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ABSTRACT
This experiment was conducted to determine the purity of benzoic acid through sublimation and melting
point determination using its crude form, impure benzoic acid. The sample of impure benzoic acid was first
sublimated, wherein crystals were formed and observed in the watch glass covering the evaporating dish
with the perforated filter paper after heating. The crystals (sublimate) were then collected. The sublimate
and the pure benzoic acid are then individually packed in capillary tubes, which are used to determine the
melting point of the substance through the use of an oil bath. The melting point of the impure benzoic acid
obtained from the experiment was then compared to the standard value of the melting point of the pure
benzoic acid, which is in the range of 122-124C.
INTRODUCTION
Sublimation, in chemistry, is the transition of a
substance directly from the solid phase to the gas
phase without passing through an intermediate
liquid phase. The vapor, which is in the gaseous
phase, can solidify, making sublimation a
purification process. Sublimation can then be
classified as a purification technique for solid
mixtures. Sublimation however, is limited to
impurities that are non-volatile or have a lower
vapor pressure than the pure compound.
Sublimation however, is not limited to its
purification properties. It is also used to describe
the reverse process, meaning gas changing back
to solid state upon cooling. Melting point
determination
is
often
associated
with
sublimation especially when trying to test the
purity of the substance or compound.
Melting point is the temperature at which a
solid changes to liquid at atmospheric pressure.
Meaning the solid and liquid phases of a
substance coexist in equilibrium. The melting
point of benzoic acid is higher than the boiling
point if water, that is why an oil bath was used in
the experiment.
There was only one compound used in the
experiment, and that is Benzoic Acid. Also known
as Dracylic acid or Benzeneformic acid.
Considered as the simplest aromatic carboxylic
acid containing carboxyl group bonded directly to
a benzene ring. Benzoic acid is a white crystalline
organic compound that has a boiling point of
247C and a melting point of 122C.
toothpastes,
mouthwashes,
deodorants and the like.
cosmetics,
EXPERIMENTAL
A. Compounds tested
5.0g Benzoic Acid (impure)
Benzoic Acid (Pure)
B. Procedure
1. Preparation of Capillary Tubes
Two capillary tubes are prepared and one of the
ends of each tube is heated using a Bunsen
burner to seal it. While heating one end of each
of the capillary tubes, the tube was rotated to
make the seal even. It was heated continuously
until the capillary tube was totally sealed.
2. Preparation of Impure Benzoic Acid
Sublimate (Sublimation)
5g of impure benzoic acid was placed in an
evaporating dish and the dish was covered with a
perforated filter paper and an inverted preweighed watch glass was placed on top of the
filter paper and then heated in a hot plate for 1015 minutes.
5.0g
94.57g
94.0485g
0.5215g
5. Percentage recovery
10.43%
Pure
Sublimate
Temperature 1
110C
112C
Temperature 2
114C
118C
REFERENCES
[1]http://en.wikipedia.org/wiki/Sublimation_(pha
se_transition)
[2]http://www.infoplease.com/encyclopedia/scie
nce/sublimation-chemistry.html
[3] http://www.ehow.com
[4] http://orgchem.colorado.edu/
[5]
http://physics.about.com/od/gloassary/g/sublima
tion.htm
[6] http://www.chemicalland21.com
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