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1.0
INTRODUCTION
The chemical oxygen demand (COD) test is usually used to measure the amount of
organic compounds in water. Mostly, the applications of COD determine the amount of
organic pollutants found in surface of water such as lakes and rivers. Measure the COD is one
of useful method to indicate the quality of water. It is expressed in milligrams per liter (mg/L)
which shows the mass of oxygen consumed per liter of solution. COD is the measurement of
the amount of oxygen in water consumed for the chemical oxidation of pollutants. Besides,
COD also determines the quantity of oxygen required to oxidize the organic matter in water
or waste water sample, under specific conditions of oxidizing agent, temperature and time.
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OBJECTIVES
To determine the amount of organic pollutants in effluents
3.0
MATERIALS
i.
ii.
Sulfuric acid (2 4 ),
4.0
i.
APPARATUS
HACH equipment
5.0
PROCEDURES
The procedure for COD test followed Standard Methods APHA 5220-C where the
samples were refluxed in strong acid solution with a known excess potassium
dichromate (K2Cr2O7), Sulfuric acid (2 4 ), Mercuric Sulfate (Hg4 ), and Silver
Sulfate in special vials used for HACH methods.
The procedures for the test are as follows:
i.
ii.
iii. The entire sample cell is then heated for two hours using COD reactor at around
150C and left to cool down to room temperature.
iv. After that, the samples were tested by using HACH equipment.
v.
The program for high range and high range plus COD is selected by pressing 2720
and details HACH PROGRAM: 2720 COD, HR, HR PLUS is shown. For low range
COD, the number 2710 is pressed and the display shows HACH PROGRAM: 2710
COD, LR.
vi. The Test N Tube Adapter is inserted into the sample cell module by sliding it under
the thumb screw and into the alignment grooves. The thumb screw is fastened.
vii. The outside of the blank is cleaned with a towel to remove fingerprints or other mark
before been placed into the adapter.
viii. After the blank been placed into the adapter, the light shield is then closed.
ix. The soft key under ZERO is pressed where the display will show 0 mg/L COD.
x.
The other sample vial is then tested using the same method. Results were displayed in
mg/L COD.
Concentration (mg/L)
Standard (mg/L)
Blank
Sample
111
80
7.0
CONCLUSION
Chemical Oxygen Demand (COD) is often measured as a rapid indicator of organic
8.0
QUESTIONS
Measure the total of all chemicals in the Measure the amount of food (or organic
water that can be oxidized.
Simple and easy to perform, can be done in Usually takes 5 days to get the result.
2 hours.
Able to determine organics which both Only
biodegradable and non-biodegradable.
able to
biodegradable.
determine
organic
for