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LAST NAME,
FIRST
Quiz #1
Note: Your answers must be correct to 3 significant figures and have the appropriate units.
I.Forthegasphasereaction
2A+BC+3D
Thereactionisreversibleatconstanttemperatureandpressure.ThefeedistwomolesofAper
onemoleofB.
1.WritetheconcentrationofAintermofCA0andX.
CA=
C A0 (1 X )
(1 X / 3)
2.WritetheconcentrationofCintermofCA0andX.
CC=
______________
______________
C A0 ( X )
2(1 X / 3)
II The irreversible elementary reaction 2A B takes place in the gas phase in an isothermal
tubular reactor. ThefeedistwomolesofAperonemoleofC,aninert. The entering temperature
and pressure are 427oC and 10 atm, respectively. Gas constant R = 0.082 atmL/moloK.
3. Determine the concentration of A at the entrance to the reactor.
____________
CA0=0.116mol/L
4. If CA0 = 1.0 mol/L, the concentration of A at 90% conversion of A is
____________
CA=0.143mol/L
III. (5) Hydrogen gas is fed to a burner, where it is combusted with 300% excess air (21% O 2).
Moles of nitrogen required for each mole of hydrogen is
______________
H2 + 0.5O2 H2O
Moles of nitrogen = 7.52 moles
____________
V =4.8 L
____________
A + 4B 2C
____________
Q = 2.5 L/min
2) Determine the concentration of A at the entrance to the reactor.
____________
CA0=0.061mol/L
3) Write the concentration of A in terms of CA0, and X.
CA=
____________
C A0 (1 X )
(1 1.5 X )
B. 100%
C. 121%
The reaction is irreversible at constant temperature and pressure with pure gas A fed to the
reactor. Write the concentration of A in terms of CA0, and X.
1 X
CA = CA0 1 2 X / 3
V) For the reaction
2A B
The reaction is reversible, non-isothermal with pure gas A fed to the reactor. Write the
concentration of A in terms of CA0, T0, T, P0, P, and X.
1 X P T0
P
CA = CA0 1 0.5 X 0 T
VI) Calculatethepartialpressureofmonatomichydrogengasat1000oKand1atmpressure.
ForH2(g)H(g)
o
G1000 K =120,000J/mol,gasconstantR=8,314J/moloK
PH=5.39107atm
_______________
2A+BC+3D
Thereactionisreversibleatconstanttemperatureandpressure.ThefeedistwomolesofAper
onemoleofB.
2.WritetheconcentrationofAintermofCA0andX.
______________
(1 X )
CA=CA0 1 X / 3
3.WritetheconcentrationofCintermofCA0andX.
CC=CA0
______________
X
2 1 X / 3
5) If the MBP feed rate is 60 lbmol/hr and the exit conversion in the CSTR is 0.4, what
conversion would be achieved if a second 500 ft3 CSTR were placed in series with the first
CSTR?
X = 0.806
6) What CSTR volume would be necessary to achieve a conversion of 95% for a molar feed rate
of MBP of 60 lbmol/hr?
V = 4691 ft3
II. A solute diffuses through a membrane that separates two compartments A and B that have
different initial concentrations. The solute concentrations in the two compartments as a function
of time, CA and CB are shown below. The volumes of the two compartments are VA and VB.
(A) VA > VB
a.AandBaretrueb.OnlyAistruec.OnlyBistrued.AandBarefalse
10
IV.Forthereaction A(g)+2B(g)C(g)+D(g,l)
ThefeedcontainsonlyAandBinstoichiometricamounts.Thetotalpressureis101.3kPaand
species D hasavaporpressureof30.39kPaattheisothermalreactiontemperatureof300 oK.
Calculatetheconversionatwhichcondensationbegins.
