Professional Documents
Culture Documents
: TIG welding 18
VARIGON
: plasma welding 20
Process gases for laser and laser-hybrid welding 21
Gases for root protection 22
Welding gases for special materials 24
Linde Gas supply solutions: efficient and economic 26
Information and services 27
CORGON
, CRONIGON
, LASGON
, LINDATA
, LINFAST
, LIPROTECT
, LISY
18,
CRONIGON
N2; this is a
TIG process gas that has a metallurgical effect
for duplex-steel applications. Or oxygen-
doped VARIGON
18 CORGON
10He30
Metal active gas Fine-grained structural CORGON
10 CORGON
25He25
steels, pressure-vessel and CORGON
S5 CORGON
S3He25
pipe steels, hot or cold- CORGON
S8
rolled steels, etc. CORGON
5S4
CORGON
13S4
Carbon dioxide
Stainless steels CRONIGON
2 CRONIGON
2He20
Corrosion-resistant, heat- CRONIGON
S1 CRONIGON
2He50
resistant, creep-resistant, CRONIGON
S3
duplex steels, etc.
Nickel-base metals Argon (MIG process) CRONIGON
Ni series
MIG Aluminum, copper, Argon VARIGON
He series
Metal inert gas nickel and their alloys VARIGON
S VARIGON
HeS series
GMA brazing Coated and uncoated sheet Argon VARIGON
He series
Gas metal arc brazing steels, stainless ferritic CRONIGON
S1 VARIGON
HeS series
steels CRONIGON
2
TIG All fusion-weldable metals, Argon VARIGON
He15
Tungsten inert gas all unalloyed and alloyed VARIGON
He30
steels, non-ferrous metals VARIGON
He50
VARIGON
He70
VARIGON
He90
Helium
Aluminum and its alloys Argon VARIGON
He series
VARIGON
S VARIGON
HeS series
Austenitic stainless steels, Argon VARIGON
H2
nickel alloys VARIGON
H6
VARIGON
He15
Duplex and super-duplex Argon VARIGON
N2He20
steels VARIGON
N series
Fully austenitic steels Argon VARIGON
N2H1
VARIGON
N series
PAW All fusion-weldable metals Argon VARIGON
He series
Plasma arc welding VARIGON
H series
Root protection All materials for which Argon Forming gas: 520% H
2
in N
2
oxidation on the root side Nitrogen VARIGON
H series
has to be avoided VARIGON
series
Joining technologies Specialty mixtures
Helium
Arc stud welding Steel CORGON
18 CORGON
10He30
Aluminum Argon VARIGON
He30S
The optimum solution for every application.
The Linde welding gases at a glance.
MAG
MIG
GMA brazing
TIG
PAW
Root protection
Laser
Arc stud welding
6 The Linde welding gases at a glance
Competence Line Performance Line EN 439 Carbon Oxygen Nitrogen Helium Hydrogen Argon
dioxide
Vol.- % Vol.- % Vol.- % Vol.- % Vol.- % Vol.- %
Argon (Ar) I1 100
Helium (He) I2 100
Carbon dioxide (CO
2
) C1 100
CORGON
10 M21 10 balance
CORGON
18 M21 18 balance
CORGON
S5 M22 5 balance
CORGON
S8 M22 8 balance
CORGON
S1 M13 1 balance
CRONIGON
S3 M13 3 balance
CRONIGON
N2 S I1 + 2N
2
2 balance
VARIGON
N3 S I1 + 3N
2
3 balance
VARIGON
N2H1 S R1 + 2N
2
2 1 balance
VARIGON
N2He20 S I3 + 2N
2
2 20 balance
VARIGON
He15 I3 15 balance
VARIGON
He30 I3 30 balance
VARIGON
He50 I3 50 balance
VARIGON
He70 I3 70 balance
VARIGON
He90 I3 90 balance
VARIGON
H2 R1 2 balance
VARIGON
/
CRONIGON
H
gases, in other words, in cases in which it is
important to prevent oxidation of very expen-
sive and sensitive metals. Owing to their supe-
rior thermal conductivity and additional recom-
bination energy, VARIGON
H gases permit
much higher TIG/PAW welding speeds than
argon. Unfortunately, these extremely benefi-
cial properties cannot be used for welding all
metals. For example, H
2
leads to pore formation
in aluminum and to cracks in ferritic steels.
