fenders, stiffeners to door panels, doors, sliding
roofs. Note that their cure could be accelerated by mild heating at 60°C for
instance in order to adapt to the production line speed. There will be no
deformation of the composite parts at these low temperatures.
One interesting application is for bonding plastic bumpers in USA: these bumpers
are made of XENOY alloy based on polycarbonate and polyester. These acrylic
adhesives are used to bond the face bar or fascia to the back bar or
reinforcement.
13 - There are also hybrid epoxy-acrylates that provide high heat resistance up to
150°C service temperatures, and urethane-acrylates.
Urethane-acrylates:
Curing conditions:
These adhesives need the addition of accelerator and catalyst, for instance
Cobalt/MEKP or amine/BPO curing systems that will initiate the cross linking
reaction between styrene monomers and the acrylates sections, in a way rather
similar to the cure of polyesters.
Marine Stainless
FRP Aluminium Teak
Ply Steel
FRP 10 4 10 10 5
Crystic
Marine Ply 4 4 4 4
Crestomer
1186PA Aluminium 10 10 5
Stainless
12 5
Steel
Teak 5
Cohesive Failure
Substrate Failure
Polyester adhesives:
Most GRP parts for naval construction or Buildings have been made traditionally
with glass fiber reinforced polyester resins. Therefore the paste adhesives that
were traditionally used for bonding or wet tabbing of these parts were also
polyester based, and are supplied by the same companies as the suppliers of
polyester resins: REICHHOLD, SCOTT BADER, ASHLAND, ...
However they are still used in naval construction in large quantities, for deck to
hull bonding, wet tabbing or bonding of stiffeners to the hull etc...and they are
cheaper than the other naval adhesives, because polyesters are manufactured in
very large quantities for GRP.
Viscosity* Typical
Description & Tanks Gel Linear
Building/ 2=Low MEKP- Hardening bond/gap
Product Main Marine & Transpose Time shrinkage
Sanitary 3,4=High 50 % Time (hrs) thickness
Characteristics Silos (mins) (%)
& thrixol (mm)
Thixotropic - Low
density - Flexible -
Bonding/ TH 06 Easy to sand - Low 3 18 2 5 0,3 - 3 <1
Joining/ shrinkage
Fixing All - around
TH 72 bonding paste - 3 10 2 3 0,3 - 3 2 - 2,5
short gel time
Same as TH 72
TH 72
with catalyst 3 10 2 3 0,3 - 3 2 - 2,5
AR
indicator
High thixotropic -
containing glass
TH 75 fibres and catalyst 4 10 2 3 3-5 2 - 2,5
indicator - Short gel
time
Fire resistance -
Catalyst indicator
TH 80 3 23 2 4 3-5 < 0,5
with low
shrinkage/exotherm
High thixotropic -
Catalyst indicator -
TH 89 4 18 1 4 3-5 < 0,5
Low shrinkage -
Low exotherm
High thixotropic -
TH 95 Catalyst indicator - 4 45 2 6 3-5 < 0,5
Low shrinkage
Low thixotropic with
long gel time -
TH 725 Shrinkage 3 35 2 5 0,3 - 3 1,5 - 2
controlled - Good
flexibility
Same as TH 725
with low viscosity -
TH 730 2 35 2 5 0,3 - 3 1,5 - 2
High mechanical
values
High thixotropic
containing glass
TH 751 fibres and catalyst 4 35 2 5 3-5 2 - 2,5
indicator - Long gel
time
Thixotropic with
TH
long gel time - Low 3 60 1,5 6 0,3 - 3 < 0,5
1725
Shrinkage
TH ixotropic - Very
TH
long gel time and 3 90 1 6 3-5 < 0,5
2000
low shrinkage
VER based resin -
Using Standard
TH
MEKP - Low 2 45 2 6 0,3 - 10 1,5 - 2
6000
thixotropic with long
gel time
All - around
TH 72 bonding paste - 3 10 2 3 0,3 - 3 2 - 2,5
short gel time
High thixotropic
containing glass
TH 75 fibres and catalyst 4 10 2 3 3-5 2 - 2,5
indicator - Short gel
time
Thixotropic - Low
density - Easy to
TH 86 3 13 2 3 0,3 - 3 1,5 - 2
sand - Short gel
time
Very flexible -
TH 90 3 18 2 4 0,3 - 3 < 0,5
Thixotropic
High thixotropic -
TH 97 4 60 1,5 6 0,3 - 3 1,5 - 2
Low density
Sandwich TH 724 Low thixotropic with
2 10 2 3 0,3 - 3 2 - 2,5
core catalyst indicator
bonding Low thixotropic with
long gel time -
TH 725 Shrinkage 3 35 2 5 0,3 - 3 1,5 - 2
