MATERIAL SAFETY DATA SHEET

PCC Airfoils, LLC

J860 un|on /ve., $.E.
V|nerva, Dn|o 44657

Emergency Telephone Number:
(330) 868-7150

Other Information:
(330) 868-7379

008l1 ll0f 0$1l86$ 008l1 ll0f 0$1l86$ 008l1 ll0f 0$1l86$ 008l1 ll0f 0$1l86$
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PRODUCT INFORMATION:

CHEMICAL NAME:
CHEMICAL FAMILY: COBALT ALLOY CASTINGS

COBALT

C50TF21 MAR M-302 WS-18
ECY-768 MAR M-509 X-40
EMS 55451 PWA 647 X-45
FSX 414 PWA 657
L 605 WI-52
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SUPPLIER 313 NOTIFICATION:

These products contain one or more of the following toxic chemicals which
are subject to the reporting requirements of Section 313 of the Emergency
Planning and Community Right-To-Know Act of 1986 (40 CFR 372):
(Except as noted, the chemicals listed below are present at a concentration not
exceeding the upper bound value)

NOMINAL PERCENT COMPOSITION

ALLOY TYPE Al Cr Co

Cobalt* <0.25 19-27 Bal

Cu Mn Mo Ni Fe

0 0-2 0 0-12 <3

Elemental percentages vary for each casting. Some elements may not be
present in all castings.

[*] Notes: 1. Cobalt alloys contain <0.3% Ti.
2. MAR M-302, PWA 657 contain <1.5% Ni.
3. Cobalt alloys contain 0-10% Ta.

HAZARDOUS COMPONENTS:



OSHA PEL (mg/m3) ACGIH TLV
Component CAS # TWA STEL Ceiling TWA STEL

Aluminum (as Al) 7429-90-5 15 - - 10 -
Respirable 5 - - 5 -
Chromium metal 7440-47-3 1 - - 0.5 -
Cr (II) & (III) 0.5 - - 0.5 -
Cr (VI) - - - 0.05 -
Cobalt metal 7440-48-4 0.1 - - 0.1 -
(dust and fume)
Copper (fume) 7440-50-8 0.1 - - 0.1 -
(dust, mist) 1 - - 1 -
Hafnium 7440-58-6 0.5 - - 0.5 -
Iron oxide 1309-37-1 10 - - 5 -
(dust, fume)
Manganese cmpds. 7439-96-5 - - 5 - -
Manganese fume - - 5 1 3
Molybdenum (sol.) 7439-98-7 5 - - 5 -
Total insoluble 15 - - 15 -
Nickel (metal,insol) 7440-02-0 1 - - 1 -
Tantalum (metal) 7440-25-7 5 - - 5 -
Titanium dioxide 13463-67-7
Total dust 15 - - 10 -
Respirable 5 - - 5 -
Tungsten 7440-33-7
Insol. cmpds. - - - 5 10
Soluble cmpds. - - - 1 3
Yttrium 7440-65-5 1 - - 1 -

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PHYSICAL DATA:

BOILING POINT: 3100 C (for cobalt, alloys lower)
MELTING POINT: 1493 C (for cobalt, alloys lower)
SPECIFIC GRAVITY: 7.7 to 9.2
SOLUBILITY IN WATER: Insoluble
VAPOR PRESSURE: Not applicable
APPEARANCE: Dependent on metal, type of finish and any
coatings
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FIRE AND EXPLOSION DATA:

FLASH POINT: Not applicable for solid form
FLAMMABILITY LIMITS: Not applicable for solid form
AUTOIGNITION TEMPERATURE: 930 C (solid iron in oxygen)

Solid, massive form of material is not combustible

FIRE EXTINGUISHING METHODS: Use special mixtures of dry
chemical, or sand. Do not use water. Fire fighters should wear self-contained
breathing apparatus and protective clothing.

UNUSUAL FIRE AND EXPLOSION HAZARDS: Fire and explosion
hazards are moderate when material is in the form of dust and exposed to heat
or flames, or by chemical reaction.
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REACTIVITY DATA:

Massive material is stable at ordinary temperatures. Finely divided dusts
present fire and explosion hazards. Material may be incompatible with acids,
bases, and oxidizers. Molten metal reacts violently with water. Store away
from oxidizers, can react violently.






