Post-collisional strongly peraluminous granites Paul J. Sylvester ),1 Research School of Earth Sciences, The Australian National Uniersity, Canberra, ACT 0200, Australia Received 28 January 1998; accepted 25 June 1998 Abstract . Strongly peraluminous SP granites have formed as a result of post-collisional processes in various orogens. In high-pressure collisions such as the European Alps and Himalayas, post-collisional exhumation of overthickened crust . )50 km , heated by radiogenic decay of K, U and Th during syn-collisional thickening, produced small- to moderate- . volume, cool -8758C SP granite melts with high Al O rTiO ratios. In high-temperature collisions such as the 2 3 2 . . Hercynides and Lachlan Fold Belt LFB , there was less syn-collisional crustal thickening F50 km . Crustal anatexis was related to post-collisional lithospheric delamination and upwelling of hot asthenosphere, forming large-volume, hot . . G8758C SP granite melts with low Al O rTiO ratios. Both clay-rich, plagioclase-poor -5% pelitic rocks and 2 3 2 . clay-poor, plagioclase-rich )25% psammitic rocks have been partially melted in high-pressure and high-temperature . collisional orogens, with the pelite-derived SP granites tending to have lower CaOrNa O ratios -0.3 than their 2 psammite-derived counterparts. The predominance of pelite-derived SP granites in the Himalayas and psammite-derived SP granites in the LFB suggests that mature continental platforms made up more of the accreted crust in the Himalayan collision than in the LFB. q1998 Elsevier Science B.V. All rights reserved. Keywords: Granites; Plate collision; Suture zones; Orogeny; Anatexis 1. Introduction Subduction of oceanic lithosphere has invariably led to closure of ocean basins, collisions between island-arcs and continental blocks, and the formation of granite magmatism along the resulting sutures
Pitcher, 1983; Pearce et al., 1984; Harris et al.,
. 1986 . This collisional tectonic setting is distinct ) Tel.: q709-737-4736; Fax: q709-737-2589; E-mail: pauls@sparky2.esd.mua.ca 1 Present address: Department of Earth Sciences, Memorial University of Newfoundland, St. Johns, NF, Canada A1B 3X5. from the preceding one of oceanic plate subduction . and commonly involves 1 an early syn-collisional stage of thrusting and folding, resulting in crustal . thickening; and 2 a later post-collisional stage of strikeslip and extensional faulting, reflecting ad- justment of the accreted blocks to waning compres- sional stresses and leading to final stabilization. Collision-related granites exhibit a variety of compositions, commonly divided into calc-alkaline . . Pitcher, 1983 , alkaline Sylvester, 1989 and, the particular concern of this paper, strongly peralumi- nous varieties. Peraluminous granites have ratios of . molecular Al O r CaOqNa OqK O or Ar 2 3 2 2 0024-4937r98r$ - see front matter q 1998 Elsevier Science B.V. All rights reserved. . PII: S0024- 4937 98 00024- 3 ( ) P.J. SylesterrLithos 45 1998 2944 30 . CNK exceeding 1, but strongly peraluminous SP granites possess ArCNK ratios G1.1. This is re- flected in a mineralogy that includes highly- aluminous primary phases such as muscovite,
cordierite, garnet, tourmaline and andalusite Miller,
. 1985 . Many are leucogranites, by definition contain- ing -5% mafic minerals, but others are granites . s.s. , granodiorites and even some tonalites Chap- . pell and White, 1992 . SiO concentrations are gen- 2 erally )67 wt.%, initial 87 Srr 86 Sr )0.706, initial 18
-y2 and d O)q9.5 Le Fort et al., 1987;
Nd . White and Chappell, 1988 . Collision-related SP granites appear to have origi- nated through a diverse set of processes. Some are exposed along thrust sheets or shear zones and are deformed; others crop out as completely post-tectonic . plutons Searle et al., 1997; Finger et al., 1997 . Some may have formed from partial melts of quartz- . ofeldspathic meta-igneous orthogneiss crustal rocks . Miller, 1985 or by reaction between basaltic melts . and crustal rocks Patino Douce, 1995 . However, many others contain metasedimentary enclaves . White and Chappell, 1988 or are associated with . migmatitic paragneiss Le Fort et al., 1987 , suggest- ing an origin wholly or dominantly from partial melts of metasedimentary rocks in the crust. Both mature argillaceous-rich pelitic rocks, principally . meta-shales Searle et al., 1997 , and immature quartzofeldspathic-rich psammitic rocks, principally . meta-greywackes White and Chappell, 1988 , seem to have been involved. Anatexis may have resulted
from decompression of over-thickened crust Le Fort
. et al., 1987 , fluid focusing along crustal shear zones . Strong and Hanmer, 1981 , or advectionrconduc- tion of mantle-derived heat into the lower crust . Wickham and Oxburgh, 1987 . In part because of the diversity of SP granite magmatism, there is considerable uncertainty about its relationship to collisional tectonism. Are most collision-related SP granites the products of syn-col- lisional crustal thickening or are they related to subsequent post-collisional events? Were all colli- sion-related SP granite generated at similar tempera- tures in the crust or were certain collisional orogens characterized by hotter granite magmas than oth- ers? What would hot SP granite magmas indicate about the evolution of the lithosphere in collision zones? Do metasedimentary-derived SP granites have dominantly pelitic sources in certain collision-related orogens and psammitic sources in others? If so, what does this suggest about the nature of the crustal blocks involved in the collisions? This paper addresses these questions and presents a general framework in which collision-related SP granites can be understood. In essence it is argued that there is a spectrum of collisional orogens, which is reflected in the diversity of collision-related SP granites. In high-pressure collisions, the crust was thickened to more than ;50 km by thrust stacking . and shortening. Cool ;8758C or less SP granite melts formed primarily by a two-step process involv- . ing 1 syn-collisional, in situ radiogenic heating; . and 2 post-collisional decompression melting along some of the deep-rooted thrusts. In high-tempera- ture collisions, the crust remained comparatively . . thin F50 km , and hot G8758C SP granite magmatism was primarily the product of a post-colli- sional, mantle-derived heat source. This model is developed by examining both the geologic character- istics and chemical compositions of collision-related SP granites and, in particular, their CaOrNa O and 2 Al O rTiO ratios. 2 3 2 2. Timing of SP granites: syn-collisional or post- collisional? . . Pitcher 1983 , Pearce et al. 1984 and Harris et . al. 1986 suggested that collision-related SP granites formed during the early syn-collisional phase of crustal shortening and stacking, and contrasted them with a later post-collisional phase of potassium-rich calc-alkaline or I-type Caledonian granites, formed during uplift, extension and strikeslip faulting. However, it is now apparent that the large majority of collision-related SP granites are best described as post-collisional, in that they were emplaced after the climax of crustal thickening. This is certainly true of the voluminous and widespread 340300 Ma SP granites of the Hercynian orogeny of Europe: almost all post-date an early collision-related . medium-pressure Barrovian metamorphic event and are instead associated with later high-temperaturer low-pressure regional metamorphism and extensional
and strikeslip fault movements Strong and Han-
. mer, 1981; Wickham, 1987; Finger et al., 1997 . The ( ) P.J. SylesterrLithos 45 1998 2944 31 SP granites are spatially and temporally associated
with calc-alkaline granites Emmermann, 1977; Frasl
. and Finger, 1991; Pamic et al., 1996 that would undoubtedly be classified as post-collisional using the PitcherPearceHarris scheme. Collision-related SP granites in the European Alps also appear to be post-collisional. Following colli- sion-related high-pressure regional metamorphism at 4535 Ma, a trivial amount of SP granite formed between 3325 Ma, along with moderate volumes of
