Professional Documents
Culture Documents
"IIIIIIIIIIII~
I
I
11111111111111111111111111111111111111
iui
l U-,~
CANDIDATE
NAME
CENTRE
NUMBER
ITllJ
INDEX
NUMBER
9647/02
CHEMISTRY
Paper 2 Structured Questions
October/November 2011
2 hours
Data Booklet.
-_
1
..._---
2
3
-----
5
- -----6
--
Total
....
~- - - _ . -
DC (LEO) 25669f7
'8:
,
,
~ Y/
i~
UNIVERSITY of CAMBRIDGE
International Examinations
[Turn over
478368502
For
Ex8JrJner's
Aspirin was one of the first drugs to be produced synthetically and is one of the most widely
used 'over-the-counter' drugs in the world. It is a white solid and is prepared by an acylation
reaction between 2-hydroxybenzenecarboxylic acid and ethanoic anhydride.
The other product of this reaction is ethanoic acid.
2-hydroxybenzenecarboxylic acid
ethanoic anhydride
aspirin
(ii)
calculate the masses of reactants you would use to prepare 10g of pure aspirin,
showing your working.
[3)
9647/02JO/N/11
Use
478368503
II
For
EtHmlner's
Use
draw a diagram of the assembled apparatus you would usa when heating the
reaction mixture;
give a full description of the procedures you would use to prepare and purify the
aspirin ;
explain how you would check the purity of your sample .
9647/02JO/N/11
[Turn
OV~
..
478368504
4
1111111111111111111111111111111111111111111111111111111
For
.... .. .. ... ... . ...... . .. .. .. ... .... .. .. .
Examiner's
Use
I!
11 1
(c) Identity one potential safety hazard in this experiment and state how you would
minimise this risk .
...... ... ........................... ...... ................. ..... .... ... .... ......... .................. ..... ....... ... .... ..... ... ... .. [1)
[Total: 12]
9647/02JOINl11
...J
478368505
II
5
1111111 111111111111111 1111111111 111111111' 11 11111111111
For
Examiners
USB
(a) Write an expression for Kc for this equilibrium, stating the units .
[2]
Phosphorus(V) chloride dissolves in some polar solvents without reaction and such solutions
conduct electricity. This is due to the presence of the two ions [PClJ+ and [PCIJ- ,
(b)
Draw the structure and suggest the shape of each of these ions.
[3]
(Total: 5]
9647/02J01N111
[Turn
ov~
478368506
II
6
1111\1111111111111111111111111111111111111111111111111I
For
EJlflmin9f's
Usa
In an experiment, 1.00mol of PC's vapour was heated in a closed S.OOdm 3 flask at SOOK
until equilibrium had been established.
The gases in the flask were then rapidly cooled, causing the formation of crystals of pels
and liquid PCl3. The chlorine gas present was pumped away and collected.
The amount of chlorine collected was x mol.
An excess of water was then very carefully added to the two remaining compounds, under
suitable conditions, causing the following reactions to occur.
3HCl + H3P03
You may assume that both H3 P0 4 and H3 P0 3 behave as dibasic (diprotic) strong acids.
(a) Determine, in terms of X, the number of moles of H+that will be formed after the addition
of water to the mixture of PCls and PCI3 "
[4)
9647/02/0/N/11
478368507
7
1111111111111111111111111111111111111111111111111111111
The resulting solution was made up to 1.00 dm 3 in a standard flask. 25.0cm 3 of this solution
was titrated with 4.00 mol dm-3 NaOH and required 37.4 cm 3 for neutralisation.
(b) (i)
Calculate the total amount, in moles, of H+ ions present in the 1.00dm3 standard
flask.
(II)
Use your answers to 3(a) and 3(b)(i) to calculate the amounts, in moles, of PCI 5 ,
PCla and Cl 2 in the original equilibrium at 500 K.
Foi
Examiner's
Use
[4J
(e) Use your answers to question 2(a) and 3(b)(ii} to calculate a value for Kc for the
equilibrium.
[2]
[Total: 1Dj
9647/02/01NJ11
[Turnov~
478368508
II
8
1111111111111111111111111111111111111111111111111111111
The elements of Group It, magnesium to barium, are metals while the elements of Group VII,
chlorine to iodine, are non -metals.
(a)
(I)
State one physical property of the elements of Group II which shows them all to be
metals.
(ii)
State one trend in the physical properties of the elements of Group VII from chlorine
to iodine, and explain Why this change occurs.
change
explanation
For
Examiner's
Use
Si
Ge
Sn
Pb
mp/oC
>3550
1410
937
232
327
(b) Carbon, silicon and germanium each form a solid with the same type of structure.