X=0.9/1.3=0.692
V.ThegasphasereactionA(g)3B(g)obeyszerothorderkineticswithr=0.25moles/literhr
at200oC.GasconstantR=0.082Latm/moloK.StartingwithpureAat1atm,calculatethe
timefor95%oftheAtobereactedawayin
9)aconstantvolumebatchreactor
t = 0.098 hr = 5.88 min = 353 s
____________
10)aconstantpressurebatchreactor
t= 0.0549 hr = 3.29 min = 198 s
______________
AB
has a unimolecular reaction rate constant of 0.0025 min-1 at 90oF. This reaction is to be carried out
in parallel tubes 10 ft long and 1 in. inside diameter under a pressure of 150 psia at 260 oF. A and B
each have molecular weights of 64. Ideal gas constant R = 10.73 psiaft3/lbmoloR = 1.99
Btu/lbmoloR. The conversion of A is 80%.
1) If 1500 lb/hr of B is required, determine the feed flow rate of A in lbmol/min
____________
FA0 = 0.488 lbmol/min
2) If the activation energy of the reaction is 35,000 Btu/lbmol, the rate constant at 260oF is
k = 4.75 min-1
3) If the reaction rate constant at 260oF is 52.6 min-1 and the feed flow rate of A is 1.0 lbmol/min,
the required volume of the reactor is
V = 1.58 ft3
4) If the reaction rate constant at 260oF is 52.6 min-1, the feed flow rate of A is 1.0 lbmol/min, and
there is also an inert flow rate of 1.0 lbmol/min, the required volume of the reactor is
V =3.16 ft3
5) If the required volume of the reactor is 1.5 ft3, the number of tubes needed is____________
nt = 28
II. Thegasphasecatalyzedhydrogenationofocresolto2methylcyclohexanoneisgivenby
ocresol(A)+2H2(B)2methylcyclohexanone(C)
Thereactionrateonanickelsilicacatalystwasfoundtobe
rA=kPB,wherek=1.74molofocresol/(kgcatminatm)at170oC
Thereactionmixtureentersthepackedbedreactoratatotalpressureof5atm.Themolarfeed
consistsof67%H2and33%ocresolatatotalmolarrateof40mol/min.
6) Neglectingpressuredrop,writetheconcentrationofCAintermofCA0andX.
CA = CA0
(1 X )
(1 2 X / 3)
7) If the pressure drop is not negligible, we need to solve the following ODEs
(1 X )
(1 2 X / 3)
dX
dy
= 0.435
y, and
= 0.34
, where y = P/P0
2y
(1 2 X / 3)
dw
dw
The above two ODEs can be solved using the following Matlab statements and function
A) wspan=0:.1:4.8;
[w,xy]=ode45('f4d22b',wspan,[0 0]);
B) wspan=0:.1:4.8;
[w,xy]=ode45('f4d22b',wspan,[0 1]);
function wx = f4d22b(W,xy)
X=xy(1);y=xy(2);
wx(1,1)=0.435*(1-X)*y/(1-2*X/3);
wx(2,1)=-0.34*(1-2*X/3)/(2*y);
function wx = f4d22b(W,xy)
X=xy(1);y=xy(2);
wx(1,1)=0.435*(1-X)*y/(1-2*X/3);
wx(2,1)=-0.34*(1-2*X/3)/(2*y);
C) wspan=0:.1:4.8;
[w,xy]=ode45('f4d22b',wspan,[0 1]);
function wx = f4d22(W,xy)
X=xy(1);y=xy(2);
wx(1,1)=0.435*(1-X)*y/(1-2*X/3);
wx(2,1)=-0.34*(1-2*X/3)/(2*y);
III. Afermentationbrothconsistsofanaqueoussolutionofnutrientsandcells.Asthecells
grow,theyclusterintosphericalpelletsofradiusR(t).Onaverage,thecelldensityinsidea
pelletis0.04mgofcellmasspercubicmillimeterofpelletvolume.Thedissolvedoxygen
concentrationinthebrothis5 g/cm3.Thecellsutilizeoxygenatarateof1.2mmolof
oxygenperhourpergramofcellmass,viaazeroorderreaction.Thediffusioncoefficient
DABofoxygenwithinthepelletis1.8105cm2/s.Thecellsandbrothhavedensitiescloseto
thatofwater.Thereisafiniteconvectiveresistancetomasstransfertothesurfaceofthe
pellet,suchthatthefluxtothesurfaceisgivenby
molarflux=kc(CBCP)
whereCBisthebrothoxygenconcentrationandCPisthe(unknown)concentrationofoxygen
atthepelletsurface.