HEALTH HAZARD INFORMATION:

GENERAL: Products do not present an inhalation, ingestion or skin
contact health hazard under normal handling and use. However, processes
such as welding, grinding, burning, melting, or otherwise generating dust,
fumes and gases may present a health hazard. The airborne exposure levels
provided in the Hazardous Components section of this MSDS are relevant to
processes generating fumes and dusts, and not to the solid casting. The
following toxicity information is applicable only to the processing of the
product.

ACUTE: High concentration inhalation of metallic fumes and dusts may be
irritating to the eyes, nose, and throat. Excessive inhalation of metal fumes
from metal oxides, including, copper, zinc, and manganese can produce an
acute reaction known as metal fume fever. Symptoms consist of chills and
fever similar to flu symptoms, a metallic taste, and dryness and irritation of
the throat. Symptoms may appear several hours after initial exposures.

CHRONIC: Extended exposure to excessive concentrations of metal
fumes and dusts can be associated with permanent changes in the lung
function and pulmonary diseases. Sensitization reactions can occur to some
elements and compounds. Systemic health effect potentials are noted with the
specific elements.

CARCINOGEN STATUS: This product, as a mixture of alloying
elements, has not been determined to be carcinogenic. However, some forms
of chromium, nickel, and iron have been associated with human
carcinogenicity as described in the table below:

Component OSHA NTP IARC ACGIH TARGET ORGAN

Chromium metal
And insol Cr (VI) No No No A1 Lung
Cobalt, alloy No 1 2B No Lung
Nickel, alloys No 2 2B No Lung, nasal

Yes - Listed as human carcinogen, No - not listed as human carcin-
IARC Classification: 1 - Positive; 2 - Probable; 3 - Not classified, 4 -
Probably negative NTP Classification: 1-Human carcinogen, 2-Reasonably
anticipated human carcinogen ACGIH Class.: A1- Confirmed human
carcinogen

ALUMINUM: Aluminum dust and fumes are a low health risk by inhalation.
Aluminum smelter workers have developed pulmonary fibrosis. Asthma
symptoms have been reported by welders exposed to aluminum fume.
Inhalation of powered aluminum by laboratory animals caused bronco-
pneumonia, emphysema, and fibrosis.

CHROMIUM: Chromium hazards are dependent on the oxidation state. The
more toxic hexavalent Cr(VI) form is produced during metal vaporization.
Repeated overexposure to hexavalent chromium compounds may cause
respiratory irritation, nosebleeds, ulceration and perforation of the nasal
septum. Cr(VI) exposure to chromate pigment makers, chrome platers,
welders, and chrome alloy foundry workers has been related to an increased
incidence of lung cancer. The American Conference of Governmental
Industrial Hygienists Documentation of the Threshold Limit Values finds
that chromium metal and trivalent compounds are not carcinogenic to humans.

COPPER: Excessive exposure to fumes can cause metal fume fever. Copper
compounds may cause skin and hair discoloration, but are not necessarily
associated with adverse health effects. Chronic inhalation of copper dust in
animal studies has caused hemolysis of red blood cells, deposition of
hemofusion in the liver and pancreas, and injury to the lung cells.

COBALT: Used primarily in the manufacturing of tungsten and titanium
carbide powders. Dust and fume exposures may cause fibrotic lung disease,
reduced lung function, and an obstructive airway syndrome which may be
allergic in nature. Symptoms are wheezing, cough, and shortness of breath.
Allergic dermatitis from skin contact may appear at the ankles, elbow flexure,
and sides of the neck. Workers exposed to cobalt powder report decreased
sense of smell, shortness of breath, gastrointestinal distress, and weight loss.

HAFNIUM: Animal studies indicate that hafnium and its compounds cause
liver damage by chronic oral and intraperitneal routes of administration.

IRON OXIDE: Long-term overexposure to iron oxide fume may result in the
development of benign pneumoconiosis (siderosis) which is observable in a
chest x-ray. No physical impairment of lung function has been associated
with siderosis. Ferric (iron) oxide may enhance the risk of lung cancer
development in workers exposed to other pulmonary carcinogens, however,
iron oxide alone has not been found to be similarly toxic.

MANGANESE: Chronic exposures may adversely affect the central nervous
system. Symptoms of excessive exposure include languor, sleepiness,
weakness, emotional disturbances, difficulty in walking, mask-like facial
expression and paralysis. Workers exposed to manganese fumes have
increased risk of pneumonia. Animal studies indicate respiratory exposure
may increase susceptibility to bacterial and viral infections.

