Professional Documents
Culture Documents
POLYMETRON 9182
Oxygen analyzer (ppb)
Marking
Products contain toxic or hazardous substances or elements.
Part Name
Hexavalent
Lead Mercury Cadmium Chromium
(Cd)
(Pb)
(Cr VI)
(Hg)
Polybrom
Biphenyls
(PBB)
Transmitter box
CPU PCB
Power PCB
Relay PCB
Module
Probes
Cable
Polybrom
Diphenyls
(PBDE)
O: Indicates that this toxic or hazardous substance contained in all homogeneous material for
this part is below the limit requirement
X: Indicates that this toxic or hazardous substance contained in at least one of the
homogeneous materials used for this part is above the limit requirement
Warning!
There are no user-serviceable parts in either the transmitter or sensor. Only Hach Ultra
Analytics personnel or their authorized representative should attempt repair of the system and
only components expressly approved by the manufacturer should be used. Any attempt to
repair the instrument in contradiction of these guidelines may result in damage to the
instrument and injury to the person making the repair. It will also void the warranty and may
compromise the safe operation, electrical integrity or CE compliance of the instrument.
Note:
This equipment has been tested and found to comply with the limits for Class A digital device,
pursuant to Part 15 of the FCC Rules. These limits are designed to provide reasonable
protection against harmful interference when the equipment is operated in a commercial
environment. This equipment generates, uses, and can radiate radio frequency energy and, if
not installed and used in accordance with the instruction manual, may cause harmful
interference to radio communications. Operation of this equipment in a residential area is likely
to cause harmful interference in which case the user will be required to correct the interference
at his own expense.
Precautionary Labels:
Read all labels and tags attached to the instrument. Personal injury or damage to this
instrument could occur if not observed.
This symbol, if noted on the instrument, references the instruction manual for
operation and / or safety information.
Electrical equipment marked with this symbol may not be disposed of in
European public disposal systems after 12 August of 2005. In conformity with
European local and national regulations (EU Directive 2002/96/EC), European
electrical equipment users must now return old or end-of life equipment to the
Producer for disposal at no charge to the user.
Note: For return for recycling, please contact the equipment producer or supplier
for instructions on how to return end-of-life equipment for proper disposal.
Important document. Retain with product records.
COPYRIGHT
WARNING
To maintain safety standards, regular maintenance,
calibration and operation of this equipment by qualified
personnel is essential. Read and understand Instruction
manual completely before operating or servicing. If any
further details are required which do not appear in this
manual contact Hach Ultra Analytics or their agent.
ii
Warnings
Changing the programming language
The programming language is English when factory-programmed, when changing
the software version and when loading the default values. To change the language
follow the procedure below (example for French):
MENU
CALIBRATION
MAINTENANCE
PROGRAMMING
SERVICE
6.59
ppb
23.2 C
O2
Disp2
Menu
Select
Enter
SERVICE
DISPLAY
Enter
CONC : ppb/ppm
AVERAGE
DISPLAY
CODE
SOFT ISSUE
DEFAUT VAL.
ADJUST mA
CONFIGURATION
POLYMETRON
TEMP. : C
PRESSURE : mmHg
LANGUAGE : GB
Select
Select
DISPLAY
AFFICHAGE
CONC : ppb/ppm
TEMP. : C
CONC : ppb/ppm
Enter
TEMP. : C
PRESSURE : mmHg
LANGUAGE : F
PRESSION : mmHg
Select
Choix
LANGUE : F
iii
Esc 3 times)
(Press
When your programming language is chosen, you may change the mains supply
frequency if necessary. This change occurs at the first switching on and
afterresetting the instrument. Follow the procedure below:
MENU
CALIBRATION
MAINTENANCE
PROGRAMMING
SERVICE
6.59
ppb
23.2C
O2
Disp2
Menu
Enter
Select
SERVICE
AVERAGE
DISPLAY
CODE
SOFT ISSUE
DEFAULT VAL.
