Question 1.

HNO3 (aq) is titrated with NaOH(aq) conductometrically, graphical representation

of the titration as :

[A]

[B]

[C]

[D]

Question 2.
Three faradays of electricity are passed through Al2O3, aqueous solution of
CuSO4 and molten NaCl each taken in different electrolytic cells. The amount of
Al, Cu & Na deposited at the respective cathodes will be in the ratio of :
[A]
[B]
[C]
[D]

1 mole : 2 mole : 3 mole

3 mole : 2 mole : 1 mole
1 mole : 1.5 mole : 3 mole
1.5 mole : 2 mole : 3 mole

Question 3.
For the following sequential reaction
:
Calculate
[A]
[B]

for

values in volts at 298 K are given

[C] 1.51 volts

[D]

Question 4.
During the electrolysis, the amount of product liberated at electrode is plotted
against charge in faraday. The correct graph is :

[A]

[B]

[C]

[D]

Question 5.
A student made the following observations in the laboratory :
I. Clean copper metal did not react with 1 molar Pb(NO3)2 solution.
II. Clean lead metal dissolved in a 1 molar AgNO3 solution and crystals of Ag
metal appeared.
III. Clean silver metal did not react with 1 molar Cu(NO3)2 solution.
The order of decreasing reducing character of the three metals is :
[A]
[B]
[C]
[D]

Cu, Pb, Ag
Cu, Ag, Pb
Pb, Cu, Ag
Pb, Ag, Cu

Question 6.
The variation of equivalent conductance of weak electrolyte with
correctly shown in figure :

is

[A]

[B]

[C]

[D]

Question 7.
The correct order of equivalent conductance at infinite dilution of LiCl, NaCl and
KCl is :
[A]
[B]
[C]
[D]

LiCl > NaCl > KCl

KCl > NaCl > LiCl
NaCl > KCl > LiCl
LiCl > KCl > NaCl

Question 8.
A 0.05 M NaOH solution offered a resistance of 31.6 ohm in a conductivity cell at
298K. If the cell constant of the conductivity cell is 0.3792
, the molar
conductance of the sodium hydroxide solution is:
[A]
[B]
[C]
[D]

Question 9.
Identify the true and false statement and answer in given options :

I.
II.
both
III.
[A]
[B]
[C]
[D]

During electrolysis of 1 M NaCl solution Cl2 does not form at the anode.
For a concentration cell with its reaction at equilibrium
and
are zero.
In a solution of HCN the concentration of
ions is given by
.

FTF
TTT
FFF
FTT

Question 10.
Acetic acid is titrated with NaOH solution. Which of the following statement is
correct for this titration?
[A]
[B]
[C]
[D]

Conductance increases upto equivalence point, then it decreases

Conductance decreases upto equivalence point, then it increases
First conductance increases slowly upto equivalence point and then increases rapidly
First conductance increases slowly upto equivalence point and then drops rapidly

Question 11.
Statement 1 : In electrochemical cell, we cannot use KCl in the salt bridge if
anodic or cathodic compartment consists of Ag+ or Pb2+ ion.
Statement 2 : Salt bridge is employed to maintain the electrical neutrality and to
minimize the liquid-liquid junction potential.
Statement-1 is True, Statement-2 is True and Statement-2 is a correct explanation for
Statement-1
[B] Statement-1 is True, Statement-2 is True and Statement-2 is NOT a correct explanation
[C] Statement-1 is True, Statement-2 is False
[D] Statement-1 is False, Statement-2 is True
[A]

Question 11.
A zinc rod weighing 25.0 g was kept in 100 mL of 1.0 (M) CuSO4 solution. After a
certain time the molarity of Cu2+ in the solution was 0.8. The molarity of
:
[A]
[B]
[C]
[D]

0.8 M
0.5 M
1.0 M
0.4 M

Question 12.
Based on the following information arrange four metals A, B, C and D in order of
decreasing ability to act as reducing agents :
I.

Only A, B and C react with 1 M HCl to give H2(g).

II.
When C is added to solutions of the other metal ions, metallic B and D are
formed.
III.

Metal C does not reduce An+.

The correct choice is :

[A]
[B]
[C]
[D]

C>A>B>D
C>A>D>B
A>C>D>B
A>C>B>D

Question 13.
For the cell :

is negative if :

[A]
[B]
[C]
[D] Both (A) and (B)

Question 14.
A graph was plotted between order conductivity of various electrolytes (NaCl, HCl
and NH4OH) and
. Correct matching will be :

[A]
[B]
[C]
[D]

I (NaCl), II (HCl), III (NH4OH)

I (HCl), II (NaCl), III (NH4OH)
I (NH4OH), II (NaCl), III (HCl)
I (NH4OH), II (HCl), III (NaCl)

Question 25.

Which of the following statements is INCORRECT ?

The conductance of a solution contained in a cubic cell of unit edge length is called
specific conductance
Specific conductance increases while molar conductivity decreases on progressive
[B]
dilution
The limiting equivalent conductivity of weak electrolyte cannot be determine exactly by
[C]
extrapolating the curve between equivalent conductivity and
[D] The conductance of metals is due to the presence of free electrons.
[A]

Question 16.
If 0.224 L of H2 gas is formed at the cathode of one cell at S.T.P., how much of
Mg is formed at the cathode of the other electrolytic cell if the other cell is
arranged in series?
[A]
[B]
[C]
[D]

4.8 gm
0.48 gm
2.4 gm
0.24 gm

Question 17.
A gas X at 1 atm, is bubbled through a solution containing mixture
of
. If their reduction potentials are in the order of Z > Y > X
then :
[A]
[B]
[C]
[D]

Y will oxidise X and not Z

Y will oxidise Z and not X
Y will oxidise both X and Z
Y will reduce both X and Z

Question 18.
One litre of 1 M CuSO4 solution is electrolysed. After passing 2F of electricity,
molarity of solution with respect to Cu+2 ions will be :
[A]
[B]
[C]
[D]

M/2
M/4
M
0

Question 19.
If 0.965 ampere current is passed through the aqueous solution of CH3COONa at
27C and 1 atm pressure for 100 minutes during Kolbe's electrolysis. Total volume
of the gases evolved at anode is :

[A]
[B]
[C]
[D]

22.14 litres
2.214 litres
1.476 litres
14.76 litres

Question 20.
A half cell is made by dipping copper rod in copper hydroxide solution of pH = 14.
If the
and
.What would be the electrode
potential of the half cell at room temperature ?
[A]
[B] 0.23 V
[C] 0.91 V
[D]

Question 21.
A voltaic cell consists of an electrode of solid silver immersed in a 0.10 M
AgNO3 solution and an electrode of unknown metal 'X' immersed in a 0.10 M
solution X(NO3)2. A porous barrier separates two half cells.
Also given:

Which of the following statements regarding the cell and X is incorrect?

[A] Standard EMF
[B] X is a stronger reducing agent than H2(g)
As the cell operates, the concentration of both
increase in their respective
[C]
half cells
As the cell operates, the concentration of X2+ increases in the anode chamber while the
[D]
concentration of
decrease in the cathode chamber

Question 22.
[A]
[B]
[C]
[D]

The direction of current flow will remain same

Polarity of the electrodes will be reversed
Cell will stop working
EMF of the cell will increase