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a b s t r a c t
Article history:
Received 4 June 2013
Received in revised form
25 August 2013
Accepted 28 August 2013
Available online 4 September 2013
In this paper, the boundary and elastohydrodynamic lubricating behaviour of glycerol and its aqueous
solutions are discussed in both rolling and sliding contacts with a view on assessing the use of glycerol as
a green lubricant. To understand the lubricating mechanism, the lm thickness of glycerol and its
aqueous solutions were studied at different velocities. The results show that the viscosity of glycerol can
be controlled for a wide range by adding different amounts of water. The lubricating behaviour of
glycerol in all lubricating regimes can be improved by adding water. The results suggest that glycerol
aqueous solutions have great potential to replace rapeseed oils as environmentally friendly base oils in
several applications.
& 2013 Elsevier Ltd. All rights reserved.
Keywords:
Glycerol
Boundary lubrication
Elastohydrodynamic lubrication
Green lubricants
1. Introduction
It is estimated that every year more than 10 million tons of mineral
oil-based lubricants and hydraulic uids leak into the ground or
waterways, or are disposed of in the environment [1]. This is
problematic from an environmental point of view since mineralbased oils may inhibit the growth of plants, are toxic to aquatic life,
and can contaminate groundwater for up to 100 years [2]. One liter
of oil released into the environment can cover an area the size of a
football pitch and contaminate as much as one million liters of
water [3].
There is growing interest in the use of green lubricants. Vegetable
oils are potential replacements for mineral oils as base oils to solve the
pollution problem [4,5]. However, the low thermal and oxidation
stabilities, narrow viscosity range and poor ow properties at low
temperatures are major problems for vegetable oils when used as
lubricants [6,7]. On the other hand, glycerol aqueous solutions have
good biocompatibility, low cost, and better low temperature properties
than vegetable oils [8]. Glycerol may thus be a better green lubricant
than vegetable oils in some applications.
During the past decades there has been a tremendous increase
in the production of bio-diesel as a substitute for the traditional
mineral oil-based diesel. Conventional production of bio-diesel, of
the fatty acid methyl ester (FAME) type, is a chemical process
n
Corresponding author at: Division of Machine Elements, Lule University of
Technology, SE97187 Lule, Sweden. Tel.: 46 920 492064; fax: 46 920 491399.
E-mail address: yijun.shi@ltu.se (Y. Shi).
0301-679X/$ - see front matter & 2013 Elsevier Ltd. All rights reserved.
http://dx.doi.org/10.1016/j.triboint.2013.08.013
40
2. Experiment
2.1. Material
CCD
Camera
Microscope
Steel ball
Steel ball
Steel disc
Lubricant
Pump
Steel disc
Lubricant
Pump
Fig. 1. Diagram of the ball on disc tribometer (WAM) for: (a) friction test; and (b) lm thickness test.
41
Viscosity (Pa s)
Pure
5wt% water
10wt% water
15wt% water
20wt% water
30wt% water
40wt% water
50wt% water
Rapeseed
oil
0.1
0.01
100
10
0.1
Friction coefficient
0.01
pure
5 wt% water
10 wt% water
15 wt% water
20 wt% water
1E-3
10
15
20
SRR (%)
30 wt% water
40 wt% water
50 wt% water
Rapeseed
oil
25
30
Table 1
The refractive index of pure glycerol, its aqueous solutions and rapeseed oil.
Lubricant
Pure glycerol
5 wt% Water
10 wt% Water
15 wt% Water
20 wt% Water
Refractive index
Lubricant
Refractive index
1.466
30 wt% Water
1.427
1.464
40 wt% Water
1.412
1.457
50 wt% Water
1.400
1.449
Rapeseed oil
1.447
1.443
42
0.26
Pure
5 wt% water
10 wt% water
15 wt% water
20 wt% water
30 wt% water
40 wt% water
50 wt% water
Rapeseed oil
0.24
0.22
Friction coefficient
0.20
0.18
0.16
0.14
0.12
0.10
0.08
0
30
60
90
120
Time (min)
Fig. 4. Typical friction coefcient as a function of test time for glycerol solutions
and rapeseed oil.