calc-alkaline granite Visona and Zirpoli, 1984; von
. Blanckenburg, 1992; Bellieni et al., 1996 and minor extension-related shoshoniticrultrapotassic magma- . tism Venturelli et al., 1984 . The granites were emplaced along the PeriadriaticInsubric strikeslip fault system during post-folding northsouth trans- gression and eastwest extension, commonly de-
scribed as post-collisional e.g., Altherr et al.,
. 1995 . In the Caledonian orogeny of Britain, the main 440390 Ma phase of plutonism is the type example of the post-collisional calc-alkaline granite suite of . Pitcher 1983 , but this event also involved the em- placement of numerous SP granites, particularly south
of the Iapetus suture Hall, 1972; Harmon et al.,
. 1984; OBrien et al., 1985; Sweetman, 1987 . There are some SP granites that formed before the main phase of plutonism, during or just after the climax of ;480 Ma Barrovian metamorphism of the Grampian Orogeny. However, as this tectonothermal event oc- curred before final closure of the Iapetus Ocean, it is unclear how these granites relate to the Caledonian . collision Harmon et al., 1984 . Even in the High Himalaya, moderate volumes of so-called syn-collisional SP granites were emplaced . between 2414 Ma Scharer et al., 1986 , probably just after the climax of high-pressure metamorphism and at the beginning of a period of rapid uplift and . exhumation Searle et al., 1997 . At just about the . same time ;20 Mapresent , small volumes of shoshoniticrultrapotassic volcanics and SP granites . McKenna and Walker, 1990 began forming to the north on the Tibetan Plateau, during extension-driven collapse that is widely described as post-collisional . e.g., Turner et al., 1996 . Thus, Himalayan SP granites formed very late in the period of collision- related crustal thickening, some 30 million years or . more after the collision began Scharer et al., 1986 , and it is likely their appearance marked the start of post-collisional events in this orogen. 3. High-pressure vs. high-temperature collisional orogens The well-studied Himalayan orogen is often used as a template for collisional orogenesis; however it has been long known that there is significant diver- . sity among collisional belts. Zwart 1967 introduced the concept of a duality of orogens, referring in part to the higher pressure regional metamorphism of the Alps as compared to that in the Hercynides. This concept remains relevant, and helps understand the diversity of post-collisional SP granites. In the Alps and Himalayas, widespread high-pres- sure metamorphism preceded SP granite plutonism . Scharer et al., 1986; von Blanckenburg, 1992 , sug- gesting that syn-collisional crustal thickening was extreme in these orogens. For instance, the presence of pyropecoesite rocks in the Alps suggests subduc- tion of sialic crust to depths of ;130 km during the
Alpine collision, at least locally Gebauer et al.,
. 1997 . Moreover, seismic data indicate that the crust
beneath Tibet is now ;70 km thick Hirn et al.,
. 1984 , twice the thickness of normal continental crust. Post-collisional exhumation of the overthick- ened crust, after an incubation period of in situ
radiogenic decay of heat-producing elements K, U,
. Th at depth, probably led to the production of small to moderate volumes of SP granites in these belts . Le Fort et al., 1987; Searle et al., 1997 . Modelling
of this process of anatexis Zen, 1988; Thompson
. and Connolly, 1995 indicates that the extent of melting would have increased with the length of the incubation period, and decreased with the exhuma- tion rate of the thickened crust. This may explain why SP granites are much rarer in the Alps than in the Himalayas. Although both collisions began at ;50 Ma, exhumation of high-pressure Alpine meta- morphic rocks occurred somewhat earlier than in the
Himalayas ;35 vs. 25 Ma; Scharer et al., 1986;
. von Blanckenburg, 1992 and, at least locally, oper-
ated at remarkably rapid rates 20 kmrMa; Gebauer
. et al., 1997 . Compared to the Alpine and Himalayan colli- sions, crustal thickening during the Hercynian colli- ( ) P.J. SylesterrLithos 45 1998 2944 32 sion was probably modest, as reflected in the early, syn-collisional regional metamorphism being more . generally of a medium-pressure Barrovian type . e.g., Finger et al., 1997 . Estimates of maximum crustal thicknesses produced during collisions in an- cient orogens are necessarily model dependent but . the balanced cross sections of Behrmann et al. 1991 suggest ;50 km for the Hercynides. Moreover, large volumes of Hercynian granites are associated with a widespread post-collisional high-tempera- turerlow pressure metamorphic event that is largely absent in the Alpine and Himalayan collisions. In situ radiogenic heating will not typically produce extensive high-temperaturerlow pressure metamor-
phism and melting in -50-km thick crust Thomp-
. son and Connolly, 1995 . Instead, the high-tempera- ture metamorphism and SP granite genesis probably reflect a large mantle heat source at the base of the
crust caused by asthenospheric upwelling Wickham
. and Oxburgh, 1987; Thompson and Connolly, 1995
following slab break-off Davies and von Blancken-
. burg, 1995 and lithospheric delamination Black and . Liegeois, 1993 . Modelling e.g., Davies and von . Blanckenburg, 1995 indicates that if the astheno- sphere was able to ascend to depths of 50 km or less, in the wake of lithosphere thinned by delamination, mantle melting would have been possible and basaltic magmatism injected into the crust could have led to widespread melting and post-collisional granite gen- esis. Unlike in the Alps and Himalayas, Hercynian SP granites are associated with large volumes of contemporaneous post-collisional calc-alkaline gran- ites, which exhibit evidence for interaction with widespread mantle-derived magmas that may have
been derived from the asthenosphere Rottura et al.,
. 1991; Pamic et al., 1996; Finger et al., 1997 . In the Alps and Himalayas, the main evidence for post-collisional mantle melting is small-volume shoshoniticrultrapotassic rocks, which probably re- flect small-degrees of melting of the mantle litho- . sphere Venturelli et al., 1984; Turner et al., 1996 . Post-collisional calc-alkaline granites are rare or ab- sent in the Himalayas and form only small to moder- . ate volumes in the Alps Bellieni et al., 1996 . Because syn-collisional lithospheric thickening was much more substantial in the Alps and Himalayas, it is likely that post-collisional lithospheric delamina- tion was insufficient to allow upwelling astheno- sphere to rise to melting depths. Asthenospheric mantle heat would have been transferred to the crust and mantle lithosphere by conduction, which has long lag times compared to advective heat transfer . Davies and von Blanckenburg, 1995 . Conductive heating from the mantle may have assisted SP gran- ite genesis in these orogens but in situ crustal radio- genic heating and decompression melting during crustal uplift would have dominated. These observations suggest that a distinction may . be made between 1 high-pressure collisions such . as the Alps and Himalayas Fig. 1A , where small- to moderate-volume cool post-collisional SP gran- ites formed by decompression melting of overthick- . ened crust )50 km heated by the in situ decay of . K, U and Th; and 2 high-temperature collisions . such as the Hercynides Fig. 1B , in which large- volume hot post-collisional SP granites formed by mantle-derived heating of normally thickened crust . F50 km after lithospheric delamination. The Cale- donian orogeny of Britain may represent an interme- diate case, as it lacks both widespread syn-collisional Fig. 1. Schematic representation of the generation of post-colli- . . sional SP granites in A thick, high-pressure orogens, and B thin, high-temperature orogens. Not drawn to scale. Intermediate cases would be likely where crustal thicknesses on opposing sides of the suture differed significantly. ( ) P.J. SylesterrLithos 45 1998 2944 33 high-pressure metamorphism and post-collisional
