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Marking suggestions
1(a)
1(b) (i)
P4O10/P2O5/SiO2 (1)
Allow SO2
1(b) (ii)
Acidbase (1)
1(b) (iii)
1(c)
2(a)
2(b) (i)
2(b) (ii)
2(b) (iii)
2(c)
2(d)
3d
4s
Fe2+ [Ar]
Fe3+ [Ar]
Marking suggestions
(1) each
The Fe3+ has a half-filled set of 3d orbitals/only one electron in each
d orbital/minimum electron repulsion (1);
hence it is more energetically stable than Fe2+ (1)
2(e)
3(a)
3(b)
3(c) (i)
3(c) (ii)
3.3 (1)
IRON
IRON
Pit in iron
containing
electrolyte
3.1 (1)
150
A2 LEVEL
Marking suggestions
3(d) (i)
Platinum
Solution of
Fe2+(aq)
and Fe3+(aq)
SS
Tin
Solution of
Sn2+(aq)
(1) for left beaker; (1) for right beaker; (1) for salt bridge;
(1) for standard conditions: all solutions 1.0 mol dm3; stated
temperature usually 298 K; 1 atm pressure
3(d) (ii)
0.91 V (1)
Ignore sign
3(d) (iii)
Marking suggestions
4(a)
Catalyst (1)
4(b)
4(c) (i)
1. NH3/H2O/en (1)
2. CN/edta4 (1)
4(c) (ii)
4(c) (iii)
It indicates the stability of the complex (1); the higher the value, the
more stable the complex compound compared to reactants (1)
4(c) (iv)
[Cu(CN)4(H2O)2]2 (1)
4(c) (v)
H2O
H3N
Cu2+
NH3
NH3
H3N
H2O
4(d) (ii)
A2 LEVEL
151