ADJUST mA
CONFIGURATION
CONFIGURATION
FREQ : 50Hz
Enter
Select
POLYMETRON
Select
CONFIGURATION
FREQ : 60Hz
Reset
the instrument
Enter
iv
Enter
Table of contents
Page
Warnings .................................................................................................................................... iii
Chapter 1: Introduction ............................................................................................................. 1-1
1.1 Introduction ........................................................................................................ 1-1
1.2 Principle of operation........................................................................................... 1-1
1.3 Main characteristics............................................................................................ 1-3
1.4 Technical characteristics..................................................................................... 1-3
1.5 Dimensions ........................................................................................................ 1-6
Chapter 2: Description of the analyser...................................................................................... 2-1
2.1 Analytical part .................................................................................................... 2-1
2.2 Hydraulic mounting ............................................................................................. 2-2
2.3 Transmitter......................................................................................................... 2-3
2.3.1 Presentation of the transmitter ................................................................. 2-3
2.3.2 Application fields .................................................................................... 2-5
2.3.3 Standard mounting possibilities (use of the red clamping bow) .................... 2-5
Chapter 3: Installation of the instrument................................................................................... 3-1
3.1 Unpacking.......................................................................................................... 3-1
3.2 Inspection .......................................................................................................... 3-1
3.3 Mounting............................................................................................................ 3-1
3.4 Location............................................................................................................. 3-1
3.5 Electrical connections ......................................................................................... 3-2
3.6 Description of the different terminals ..................................................................... 3-3
3.7 Mains connection ............................................................................................... 3-4
3.8 Starting the transmitter........................................................................................ 3-4
3.9 Adjusting the display contrast.............................................................................. 3-4
Chapter 4: Using the instrument................................................................................................ 4-1
4.1 Front panel keys................................................................................................. 4-1
4.2 Displays 1 to 4 (live displays)............................................................................... 4-2
4.3 Description of the function keys ........................................................................... 4-3
4.4 Icons ................................................................................................................. 4-3
4.5 Enter or modify a value........................................................................................ 4-4
4.6 Warnings ........................................................................................................... 4-4
Chapter 5: Programming the transmitter .................................................................................. 5-1
5.1 Main menu......................................................................................................... 5-1
5.1.1 Calibration Menu..................................................................................... 5-2
5.1.2 MAINTENANCE Menu............................................................................. 5-3
5.1.3 PROGRAMMING Menu........................................................................... 5-3
5.1.3.1 MEASURE Menu ....................................................................... 5-4
5.1.3.2 ALARMS Menu .......................................................................... 5-5
5.1.3.3 mA OUTPUTS menu................................................................... 5-8
5.1.3.4 RS485 Menu.............................................................................5-11
5.1.4 SERVICE Menu.....................................................................................5-12
5.1.4.1 AVERAGE Menu.......................................................................5-12
5.1.4.2 DISPLAY Menu.........................................................................5-13
5.1.4.3 CODE Menu .............................................................................5-14
Chapter 1: Introduction
1.1 Introduction
The 9182 oxygen analyser is a one-channel analyser for the measurement of dissolved oxygen in
the boiler feedwater, economizers, condensers and more generally all thermal equipment using
water as a heat transfer liquid.
1-1
1
4
2
3
5
2
6
7
8
2
7
9
1 : Assembled electrode
6 : Membrane holder
2 : Electrolyte
7 : Membrane
3 : Probe body
8 : Cathode
4 : Filling hole
9 : Sample
5 : Anode
1-2
Temperature
0-45 C (32-113 F)
Working pressure
Atmospheric pressure
Flowrate
4...10 l/h
ELECTRICAL CHARACTERISTICS
Mains
Standard version:
100...240 VAC - 50/60 Hz
Power consumption
25 VA
Connections
Fuse
1-3
ANALYSIS
Measuring range
0...2 ppm
Sensibility
0,5 ppb
Reproducibility
Detection limit
1 ppb
3 min
Ambient temperature
-20...60 C (-4...140 F)
Relative humidity
10...90%
TRANSMITTER
Display
Units
Calibration
Interferences
Analogue outputs
Alarms
Number: 4
- Functions: alarm - system alarm - timer
- Hysteresis: 0...10%
- Delay: 0...999s
- Breaking power:
250 VAC, 3A maximum
30 VDC, 0,5A maximum
Use a cable (rated 105 C and AWG22 to 14).
The external cable insulation should be cut as
close as possible from the terminal block.
1-4
Temperature compensation
Automatic in
(32...113 F)
the
range
of
0...45
RS485 (option)
Transmitter protection
Measurement category
Error reports
ELECTROMAGNETIC COMPATIBILY
European standards
IEC61010-1
File E226594
MATERIALS
Working electrode
Cathode: gold
Counter-electrode
Anode: silver
Membrane holder
Noryl
Membrane
PFA
Transmitter
Probe body
Noryl
1-5
MAINTENANCE
Approximative membrane lifetime
Cleaning
OPERATING CONDITIONS
Ambient temperature
-20...+60 C
Relative humidity
10...90 %
10 %
Pollution degree
Altitude
< 2 000 m
Measurement category
1.5 Dimensions
(Dimensions are in mm and [in inches])
polymetron
polymetron
1-6
1 : Connector
1 : Adjusting nut
2 : Anode holder
2 : Electrode
3 : Anode
3 : Probe body
4 : Cathode holder
4 : Membrane
5 : Cathode
5 : Filling screw
6 : Temperature sensor
6 : Gasket
2-1
5 : Cell
2 : Shrink ring
3 : Assembled probe
4 : Probe gasket
2-2
2.3 Transmitter
2.3.1 Presentation of the transmitter
Polymetron
S1
2.10 S3
ppb
O2
18.6 C
S2 Disp2 Menu S4
Esc
Enter
The electronic unit amplifies the signal of the amperometric measuring cell and converts it into a
direct digital readout in ppm, mg/l, ppb, g/l, C and F. The transmitter comprises the following
items:
n Potentiostat which maintains the working electrode potential constant
n Amperometric measuring module
n Analog multiplexer
n Microprocessor unit
The analog multiplexer allows measurements to be acquired from the measuring cell, temperature
sensor and internal checkpoints. Further, the microprocessor operates the relays, the RS485
interface (optional) and the analog outputs.
