Professional Documents
Culture Documents
-154
Pergamon Press Ltd., 1979. Printed in Great Britain
0038--092X/7910201-0149l$02.0010
I. INTRODUCTION
(2)
=l(h~-hw)+hw+(RYr
2. CYCLE ANALYSIS
(I)
(3)
l)h,-Rh7
If sensible heat exchangers are used between the absorber and the generator for both the water-lithium
bromide and the ammonia-water systems so that the
strong solution leaving the absorber is heated by the
weak solution leaving the generator, the temperature rise
of the strong solution A Ts, is given by the following
equation
(4)
F(x, k) = ~ eX~,lk~_,_ k
(5)
150
S. ALIZADEHet al.
Refrig.
vapour
Condenser t
(7)
j
]
Strong
Generator
solution
(3)
(Solar energy) 0G
(4)
Weak
solution
(8)
.I
Solution heat
exchanger
(2)
Exp.
(G)]
Evaporator
f
[Ab=b7
(,61
o."
Fig. 1. Schematic of the water-lithium bromide system.
5
Reflux
condenser
6[<
Condenser I
tw
Generator
~ 0 G(Solar energy)
Solution
heat
exchanger
Absorber
Exp.
valve
IO
(
oJ
Fig. 2. Schematic of the ammonia-water system.
relation
UA
__~pms'--
(6)
Cps
(7)
Co -- - 3.09y + 4.18
(8)
(9)
151
IIO
/ /f
Tc = 3 5 *C
TE = 1.7 *C
85
_P=___4zmm
h~
~D
35
I0
04
05
06
L i t h i u m bromide,
075
07
wl %
Tc = 3 5 "C
TE = 1.7 *C
Iio
.,.o/3
P
E
8o
o
50 -
20
035
040
045
0,50
Ammonia,
0,55
065
060
wl %
for both the water-lithium bromide and the ammoniawater cycles. The thermodynamic paths of the two
cycles have also been shown by the solid lines in Figs. 3
and 4. The value of x = pc in Figs. 5 and 6 could actually
be considered as heat exchanger parameters above 10.
The sensible heat exchangers between the fluid
streams entering and leaving the generator should transfer the maximum amount of heat consistent with
economy of construction. Assuming streamline flow for
the weak solution in the heat exchanger (this can usually
be done by selecting the proper diameter for the exchanger tube) it can be shown that [4] the value of UA
for the exchanger is proportional to the cube root of the
mass flow rate of the weak solution. By applying various
simplifications, Duflie and Sheridan[5] have shown that
the UA value for the exchanger could be approximated
by
UA = 379 m ~13
(10)
I)]'/3
(II)
152
S. ALIZADEH et aL
09
0.8
07--
0.6
._0
0.5---0
._~
8 0.4
U
C ~ - -
@__
-r
-- =
o~
i,
0.2
0.1
O3
60
To
75
80
Generator
8~
temp,
90
9~
G e n e r a t o r temp,
0.7
J
X=I
05
.9
04
(J Q3
I/! ...........
,o
I
i
I
o.2
. . . .
"r"
TE=I.7 %
T~ = 35 c
i
70
80
90
I00
Generator
I I0
temp,
120
t30
140
60
70
80
90
I00
I10
120
130
140
Generator temp, =C
the absorber and it also varies from refrigerant to refrigerant. For evaporator temperature of 1.7C, condenser
temperature of 35C and absorber temperature of 21C,
the constant B for water-lithium bromide case is 46.6
and for the ammonia-water case it has a value of 16.1.
Since R is a function of the generator temperature only
when other conditions of the system are fixed, x in eqn
(11) is a function of the generator temperature for a
specified value of C. Therefore x can be plotted vs the
generator temperature for different values of C as in
Figs. 7 and 8. These figures show that as the generator
temperature decreases the circulation factor increases
for a given C. This places a lower bound for the generator temperature because as the circulation factor increases the mass flow rates in the system also increase
and this suggests larger heat exchange surfaces and
,8
rAlal *c
re- I z *c
r~=3~*c
116
i
I5
1.4
1.2
(12)
153
(13)
--
m, = 12660 h-~I~'
(14)
0.9
I:
0.8--
Ol~55
I
]
60
65
--
70
75
80
85
Generotor ten'@, *C
90
.,
95
the water-lithium bromide system. The collector surface emissivity is 0.1 and the collector tilt angle is 300 at 40 North Lat.