MOLYBDENUM: Burning and welding operations may generate both
insoluble molybdenum compounds (metal and molybdenum dioxide) and
soluble molybdenum compounds (molybdenum trioxide). Insoluble
compounds generally exhibit a low order of toxicity. The soluble trioxide
forms are more toxic. Reports indicate dusts cause eye, skin, nose, and throat
irritation in animals.

NICKEL: Skin exposure to metal dust and compounds can cause contact and
sensitization dermatitis. Respiratory exposure to dusts and fumes may cause
irritation, asthma, pulmonary fibrosis, and edema. Nickel smelter and refinery
workers exposed to complex compounds of nickel have been found to have
increased rates of nasal and lung cancers. Other nickel exposed trades have
not been found to be at similar risk. Specific soluble nickel compounds have
caused lung cancer in animal experiments.

TANTALUM: The dust and fume has a low order of toxicity. Systemic
effects in humans have not been reported from workplace exposures. Animal
exposures to heavy dust concentrations cause reversible lesions in lung tissue,
as well as, bronchitis, interstitial pneumonitis, and hyperemia.

TITANIUM: Titanium dioxide and metal are practically inert. Titanium
dioxide can be a mild respiratory irritant. There is no evidence of a long term
health hazard from inhalation of titanium dioxide in concentrations at the
PEL.

TUNGSTEN: Evidence indicates that tungsten does not cause short-term
effects in humans. As tungsten carbide, chronic exposures produce hard
metal disease which is characterized by cough, shortness of breath, wheezing
and minor changes in x-ray appearance. Asthma-like allergic reactions
sometimes occur, progressing to pulmonary fibrosis.

YTTRIUM: Yttrium and compounds have caused pulmonary irritation in
animals. Yttrium may cause severe eye damage. Those with pre-existing eye
problems may be at increased risk from exposure.


AGGRAVATION OF EXISTING HEALTH CONDITIONS: Exposures
to metal fumes and dusts may aggravate existing disorders of the respiratory
system. Individuals with preexisting skin problems or sensitizations may be
adversely affected.
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EMERGENCY AND FIRST AID PROCEDURES:

INHALATION: For overexposure to metal fumes and gases, remove to fresh
air. If breathing is difficult or has stopped, administer artificial respiration as
necessary. Seek medical attention.

EYE CONTACT: Flush well with running water to remove particulate. Get
medical attention.

SKIN CONTACT: Brush off excess dust. Wash area thoroughly with soap
and water.

INGESTION: Seek medical attention.
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PERSONAL PROTECTION INFORMATION:

Use general and local mechanical exhaust ventilation to keep airborne
concentrations of gases, dust, and fumes below the acceptable workplace
exposure limits. When mechanical controls are not sufficient to reduce
exposure, use MSHA or NIOSH approved respirators. Select filters and
cartridges approved for protection against Dust or Fumes, Dust, Fumes,
Mists, and Radionuclide, or air-supplied systems appropriate to provide the
necessary degree of protection for the exposure. Consult with a health and
safety professional for proper respirator selection. Assign respirators only to
properly trained and qualified persons as required in 29 CFR 1910.134.

Protective clothing should be worn to protect against skin irritation.
Showering is recommended before changing into street clothes. Wear gloves
to prevent skin irritation and dermatitis.

Wear safety glasses or goggles when grinding, cutting or generating dust.
Protect skin and eyes from intense ultraviolet, infrared, and visible light
generated during welding and cutting.
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SPILL AND DISPOSAL PROCEDURES:

Precautions are not necessary for solid castings. If large quantities of dust are
spilled, collect the material in labeled containers and dispose of according to
local, state, and federal guidelines. Residues should be evaluated according to
the Toxic Characteristic Leaching Procedure (40 CFR 261.24). Do not use
compressed air for cleanup. Wear protective clothing and respirators.
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SPECIAL PRECAUTIONS:

Use good housekeeping practices to prevent accumulations of dust and to
keep airborne dust concentrations at a minimum. Avoid breathing dust and
fumes. Store material away from incompatible materials, and keep dust away
from sources of ignition.

Although reasonable care has been taken to provide current and accurate
information herein, PCC Airfoils, Inc. extends no warranties, expressed or
implied, makes no representations regarding the accuracy or completeness of
the information and assumes no liability for any loss, damage, or injury of any
kind which may result from or arise out of the use of or reliance on the
information by any person. Responsibility for the compliance with federal,
state and local law and regulations concerning the use of this product rests
solely upon the purchaser.
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Original date of preparation: January 1993
Revision date: May 2004
Prepared by: David M. Hadzinsky, Division Manager Environmental
Affairs