high-temperature metamorphism Harmon et al.,
. 1984 . Another example of a high-temperature collisional . orogen may be the Lachlan Fold Belt LFB of southeastern Australia. The belt lacks the characteris- tic high-pressure metamorphism and extreme . . Fig. 2. SiO vs. A molecular Al O r CaOqNa OqK O or 2 2 3 2 2 . . ArCNK and B FeO qMgOqTiO wt.% for post-collisional t 2 SP granite intrusions compiled from the literature. Data sources: . European Alps: Bellieni et al. 1996 , Cima di Vila granite dike . . . number of sampless1 ; Harris et al. 1986 , Novate 1 ; Visona . . and Zirpoli 1984 , Moschumandl 4 . Himalayas: Ayres and . . . Harris 1997 , biotite 13 and tourmaline 25 phases of Zanskar; . . Crawford and Windley 1990 , Sumayar 5 ; Dietrich and Gansser . . . . 1981 , Chung La 3 , Gophu La 1 , Monlakarchung-Pasalum 5 ; . . . . Harris et al. 1986 , Gabug 1 ; Inger and Harris 1993 , biotite 4 . . and tourmaline 3 phases of Langtang; Le Fort et al. 1983 , . . . Karakorum 2 ; Le Fort et al. 1987 , Manaslu 201 ; McKenna . . . . and Walker 1990 , BKSP 1 , UBTG 1 and 2MGR 1 of Ulugh . . . Muztagh; Scaillet et al. 1990 , Gangotri 40 ; Searle et al. 1997 , . . biotite 6 and tourmaline 6 phases of Shisha Pangma. European . . . Hercynides: Arniaud et al. 1984 , Auriat 10 ; Bea et al. 1994 , . . . Pedrobernardo 37 ; Emmermann 1977 , Buhlertal 30 , Forbach . . . . 57 , Oberkirch 20 , Raumunzach 22 , St. Blasien 65 , Steebach . . . . 55 ; Frasl and Finger 1991 , Altenberg 1 , Eisgarn 1 , Freistadt . . . . 1 , Plochwald 1 , Scharding 1 ; Gil Ibarguchi et al. 1984 , . . . . Dumbria 1 , La Runa 1 , Muxia 1 ; Harris et al. 1986 , . . . Barousse 1 ; Cornwall 1 ; Holtz and Barbey 1991 , Tourem . . . felsic 3 and heterogeneous 5 granites; Neiva et al. 1987 , . . . Covao do Curral 1 , Lagoa Comprida 1 , Vale do Rossim 3 , . . . Covao do Meio 2 ; Pamic et al. 1996 , Slavonian Mts 38 ; . . . Rottura et al. 1989 , Bejar MCG 8 ; Rottura et al. 1991 , Capo . . . Vaticano 12 ; Rottura et al. 1993 , Capo Rasocolmo 8 ; Villa . . . San Giovanni 4 ; Shaw and Guilbert 1990 , Almendra 1 , . . . Barruecopardo 1 , Carnmenellis 1 , Clisson-Mortangne 1 , . . . . Duero R. 1 , Lands End 1 , Martinamor 1 , St. Austell 1 , St. . . . Sylvestre 2 , Tolaba 1 , Vysoky-Kamen 1 ; Strong and Hanmer . . . . . 1981 , Ploermel 5 , Plomeur 9 , Pontivy 7 , Questembert 16 , . . . Quimper 12 ; Wickham 1987 , Trois Seigneurs leucogranite 8 . . . British Caledonides: Dunham et al. 1965 , Weardale 2 ; Hall . . . 1972 , Foxdale 1 , northern unit, Leinster 1 , Tullow Lowlands . . . unit, Leinster 1 ; OBrien et al. 1985 , Threlkeld 13 , Eskdale . . . 9 , Skiddaw 25 ; Phillips et al. 1981 , Stephens and Halliday . . . 1980 , Criffell inner granite 2 ; Sweetman 1987 , Non- . porphyritic Blackstairs Unit, Leinster 9 ; Tindle and Pearce . . 1981 , Loch Doon cordierite microgranite 1 . Lachlan Fold . . . Belt: Chappell and White 1992 , Bethanga 1 , Cooma 1 , . . . Dalgety 1 , Granya 1 , Jillamatong 1 ; Elburg and Nicholls . . 1995 , Wilsons Promontory biotite adamellite 1 ; Higgins et al. . . . . 1985 , Ansons Bay 1 ; Price 1983 , Koetong 5 ; White and . . . Chappell 1988 , KB142 1 and KB45 1 of Bullenbalong, . . CV130 1 and CV115 1 of Strathbogie. amounts of crustal thickening and uplift seen in the . Alps and Himalayas Coney, 1992 but does have many features suggesting plate convergence and col- lision, including early island-arc rock assemblages
and thin-skinned thrusts Scheibner, 1985; Gray et
. al., 1997 . In addition, large volumes of syn- to . post-tectonic ;430380 Ma calc-alkaline I-type . and SP S-type granites Price, 1983; White and Chappell, 1988; Chappell and White, 1992; Elburg . and Nicholls, 1995 were emplaced over a wide area, including in and along a high-temperaturerlow-pres- . sure metamorphic complex the WaggaOmeo zone , similar to the situation in the Hercynides. The LFB I-type granites are similar in composition to the post-collisional calc-alkaline granites of the British
Caledonides Pitcher, 1983; Chappell and Stephens,
. 1988 , adding further weight to a collisional model for the LFB. ( ) P.J. SylesterrLithos 45 1998 2944 34 4. Chemical compositions of post-collisional SP granites In order to test the idea that some collisions produce hotter SP granites than others, and to exam- ine differences in the sources of SP granites in different orogens, the chemical compositions of 88 felsic intrusions from the Alps, Himalayas, Her- cynides, British Caledonides and LFB have been
compiled from the literature Fig. 2; complete data
. available from the author on request . Where multi-
ple analyses from an individual intrusion or a dis-
. tinct magmatic unit of an intrusion were available, a mean was calculated. Because the large majority of the SP felsic intrusions have SiO concentrations of 2 67 to 77 wt.%, samples falling outside this range were excluded. Only samples with ArCNK ratios G1.1 were considered: most intrusions have ratios . falling between 1.1 and 1.4 Fig. 2A . Concentra- . . tions in wt.% of TiO 0.030.73 , Al O 13.1 2 2 3 . . . 16.5 , FeO 0.234.64 , MgO 0.012.22 , CaO t . . 0.352.92 , Na O 1.384.57 and K O 2.90 2 2 . 6.02 span wide ranges. The high concentrations of
K O suggest that SP trondhjemitic intrusions -2.5
2 . wt.% K O are rare or absent in these orogens. The 2 sum of FeO qMgOqTiO varies inversely with t 2 . SiO Fig. 2B . Many intrusions with )72 wt.% 2 SiO have -2 wt.% FeO qMgOqTiO , consis- 2 t 2 tent with a large proportion of the SP granites being leucogranites. Fig. 3 illustrates that Al O rTiO ratios of post- 2 3 2 collisional SP granites tend to increase as CaOrNa O 2 . ratios decrease Fig. 3A , a trend identified previ- . ously by Sylvester 1994 on the basis of a smaller data base. The array of granite analyses plotted in Al O rTiO CaOrNa O space are encompassed 2 3 2 2 largely by a quadrilateral which can be defined by four end-members whose compositions are given in Table 1. Individual intrusions within the quadrilateral could be related to one another by fractional crystal- lization but this is an unlikely explanation for the overall trend. The net effect of precipitating oligo- Fig. 3. CaOrNa O vs. Al O rTiO ratios for post-collisional SP granite intrusions subdivided by orogen. Most data fall within the field 2 2 3 2 defined by four end-member intrusions: BesBethanga; MosMoschumandl; VysVysoky-Kamen; ShsShisha Pangma. Data sources as . . . . in Fig. 2. Vectors for fractional crystallization of oligoclase An , K-feldspar kspar , biotite biot and ilmenite ilm are shown. 20 ( ) P.J. SylesterrLithos 45 1998 2944 35 Table 1 Compositions of end-member SP granites Pluton Be Mo Vy Sh ( ) Major elements wt.% SiO 67.87 69.88 72.98 74.71 2 TiO 0.73 0.22 0.20 0.03 2 Al O 14.80 16.28 13.60 14.31 2 3 FeO 4.64 2.04 1.28 0.77 t MnO 0.06 0.04 0.04 0.05 MgO 2.01 0.80 0.30 0.10 CaO 1.05 2.92 0.35 0.47 Na O 1.38 3.17 3.24 4.15 2 K O 4.37 3.25 4.74 4.17 2 P O 0.19 0.27 0.22 2 5 Ratios ArCNK 1.66 1.16 1.23 1.17 Al O rTiO 20 75 68 480 2 3 2 CaOrNa O 0.761 0.921 0.11 0.11 2 ( ) Trace elements ppm Rb 186 110 300 456 Sr 126 279 54 10 Ba 610 299 18 Ratios RbrSr 1.48 0.394 5.6 46 RbrBa 0.305 1.00 25 BesBethanga number of sampless1, Chappell and White, . . 1992 ; MosMoschumandl ns4, Visona and Zirpoli, 1984 ; . VysVysoky-Kamen ns1, Shaw and Guilbert, 1990 ; Shs . tourmaline-bearing Shisha Pangma ns6, Searle et al., 1997 . . . clase An , K-feldspar Or , biotite and ilmenite, 20 90 a likely assemblage, from SP granite magmas with . high CaOrNa O ratios )0.3 would be to increase 2 both CaOrNa O and Al O rTiO ratios in the 2 2 3 2
derivative liquids, oblique to the observed trend Fig.