(I)
(ii)
Suggest why the melting points 01 these elements decrease from carbon to
germanium .
(e)
(I)
(il)
i .
.. A'
Use the Data Booklet to obtain values for the C-Cl and Si-Cl bond energies.
C-Cl
kJ mor"
Si-Cl
9647102JO/N/11
'
kJ mor?
...J
478368509
II
9
1111111111111111111111111111111111111111111111111111111
(III) Suggest an explanation for the inertness of CC14 to water.
For
ExaminBJ's
Use
..............................................................................................................................[3]
Lead forms two chlorides, PbCl2 and PbCl4 .
When chlorine is passed into a saturated solution of PbCl2 in NH4Cl(aq), a yellow salt, V, is
formed which has the following composition by mass:
(II)
cation
(iii)
(Iv)
When Y is treated with cold concentrated H2S04 , PbCl4 is formed as an oily liquid.
(e)
By using appropriate values from the Data Booklet, predict what, if anything, will happen
when a solution of PbCl4 in hydrochloric acid is added to a solution containing V3+(aq).
[2]
[Total: 17]
9647J02fOJNl11
[Turnov~
478368510
II
10
111111111111111111111111111111111111111111 1111111111111
for
ExBlTliner's
USe
(a) Use all of the above information to determine the identity and number of each of the
functional groups present in compound K.
For each functional group you identify, explain how you came to your decision .
(I)
(II)
(5]
9647/0210/N/11
478368511
11111111111111111111111111111111111111111111111
~I I I
11
(b) Draw the displayed formulae of all the possible stereoisomers of K which have the
following features.
For
Examiner's
US8
They have molecular formula C4H a0 2 and give the reactions on page 10.
No oxygen atom is attached to any carbon atom which is involved in a double bond.
No carbon atom has more than one oxygen atom joined to it.
For each structure you draw, state the type of stereoisomerism it shows and give one
further piece of relevant information about it.
You are not required to label functional groups.
[7]
[Total: 12]
9647/02JO/NJ11
[Turnov~
478368512
~II
12
-111111111111111111111111111111111111111111111111111
6 Compound W has the molecular formula C7H 70Cl. It is an aromatic compound which
contains two functional groups.
Data about the reactions of Ware given in the table.
._- ,-_.....
reaction
reagent
AgN03(aq). warm
Br2(aq)
in an excess
.._...
Fol
ElI8mlner's
Use
.....
result
i, excess of NH3(aq)
I, white solid formed which has Mr =379.2
I
I
I
----_._-
I Mn0 4 - is decolourised;
= 138
._._.!,
NaOH(aq) at room
I temperature
-- _.-
'--
1---'--'-
..
- -..-._-.
In this question, when identifying functional groups, your answers should be unambiguous.
(8)
(I)
(II)
(iii)
Based only on reaction 4, give the names of two different functional groups that
could be present in W .
.................................. and
(iv)
Which of the functional groups you have named in (III) is confirmed by reaction 5?
Explain your answer.
.............................................................................................................................. [5]
(b) Deduce the molecular formula of the organic product formed in reaction 3.
[1]
9547/02JOIN/11
..J
478368513
13
1111111111 111111111111111111111111111111111111111111111
(e)
(i)
For
Examiner's
U$(J
(II)
(ill)
Explain clearly how the formation of this compound shows that compound W is an
aromatic compound rather than an aliphatic compound.
(Iv)
(v)
.............................................................................................................................. [6]
(d) You now have enough information to determine the structural formula of W.
(i)
(Ii)
Explain clearly why you have placed each of the two functional groups in their
particular positions .
.............................................................................................................................. [4]
[Total: 16]
9647/02/0/N/11
478368514
14
111111111111111111111111111111111111111111111111111111
BLANK PAGE
~UCLES
9647102l01N/11
..
478368515
1111111111111111111111111111111111111111111111111111111
15
BLANK PAGE
9647/02JO/N/11
- 478368516
IIIIIIIIIIIIIIIIIIIIIIIIIIIII'IIIIIIIIII~
16
I1III11111111
BLANK PAGE
Permission to reproduce ~ems Where third-party owned matorial protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made 'at the publisher (UClES) to trace copyright holders, but II any hems requiring clearance have unwIttingly been included, the
publisher wW be pleased 10make amends at the earliest possible opportun~.
Univol5ity of Carrt>rll1ge International Examlnatlons is part of the Cambridge Assessment Group. Cambridge Assessmem ts the brand name of University 01
Cambridge Local ExaminaUons Syndicate (UCLES), which Is itseW a department of Ihe University of Cambridge .
9647/02l0/N/l1
..J