The unit has a built-in concentration-autoranging feature and a microprocessor-operated
calibration routine.
The output of the potentiostat is monitored for possible overdriving of the potentiostat-output stage.
This condition can occur with the connections to the measuring cell open, inoperable electrodes or
a defective reference electrode.
2-3
1 : Programmable potentiostat
6 : Auxiliary input
7 : Multiplexer
8 : A/D converter
9 : Microprocessor
2-4
Panel mounting
Panel cutting
Front panel dimensions
: 138 138 mm
: 144 144 mm
2-5
Wall mounting
2 screws 4 mm lg 60 flat head (not provided) / 80 mm center distance
(provided)
polymetron
(provided)
2-6
3.2 Inspection
The analyzer has been factory-checked and tested prior to shipment, it is however advisable to
inspect all parts immediately upon receipt for any damage which may have occurred during
shipment. A damaged shipping container may indicate internal damage which may not be
immediately obvious. If there is any evidence of damage, keep the shipping container and refer to
your local agent or to:
Hach Ultra Analytics
6 route de Compois - CP212
CH-1222 Vesenaz Geneva
3.3 Mounting
CAUTION!
Mounting should be done by qualified service personnel only. No power should be
applied until the installation is complete.
3.4 Location
The analyser should be located in an accessible site.
The site should permit the access for any checking or maintenance operation.
The sample flowrate has to be maintained within the specifications (See 1-4).
3-1
2
1.
2.
3.
4.
5.
Microprocessor board
Relay board
Amperometric board
Power supply board
Program update connector
The different terminals represented on the right side are accessible by removing the armour
plate.
3-2
Description
020 mA or 420 mA (n1) [+]
Connection
user
user
user
user
user
Option RS485
user
Amperometric module
Description
Temperature sensor [+]
Temperature sensor [-]
Colour
black
blue
Reference if use of
3 electrodes
Counter electrode (anode)
Working electrode (cathode)
Auxiliary input
External shield
braid
armour plate
Internal shield
brown
GND
Connection
temp +
temp -
n.c.
Connection
user
user
user
user
3-3
Before servicing the instrument, ensure that the power supply is switched
off.
3-4
Sample concentration
Sample temperature
Diffusion current
Programming codes
Programming arguments
Polymetron
S1
2.10 S3
ppb
O2
18.6 C
S2 Disp2 Menu S4
Oxygen
application
Suppress an action or
go back to previous step
Esc
Enter
4-1
6.59
S3
ppb
S2
S1
S2
S1
23.2 C
Disp2
O2
Menu
6.59 ppb
23.2 C
5.942 A
Disp3
S1 : ppb > 3
S2 : OK
S3 : ppb > 5
S4 : OK
S4
S3
S4
S3
Disp4
I1 : Conc
4.9 mA
I2 : Conc
4.9 mA
Main
4-2
Main
Menu
Disp2
Display screen 2
Disp3
Display screen 3
Disp4
Display screen 4
OK
Yes
Confirm a command
Decrease a value
Increase a value
4.4 Icons
Symbol of waiting or instrument reset
4-3
1 3 . 89 ppb
Enter
1 3 . 89 ppb
1 5 . 89 ppb
Enter
15 . 89 ppb
Enter
15 . 8 9 ppb
15 . 3 9 ppb
Enter
15 . 3 9 ppb
15 . 3 7 ppb
Enter
15 . 37 ppb
to change the unit
15 . 37 ppm
4.6 Warnings
Note 1: If you do not use the keyboard for at least 10 minutes, the instrument returns to the
measuring mode.
Note 2: An access code may be required for the calibration, programming and service menu (see
CODE menu).
Possibility to display a negative first digit "-"
Possibility to display a "." for the other digits
4-4
S1
6.59
S3
ppb
S2
23.2 C
O2
Disp2
S4
Menu
MENU
CALIBRATION
MAINTENANCE
PROGRAMMING
SERVICE
Select
CALIBRATION
CONC. CALIB.
TEMP. CALIB.
PARAMETERS
F
Select
Choix
MAINTENANCE
PROGRAMMING
MEASURE
ALARMS
mA OUTPUTS
RS485
54.90 ppb
23.2 C
8.05 A
Select
SERVICE
AVERAGE
DISPLAY
CODE
SOFT ISSUE
DEFAULT VAL.
ADJUST mA
CONFIGURATION
POLYMETRON
Select
5-1
CALIBRATION
CONC. CALIB.