. 3A . Post-collisional SP granites from different oro- gens occupy different parts of the quadrilateral. The
rare Alpine SP granites have high CaOrNa O )
2 . . 0.3 and medium to high Al O rTiO )60 ratios 2 3 2 . Fig. 3B , whereas Caledonian SP granites tend to have low CaOrNa O and medium Al O rTiO ra- 2 2 3 2 . tios Fig. 3C . Hercynian SP granites fall largely all along the low Al O rTiO join of the quadrilateral 2 3 2 . Fig. 3D , whereas Himalayan SP granites tend to plot along the high Al O rTiO join, but only with 2 3 2 . medium to low CaOrNa O ratios Fig. 3E . LFB SP 2 granites mostly occupy the low Al O rTiO , high 2 3 2 . CaOrNa O region of the quadrilateral Fig. 3F . 2 5. Significance of CaOrr rrrNa O and Al O rr rrrTiO 2 2 3 2 relationships 5.1. CaOrNa O as an index of source composition 2 . Chappell and White 1992 argued that the low concentrations of CaO and Na O in SP granites in 2 the LFB are inherited from their sedimentary sources, which lost these elements during the formation of clay from feldspar. They suggested that variations in the abundances of these oxides in LFB SP granites reflect different amounts of clay in their protolith. In fact, CaOrNa O ratios are probably a better mea- 2 sure of the fraction of argillaceous material in the sedimentary sources of SP granites. This is because melts of SP granite composition produced by partial . fusion of pelites meta-shales and psammites . meta-greywackes in laboratory experiments exhibit a wide range of CaO and Na O concentrations, 2 . being a function of temperature extent of melting , pressure and H O activity, as well as protolith com- 2
position Holtz and Johannes, 1991; Patino Douce
and Johnston, 1991; Patino Douce and Beard, 1995; . Skjerlie and Johnston, 1996 . CaOrNa O ratios are 2 affected by each of these variables as well but the dominant control is the plagioclaserclay ratio of the source: SP granite melts produced from plagioclase- poor, clay-rich sources will tend to have lower CaOrNa O ratios than melts derived from sources 2 which are plagioclase-rich and clay-poor. In both pelites and psammites, much of the CaO and Na O is held in plagioclase. In pelites, plagio- 2 clase is commonly a minor phase, having been mostly converted to clay. According to the vapor-absent melting experiments of Patino Douce and Johnston . . 1991 on a plagioclase-poor 4% natural pelite, when plagioclase reacts with muscovite to form alu- minosilicate, and the aluminosilicate reacts with bi- otite to form melt and garnet, Na O dissolves in the 2 melt, and CaO is stabilized in garnet. Thus, once the . plagioclase disappears completely ;8008C , the melt is much richer in Na O than the pelite source 2 but poorer in CaO. As melting proceeds in the absence of plagioclase, concentrations of CaO and Na O become progressively diluted in the melt but 2 CaOrNa O ratios remain very much lower than that 2 of the pelite, until garnet is consumed at very high . temperatures G9758C . Below temperatures at which garnet disappears, there is little variation of ( ) P.J. SylesterrLithos 45 1998 2944 36 CaOrNa O ratios with pressure between 7 and 13 2 kbar. In contrast to pelites, psammites contain large proportions of plagioclase, which is not commonly consumed completely during partial melting. Accord- ing to the vapor-absent melting experiments of Skjer- . . lie and Johnston 1996 on a plagioclase-rich 26% natural psammitic paragneiss, concentrations of both CaO and Na O in initial melts are lower than those 2 in their psammitic sources but increase steadily as plagioclase is progressively consumed with further melting. CaOrNa O ratios in the melts will be thus 2 equal to or, if a refractory Ca-bearing phase such as garnet or amphibole is present, slightly lower than those in the psammitic source rocks, and remain broadly constant with increasing temperature. How- ever, as pressure increases from 10 to 20 kbar, and garnet is increasingly stabilized by reaction of or- thopyroxene and the anorthite component of plagio- clase, CaOrNa O ratios in the melts will decrease. 2 As pressure decreases from 10 to 5 kbar, there is also a decrease in the CaOrNa O ratios of the melts, 2 according to the vapor-absent melting experiments of . Patino Douce and Beard 1995 on a plagioclase-rich . 26% synthetic psammite-like biotite gneiss. This presumably reflects preferential stability of the anor- thite component of plagioclase at low pressures.
As the mean CaOrNa O ratios of shales 0.96,
2 . Shaw, 1956; 1.2, Condie, 1993 and greywackes . 0.86, Pettijohn, 1963; 0.93, Condie, 1993 are broadly comparable, pelite-derived SP granites should have, on average, lower CaOrNa O ratios 2 than psammite-derived SP granites. However, the distinction may be less clear for psammite-derived . SP granites generated at low 5 kbar or very high . 20 kbar pressures. Also, as the mineralogy and mean CaOrNa O ratios of igneous rocks of interme- 2
diaterfelsic composition ;1 for tonalitesrgrano-
. diorites; Condie, 1993 are not much different than psammites, it is not possible to distinguish between . psammitic and meta-igneous orthogneiss sources on the basis of the CaOrNa O ratios of SP granites 2 alone. 5.2. Al O rTiO as a measure of temperature 2 3 2 The relatie temperatures of SP granite melts are reflected in their Al O rTiO ratios. During ana- 2 3 2
texis of both pelites and psammites Patino Douce
and Johnston, 1991; Patino Douce and Beard, 1995; . Skjerlie and Johnston, 1996 , concentrations of Al O in SP granite melts remain nearly constant 2 3 with increasing temperatures of melting due to the stability of aluminous refractory phases such as gar- net, aluminosilicate or plagioclase. In contrast, con- centrations of TiO increase steadily with increasing 2 temperature due to the progressive breakdown of Ti-bearing phases such as biotite and ilmenite. As
the mean Al O rTiO ratios of shales 21, Shaw,
2 3 2 . 1956; 22, Condie, 1993 and greywackes 21, Petti- . john, 1963; 20, Condie, 1993 are almost identical, pelite- and psammite-derived SP granites with low Al O rTiO ratios will have been derived at higher 2 3 2 temperatures than those with high Al O rTiO ra- 2 3 2 tios. There is a secondary dependence of Al O rTiO 2 3 2 ratios on pressure during vapor-absent melting caused by the decrease of H O activity with increasing 2 . pressure Patino Douce and Beard, 1995 . For con- stant melt fractions, refractory mafic phases will be progressively preserved with increasing pressure at the expense of feldspar and quartz. Thus, Al O rTiO ratios in SP granite melts increase with 2 3 2 pressure from 5 to 10 kbar where Ti-bearing biotite and ilmenite are the major refractory phases involved . Patino Douce and Beard, 1995 , and decrease from 10 to 20 kbar where Ti-poor garnet is increasingly . stabilized instead Skjerlie and Johnston, 1996 . 5.3. Comparison of experimental and natural SP granite compositions Fig. 4 compares the CaOrNa O and Al O rTiO 2 2 3 2 ratios of experimental melts of plagioclase-poor nat- . ural pelite Patino Douce and Johnston, 1991 and
plagioclase-rich synthetic Patino Douce and Beard,