controlled - Good
flexibility
Low thixotropic -
TH 727 2 17 1 4 0,3 - 3 < 0,5
Low shrinkage
High thixotropic
containing glass
TH 751 fibres and catalyst 4 35 2 5 3-5 2 - 2,5
indicator - Long gel
time
Low viscosity - Low
TH 761 density - Low gel 2 35 1,5 5 0,3 - 3 1,5 - 2
time - Easy to sand
Thixotropic with
TH
long gel time - Low 3 60 1,5 6 0,3 - 3 < 0,5
1725
shrinkage
Table 5: Technical characteristics of polyester bonding parts ENGUARD® (registered symbol) from
ASHLAND
In the next section, we will study the other adhesives that may be used for
composites bonding, namely Polyurethanes, heat stable adhesives and also
syntactics
Part 4
Various types of Adhesives for Composites: Polyurethanes,
Heat stable adhesives, Syntactics, etc…
Introduction
Polyurethanes:
Therefore we must define here the types of PU adhesives which are used for
composite bonding: these adhesives are usually 2 components, semi-structural,
high performances adhesives. They may cure at room temperature or provide
accelerated curing by mild temperature heat curing, at temperature ranging from
60 to 100°C.
Isocyanate terminated prepolymers can react with water, alcohols, amines and
other reactive chemicals. For more details we advice our readers to refer to
comprehensive handbooks on PU chemistry, which is very complex, and cannot
be explained here in details.
TEST METHOD
Viscosity: ASTM D-2393
Specific Gravity: ASTM D-792
Pot Life: ASTM D-2471
Lap Shear Strength: ASTM D-1002 (Tested on aluminum)
Tg per DMA
Elongation ASTM D-638
Ultimate Tensile Strength: ASTM D-638
Coefficient of Thermal Expansion: ASTM E-831
' Below Tg
" Above Tg
+77°F = 25°C
104°F = 40°C
140°F = 60°C
180°F = 82°C
212°F = 100°C
248°F = 120°C
302°F = 151°C
356°F= 180°C
a = Tested on SMC
b = Time to achieve 150 psi lap shear strength
c = Time to achieve 1500 psi lap shear strength, in most products
d = After room-temperature cure
e = Temperature at which bond maintains 1,000 psi lap shear strength, in most
products
VISCOSITY IN CENTIPOISE CONSISTENCY SIMILAR TO
1 Water
500 #10 Motor Oil
2,500 Pancake Syrup
10,000 Honey
25,000 Chocolate Syrup
50,000 Catsup
This means that the work required to break the bond, which is proportioned to the
area under these curves, is higher for the PU adhesives, although the tensile
strength of the PU is lower. This fact has been used in the last 15 years by PU
adhesives manufacturers to promote these PU adhesives even in structural
applications, mostly for automotive and transportation equipment.
Let us consider for instance the bonds of composite parts to metal parts in
automotives. Here there are sometimes large deformations of the parts and the
bond, because of the relative movements of the car body. PU adhesives and
sealants will withstand very well these movements thanks to their flexibility, while
rigid epoxies will not. Epoxies are perfect for metal to metal bonding and rigid
bonding with very low deformations, but when it comes to bonding of reinforced
plastics to metals, semi-structural PU may be a better choice.
Note: Some PU reactive Hot melts may be also used for composites bonding.
Utilisations of PU adhesives for composites bonding:
in Car manufacturing :
bonding of RRIM injected fenders made of glass fibers reinforced PU
resin, to metal frame, bonding of glass fiber reinforced stiffeners to door
panels, roof panels, reinforced PU spoilers, ( figure 5 ) hood and fenders
assemblies for trucks, some truck's cabs are made with a complete outer
shell made of SMC panels , including the front, sides, doors, rear and
underbody ,which are bonded to a steel frame with 2 components PU
adhesives. Bonding body parts for buses and recreational vehicles (
caravans walls and roof panels ) assembly of front grills and fascia made
of reinforced thermoplastics,...
