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Institute of Nuclear Chemistry and Technology, Dorodna 16, 03-195 Warsaw, Poland
Warsaw University of Technology, Faculty of Chemical and Process Engineering, Warynskiego 1, 00-645 Warsaw, Poland
c
Institute of Atomic Energy, 05-400 Otwock-Swierk, Poland
Abstract
Electron beam ue gas treatment technology is one of the most advanced technologies among new generation
processes for air pollution control. The process, which has been developed in Japan, the United States, Germany and
Poland allows simultaneous removal of SO2 and NOx with high efciency and by-product generated can be applied as
fertilizer. Two industrial installations using this technology have been constructed in the world, one in China and the
second in Poland. Other plants are constructed in Japan and China. Chinese installation is mostly SO2 removal oriented
(since the NOx emission limits in China are not imposed up to now), so Polish plant one is as a matter of fact the rst
installation for simultaneous desulfurization and denitrication of ue gases. The plant located in EPS Pomorzany in
Szczecin treats the ue gases emitted from two Benson boilers of 65 MWe and 100 MWth each. The ue gases of
maximum ow of 270 000 N m3/h are irradiated by four accelerators of 700 keV electron energy and 260 kW beam
power each. Description of the plant and the results obtained have been presented in this paper. The plant has been in
operation for more than 2500 h (5500 h including one accelerator set operation). Removal efciencies up to 95% for
SO2 and up to 70% for NOx were achieved. Several thousand tons of the by-product was sold in the form of NPK
fertilizer. Economically, the technology is competitive with the conventional ones.
r 2004 Elsevier Ltd. All rights reserved.
Keywords: Electron beam technology; Flue gas treatment; SO2 removal; NOx removal
1. Introduction
The fossil fuel combustion process involves high
emission of acidic pollutants like SO2 and NOx that
creates a major world environmental problem. In
Poland the biggest sources of pollution are located in
south west region of the country where industrial centers
are located. In spite of this over 45% of the total SO2
and about 70% of NOx pollutants distributed over
Polish territory come from external sources. Poland,
where the energy is generated mainly from pit and
*Corresponding author. Fax: +48-22-811-15-32.
E-mail address: pawelec@orange.ichtj.waw.pl (A. Pawelec).
0969-806X/$ - see front matter r 2004 Elsevier Ltd. All rights reserved.
doi:10.1016/j.radphyschem.2004.03.020
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440
2. Industrial installation
The rst industrial installation for simultaneous
removal of SO2 and NOx was located in Electropower
Station Pomorzany in Szczecin, north of Poland
(Chmielewski et al., 2001). The installation puries ue
gases from two Benson boilers of 65 MWe and
100 MWth each, the total maximum ow rate is
270 000 N m3/h. With its 1.05 MW total beam power
installed it is the biggest accelerator facility in the world.
The installation consists of four main, separated
systems:
*
*
*
*
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3. Operational experiences
450.0
Removal [mg/Nm ]
400.0
350.0
300.0
250.0
6 kGy
8 kGy
200.0
10 kGy
12 kGy
150.0
300
400
500
600
700
800
900
1000
1100
2000
Removal [mg/Nm ]
1800
1600
1400
1200
1000
800
600
400
200
0
60
65
70
75
80
85
90
Temperature [C]
1800
1600
Removal [mg/Nm3]
1400
1200
1000
800
600
SO2
NOx
400
200
0
30.00
40.00
50.00
60.00
70.00
80.00
90.00
100.00
100
90
Fig. 4. SO2 and NOx removal efciency vs. ammonia stoichiometry (observed).
SO2
80
Removal [%]
441
70
60
50
NOx
40
30
20
10
0
5.0
5.5
6.0
6.5
8.5
9.0
9.5
10.0
ARTICLE IN PRESS
A.G. Chmielewski et al. / Radiation Physics and Chemistry 71 (2004) 439442
442
100
90
Removal [%]
80
70
60
References
50
40
30
20
10
0
0.00
0.10
0.20
0.30
0.40
0.50
0.60
0.70
0.80
0.90
1.00
4. Conclusions
The industrial electron beam ue gas treatment
installation for simultaneous removal of SO2 and NOx
has been constructed in EPS Pomorzany in Szczecin,
Poland. The installation proved high effectiveness of the
process against the pollutants removal. Among the other
parameters the dose is the most important from the NOx
removal point of view. In the case of SO2 the most
important parameters are temperature, ammonia stoichiometry and the ammonia dosing way. The accelerators of this power were not applied ever before, so
5000 h of their operation in severe industrial conditions
delivered a lot of experience for further technology
implementation.
The radiation ue gas treatment method is one of the
most attractive air pollution control processes due to its
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