. . 1995 and natural Skjerlie and Johnston, 1996 psammitic gneisses, at various temperatures, melt fractions and pressures, to the same ratios in the SP granites. The data illustrate that the pelite-derived . melts have lower CaOrNa O ratios -0.3 than the 2 . psammite-derived melts )0.3 , even when the lat- . ter are produced at low 5 kbar or very high 20 . kbar pressures. Also, for a given source composition and pressure, hotter, large-fraction melts have lower Al O rTiO ratios than do cooler, small-degree 2 3 2 ( ) P.J. SylesterrLithos 45 1998 2944 37 Fig. 4. CaOrNa O vs. Al O rTiO ratios for experimental 2 2 3 2 . . vapor-absent melts of A natural pelite; B synthetic biotite . gneiss; and C natural volcanoclastic paragneiss, compared to field of post-collisional SP granite intrusions data sources as in . Fig. 2 . Temperatures, pressures and percentages of melt produced . in the experiments are indicated. Vectors shown in B schemati- cally illustrate that Al O rTiO ratios decrease with increasing 2 3 2 melt temperature, whereas CaOrNa O ratios decrease with in- 2 creasing clay-rich source rocks. melts. These relationships are illustrated schemati- cally by the vectors shown in Fig. 4B. Comparison of Figs. 3 and 4 suggests that SP granites in the Himalayas and Caledonides formed dominantly from mature, clay-rich source rocks . pelites , whereas those from the Alps and LFB had more immature, quartzofeldspathic-rich sources . psammites or tonalitesrgranodiorites . Moreover, most Himalayan and Alpine SP granite melts seem
to have been cooler -8758C, according to tempera-
. tures of the experimental melts than their Caledo- . nian and, particularly, LFB 87510008C counter- parts. Hercynian SP granites appear to have both mature and immature sources, generated largely at . high temperatures 87510008C . Thus, the Al O rTiO data are consistent with the notion that 2 3 2 the LFB and Hercynides represent higher tempera- ture collisional orogens than do the Himalayas and Alps, as postulated in Fig. 1. 5.4. Effect of added H O 2 The preceding discussion pertains to anatexis of source rocks that contain H O held only in their 2 constituent mineral phases, primarily micas and am- phiboles. Production of SP granite melt can also occur in the presence of a H O-rich fluid phase that 2 has been added to the source rocks. The melting . experiments of Holtz and Johannes 1991 on a natural SP gneiss show how added H O affects the 2 CaOrNa O and Al O rTiO ratios of SP granite 2 2 3 2 . melts Fig. 5A . With increasing amounts of added H O, CaOrNa O ratios increase progressively, as 2 2 the melting point of plagioclase, and particularly the anorthite component, decreases. In contrast, Al O rTiO ratios change little because biotite sta- 2 3 2 bility remains virtually unchanged with the addition of H O. Thus, some pelite-derived SP granite melts 2 generated in the presence of a H O-rich fluid phase 2 could, in principle, have high CaOrNa O ratios 2 . )0.3 . However, because of the negative d PrdT slope of the H O-saturated granite solidus, SP melts 2 containing excess H O are unlikely to have risen far 2 from their sources before solidifying. 5.5. Interlayered source rocks and magma mixing Another factor that may affect CaOrNa O and 2 Al O rTiO ratios of SP granite melts is exchange 2 3 2 ( ) P.J. SylesterrLithos 45 1998 2944 38 . Fig. 5. CaOrNa O vs. Al O rTiO ratios for A experimental 2 2 3 2 melts of SP gneiss in the presence of various amounts of added . . water indicated in wt.% ; B experimental vapor-absent melts of . natural pelite interlayered with tonalite and basalt; and C the mixing curve between the average Phanerozoic basalt of Condie . 1993 and the 8508C, 10 kbar pelite-derived melt of Patino Douce . and Johnston 1991 , compared to field of post-collisional SP . granite intrusions data sources as in Fig. 2 . Temperatures and . . pressures of the experimental melts are shown in A and B . . Percentages of basalt mixing are indicated in C . of elements between sedimentary protoliths and in- terlayered meta-igneous rocks during melting, as- suming crustal temperatures exceed the solidii of both. If the interlayered rocks have CaOrNa O and 2 Al O rTiO ratios similar to those of pelites and 2 3 2 psammites, as would be the case for many intermedi- ate and felsic meta-igneous compositions, changes in these ratios are not likely to be great. Skjerlie et al. . 1993 found that, when interlayered with a tonalite gneiss, laboratory melt derived from the pelite of . Patino Douce and Johnston 1991 had only slightly higher CaOrNa O and Al O rTiO ratios than 2 2 3 2 . when the pelite was melted alone Fig. 5B . If the interlayered material is mafic, however, CaOrNa O ratios of pelite-derived SP granite melts 2 may be increased significantly. McCarthy and Patino . Douce 1997 found that, when interlayered with subliquidus basalt, the pelite of Patino Douce and . Johnston 1991 produced SP granite melts with high . CaOrNa O ratios )0.3 , particularly at the inter- 2 . face with the basalt layer Fig. 5B . The same effect can be produced by mixing of basalt melt with pelite-derived SP granite melt. As shown in Fig. 5C, . SP granites with high CaOrNa O ratios )0.3 can 2 be generated by mixing the pelite-derived SP granite . melt 8508C, 10 kbar of Patino Douce and Johnston . 1991 with up to ;20% of the average Phanero- . zoic basalt of Condie 1993 . Thus, it is possible that
some SP granites with high CaOrNa O ratios )
2 . 0.3 , and thus appearing to have clay-poor sources, were actually produced from pelite-derived melts that interacted with mafic magmas. 5.6. Relationship of CaOrNa O to SiO and FeO 2 2 t qMgOqTiO 2 As noted in Fig. 2B, SP granites exhibit an in- verse relationship between SiO and FeO qMgOq 2 t . TiO . Fig. 6 compares SP granites with high )0.3 2 . and low -0.3 CaOrNa O ratios in terms of SiO 2 2 and FeO qMgOqTiO . Granites with high SiO t 2 2 . )71 wt.% and low FeO qMgOqTiO -4 t 2 . wt.% have both high and low CaOrNa O ratios but 2 . granites with low SiO -71 wt.% and high FeO 2 t . qMgO qTiO )4 wt.% have only high 2 CaOrNa O ratios. These relationships are consistent 2 with the low-CaOrNa O SP granites having pelitic 2 sources and high-CaOrNa O SP granites having 2 ( ) P.J. SylesterrLithos 45 1998 2944 39 . . Fig. 6. SiO vs. FeO qMgOqTiO wt.% for low -0.3 and 2 t 2 . high )0.3 CaOrNa O, post-collisional SP granite intrusions 2 . data sources as in Fig. 2 , compared to experimental vapor-absent . 10 kbar melts of natural pelite Patino Douce and Johnston, 1991 , . synthetic biotite gneiss Patino Douce and Beard, 1995 and . natural volcanoclastic paragneiss Skjerlie and Johnston, 1996 . End-member intrusions labelled as in Fig. 3. Also shown is part of the basaltrpelite-derived melt mixing curve of Fig. 5C. Tempera- tures of the experiments and percentages of basalt mixing are indicated. psammitic sources. Whereas SP granite melts pro- duced from the synthetic biotite gneiss of Patino . Douce and Beard 1995 and natural paragneiss of . Skjerlie and Johnston 1996 exhibit strong decreases in SiO and increases in FeO qMgOqTiO with 2 t 2 progressive melting, the pelite-derived SP granite . melts of Patino Douce and Johnston 1991 do not . Fig. 6 . However, high-CaOrNa O SP granites 2 formed by mixing of basalt and pelite-derived SP melt would also be expected to have low SiO and 2 high FeO qMgOqTiO , again with up to ;20% t 2 . basalt in the mixture Fig. 6 . 