Enter
Enter
TEMP. CALIB.
PARAMETERSF
CONC. CALIB.
Choix
Select
TEMP. CALIB.
EXECUTION
ZERO
Enter
SLOPE
F
Select
Choix
Select
PARAMETERS
DATE : 01/01/98
P : 1.000 A/ppm
F
T : 0.0 C
PARAMETERS
DATE
xx/xx/xx
x.xxx A/ppm
Slope value
x.x C
5-2
MAINTENANCE
6.75 ppb
21.6 C
5.559 A
PROGRAMMING
MEASURE
ALARMS
mA OUTPUTS
RS485
Select
5-3
Choix
Select
Enter
TEMP. COMP.
SENSOR : NTC
TYPE : Manual
TEMP. : 25.02FC
Choix
Select
TEMPERATURE COMPENSATION
TYPE
- Auto
- Manual
TEMP.
- xx.x C
SENSOR
NTC/AD590
5-4
Choix
Select
LIMIT FUNCTION:
The alarm relays are activated if the comparison of the measured value with the limit programmed
meets the alarm function condition (up or down). The limits are programmed according to the
following programming variables:
ALARMS 1 4 (LIMIT)
AFFECT
- Conc.
- No
- C/F
LIM
xxxx
DIR : Down
DIR.
- Up
- Down
DELAY
xxxs
HYST.
XX %
RELAY
- NO
- NC
ALARMS
AFFECT. : Conc.
DELAY : 000s
HYST. : 00 %
RELAY : NO
Select
5-5
MODE
- No
- Limit
- Syst.
ACCEPT
- Auto
- Manu
RELAY
- NO
- NC
MODE : Syst.
ACCEPT. : Auto
RELAY : NC
Select
5-6
TIMER FUNCTION:
Relay S4 may be affected to a timer function.
ALARM 4 (TIMER)
MODE
- No
- Limit
- Timer
INTERV
XXXXmn
IMPUL.
Ton
XXXs
Toff
XXXs
TmA
XXmn
ALARM 4
MODE :
Timer
Interv : 1440 mn
IMPUL. : 5
Ton : 005 s
Toff : 003 s
TmA : 05 mn
Select
the
configuration of the menu mA OUTPUTS/SPECIAL
PROG./TIMER
Relay S4
Pulse number
Closed
Open
Time
Ton Toff
TmA
Interval
5-7
The analogue output signals allow the transmission of the measurements from the analyser to any
external control system.
It is highly recommended to use shielded cables for the output signals. This shielding should be
connected to the earth terminal on the armour plate.
mA OUTPUTS
OUTPUT 1
OUTPUT 2
SPECIAL PROG.
TEST
Enter
Enter
Select
SPECIAL PROG.
OUTPUTS 1/2
MAINTENANCE
CALIBRATION
SYST. ALARM.
TIMER
Enter
Select
AFFECT. : A
TYPE : 4-20
MODE : Lin
LOW : 00001 nA
UP : 100.0 A
Select
Enter
SPECIAL PROG.
MODE :
TEST
Preset
VALUE :
VALUE : 00 mA
F
00 mA
F
Choix
Select
5-8
5-9
OUTPUTS 1/2
AFFECT
- Conc
- A
- C/F
TYPE
0/20
4/20
MODE
- Lin
- Dual
LOWER
XXXX
MIDD.
XXXX
UPPER
XXXX
MODE
- last
- preset
- live
VALUE
XX
TEST
Upper
20
(mA)
20
16
15
12
10
Linear
Middle
Lower
Dual
10
20
30
40
5-10
50 60 70
80
90 100 (%)
RS485
N : 00
BAUD : 9600
PARITY : No
STOP BIT : 1
Select
RS485
N
XX
BAUD
PARITY
- No
- Odd
- Even
BIT STOP
- 1
- 2
1 bit stop
2 bit stop
300
600
1200
2400
4800
9600
5-11
SERVICE
AVERAGE
DISPLAY
CODE
SOFT ISSUE
DEFAULT VAL.
ADJUST mA
CONFIGURATION
POLYMETRON
Select
TEST
AVERAGE
AVERAGE : 9
TEST
Average
3.46 ppb
Real
3.49 ppb
Enter
Select
AVERAGE
AVERAGE
TEST
5-12
DISPLAY
CONC :
ppb/ppm
TEMP. : C
PRESSURE : mmHg
LANGUAGE : F
Select
DISPLAY
CONC
- ppb/ppm
- g-mg/l
TEMP.
- C
- F
PRESSURE
- mmHg
- mbar
- InHg
LANGUAGE
-
F
GB
D
SP
I
5-13
0000
PROG. :
0000
SERVICE : 0000
Select
CODE
CALIB.
XXXX
PROG.
XXXX
SERVICE
XXXX
If you forget your access code, press simultaneously ESC and ENTER to enter into the
menu selected.