Thus, H
2
s compatibility with a given material
always has to be tested.
Ar and He are the inert gases used in welding.
Since they do not react with any metal, they
can be used with all metals that can be fusion
welded.
Other relevant properties
Relative density: influences the position-
dependent effectiveness of the shielding gas
Heat transfer coefficient: He can transfer heat
to a metal surface much more effectively
than Ar
Purity levels and mixing accuracies
Shielding gases are standardized in EN 439 and
ISO 14175. These standards specify, amongst
other things, the minimum quality requirements
of the components and mixtures. However,
depending on the material, process, method
and quality requirements, higher qualities may
be necessary. In this case, please contact the
specialists at Linde.
30 25 20 15 10 5 0
Argon (Ar)
Helium (He)
Hydrogen (H
2
)
Nitrogen (N
2
)
Carbon dioxide (CO
2
)
Oxygen (O
2
)
15.8
24.6
4.5
9.8
4.3
5.1
13.6
14.5
14.4
13.6
Dissociation and ionization energy of the gas components
Parameters for ignition properties, welding voltage and arc energy
Ionization energy, 1st stage Dissociation energy
2,000 4,000 6,000 8,000 10,000
0.16
0.12
0.08
0.04
0
H
2
He
Ar
O
2
CO
2
Thermal conductivity of the gases
Heat transfer from the arc to the base metal depends on the thermal conductivity of
the different gases. Helium and hydrogen offer particularly high thermal conductivity
values.
T
h
e
r
m
a
l
c
o
n
d
u
c
t
i
v
i
t
y
[
W
/
c
m
K
]
Temperature [C] [eV]
Metallurgy via process gases: control of austenite-
ferrite ratio when TIG welding duplex steels with
VARIGON
N
9 Complex properties for specific uses
Use of scientific research methods to investigate plas-
ma-physical processes in the arc: section of a spectral
analysis of the MIGp welding process of aluminum with
VARIGON
He30S
Proven under toughest conditions.
CORGON
18 or CO
2
is used; lower levels of CO
2
are not recommended since penetration can
become critical.
Competence Line
CORGON
10 CORGON
18
CORGON
S5 CORGON
S8
CORGON
5S4 CORGON
13S4
Carbon dioxide (CO
2
)
Performance Line
CORGON
10He30 CORGON
25He25
CORGON
S3He25
10 CORGON
10 CORGON
18 CORGON
S5 CORGON
10He30
Influence of gas components on penetration and seam surface: as an example, a fillet weld on a T-joint, sheet thickness 10 mm
Fully mechanized MAGprobot weldments with constant travel- and wire feed speed
11 CORGON
2 CRONIGON
S1
CRONIGON
S3
Performance Line
CRONIGON
2He20 CRONIGON
2He50
CRONIGON
2 CRONIGON
S1 CRONIGON
S3 CRONIGON
CRONIGON
2He20 2He50
Degree of oxidation Good Good Limited Very good Very good
Wetting properties Good Good Good Very good Very good
Welding speed Good Limited Good Very good Very good
Interpass weldability Good Good Limited Good Very good
Spatter Good Good Very good Good Good
Arc stability Good Good Very good Good Good
Penetration Good Limited Good Very good Very good
Carbon pickup and loss with different shielding gases
Carbon content of the wire electrode: 0.016 %
CORGON
S8
0.014
CRONIGON
S1
ELC-limit
CRONIGON
2
0.022
CORGON
5S4
0.026
CORGON
18
0.039
CO
2
0.065
For austenitic-ferritic stainless steels, referred
to as duplex steels, the same gases are recom-
mended as for austenites. If duplex steel is
used in a particularly corrosive environment,
argon-oxygen mixtures are not suitable. Due
to their higher oxidation properties, these gas
mixtures would unnecessarily reduce the poten-
tial for corrosion resistance.