8) Determine the reaction rate, R, per unit volume of the cell in mol/(cm3s)
R = 1.3310-8 mol/(cm3s)
9) IfR = 2.5109mol/(cm3s),R=5.0102cmand2kcR/DAB=4determineCP(g/cm3)
CP = 3.15106g/cm3
10) If R is the reaction rate per unit cell volume, the differential equation for the concentration of
oxygen, CA, in the spherical pellet is
d 2 dC A
d 2 dC A
D
D
A) AB
r
+R = 0
r
R = 0
B) AB
2
dr
dr
dr
dr
r
r
C)
D AB d 2 dC A
r
R = 0 Ans
dr
r 2 dr
D)Noneoftheabove
3) If the concentration of oxygen in air at the surface of the cellular organism is 8.5106
mol/cm3,theconcentration ofoxygen(mol/cm3)inthecell atthesurfaceofthecellular
organismis
___________
6
3
CAs|cell = 1.45510 mol/cm
III.Hexamethylenetetraamnie,N4(CH2)6,istobeproducedinawellstirredsemibatchreactor
byadding20oCaqueousammoniasolutionataconstantrateof25liters/mintoaninitialcharge
offormalinsolution:
6HCHO+4NH3>N4(CH2)6+6H2O
(A)(B)
The reaction is instantaneous, irreversible, and exothermic. The initial charge of formalin
solution is 5000 liters with a formaldehyde concentration, CAi, of 20.0 mol/liter. The
concentrationofammoniainthesolutionisCB=12.0mol/liter.Heatcapacityofbothammonia
andformalinsolutionis1000cal/liter oC.Heatofreactionis74.6kcal/molofN4(CH2)6.The
initialtemperatureofformalinsolutioninthereactoris25oC.
4)Therateofheatgeneratedbythechemicalreactionis
____________
5595kcal/min
5)Timerequiredforcompleteconsumptionofformaldehydeis
____________
t = 222 min
IV.ThefirstorderreactionABiscarriedoutinanadiabaticCSTRwithCA0=2mol/liter
andT0=300oK.Itisfoundthat50%conversionisobtainedwith(=V/Q)=4min,andthe
reactortemperatureis350oK.
6)Thereactionrateconstantkat350oKis
k=0.25min
___________
7)ThereactionisinwaterwithCp=1000cal/literoK.Findtheheatofreaction.
___________
Hr = 50kcal/mol
V.Theirreversible,liquidphasereactionABistobecarriedoutinanidealPFR.Theinlet
concentrationofA, CA0,is2,500mol/m3,andthefeedtemperature is150oC.Thefractional
conversion of A in the reactor effluent must be at least 0.90. The reactor will operate
isothermallyat150oC.ThereactionissecondorderinA.Therateconstantat150 oCis1.40104
m3/(molAs).At150oCHRx=165kJ/mol.Theflowratetothereactoris0.01m3/s.
8)DeterminethevolumeofthePFRrequiredfor90%conversion.
___________
V= 0.257m3
9)Determinetherate(kJ/min)atwhichheatisremovedfromthewholereactor. ___________
Q&=2.23105 kJ/min
10
VI)(10)ThefollowingMATLABprogramcanevaluate ( 1) n
n 0
A.
x = 2;
sum = 1;
For n=0:10
sum = sum + (1)^n*x^n/factorial(2*n+1);
end
B. (Ans.)
x = 2;
sum = 1; z = 1;
For n=1:10
z = z*x/(2*n)/(2*n+1); sum = sum+z
end
xn
forx=2
( 2n 1)!
C.
x = 2;
sum = 1; z = x;
For n=1:10
z = z*x/(2*n+1); sum = sum+z
end
D.
None of the above