5-14
SOFT ISSUE
MONEC 9182
OXY 1.00
DEFAULT VAL
Loading
!
values?
default
Yes
5-15
ADJUST mA
ADJUST mA
OUTPUT 1
OUTPUT 2
VALUE
0000
Enter
Select
5-16
CONFIGURATION
FREQ :
60 Hz
FREQ :
50 Hz
Select
Enter
Please
wait...
Start up ...
Disp2
Disp2
Menu
Disp2
Menu
POLYMETRON
0000
5-17
NOTE
See chapter 5 for programming the commands.
REMARK
Any result (calibration or measurement) is always brought back to the reference temperature
(25C, 77F). If the sample temperature is different from the reference temperature, it is required
to execute a temperature compensation which can be either manual or automatic.
6-1
MEASURE
TEMP. COMP.
Select
Enter
TEMP. COMP.
TYPE : Auto.
SENSOR : NTC
TEMP : 25.0C
Select
EXECUTION
TEMP. CALIB.
EXECUTION
Enter
Select
21.2
21.2
CAL
CAL
2 1.2 C
6.87 ppm
OK
Possibility to change
the value
TEMP. CALIB.
T : 0.0 C
Enter
ENTER : ok
ESC : cancel
6-2
PROGRAMMING
MEASURE
TEMP. COMP.
Select
Enter
TEMP. COMP.
TYPE : Manual
SENSOR : NTC
Select
Enter
TEMP. COMP.
TYPE : Manual
TEMP. : 25.0 C
SENSOR : NTC
Select
EXECUTION
Not applicable when a manual temperature
compensation is chosen.
6-3
CONC. CALIB.
ZERO
Enter
Enter
SLOPE
Select
ZERO CALIB.
SLOPE CALIB.
PROGRAMMING
PROGRAMMING
EXECUTION
Select
Enter
Select
ZERO CALIB.
SLOPE CALIB.
Enter
SLOPE:
Enter the atmospheric pressure in mmHg.
Enter the ambient temperature in C.
AIR
TYPE :
TYPE : AutoElec.
P = 760.0 mmHg
Select
Tamb = 20 C
Select
EXECUTION
SLOPE:
Humidify the wadding of the calibration cap and
take off the probe from the sample. Position the
cap on the electrode and press ENTER.
The probe should be positioned vertically with
the membrane downwards (see page 7.1).
SLOPE CALIB.
PROGRAMMING
EXECUTION
Enter
Select
21.2
SLOPE CALIB.
ppm
25.0 C
5.693 A
CAL
DATE : 01/01/98
P:
1 nA/ppm
OK
Possibility to enter the
date of the calibration
6-4
ZERO:
Choice of the chemical zero.
Choice of the slope in the air.
ZERO
Enter
Enter
SLOPE
Select
ZERO CALIB.
SLOPE CALIB.
PROGRAMMING
PROGRAMMING
SLOPE:
Enter the atmospheric pressure in mmHg.
Enter the value of the ambient temperature.
EXECUTION
Select
Enter
Select
SLOPE CALIB.
ZERO CALIB.
Enter
TYPE : AIR
TYPE : Chem.
P = 760.0 mmHg
Select
Select
Tamb = 20 C
EXECUTION
ZERO CALIB.
ZERO:
Make sure the water used for the chemical
zero is really oxygen-free (< 1 ppb).
Press ENTER, the "CAL" message flashes
and indicates the instrument is in calibrating
mode.
Wait
for
the
current
stabilisation
(approximately 10 min.) and press OK to
validate the calibration. The oxygen
concentration value flashes during 3 seconds.
The instrument displays zero.
PROGRAMMING
EXECUTION
Enter
Select
21.2
ppm
25.0 C
CAL
5.693 A
OK
0
ppm
25.0 C
CAL
5.693 A
OK
SLOPE CALIB.
PROGRAMMING
EXECUTION
Enter
Select
21.2
SLOPE CALIB.
ppm
25.0 C
5.693 A
CAL
DATE : 01/01/98
P:
1 nA/ppm
OK
Possibility to enter the
date of the calibration
SLOPE:
Humidify the wadding of the calibration cap and
take off the probe from the sample. Position the
cap on the electrode and press ENTER.
The probe should be positioned vertically with
the membrane downwards (see page 7.1).
The flashing "cal" message indicates that the
instrument is in calibration mode. Wait for the
current stabilisation (approximately 10 min.)
and press OK to validate the calibration. The
oxygen concentration value flashes during
3 seconds.
The analyser displays the date of the last
calibration and the new slope calculated.
Modify the date if you wish. Put back the
electrode in water.
6-5
CONC. CALIB.
ZERO
Enter
Enter
SLOPE
Select
ZERO CALIB.
SLOPE CALIB.
PROGRAMMING
PROGRAMMING
EXECUTION
Select
Enter
Select
ZERO CALIB.
SLOPE CALIB.
TYPE : AutoElec.