CRONIGON
S1 CRONIGON
2 CRONIGON
2He50
Impact of gases on surface oxidation
MAGp fillet welds on stainless steel 1.4301/304, sheet thickness 8 mm, mechanized welding
13 CRONIGON
S
Performance Line
VARIGON
He VARIGON
HeS
Maximum productivity: MIGp and MIG tandem welding of
safety relevant chassis components with VARIGON
He and VARIGON
HeS series
contain helium, which makes the arc hotter,
broader and more stable.
Benefits
Reduced porosity
Improved penetration, prevents lack of fusion
Higher welding speeds
Better gap bridging
Less/no preheating of thick-walled
components
The more uniform heat input and better di-
rectional stability, facilitates the welding of
components of different thermal conductivity,
for example, thick-thin joins or cast nodes
Reduced notch effect and better distribution
of forces thanks to wider, flatter seams
The performance-enhancing effect of helium
components and the arc-stabilizing benefits of
oxygen doping are effectively combined in the
VARIGON
S (left) in comparison
with argon (right)
Enhancing performance does not always just mean faster welding speeds
Examples of potential quality improvements through the use of specialty gases
The somewhat colder joint.
Shielding gases for arc brazing.
Gas metal arc brazing (GMA brazing) is an
alternative method for joining primarily thin
(t < 3.0 mm) sheets that have been coated
for corrosion protection. This method offers
considerable advantages over MAG welding
since an alloy metal with a lower melting
point than the base metal is used as filler
metal.
Lower heat input
Less burn-off of the coating
Corrosion-resistant, copper-based filler metal
Much less spatter formation
Almost no seam corrosion
Reduced distortion
Good gap bridging
The right choice of shielding gas can further
boost these positive properties. In addition to
the shielding gas, other key factors influencing
the quality of the join are the base metal, the
type and thickness of the coating, and the alloy
used for the filler metal.
Both short and pulsed arc GMA brazing are
possible. Pulsed arc brazing can be further
classified as DC pulsed and AC pulsed brazing
since power sources enabling brazing with an
alternating current have now been available
for some time. AC pulsed brazing enables an
accurate distribution of energy between the
workpiece and the wire electrode. This is even
gentler on the coating and results in even
better gap bridging.
The shielding gas has a varying effect on the
final brazing result, depending on the type of
solder used and the base metal or its surface
condition. Argon is the universal shielding gas
for GMA brazing since it can be used with all
solders, for all types of arcs and in all positions.
It offers impressive all-round properties and a
low heat input. The disadvantages of argon are
a somewhat unstable arc and a tendency to-
wards porosity. Although the very small gas
pockets do not have a negative effect on the
strength of the join, they appear when the
seam is being polished. This results in extensive
finishing work, particularly in visible areas.
When brazing coated sheets with SG-CuSi3, the
result can be improved by adding active com-
ponents. CRONIGON
S1 CRONIGON
2
Performance Line
VARIGON
He VARIGON
HeS
GMA brazing of hydraulic components with CuAl8Ni2
and VARIGON
He and VARIGON
He /VARIGON
S1
Improvement in process stability, seam appearance, and wetting
with robotic GMAp brazing of coated sheets with SG-CuSi3 using CRONIGON
S1
17 Shielding gases for arc brazing
Application advice
The addition of hydrogen or helium is especially
beneficial to heat distribution and heat transfer
in the arc, particularly with TIG welding. The
Performance Line offers a broad range of special-
ty gases that, owing to their hydrogen or helium
content, enable a distinct increase in productivity.
The products in the VARIGON
H series are
primarily recommended for TIG welding of
austenitic stainless steels and some nickel-
based alloys. The hydrogen content in the gas
permits more energy to be exchanged in the
arc. This, in turn, results in deeper penetration
and/or greater welding speeds. The hydrogen
content may be as much as 15%, although the
realistic upper limit for manual welding is 6.5%.