14
12
10
8
6
4
2
1.29
1.15
0
Pure
5wt%
water
Sample
Fig. 5. The wear volume loss of the disc lubricated by glycerol solutions and
rapeseed oil.
Table 2
Surface roughness (Ra-nm) of the track after WAM tests.
Lubricant
Native surface
Pure glycerol
5 wt% water
10 w.% water
15 w.% water
Ra (nm)
Lubricant
Ra (nm)
92
20 wt% water
80
90
30 wt% water
75
88
40 wt% water
65
86
50 wt% water
50
88
Rapeseed oil
87
1000
800
time of about 15 min when the water content is below 20 wt% and
also the stable friction coefcient obtained after the running in
period decreased with increasing water content. Martin et al. [13]
came up with a hypothesis that water produced inside of the
contact region was the reason for the low friction coefcient when
the friction surface is lubricated by pure glycerol. According to this
hypothesis, water is benecial for glycerol to decrease its friction
coefcient.
Fluctuation of the friction coefcient is observed when the
water content is higher than 30 wt%. This indicates that a stable
boundary lm cannot be formed when the water content is higher
than 20 wt%. This may be due to the decreasing viscosity of
glycerol aqueous solutions with the increase of water content,
which leads to the decrease of load carrying capacity. Glycerol
aqueous solutions cannot develop effective uid lm between
friction surfaces when the water content is above 20%. This results
in more solid-to solid contact during the test, which increases the
friction coefcient. At the same time, the wear of the friction
surface also becomes severe (Fig. 5). Wear particles generated may
then lead to a high and unstable friction coefcient.
Moreover, the friction coefcient at the steady state of rapeseed
oil is about 3050% higher than that of the glycerol aqueous solutions
when the water content is below 20%. Combined with the elastohydrodynamic lubricating results, it can be concluded that glycerol and
glycerol aqueous solutions with low water content have lower
friction behaviour than traditional environmental friendly lubricants
in all lubricating regimes under the conditions studied.
As shown in Fig. 5, the wear volume loss of the disc increased
with increasing water content for the glycerol aqueous solutions. It
may thus be concluded that water increases wear of material
though a small amount of water decreases the friction coefcient
effectively. This may be attributed to the corrosive behaviour of
water [15] and the decreasing load carrying capacity of glycerol
aqueous solutions with increasing water content.
The wear volume loss for glycerol with 10 wt% water is about
twice as high as that for pure glycerol, while for glycerol with
50 wt% water the wear volume loss is about 12 times higher than
for that lubricated by pure glycerol. The wear volume loss of the
disc lubricated by rapeseed oil is a little higher than that for pure
glycerol, which shows that the anti-wear property of glycerol is
better than that of rapeseed oil. Considering that the viscosity of
pure glycerol is much higher than that of pure rapeseed oil, the
better anti-wear property of pure glycerol should be attributed to
the viscosity effect.
43
100
pure
5%water
10%water
15%water
20%water
30%water
40%water
50%water
Rapeseed oil
10
1
1
10
100
1000
44
Table 3
Calculated pressureviscosity coefcients of glycerol aqueous solutions and rapeseed oil.
Lubricant
Pure glycerol
5 wt% Water
10 wt% Water
15 wt% Water
20 wt% Water
30 wt% Water
Rapeseed oil
( 10 9 Pa 1)
4.9
4.3
4.2
4.2
4.0
4.0
14.1
0 U e
0
Rx E
3
4. Conclusion
2 U FN
R2x U E0
G 2E0
5
0:64
C o 10:61e0:752Rx =Ry
Ue
U1 U2
2
that of rapeseed oil, which may be one of the reasons for the low
friction coefcient of glycerol aqueous solutions. As discussed in
Section 3.2, the friction coefcient for the lubricant in the elastohydrodynamic lubrication regime is governed by the viscosity of the
lubricant in the high pressure contact zone. The high of the
rapeseed oil causes much higher viscosity under these conditions,
which leads to higher friction coefcient [18].
6
7
Acknowledgements
The authors are grateful for the nancial support of FORMAS
(Project no. 2009-925), the National Natural Science Foundation of
China (Project no. 51005123), the Priority Academic Programme
Development of Jiangsu Higher Education Institutions and the
fruitful discussions with Dr. Mikael strand at Lantmnnen, AB,
Sweden.
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