TYPE : PROCESS
Select
Select
Enter
EXECUTION
SLOPE CALIB.
PROGRAMMING
EXECUTION
Enter
Select
21.2
SLOPE CALIB.
ppm
25.0 C
5.693 A
CAL
DATE : 01/01/98
P:
1 nA/ppm
OK
SLOPE:
The "CAL" message flashes and indicates the
instrument is in calibrating mode. Wait for the
current stabilisation and press OK.
You have the possibility to adjust the
concentration value digit by digit with the
function key
to the value obtained
with your reference analysis method.
The analyser displays the date of the last
calibration and the new slope calculated.
Modify the date if you wish.
6-6
ZERO:
Choice of the chemical zero
Choice of the slope process
ZERO
Enter
Enter
SLOPE
Select
ZERO CALIB.
SLOPE CALIB.
PROGRAMMING
PROGRAMMING
EXECUTION
Select
Enter
Select
SLOPE CALIB.
ZERO CALIB.
TYPE : Chem.
TYPE : PROCESS
Select
Select
Enter
EXECUTION
ZERO CALIB.
ZERO:
Make sure the water used for the chemical
zero is really oxygen-free (< 1 ppb).
Press ENTER, the "CAL" message flashes
and indicates the instrument is in calibrating
mode.
Wait
for
the
current
stabilisation
(approximately 10 min.) and press OK to
validate the calibration. The oxygen
concentration value flashes during 3 seconds.
The instrument displays zero.
PROGRAMMING
EXECUTION
Enter
Select
21.2
ppm
25.0 C
CAL
5.693 A
OK
0
ppm
25.0 C
CAL
5.693 A
OK
SLOPE CALIB.
PROGRAMMING
EXECUTION
Enter
Select
21.2
SLOPE CALIB.
ppm
25.0 C
5.693 A
CAL
DATE : 01/01/98
P:
1 nA/ppm
OK
Possibility to enter the
calibration date
SLOPE:
The flashing "cal" message indicates that the
instrument is in calibration mode. Wait for the
current stabilisation (approximately 10 min.)
and press OK to validate the calibration. The
oxygen concentration value flashes during 3
seconds.
The analyser displays the date of the last
calibration and the new slope calculated. Modify
the date if you wish.
6-7
7-1
7-2
Note 1: There is electrolyte in the probe, keep it head down when you remove it from the water.
Note 2: Never shake the probe during a calibration, it may provoke an introduction of oxygen
in the electrolyte and a temporary cell current increase.
7-3
7-4
7-5
F. Screw the new membrane on the body till the dead stop.
G. Replenish the probe body with 5 ml of electrolyte. Check there is no impurity or bubble in the
electrolyte.
H. Preposition the electrode without forcing. It should take its place by simple gravity.
I. Screw the probe nut till the electrode meets a resistance.
J. Put back the cap and gasket, screw the cap to ensure watertightness.
7-6
Problem: No significant current increase when the probe is in the air for the calibration
Causes and solutions:
a) There is an important pollution of the electrolyte due to an incorrect adjustment of the filling
screw
! Change the electrolyte. Check there is a gasket and the screwing. Check the
Teflon band is correctly positioned or that the probe is not damaged.
b) The membrane holder is incorrectly screwed. Risk of electrolyte pollution
! Change the electrolyte and tighten correctly the membrane holder.
c) The membrane has been torn
! Change the membrane.
d) The electrode is not correctly mounted in the probe body: there is an important looseness
between the membrane and the golden cathode
! Tighten the electrode screw (rep 3 page 7-1).
7-8
7-9
Other problems
a) The probe current is null
! There is no electrolyte in the probe (leak).
b) The probe current is negative
! Connexion problem to the anode circuit (loose contact).
! AgBr deposit on the anode
c) The sample temperature corresponds to the specifications but there is an error on the
temperature
! There may be a short-circuit on the temperature connection.
7-10
POSSIBLE CAUSE
REMEDIES
Defective fuse
Check fuse
Hardware is defective
CPU hardware
7-11
MALFUNCTION
Measurement is not
correct
Measurement is not
stable
Temperature
measurement is not
correct
POSSIBLE CAUSE
REMEDIES
Recheck programmed
parameters. Do they agree with
the probe's characteristics?
