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DEFINITION OF WETTABILITY
When 2 or more fluids are present, there are at least 3 sets of forces acting on the
fluids and affecting HC recovery
Oi
l
wo
so
Water
sw
Solid
0 < q < 90
Interfacial tension between the rock surface and water is less than
between the rock surface and oil.
Water
wo
Oil
Solid
OIL
Ai
r
<
90
Oi
l
OIL
WATER
SOLID (ROCK)
GRAIN
WATER
>
90
WATER
OIL
WATER
SOLID (ROCK)
GRAIN
OIL
RIM
BOUND WATER
FREE WATER
Ayers, 2001
WATER-WET
OIL-WET
WETTABILITY IS AFFECTED BY:
Composition of pore-lining minerals
Composition of the fluids
Saturation history (hysteresis effects)
WETTABILITY CLASSIFICATION
Strongly oil- or water-wetting
Neutral wettability no preferential wettability to either water
or oil in the pores
Fractional wettability reservoir that has local areas that are
strongly oil-wet, whereas most of the reservoir is strongly waterwet- Occurs where reservoir rock have variable mineral
composition and surface chemistry
Mixed wettability smaller pores area waterwet are filled with water, whereas larger pores
are oil-wet and filled with oil
F
R
E
E
W
A
T
E
R
IMPLICATIONS OF WETTABILITY
Primary oil recovery is affected by the wettability of the system.
A water-wet system will exhibit greater primary oil
recovery.
Oil recovery under waterflooding is affected by the wettability of
the system.
A water-wet system will exhibit greater oil recovery under
waterflooding.
Wettability affects the shape of the relative permeability curves.
Oil moves easier in water-wet rocks than oil-wet rocks.
WETTABILITY AFFECTS:
Capillary Pressure
Irreducible water saturation
Residual oil and water saturations
Relative permeability
Electrical properties
LABORATORY MEASUREMENT OF WETTABILITY
Most common measurement techniques
Contact angle measurement method
Amott method
United States Bureau of Mines (USBM) Method
Introduction to Capillary Pressure
Applications of Capillary Pressure Data
Determine fluid distribution in reservoir (initial conditions)
Accumulation of HC is drainage process for water wet
reservoirs (max possible HC saaturation)
Sw= function of height above OWC (oil water
contact)
Determine recoverable oil for water flooding applications
Imbibition process for water wet reservoirs
Pore Size Distribution Index,
Absolute permeability (flow capacity of entire pore
size distribution)
Relative permeability (distribution of fluid phases
within the pore size distribution)
DRAINAGE PROCESS
Fluid flow process in which the saturation of the nonwetting phase
increases
Examples:
Hydrocarbon (oil or gas) filling the pore space and displacing the
original water of deposition in water-wet rock
Waterflooding an oil reservoir in which the reservoir is oil wet
Gas injection in an oil or water wet oil reservoir
Pressure maintenance or gas cycling by gas injection in a
retrograde condensate reservoir
Evolution of a secondary gas cap as reservoir pressure decreases
IMBIBITION PROCESS
16
Decreasing
Permeability,
Decreasing
12
C
B
0.
2
0.
4
0.
6
C
a
pi
ll
a
r
y
P
r
e
s
s
u
r
e
Water Saturation
Effect of Grain Size Distribution on Shape
0.
8
1.
0
Well-sorted
Poorly sorted
C
ap
ill
ar
y
pr
es
su
re
,
ps
ia
Water saturation, %
CAPILLARY PRESSURE
- DEFINITION The pressure difference existing across the interface separating
two immiscible fluids in capillaries (e.g. porous media).
Calculated as:
Pc = pnwt pwt
Where:
Pc = capillary pressure
Pnwt = pressure in nonwetting
phase
pwt = pressure in wetting phase
Air
Water
Considering the porous media as a collection of capillary tubes
provides useful insights into how fluids behave in the reservoir pore
spaces.
Water rises in a capillary tube placed in a beaker of water, similar to
water (the wetting phase) filling small pores leaving larger pores to
non-wetting phases of reservoir rock.
2 aw cos
h
The height of water in a capillary tube is a function
of: r g aw
Adhesion tension between the air and water
Radius of the tube
Density difference between fluids
This relation can be derived from balancing the upward force due to
adhesion tension and downward forces due to the weight of the fluid (see
ABW pg 135). The wetting phase (water) rise will be larger in small
capillaries.
h =
Height of water rise in capillary tube, cm
aw =
Interfacial tension between air and water,
dynes/cm
=
Air/water contact angle, degrees
r
=
Radius of capillary tube, cm
g
=
Acceleration due to gravity, 981 cm/sec2
Draw =
Density difference between water and air, gm/cm3
Contact angle, q, is measured through the more dense phase (water in this
case).
AIR
WATER
h
pa2
pw2
pa1
pw1
Air
Water
pw1 = p2 w g h
Pc
= pa1 - pw1
= w g h - a g h
= g h
Combining the two relations results in the following expression
for capillary tubes:
2 cos
Pc
aw
2 ow cos
r
Pc
= Capillary pressure between oil and water, dyne/cm2
ow = Interfacial tension between oil and water, dyne/cm
= Oil/water contact angle, degrees
r
= Radius of capillary tube, cm
LABORATORY METHODS FOR MEASURING CAPILLARY
PRESSURE
Determination of Pc(Sw) function
Porous diaphragm method
Mercury injection method
Centrifuge method
Dynamic method
COMMENTS ON POROUS DIAPHRAGM METHOD
Advantages
Very accurate
Can use reservoir fluids
Disadvantages
Very slow (days, weeks, months)
Range of capillary pressure is limited by displacement
pressure of porous disk
Wetting phase of disk should be same as core sample
C Pc
Cos
C Pc
cos
J(Sw )
C Pc
cos
Lab
Reservoir
Exercises:
1. In the laboratory, a capillary pressure difference of 5 psi has been
measured between water and air in a core sample. Calculate the
corresponding height above the OWC in the reservoir from where the
core originates, when the following information is given (assume
capillary pressure at the OWC to be zero).
2. Use the air - water capillary pressure curve for laboratory conditions,
below, to calculate the saturations; So, Sg and Sw at the reservoir level
(hight) 120 f t above the oil-water contact (assume Pc = 0 at this level).
The distance between the contacts (OWC and GOC) is 70 f t.
Additional data:
.
Answers to questions:
1. h = 5.8m, 2. So = 0.2, Sg = 0.62 , Sw = 0.36,
3. Calculate the rise of water in a silica
capillary tube with diameter of 1 mm, given
that the interfacial tension and contact
angle between water and isoquinoline are 30
dynes/cm and 158, respectively, and the
densities of water, isoquinoline, and silica
are 1.00, 0.91, and 2.65 g/cm3, respectively.
4. a. What causes the accumulation of
hydrocarbons in a trap?
b.Give a quantitative definition of capillary
pressure in a gas reservoir (Pc).
Define
all terms.
c.Calculate the capillary pressure in a gas
reservoir at a point 15 feet above the free
water level (Pg = Pw = 2200 psia) if the
gas and water pressure gradients are 0.45
and 0.15 psi/ft, respectively.
5. a.
What is a drainage displacement
process?
b.What is an imbibition displacement process?
c.Give one example (each) of drainage and
imbibition
displacement
processes
that
might occur in a gas reservoir.
6. The integrated form of Darcys Equation for
linear, horizontal flow of an incompressible
liquid is shown below. This equation is
coherent for Darcys units (C=1).
q
a.
C k A p
L
q
k
A
p
L
b.
ft3/da
y
Md
ft2
Psia
Cp
Ft