2
%
o"
O
GecN~'amr ten'@, *C
S. ALIZADEHet al.
154
A
A!
A,
C
Cp
F
HAy
h
h!~
K
m
p
R
T
AT
U
x
y
NOMENCLATURE
heat exchanger area, m 2
flat plate collector area, m2kJ-t hr
total flat plate collector area, mz
system capacity, refrigeration ton = 12660 LI hr -~
specific heat, kJ kg-I C-I
heat exchanger effectiveness
average horizontal insolation, kJ hr -~ m -z
enthalpy, kJ kg-~
enthalpy of vaporization, LI kg -~
generator temperature parameter
mass flow rate, kghrpressure
circulation factor
temperature, C
temperature difference.C
overall heat transfer coefficient of heat exchanger,
kj hr-I m-2OC-I
heat exchanger parameter
lithium bromide or ammonia weight per cent
cooling ratio
Subscripts
a
A
C
E
]"
m
r
s
t
v
w
weak solution
absorber
condenser
evaporator
fiat plate collector
maximum
refrigerant
strong solution
total
vapour
saturated water
REFERENCES
I. E. H. Perry, The theoretical performance of the lithium
bromide-water intermittent absorption refrigeration cycle.
Solar Energy 17, 321 (1975).
2. J. C. V. Chinnappa, Performance of an intermittent refrigerator operated by a flat-plate collector. Solar Energy 6, 143
(1962).
3. S. L. Sargent and W. A. Beckman, Theoretical performance of
an ammonia sodium thiocyanate intermittent absorption
refrigeration cycle. Solar Energy 12, 137 (1968).
4. William H. McAdams, Heat Transmission. 3rd Edn. pp. 229235. McGraw-Hill, New York (1954).
5. J. A. Duffie and N. R. Sheridan, Lithium bromide-water
refrigerators for solar operation. Mech. and Chem. Engng
Trans.. the Institution of Engineers. Australia (1965).
1/3(12660C)(24)
D
(Al)
1/3(12660C)(24) + 0.20(12660C)(24)
D
(A2)
1.60
or
Af = 1.60 A~
(A3)
(A4)
Resumen--Un estudio general te6rico ha sido hecho sobre disefio y mejora de los ciclos de absorci6n refrigerativa
de agua-bromido de litio y amonia-agua. Los resultados de este estudio muestran queen general para condiciones
iniciales fijas y sistema dado de capacidad de refrigeraci6n, la temperatura mils alta del generador causa un radio
mis alto de enfriamiento con menor cambio de superficies de calory consecuentemente menor costo. Una
comparaci6n de los dos ciclos tambi6n indica que el sistema de agua-bromido de litio es mils simple que el sistema
de amonia-agua y opera en un radio de enfriamiento mils alto y menor cambio de superficies de calor para las
mismas condiciones.
R6sum6--Une 6tude sur la fabrication et l'optimization des cycles de refroidissement par absorption a 6t6
entreprise sur des syst6mes eau-bromure de lithium et eau-ammoniaque. Les r~sultats de cette 6tude montrent que
si on fixe les conditions initiales et la capacit6 de r6frig6ration, des temp6ratures plus 61ev6es du g6n6rateur
aboutissent h des refroidissements plus 61ev6s avec une surface plus petite des 6changeurs. done fi un cofit moins
61ev6. Une comparaison des deux syst6mes montre que le syst6me eau-bromure de lithium est plus simple que le
syst6me eau-ammoniaque, donne des refroidissements plus 61ev6s et ncessite de plus petites surfaces d'6changeurs duns les mimes conditions.
(A5)