Probe malfunctioning,
possibly incompatible with the
application
Faulty probe
Interferences
7-12
MALFUNCTION
Display reading static;
cannot be changed in
any way
POSSIBLE CAUSE
REMEDIES
Hardware is defective
Hardware is defective
Polarization voltage
incorrect
Wrong configuration
(3 electrode mode)
Wrong programming
7-13
Description
CONCENTRATION
TOO HIGH
Electrode protection
STAND-BY
1.99 ppb
CONCENTRATION
TOO LOW
TEMPERATURE
ERROR
8-1
CURRENT
TOO LOW
CURRENT
TOO HIGH
21.6
C
T
OUT OF LIMITS
8-2
mm Hg
mm H2O
psi
inches Hg
inches H2O
920.00
690
9503.60
13.34
27.16
374.16
925.00
693.8
9555.25
13.42
27.31
376.19
930.00
697.5
9606.90
13.49
27.46
378.22
935.00
701.3
9658.55
13.56
27.61
380.26
940.00
705
9710.20
13.63
27.76
382.29
945.00
708.8
9761.85
13.71
27.90
384.32
950.00
712.5
9813.50
13.78
28.05
386.36
955.00
716.3
9865.15
13.85
28.20
388.39
960.00
720
9916.80
13.92
28.35
390.43
965.00
723.8
9968.45
14.00
28.50
392.46
970.00
727.5
10020.10
14.07
28.64
394.49
975.00
731.3
10071.75
11.14
28.79
396.53
980.00
735
10123.40
14.21
28.93
398.56
985.00
738.8
10175.05
14.29
29.08
400.59
990.00
742.5
10226.70
14.36
29.23
402.63
995.00
746.3
10278.35
14.43
29.38
404.66
1000.00
750
10330.00
14.50
29.53
406.69
1005.00
753.8
10381.65
14.58
29.68
408.73
1010.00
757.5
10433.30
14.65
29.82
410.76
1015.00
761.3
10484.95
14.72
29.97
412.79
1020.00
765
10536.60
14.79
30.12
414.83
1025.00
768.8
10588.25
14.87
30.27
416.86
1030.00
772.5
10639.90
14.94
30.42
418.89
A2-1
F = 1,8 C + 32
K = C + 273,15
32
273,15
24
75,2
297,15
33,8
274,15
25
77
298,15
35,6
275,15
26
78,8
299,15
37,4
276,15
27
80,6
300,15
39,2
277,15
28
82,4
301,15
41
278,15
29
84,2
302,15
42,8
279,15
30
86
303,15
44,6
280,15
31
87,8
304,15
46,4
281,15
32
89,6
305,15
48,2
282,15
33
91,4
306,15
10
50
283,15
34
93,2
307,15
11
51,8
284,15
35
95
308,15
12
53,6
285,15
36
96,8
309,15
13
55,4
286,15
37
98,6
310,15
14
57,2
287,15
38
100,4
311,15
15
59
288,15
39
102,2
312,15
16
60,8
289,15
40
104
313,15
17
62,6
290,15
41
105,8
314,15
18
64,4
291,15
42
107,6
315,15
19
66,2
292,15
43
109,4
316,15
20
68
293,15
44
111,2
317,15
21
69,8
294,15
45
113
318,15
22
71,6
295,15
23
73,4
296,15
A2-1
PARAMETERS
DATE : 01/01/98
S
: 1.000 A/ppm
T
: 0.0 C
: Air
: 760 mmHg
: 20.0 C
PROGRAMMING
MEASURE
TEMP. COMP.
TYPE
: Auto
SENSOR
: NTC
ALARMS
ALARMS S1/S2/S4
AFFECT. : Conc.
LIM.
: 0.00 ppb
DIR.
: Low
DELAY
: 000 s
HYST.
: 00%
RELAY
: NO
ALARM S3
AFFECT. :
ACQUIT :
RELAY
:
System
Auto
NC
mA OUTPUTS
OUTPUT 1
AFFECT.
TYPE
MODE
LOW
UP
:
:
:
:
:
Conc.
4-20
Lin.
0.000 ppm
1.000 ppm
OUTPUT 2
AFFECT. :
TYPE
:
MODE
:
LOW
:
UP
:
A3-1
Conc.
4-20
Lin.
0.000 ppm
1.000 ppm
SPECIAL PROG.
MAINTENANCE
MODE : Last
CALIBRATION
MODE : Last
TIMER
MODE :
ALARM SYSTEM
MODE : Last
Last
RS485
N
BAUD
PARITY
STOP BIT
:
:
:
:
0
9600
No
1
SERVICE
AVERAGE
AVERAGE :
1
DISPLAY
DISPLAY
CONC.
TEMP.
:
:
PRESSURE :
LANGUAGE :
ppb/ppm
C
mmHg
GB
CODE
CODE
CALIB.
: 0000
PROG.
: 0000
SERVICE : 0000
CONFIGURATION
CONFIGURATION
FREQ. : 50 Hz
A3-2
Rep.
Colour
Function
Rep. connector
Black
T+
Blue
T-
White
Work
Red
Counter
White
GND
White
Earth
A4-1
361 C
Vapor pressure
IMM 719 C
Specific gravity
2.044
stable
Incompatibilities
A5-1
TOXICOLOGICAL INFORMATION
Acute effects: harmful if swallowed, inhaled or absorbed through skin. Material is extremely destructive to
tissue of the mucous membranes and upper respiratory tract, eyes and skin. Inhalation may be fatal as a
result of spasm, inflammation and edema of the larynx and bronchi, chemical pneumonitis and pulmonary
edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness
of breath, headache, nausea and vomiting.