As a rule, gases with a higher hydrogen content
are only recommended for mechanized weld-
ing, since it is more difficult to control the heat
and the pool is very fluid. Gases containing
hydrogen must not be used to weld aluminum
alloys or steels sensitive to hydrogen since this
can lead to greatly increased porosity or embrit-
tlement.
Since helium, like argon, is an inert gas, the gas
mixtures in the VARIGON
He30S and
VARIGON
N series were
developed especially for TIG welding duplex
steels or fully austenitic materials. The addition
of nitrogen causes the austenization of the
weld metal, which is particularly beneficial
when TIG welding duplex steel without filler
metal. These gases have also proven valuable
for low-ferrite welding of high-alloy metals in
the chemical industry. It should be noted that,
due to its hydrogen content, VARIGON
N2H1 is
not suitable for duplex steels.
For top quality requirements.
VARIGON
: TIG welding.
Competence Line
Argon VARIGON
N
VARIGON
S
Performance Line
VARIGON
H VARIGON
N2H1
VARIGON
He VARIGON
N2He20
VARIGON
HeS
TIG the arc method for top quality results, also in the
aerospace industry
18 VARIGON
: TIG welding
Competence Line Performance Line Material Comments
Argon All fusion-weldable metals Suitable for universal use, minimum purity requirement
with highly reactive materials 4.8
VARIGON
S VARIGON
He30S Al and Al alloys Improved arc stability and ignition safety with alternating-
current welding
VARIGON
He70
VARIGON
N2 VARIGON
N2He20 Duplex and super duplex steels Control of the austenite-ferrite ratio in the weld metal
VARIGON
N2 VARIGON
N2H1 Fully austenitic steels Suppresses ferrite phase for special requirements
VARIGON
H6, v
s
= 18 cm/min TIG AC, argon TIG AC, VARIGON
S
VARIGON
: TIG welding
Two gas flows are required for PA welding:
inner plasma gas and shielding gas. Argon is
generally used as the plasma gas. In rare cases,
argon with a H2 content of up to 2% is also
used, but it must be compatible with the metal.
The shielding gas is selected according to the
same criteria as for TIG welding. Argon is a very
good all-round gas that can be used with all
materials. The use of VARIGON
S when weld-
ing aluminum stabilizes the arc.
Performance Line shielding gases are gen-
erally used to increase welding performance.
VARIGON
HeS
gases for aluminum.
Depending on the type of method and perfor-
mance range, PA welding can be further classi-
fied into micro-plasma welding (0.150 A,
t = 0.05 2.5 mm), plasma thick-sheet welding
(50350 A, t = 2.510 [12] mm) and plasma
keyhole welding (from 60 A, t > 2 mm).
Plasma arc welding (PA welding) differs from
TIG welding in that the arc is constricted by
means of an additional, water-cooled nozzle.
At the same time the electrode is moved
backwards to the inside of the burner. This
constricted arc has a much greater power
density than a TIG arc.
Metals suitable for plasma welding
Unalloyed/low-alloy steels
High-alloyed steels: CrNi and CrNiMo (good
for keyhole methods due to high viscosity of
the melt)
Ni, nickel-based alloys
Titanium and its alloys
CuNi alloys, Cu
Aluminum and its alloys
Applications of this welding method include
Chemical equipment manufacture
Aerospace industry
Vessel construction
Food industry
Automotive industry
Greater power density thanks to constricted arc.
VARIGON
: plasma welding.
Competence Line
Argon
Performance Line
VARIGON
H VARIGON
He
Plasma-spirally-welded aluminum pipes
(Source: Linde Engineering)
20 VARIGON
: plasma welding
Where precision and speed meet.
Process gases for laser and laser-hybrid welding.
Laser welding (Source: TRUMPF GmbH + Co. KG) At high welding speeds, laser welding offers
targeted heat input and low distortion.