These are adhesives that withstand fairly high temperatures, higher than the
standard epoxies ( which resist only to service temperatures up to 100-150°C )
Bismaleimides
( in short BMI ) may withstand service temperatures up to 230 - 250°C
Up to now, they are used only for aircrafts manufacturing because their price is
very high ( 200 euros / M2 for films ) They are used to cure with BMI prepregs.
Let us mention here the HYSOL EA 9673 film from HENKEL Aerospace that may
withstand a service temperature up to 290°C, and REDUX HP 655 from
HEXCEL, maximum service temperature 230°C. Figure 6 describes the
chemistry of these resins and adhesives.
Cyanate esters:
These are based on cyanate ester resin, supplied by LONZA for instance, refer
to figure 7 showing their chemical base formulation. Cyanate ester resins and
adhesives requires high curing temperature up to 300°C. Service temperatures
may reach up to 400°C. Of course these products are still quite expensive, and
they are used only for special aircrafts and aerospace parts.
Figure 7: Chemical formulation of Cyanate esters
Syntactic compounds are resins filled with low density, high strength, glass
microspheres.
Syncore from HENKEL Aerospace is supplied as a controlled thickness film, it is
used with reinforced thermoset or thermoplastic prepreg face sheets, ( figure 9 );
after assembly the sandwich laminate is vacuum bagged and cured by using the
recommended cure cycle of the prepreg itself.
Syntactics are used for thin but strong sandwich construction in aircraft
construction, for inserts reinforcements and protection, they seal the sides of the
parts against moisture, they provide high stiffness to weight panels with
decreased deflection compared to a solid laminate design, close the honeycomb
edges and tapers, absorb acoustic vibrations.
Pot
Mix Room Compressive
Product Specific life Accelerated Max service
ratio by temperature strength Features
Reference Gravity at heat cure temperature
weight cure MPa
23°C
• long work
life at room
EPOCAST 30
0.5 - - 120°C 1 hr 90°C 17 at 23°C temperature
1610 days
• ultra low
density
• 8 hour
work life
• good
strength up
120°C 90 117 at 23°C
EPOCAST to 180°C
0.75 - 8 hrs - mins 180°C 76 at 120°C
1614ATF • low
175°C 1 hr 62 at 175°C
COLD density
STORAGE 1 • extrudable
COMPONENT • self-
extinguishing
• very high
compressive
strength
• excellent
120°C 90 150 at 23°C
EPOCAST 24 temperature
1.2 - - mins 200°C 90 at 175°C
927 hrs performance
175°C 1 hr 69 at 200°C
up to 200°C
• extrudable
• self-
extinguishing
• soft paste,
non-sag
after
application
EPOCAST
• pale
ROOM 87005A/B- 0.5 100.50 2 hrs 2 days 50°C 5 hr 90°C 17 at 23°C
cream color
TEMPERATURE 80 suitable for
STORAGE 2 interior
COMPONENTS • ultra low
density
• ultra low
density
EPOCAST •
50 50°C 5 hrs
0.5 100.30 2 days 100°C 17 at 23°C extrudable,
1637A/B-1 mins 65°C 2 hrs
non-flow
after
application
• low out-
gassing
• self-
ARALDITE 60
0.65 100.40 3 days 70°C 2 hr 80°C 35 at 23°C extinguishing
252A/B mins
• good
surface
finish
• soft paste,
easy to
handle
60-
EPOCAST • high
0.7 100.20 90 7 days 50°C 5 hr 90°C 38 at 23°C
1617A/B strength,
mins
room
temperature
cure
• easy to
apply from
1:1 mix
cartridges
• good
EPOCAST 15
0.7 100.100 5 days 50°C 5 hr 70°C 31 at 23°C compression
1631A/B mins
strent
• self-
extinguishing
• cream
color
Table 4: Syntactics from HUNTSMAN
We have now finished the study of the different types of Adhesives for
Composites, and in the next sections we will study the numerous applications in
Aerospace, Aircrafts, Automotive and Transportation equipment, buses and
railway equipment, sports goods and other industries.