6. RbSrBa systematics 6.1. Pelite and psammite melting RbSrBa variations in post-collisional SP gran- ites are consistent with both pelitic and psammitic sources playing a role in their origin. Unlike many trace elements, whose interpretation in granitic sys- tems is complicated by the presence of accessory mineral phases, practically all of the Rb, Sr and Ba in granitic systems is contained in mica and feldspar . e.g., Harris and Inger, 1992 . Fig. 7 plots RbrSr vs. RbrBa ratios for the SP granites. The data form a linear array of increasing . RbrSr with RbrBa Fig. 7A . SP granites with high . CaOrNa O ratios )0.3 tend to have lower RbrSr 2 and RbrBa than do those with low CaOrNa O 2 Fig. 7. RbrSr and RbrBa ratios for post-collisional SP granite . . intrusions subdivided on the basis of A orogen and B low . . -0.3 and high )0.3 CaOrNa O ratio. Data sources as in 2 Fig. 2. End-member intrusions labelled as in Fig. 3, except Moschumandl, for which there are incomplete data. The dashed line divides SP granites derived mostly from clay-poor sources from those formed mostly from clay-rich source rocks. Also plotted are calculated compositions of pelite- and psammite-de- rived SP granite melts, the average compositions of Phanerozoic . basalt, shale and greywacke of Condie 1993 , and a calculated basaltrpelite-derived melt mixing curve with various percentages . of mixing indicated . ( ) P.J. SylesterrLithos 45 1998 2944 40 . ratios, albeit with some overlap Fig. 7B . This distinction probably reflects the higher RbrSr and RbrBa ratios of clay-rich sources as compared to clay-poor ones. For instance, as shown in Fig. 7B, the average shale has higher RbrSr and RbrBa than . does the average greywacke Condie, 1993 . The overlap of low- and high-CaOrNa O SP 2 granites in Fig. 7B is probably the result of differ- ences in the mineralogy of restites formed from pelite and psammite melting. Large amounts of pla- gioclase will be left behind after psammite melting
Patino Douce and Beard, 1995; Skjerlie and John-
. ston, 1996 . Because Sr and Ba are compatible in
plagioclase, whereas Rb is incompatible e.g., Harris
. and Inger, 1992 , psammite-derived melts will tend to have higher RbrSr and RbrBa than their sources. In contrast, pelite melting will leave behind little
residual plagioclase Patino Douce and Johnston,
. 1991 . Thus, pelite-derived SP granite melts do not get the same residual plagioclase boost to their RbrSr and RbrBa ratios seen in their psammite-de- rived counterparts. However, formation of residual K-feldspar, which, like plagioclase, partitions Sr and . Ba in preference to Rb e.g., Harris and Inger, 1992 , would provide some increase in the RbrSr and RbrBa of pelite-derived SP granite melts relative to their sources. Thus, RbrSr and RbrBa of SP granite melts is a function not only of source composition but also the amounts of plagioclase and K-feldspar left behind in the source region. To illustrate these melting relationships, calcu- lated compositions of possible pelite- and psammite-derived SP granite melts are plotted in Fig. 7B. The pelite-derived melt composition is derived . from the calculation of Harris and Inger 1992 , using their preferred mineral-melt distribution coeffi- cients, and assumes breakdown of all biotite and most plagioclase via the reaction, biotiteqaluminosilicateqquartzqplagioclase sK-feldsparqgarnet qmelt. 1 . Their calculation assumes equilibrium batch melting . melt fraction s28% with residual quartzrsil- limanitergarnetrplagioclaserK-feldspar in the pro- portions 24r13r42r6r14. Concentrations of Rb, Sr and Ba in the source are those of the average shale . of Condie 1993 . As quartz, sillimanite and garnet do not partition Rb, Sr and Ba to any significant . degree Harris and Inger, 1992 , the observed in- crease of RbrSr and RbrBa in the calculated melt relative to the shale parent is simply a function of the amount of residual plagioclase and K-feldspar pre- sent. The psammite-derived melt composition was cal- culated here in an analogous manner, with the same distribution coefficients used by Harris and Inger . 1992 . Biotite breakdown is assumed to have oc- curred by, biotiteqquartzqplagioclasesorthopyroxene qorthoclase component of plagioclase qgarnet qmelt 2 . . Vielzeuf and Montel, 1994 producing 50% melt and leaving a residual assemblage of quartzrortho- pyroxenergarnetrplagioclase in the proportions 15r40r10r35. The melt fraction and residual as- semblage are similar to those found in the psammite melting experiments of Patino Douce and Beard . . 1995 and Skjerlie and Johnston 1996 . Concentra- tions of Rb, Sr and Ba in the source are those of the . average greywacke of Condie 1993 . Because quartz, orthopyroxene and garnet do not concentrate Rb, Sr . and Ba significantly Harris and Inger, 1992 , the increase of RbrSr and RbrBa in the calculated melt relative to the greywacke parent is a function of the amount of residual plagioclase. 6.2. Mixing of basalt with pelite-deried SP melt
On the basis of major elements Fig. 5C and Fig.
. 6 , high-CaOrNa O SP granites can be explained as 2 mixtures of basalt and low-CaOrNa O, pelite-de- 2 rived SP melt, with as much as ;20% basalt in- volved. In terms of RbSrBa, progressive addition . of the average Phanerozoic basalt of Condie 1993 to the calculated pelite-derived melt of Fig. 7B will reduce the RbrSr and RbrBa ratios of the mixture to levels typical of most high-CaOrNa O SP gran- 2 ( ) P.J. SylesterrLithos 45 1998 2944 41 ites. This is because the RbrSr and RbrBa ratios of the basalt are much lower than those of the pelite-de- rived melt. However, unrealistically large fractions . of basalt )80% would be needed to produce the . . lowest RbrSr -0.4 and RbrBa -0.2 ratios of high-CaOrNa O SP granites. Moreover, most of the 2 remaining high-CaOrNa O SP granites would re- 2 . quire larger basalt fractions )30% than those cal- . culated on the basis of major elements -20% . This presents a problem for the magma mixing model. 7. Discussion and conclusions In collisional orogens, syn-collisional crustal thickening has been followed by delamination of
substantial amounts of mantle lithosphere Black and
. Liegeois, 1993; Davies and von Blanckenburg, 1995 and the formation of post-collisional SP granites. In high-pressure collisions, such as the Alps and Hi- . malayas, crustal thickening was extreme )50 km . Post-collisional exhumation of the overthickened crust, previously heated by radiogenic decay of K, U and Th during syn-collisional thickening, produced . small- to moderate-volume cool -8758C SP gran- ite melts with high Al O rTiO ratios. Because 2 3 2 syn-collisional crustal thickening was extensive, post-collisional upwelling of asthenosphere beneath the delaminated lithosphere boundary was largely unable to reach depths sufficiently shallow for melt- ing. Mantle heat was transferred to the crust and remaining mantle lithosphere mainly by conduction, producing minor ultrapotassic volcanics and, in the Alps, calc-alkaline granites. In comparison, crustal . thickening was modest F50 km in high-tempera- ture collisions such as the Hercynides and LFB. Upwelling asthenosphere was able to rise to shallow mantle depths and produce basaltic magmas that carried heat to the crust, inducing anatexis. Volumi- nous SP and calc-alkaline granites resulted. The SP . granites formed from hot G8758C SP melts with low Al O rTiO ratios. 2 3 2 Chemical compositions of post-collisional SP granites suggest that both clay-rich, plagioclase-poor . -5% pelitic rocks and clay-poor, plagioclase-rich . )25% psammitic rocks have been partially melted in high-pressure and high-temperature collisional orogens. In particular, pelite-derived SP granite melts . tend to have lower CaOrNa O ratios -0.3 than 2 psammite-derived SP granite melts. SP granites with . high CaOrNa O ratios )0.3 could, in principle, 2 have been produced through mixing of basaltic melts with pelite-derived melts, rather than simply by ana- texis of psammites. This would be especially likely in high-temperature collisional orogens where as- thenospheric-derived basaltic melts have invaded the . crust Patino Douce, 1995 . In practice, however, there are difficulties in reconciling the amounts of basalt involved, as recorded by major elements on one hand and RbSrBa on the other. It is also possible that SP granites with high CaOrNa O ratios were derived from orthogneiss 2 . sources rather than psammites Miller, 1985 . The mineralogy of many orthogneisses are similar to those of psammites and, assuming the orthogneisses