Mostly laser welding is performed without
any additional material. However, in some
cases this may be necessary due to metallur-
gical reasons or to bridge gaps. Steels, light-
weight metals and thermoplastics are suit-
able for laser welding.
Different types of lasers are used for laser
welding: CO
2
lasers or solid-state lasers
(Nd:YAG, diode, fiber or disc lasers). Shielding
gases are essential for high-quality welds,
whatever the laser type. Whereas material
considerations determine the choice of shield-
ing gas when using solid-state lasers, when
using CO
2
lasers, the interaction between the
shielding gas and the laser beam also has to
be taken into account.
Therefore, helium and gas mixtures containing
helium are used when welding with CO
2
lasers.
For example, LASGON
H series.
Competence Line
Argon VARIGON
N
Nitrogen
Performance Line
Forming gas 95/5 70/30
VARIGON
H
Welding with additional forming gas
22 Gases for root protection
To prevent the formation of temper colors,
after welding, purging should continue until the
component has cooled to a temperature of
below approx. 220 C. If the root of the weld is
not accessible after welding for reworking, a
root shielding gas should be used when tacking
the component since temper colors will not be
dissolved by welding over the tack point.
In the case of Ti-stabilized stainless steels, gases
containing N
2
cause a clearly visible yellowing
of the root of the weld as a result of the forma-
tion of titanium nitride. With duplex and super-
duplex steels, using root-shielding gases that
contain nitrogen or pure nitrogen improves
corrosion resistance.
Application advice
The gases for root protection are standardized
in EN439.
Group R (Ar-H
2
mixtures)
Group I (Ar or Ar-He mixtures)
Group F (N
2
or N
2
-H
2
mixtures)
Minimum purging times have to be observed to
prevent the formation of temper colors. The re-
quired purging time depends on the geometry of
the component and on the volumetric flow rate
of the gas. The recommended value for required
backing gas volume for pipelines, for example, is
2.53 times the geometric volume of the compo-
nent, calculated from the supply point to the
welding point. Depending on pipe diameter, a
gas flow rate of 512 l/min is recommended. The
use of a measuring device to measure the resid-
ual oxygen content is recommended.
Root shielding gases for various materials
Shielding gas Material
Argon All fusion-weldable metals
VARIGON
H series Ar-H
2
mixtures Austenitic stainless steels
Forming gas N
2
-H
2
mixtures Austenitic stainless steels (not Ti-stabilized)
Unalloyed steels (not high-strength fine-grained steels!)
VARIGON
N Ar-N
2
mixtures Austenitic stainless steels (not Ti-stabilized)
series N
2
Duplex and super duplex steels
H
e
a
v
i
e
r
t
h
a
n
a
i
r
L
i
g
h
t
e
r
t
h
a
n
a
i
r
1.4
1.3
1.2
1.1
1.0
0.9
0.8
0.7
0.6
N
2
mixtures
Ar mixtures
Air
4 8 12 16 20
%of H
2
by volume
24
Safety information
Root shielding gases with a hydrogen content
of more than 4%can form explosive mixtures
if they come into contact with air or oxygen.
Users must take certain precautionary mea-
sures to prevent the formation of such gas
mixtures. For safety reasons, DVS leaflet 0937
recommends burning-off if the hydrogen con-
tent in the root shielding gas is 10% or higher.
When forming large, closed components,
adequate ventilation must be available before
inspection to prevent the risk of suffocation.
When working in small rooms, oxygen deple-
tion should be taken into account.
TIG seam, root side , no root protection
TIG seam, root side, with root protection
Relative density of root shielding gases
23 Gases for root protection
Practical solutions for extraordinary materials.
Welding gases for special materials.
Nickel metals
In the case of nickel alloys, the choice of a
suitable shielding gas greatly depends on the
type of alloy to be welded. A variety of nickel
alloys are available on the market, which, de-
pending on their area of application, vary great-
ly in terms of their metallurgical properties and
suitability for welding. As a result, there are
also a number of different recommended gases.