DISPOSAL CONSIDERATIONS
Contact a licensed professional waste disposal service to dispose of this material.
The above information is believed to be correct but does not purport to be all inclusive and shall be used only
as a guide.
A5-2
Potassium bromide
PHYSICAL AND CHEM ICAL PROPERTIES
White crystals
Melting point
770 C
Specific gravity
1.984
Water spray.
A5-3
TOXICOLOGICAL INFORMATION
Acute effects: harmful if swallowed, inhaled or absorbed through skin. Causes eye and skin irritation.
Material is irritating to mucous membranes and upper respiratory tract. To the best of our knowledge, the
chemical, physical, and toxicological properties have not been thoroughly investigated. Ingestion of large
quantities can cause weakness, gastrointestinal irritation and circulatory disturbances.
DISPOSAL CONSIDERATIONS
For small quantities: cautiously add to a large stirred excess of water. Adjust the pH to neutral, separate
any insoluble solids or liquids and package them for hazardous-waste disposal. Flush the aqueous
solution down the drain with plenty of water. The hydrolysis and neutralization reactions may generate
heat and fumes which can be controlled by the rate of addition. Observe all federal, state and local
environmental regulations.
The above information is believed to be correct but does not purport to be all inclusive and shall be used only
as a guide.
A5-4
Part number
09125=A=2485
09185=A=3500
363144,00100
09182=A=1000
Calibration cap
09182=A=1200
09180=A=6201
Connection cable 10 m
09078=A=3010
09078=C=1010
09078=C=1020
09078=C=1030
09078=A=2000
Syringe
460150,21951
CPU board
09125=A=1001
Power supply
09125=A=2000
09180=A=1500
Display board
09125=A=1010
09180=A=0300
09180=A=0311
621=191=082
621=091=082
621=291=082
621=491=082
621=591=082
A6-1
0121
(0:Process, 1:Air)
0221
0222
0223
MEASURE menu
/MEASURE
/TEMP.COMP.
/Type
/Temp.
(0:Manual, 1:Auto)
1220
1230
ALARMS menu
/ALARM1
/Affect
/Lim.
/Dir.
/Delay
/Hyst.
/Relay
/ALARM2
/Affect
/Lim.
/Dir.
/Delay
/Hyst.
/Relay
(0:N.O., 1:N.C.)
(0:conc, 1:C/F, 2:No)
(0:Low, 1:Up)
(0:N.O., 1:N.C.)
A7-1
2120
2130
2140
2150
2160
2170
2220
2230
2240
2250
2260
2270
/ALARM3
/Mode
/Affect
/Lim.
/Dir.
/Delay
/Hyst.
/Relay
/Accept
/ALARM4
/Mode
/Affect
/Lim.
/Dir.
/Delay
/Hyst.
/Relay
/Interv
/Impul.
/Ton
/Toff
/TmA
(0:N.O., 1:N.C.)
(0:Manu, 1:Auto)
(0:Limit, 1:Timer, 2:No)
(0:conc, 1:C/F, 2:Non)
(0:Low, 1:Up)
(0;N.O., 1:N.C.)
2310
2320
2330
2340
2350
2360
2370
2380
2410
2420
2430
2440
2450
2460
2470
2401
2402
2403
2404
2405
mA OUTPUTS menu
/OUTPUT1
/Affect
/Type
/Mode
/Low
/Mid.
/Upp.
/OUTPUT2
/Affect
/Type
/Mode
/Low
/Mid.
/Upp.
4110
4120
4150
4130
4160
4140
4210
4220
4250
4230
4260
4240
A7-2
/SPECIAL PROG.
/MAINTENANCE
/Mode
/Value
/CALIBRATION
/Mode
/Value
/SYST. ALARM
/Mode
/Value
/TIMER
/Mode
/Value
/TEST
4311
4312
4321
4322
4331
4332
4341
4342
RS485 menu
/N
/Baud
/Parity
/Stop bit
5100
5200
5300
5400
SERVICE menu
/AVERAGE
/Average
/TEST
/DISPLAY
/Conc.
/Temp
/Pressure
/Language
/CODE
/Calib.
/Program
/Service
/SOFT ISSUE
/DEFAULT VAL.
/ADJUST mA
/OUTPUT1
/OUTPUT2
/CONFIGURATION
/Freq
(0:0,...10:10)
7210
(0:ppb-ppm, 1:g-mg/l)
(0:C, 1:F)
(0:mmHg, 1:mbar, 2:inHg)
(0;F, 1:GB, 2:D, 3:Sp, 4:I)
7360
7320
7370
7330
7410
7420
7430
(0:60HZ, 1:50Hz)
Values measured:
Adr 0000: concentration value
Adr 0002: temperature value
Adr 0004: current value
Adr 0006: auxiliary value measured
A7-3
7810
A7-4