possessed the proper isotopic characteristics initial
87 Srr 86 Sr )0.706, initial -y2 and d 18 O) Nd . q9.5 , it would not be possible to distinguish orthogneiss-derived SP granites from their psam- mite-derived counterparts on chemical grounds. However, the widespread association of SP granites with metasedimentary enclaves and migmatitic paragneiss country rocks suggests that psammitic sources have dominated. Psammitic rocks, particu- larly meta-greywackes, are widespread at convergent plate margins and are thus likely to have been avail- able for anatexis in many crustal blocks accreted in . collisional zones Vielzeuf and Montel, 1994 . The predominance of pelite or psammite sources of SP granites in a particular collision belt may reflect the maturity of the accreted crustal blocks, with pelite sources indicating mature deeply-eroded continental platforms and psammite sources pointing . to immature plate margin island- and continental-arc successions. The situation in the Alps is ambiguous because there are so few SP granites present but in the Himalayas and Caledonides, where dominantly pelite-derived SP granites are found, collision and anatexis of mature platforms is suggested. In the LFB, the dominantly psammite-derived SP granites probably reflect accretion and anatexis of immature arcs. In the Hercynides, the presence of both pelite- and psammite-derived SP granites suggests collision of both mature and immature crustal blocks. ( ) P.J. SylesterrLithos 45 1998 2944 42 Acknowledgements D. Demaiffe and A. Patino Douce are thanked for helpful reviews. References Altherr, R., Lugovic, B., Meyer, H.-P., Majer, V., 1995. Early Miocene post-collisional calc-alkaline magmatism along the easternmost segment of the Periadriatic fault system Slovenia . and Croatia . Mineral. Petrol. 54, 225247. Arniaud, D., Dupuy, C., Dostal, J., 1984. Geochemistry of Auriat . granite Massif Central, France . Chem. Geol. 45, 263277. Ayres, M., Harris, N., 1997. REE fractionation and Nd-isotope disequilibrium during crustal anatexis: constraints from Hi- malayan leucogranites. Chem. Geol. 139, 249269. Bea, F., Pereira, M.D., Corretge, L.G., Fershtater, G.B., 1994. Differentiation of strongly peraluminous, perphosphorus gran- ites: the Pedrobernardo pluton, central Spain. Geochim. Cos- mochim. Acta 58, 26092627. Behrmann, J., Drozdzewski, G., Heinrichs, T., Huch, M., Meyer, W., Oncken, O., 1991. Crustal-scale balanced cross sections through the Variscan fold belt, Germany: the central EGT-seg- ment. Tectonophysics 142, 173202. Bellieni, G., Cavazzini, G., Fioretti, A.M., Peccerillo, A., Zant- . edeschi, P., 1996. The Cima di Vila Zinsnock Intrusion, Eastern Alps: evidence for crustal melting, acid-mafic magma mingling and wall-rock fluid effects. Mineral. Petrol. 56, 125146. Black, R., Liegeois, J.-P., 1993. Cratons, mobile belts, alkaline rocks and the continental lithospheric mantle: the Pan-African testimony. J. Geol. Soc. Lond. 150, 8998. Chappell, B.W., Stephens, W.E., 1988. Origin of infracrustal . I-type granite magmas. Trans. R. Soc. Edin. Earth Sci. 79, 7186. Chappell, B.W., White, A.J.R., 1992. I- and S-type granites in the Lachlan fold belt. Trans. R. Soc. Edin. Earth Sci. 83, 126. Condie, K.C., 1993. Chemical composition and evolution of the upper continental crust: contrasting results from surface sam- ples and shales. Chem. Geol. 104, 137. Coney, P.J., 1992. The Lachlan belt of eastern Australia and Circum-Pacific tectonic evolution. Tectonophysics 214, 125. Crawford, M.B., Windley, B.F., 1990. Leucogranites of the Hi- malayarKarakoram: implications for magmatic evolution within collisional belts and the study of collision-related leucogranite petrogenesis. J. Volcan. Geotherm. Res. 44, 119. Davies, J.H., von Blanckenburg, F., 1995. Slab breakoff: a model of lithosphere detachment and its test in the magmatism and deformation of collisional orogens. Earth Planet. Sci. Lett. 129, 85102. Dietrich, V., Gansser, A., 1981. The leucogranites of the Bhutan . Himalaya crustal anatexis versus mantle melting . Schweiz. Mineral. Petrogr. Mitt. 61, 177202. Dunham, K.C., Dunham, A.C., Hodge, B.L., Johnson, G.A.L., 1965. Granite beneath Visean sediments with mineralization at Rookhope, northern Pennines. Q. J. Geol. Soc. Lond. 121, 383417. Elburg, M.A., Nicholls, I.A., 1995. Origin of microgranitoid enclaves in the S-type Wilsons Promontory Batholith, Victo- ria: evidence for magma mingling. Aust. J. Earth Sci. 42, 423435. Emmermann, R., 1977. A petrogenetic model for the origin and evolution of the Hercynian granite series of the Schwarzwald. N. Jb. Miner. Abh. 128, 219253. Finger, F., Roberts, M.P., Haunschmid, B., Schermaier, A., Steyrer, H.P., 1997. Variscan granitoids of central Europe: their typology, potential sources and tectonothermal relations. Mineral. Petrol. 61, 6796. Frasl, G., Finger, F., 1991. Geologisch-petrographische exkursion in den osterreichischen teil des sudbohmischen batholiths. Eur. J. Mineral. 3, 2340. Gebauer, D., Schertl, H.-P., Brix, M., Schreyer, W., 1997. 35 Ma old ultrahigh-pressure metamorphism and evidence for very rapid exhumation in the Dora Maira Massif. West. Alps. Lithos 41, 524. Gil Ibarguchi, J.I., Bowden, P., Whitley, J.E., 1984. Rare earth element distribution in some Hercynian granitoids from the Finisterre region. N.W. Spain J. Geol. 92, 397416. Gray, D.R., Foster, D.A., Bucher, M., 1997. Recognition and definition of orogenic events in the Lachlan fold belt. Aust. J. Earth Sci. 44, 489501. Hall, A., 1972. New data on the composition of Caledonian granites. Mineral. Mag. 38, 847862. Harmon, R.S., Halliday, A.N., Clayburn, J.A.P., Stephens, W.E., 1984. Chemical and isotopic systematics of the Caledonian intrusions of Scotland and Northern England: a guide to magma source region and magmacrust interaction. Philos. Trans. R. Soc. London A310, 709742. Harris, N.B.W., Inger, S., 1992. Trace element modelling of pelite-derived granites. Contrib. Mineral. Petrol. 110, 4656. Harris, N.B.W., Pearce, J.A., Tindle, A.G., 1986. Geochemical characteristics of collision-zone magmatism. In: Coward, M.P., . Ries, A.C Eds. , Collision Tectonics, Vol. 19. Geol. Soc. Spec. Publ., pp. 6781. Higgins, N.C., Solomon, M., Varne, R., 1985. The genesis of the Blue Tier Batholith, northeastern Tasmania, Australia. Lithos 18, 129149. Hirn, A., Lepine, J.-C., Jobert, G., Sapin, M., Wittlinger, G., Xin, X.Z., Yuan, G.E., Jing, W.X., Wen, T.J., Bai, X.S., Pandey, M.R., Tater, J.M., 1984. Crustal structure and variability of the Himalayan border of Tibet. Nature 307, 2325. Holtz, F., Barbey, P., 1991. Genesis of peraluminous granites: II. Mineralogy and chemistry of the Tourem Complex North . Portugal . Sequential melting vs. restite unmixing. J. Petrol. 32, 959978. Holtz, F., Johannes, W., 1991. Genesis of peraluminous granites: I. Experimental investigation of melt compositions at 3 and 5 kb and various H O activities. J. Petrol. 32, 935958. 2 Inger, S., Harris, N., 1993. Geochemical constraints on leucogran- ite magmatism in the Langtang Valley, Nepal Himalaya. J. Petrol. 34, 345368. Le Fort, P., Michard, A., Sonet, J., Zimmerman, J.