Users should contact Linde Gas or the material
manufacturer if there is any doubt as to which
gas to use.
TIG welding
Many nickel alloys can be easily welded using
argon-hydrogen mixtures, e.g. VARIGON
H2.
Other materials, for example, those that are
particularly susceptible to hot cracks, are better
processed with pure argon. However, for metal-
lurgical reasons, some high-temperature nickel-
based alloys require the addition of nitrogen to
the shielding gas, e.g. VARIGON
N2.
Reactive materials: Ti, Ta, Zr
Titanium, tantalum and zirconium are termed
reactive materials since they react readily with
O
2
, N
2
and H
2
. These processes are promoted by
the heat generated during welding. Picking up
even tiny quantities of atmospheric gases can
lead to the total embrittlement of the weld
seam. This embrittlement cannot be reversed
by heat treatment. Under the influence of heat,
oxygen also causes greater surface oxidation,
which severely affects the corrosion resistance
of these materials. The use of appropriate gas
protection during welding is the most important
factor in protecting such valuable materials
from these negative influences.
TIG welding, generally with pure argon as
shielding gas, is the most common welding
process used for such materials. Purity should
be at least 4.8 (99.998 %). Inert He mixtures,
such as VARIGON
N
Performance Line
VARIGON
He VARIGON
HeS
CRONIGON
Ni10 CRONIGON
Ni20
CRONIGON
Ni30
MAGp arc under CRONIGON
Ni30
24 Welding gases for special materials
MAG welding
The gases in the CRONIGON
Ni series were
specially developed for MAG welding of nickel-
based materials. These patented gas mixtures
are all doped with CO
2
. This minute amount of
CO
2
stabilizes the arc perceptibly without imper-
missibly altering the carbon content of the weld
metal.
CRONIGON
Ni20 also
contain hydrogen or helium, which improves
flow properties and seam appearance and at
the same time, maintains the materials corro-
sion resistance.
CRONIGON
He30
or VARIGON
He mixtures
are generally recommended as shielding gas as
they can reduce pore formation.
Only shielding gases with very high helium
content, such as VARIGON
6025HT/
alloy 602CA with CRONIGON
Ni30.
(Source: H. BUTTING GmbH & Co. KG)
25 Shielding gases for special materials
Linde Gas supply solutions:
efficient and economic.
State-of-the-art production facilities, regular
quality checks and a national supply net-
work offer maximum supply reliability.
Caution: new color-coding
In accordance with the new standard EN 1089
part 3, cylinders are color-coded on the shoul-
der. As the standard has a changeover period
until 2006, cylinders with the old color-coding
may be still in circulation until this time. For
further information on the changeover to the
new color-coding system, please contact the
Linde Distribution Center.
Total Gas Management
Would you prefer to sit back and turn over all
your gas business to a safe and reliable part-
ner? When it comes to supplying gas, servicing,
maintenance or safety, our Total Gas Manage-
ment team takes care of it all.
Our supply channels are both diverse and eco-
nomical. Linde offers the right quantity at the
right price for every customer: from small 10-
liter cylinders to 75,000-liter liquid tanks. The
companys dense supply network, its many
production sites and comprehensive product
lines guarantee high product availability, trans-
port safety, short delivery channels for self
serving customers.
In addition, Linde also offers safe, economical
and functional central gas supplies. We plan
and manufacture these to your own individual
requirements.
Steel cylinders
Capacity Filling*
Liter m
3
10 2.12.4
20 4.04.7
50 9.111.8
* Content gaseous, filling quantity of the cylin-
der depends on the type of gas.
Upright tanks
Content
60075,000 l
Cylinder bundle
Content* m
3
106.8141.6
* Content gaseous, filling quantity of the bundle
depends on the type of gas.
26 Linde Gas supply solutions
Information and services.
LISY
tec
LISY
gas mixtures
LINDATA
mixed-gas welding
LINDATA
1
.
2
A
u
S
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b
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