-L., 1983. ( ) P.J. SylesterrLithos 45 1998 2944 43 Petrography, geochemistry and geochronology of some sam- . ples from the Karakorum axial batholith Northern Pakistan . . In: Shams, F.A. Ed. , Granites of the Himalayas, Karakorum and Hindukush. Inst. of Geology, Punjab Univ., Lahore, pp. 377387. Le Fort, P., Cuney, M., Deniel, C., France-Lanord, C., Sheppard, S.M.F., Upreti, B.N., Vidal, P., 1987. Crustal generation of the Himalayan leucogranites. Tectonophysics 134, 3957. McCarthy, T.C., Patino Douce, A.E., 1997. Experimental evi- dence for high-temperature felsic melts formed during basaltic intrusion of the deep crust. Geology 25, 463466. McKenna, L.W., Walker, J.D., 1990. Geochemistry of crustally derived leucocratic igneous rocks from the Ulugh Muztagh area, northern Tibet and their implications for the formation of the Tibetan Plateau. J. Geophys. Res. 95, 2148321502. Miller, C.F., 1985. Are strongly peraluminous magmas derived from pelitic sedimentary sources?. J. Geol. 93, 673689. Neiva, A.M., Neiva, J.M.C., Parry, S.J., 1987. Geochemistry of the granitic rocks and their minerals from the Serra da Estrela, Central Portugal. Geochim. Cosmochim. Acta 51, 439454. OBrien, C., Plant, J.A., Simpson, P.R., Tarney, J., 1985. The geochemistry, metasomatism and petrogenesis of the granites of the English Lake District. J. Geol. Soc. Lond. 142, 1139 1157. Pamic, J., Lanphere, M., Belak, M., 1996. Hercynian I-type and S-type granitoids from the Slavonian mountains southern . Pannonian Basin, northern Croatia . N. Jb. Mineral. Abh. 171, 155186. Patino Douce, A.E., 1995. Experimental generation of hybrid silicic melts by reaction of high Al basalt with metamorphic rocks. J. Geophys. Res. 100, 623639. Patino Douce, A.E., Johnston, A.D., 1991. Phase equilibria and melt productivity in the pelitic system: implications for the origin of peraluminous granitoids and aluminous granulites. Contrib. Mineral. Petrol. 107, 202218. Patino Douce, A.E., Beard, J.S., 1995. Dehydration-melting of biotite gneiss and quartz amphibolite from 3 to 15 kbar. J. Petrol. 36, 707738. Pearce, J.A., Harris, N.B.W., Tindle, A.G., 1984. Trace element discrimination diagrams for the tectonic interpretation of granitic rocks. J. Petrol. 25, 956983. Pettijohn, F.J., 1963. Chemical composition of sandstones-exclud- ing carbonate and volcanic sands. U.S. Geol. Surv. Prof. Pap., 440-S, 21 pp. Phillips, W.J., Fuge, R., Phillips, N., 1981. Convection and crys- tallization in the CriffellDalbeattie pluton. J. Geol. Soc. Lond. 138, 351366. Pitcher, W.S., 1983. Granite type and tectonic environment. In: . Hsu, K. Ed. , Mountain Building Processes, Vol. 1940, Academic Press, London. Price, R.C., 1983. Geochemistry of a peraluminous granitoid suite from north-eastern Victoria, south-eastern Australia. Geochim. Cosmochim. Acta 47, 3142. Rottura, A., Bargossi, G.M., Caironi, V., Damico, C., Maccar- rone, E., 1989. Petrology and geochemistry of late-Hercynian granites from the Western Central System of the Iberian Massif. Eur. J. Mineral. 1, 667683. Rottura, A., Del Moro, A., Pinarelli, L., Petrini, R., Caggianelli, A., Bargossi, G.M., Piccarreta, G., 1991. Relationships be- tween intermediate and acidic rocks in orogenic granitoid . suites: petrological, geochemical and isotopic Sr, Nd, Pb data . from Capo Vaticano southern Calabria, Italy . Chem. Geol. 92, 153176. Rottura, A., Caggianelli, A., Campana, R., Del Moro, A., 1993. Petrogenesis of Hercynian peraluminous granites from the Calabrian Arc, Italy. Eur. J. Mineral. 5, 737754. Scaillet, B., France-Lanord, C., Le Fort, P., 1990. Badrinath . Gangotri plutons Garhwal, India : petrological and geochemi- cal evidence for fractionation processes in a high Himalayan leucogranite. J. Volcan. Geotherm. Res. 44, 163188. . Scharer, U., Xu, R.H., Allegre, C.J., 1986. U Th Pb systemat- ics and ages of Himalayan leucogranites, south Tibet. Earth Planet. Sci. Lett. 77, 3548. Scheibner, E., 1985. Suspect terranes in the Tasman fold belt . system, eastern Australia. In: Howell, D.G. Ed. , Tectonos- tratigraphic Terranes of the Circum-Pacific Region, Vol. 493 514. Circum-Pacific Council for Energy and Mineral Re- sources, Houston. Searle, M.P., Parrish, R.R., Hodges, K.V., Hurford, A., Ayres, M.W., Whitehouse, M.J., 1997. Shisha Pangma leucogranite, south Tibetan Himalaya: field relations, geochemistry, age, origin, and emplacement. J. Geol. 105, 295317. Shaw, D.M., 1956. Geochemistry of pelitic rocks. Part III: Major elements and general geochemistry. Bull. Geol. Soc. Am. 67, 919934. Shaw, A.L., Guilbert, M., 1990. Geochemistry and metallogeny of Arizona peraluminous granitoids with reference to Ap- palachian and European occurrences. In: Stein, H.J., Hannah, . J.L. Eds. , Ore-Bearing Granite Systems; Petrogenesis and Mineralization Processes. Geol. Soc. Am. Spec. Pap., 246, pp. 317352. Skjerlie, K.P., Johnston, A.D., 1996. Vapour-absent melting from 10 to 20 kbar of crustal rocks that contain multiple hydrous phases: implications for anatexis in the deep to very deep continental crust and active continental margins. J. Petrol. 37, 661691. Skjerlie, K.P., Patino Douce, A.E., Johnston, A.D., 1993. Fluid absent melting of a layered crustal protolith: implications for the generation of anatectic granites. Contrib. Mineral. Petrol. 114, 365378. Stephens, W.E., Halliday, A.N., 1980. Discontinuities in the composition surface of a zoned pluton, Criffell, Scotland. Bull. Geol. Soc. Am. 91, 165170. Strong, D.F., Hanmer, S.K., 1981. The leucogranites of southern Brittany: origin by faulting, frictional heating, fluid flux and fractional melting. Can. Mineral. 19, 163176. Sweetman, T.M., 1987. The geochemistry of the Blackstairs unit of the Leinster Granite, Ireland. J. Geol. Soc. Lond. 144, 971984. Sylvester, P.J., 1989. Post-collisional alkaline granites. J. Geol. 97, 261280. Sylvester, P.J., 1994. Archean granite plutons. In: Condie, K.C. . Ed. , Archean Crustal Evolution, Vol. 261314. Elsevier, Amsterdam. ( ) P.J. SylesterrLithos 45 1998 2944 44 Thompson, A.B., Connolly, J.A.D., 1995. Melting of the continen- tal crust: some thermal and petrologic constraints on anatexis in continental collision zones and other tectonic settings. J. Geophys. Res. 100, 1556515579. Tindle, A.G., Pearce, J.A., 1981. Petrogenetic modelling of in situ fractional crystallization in the zoned Loch Doon pluton, Scotland. Contrib. Mineral. Petrol. 78, 196207. Turner, S., Arnaud, N., Liu, J., Rogers, N., Hawkesworth, C., Harris, N., Kelley, S., Van Calsteren, P., Deng, W., 1996. Post-collision, shoshonitic volcanism on the Tibetan Plateau: implications for convective thinning of the lithosphere and the source of ocean island basalts. J. Petrol. 37, 4571. Venturelli, G., Thorpe, R.S., Dal Piaz, G.V., Del Moro, A., Potts, P.J., 1984. Petrogenesis of calc-alkaline, shoshonitic and asso- ciated ultrapotassic Oligocene volcanic rocks from the North- western Alps, Italy. Contrib. Mineral. Petrol. 86, 209220. Vielzeuf, D., Montel, J.M., 1994. Partial melting of meta- greywackes: I. Fluid-absent experiments and phase relation- ships. Contrib. Mineral. Petrol. 117, 375393. Visona, D., Zirpoli, G., 1984. The Moschumandl acidic body . Iseltal, Austria . N. Jb. Miner. Mh. 9, 413423. von Blanckenburg, F., 1992. Combined high-precision chronome- try and geochemical tracing using accessory minerals: applied . to the Central-Alpine Bergell intrusion central Europe . Chem. Geol. 100, 1940. . White, A.J.R., Chappell, B.W., 1988. Some supracrustal S-type granites of the Lachlan Fold Belt. Trans. R. Soc. Edin. Earth Sci. 79, 169181. Wickham, S.M., 1987. Crustal anatexis and granite petrogenesis during low-pressure regional metamorphism: the Trois Seigneurs Massif, Pyrenees, France. J. Petrol. 28, 127169. Wickham, S.M., Oxburgh, E.R., 1987. Low-pressure regional metamorphism in the Pyrenees and its implications for the thermal evolution of rifted continental crust. Philos. Trans. R. Soc. London A 321, 219242. Zen, E-an, 1988. Thermal modelling of stepwise anatexis in a thrust-thickened sialic crust. Trans. R. Soc. Edin. Earth Sci. 79, 223235. Zwart, H.J., 1967. The duality of orogenic belts. Geol. Mijnbouw 46, 283309.