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AIEEE 2009
CHEMISTRY
1.For a melting of a solid at 250C, the fusion process requires energy equivalent to 2906 J to be added to
system considering the process to be reversible at fusion point, the entropy change for the process is
a)
9.75 J K1
b)
Insufficient data
11.272 J K1
c)
2.33 J K1
d)
d)
infinity
positive b)
negative
c)
zero
3.1 mole of an ideal gas 300 K is expanded isothermally from an initial volume of 1L to 10 L.
The E for this process is (R=2 cal.K1mol1)
a)
163.7 cal
b)
1381.1 cal
c)
c)
x+y
9 lit atm d)
zero
4.S+32O2SO3+2xkcal...(1)
SO 2 + 1 2 O 2 SO 3 + y kcal ..... ( 2 )
Find out the heat of formation of SO2
a)
2xy
b)
2x+y
d)
2xy
H=HPHR b)
H=HPdHR
H=dHP+dHRc)
H=dHpdHR d)
(H+TS)mustbenegative
Smust be negative
c)
b)
d)
c)
8.If the enthalpy of vapourisation of water is 186.5 J mol1,the entropy of its vapourisation will be
a)
0.5JK1mol1 b)
2.0 JK1mol1
1.0JK1mol1 c)
1.5 JK1mol1 d)
9.All the naturally occuring processes proceed spontaneously in a direction which leads to
a)
Decrease of entropy
Increase of free energy d)
b)
Increase of Enthalpy
Decrease of free energy
c)
10.The heat of formation of COand CO2are -26.4 kcal and -94 kcal respectively. Heat of combustion of
CO will be
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a)
26.4 kcal
+52.8
b)
-67.6 kcal
c)
-120.6 kcal
d)
11.In which of the following neutralisation reaction, the heat of neutralisation will be highest.
a)
KOH
d)
NH4OHand H2SO4
b)
CH3COOHand NH4OH
HCland NaOH c)
CH3COOHand
12.Heat of neutralisation of strong acid against strong base is constant and is equal to
a)
-13.7 kcal
all of the above
b)
-57 kJ c)
5.7104J
d)
13.The number of atoms in 100g of an FCC crystel with density d=10g/cm3and cell edge as 200 pm is
equal to
a)
31025 b)
51024 c)
11025 d)
21025
14.For the reaction H2Cl2sunlight2HCl taking place on water, the order of reation is
a)
b)
c)
d)
15.In which of the following species is the underlined carbon having sp3hybridisation
a)
CH3 COOH
CH2CHCH3
b)
CH3CH2OH
c)
CH3COCH3
d)
c)
O2
b)
O2
c)
O2
d)
O22
Ionic bond
b)
Hydrogen bond
Covalent bond c)
Co-ordinate bond
BCl3
b)
PCl3
c)
PCl5
d)
NH3
HF
d)
NH3
CCl4
b)
CHCl3 c)
c)
chemical inertness of
metals
22.The hybrid states of carbon in diamond, graphite, and acetylene are respectibvely.
a)
sp2spsp3
sp2sp3sp
b)
spsp2sp3
c)
sp3sp2sp
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d)
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23.In a homonuclear molecule which of the following set of orbitals are degenerate?
a)
2s1s
b)
2px2py c)
2px2pz d)
2pz, 2px
FClBrI d)
IBrClF
H2S
HF
ClBrIF b)
FIBrCl c)
H2O
b)
H2Se
c)
d)
b)
d)
c)
CH4
b)
NH3
c)
H2O
d)
CO2
c)
1050
d)
750
12scharacter
c)
900
b)
1800
14scharacter
23scharacter
b)
32scharacter
d)
C-O
b)
C-Br
c)
C-F
d)
C-S
c)
Concentrated
d)
Polar solvents b)
All solvents
Non-polar solvents
32.Element X is strongly electropositive and element Y is strongly electronegative. Both are univalent.
The compound formed would be
a)
XY
b)
XY
c)
X-Y
d)
XY
33.Among the 2nd group elements, the metal forming predominently covalent compund is
a)
Be
b)
Mg
c)
Sr
d)
Ca
Co-valent character
Oxygen bonding character
b)
d)
c)
ClO2
b)
CO2
c)
NO2
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d)
SO2
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a)
P>S
b)
C >N
c)
Br >Cl d)
Sr >Ca
Al & Si c)
Fe & S d)
38.In the modern periodic table, elements are arranged in the increasing order of
a)
Atomic mass b)
Isotopic number
Atomic number c)
Mass number
d)
b)
c)
d)
Cl
Na>Mg>Al>Si
Si>Mg>Al>Na
b)
Mg>Na>Al>Si
c)
Al>Mg>Na>Si
d)
N3>O2>F>Na b)
Na>F>O2>N3
N3>Na>O2>F c)
Na>O2>N3>F d)
lowest IE
highest IE
smallest size b)
highest electro negtivity
c)
N3
b)
Na
c)
d)
Ti
c)
d)
10
c)
d)
Li
d)
Cl
b)
b)
Mg
b)
Rb
c)
Ionic Radiaus
Boiling point
b)
Atomic radius
c)
IE
d)
48.Which of the following requires radiation of highest frequency to cause emission of electron?
a)
Na
b)
Mg
c)
d)
49.Which of the following is associated with biggest jump between 2nd and 3rd IE?
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Ca
d)
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a)
1s22s22p2
1s22s22p1
b)
1s22s22p63s1 c)
1s22s22p63s2 d)
50.Among the following which one will have highest electron affinity?
a)
1s1
1s22s22p5
b)
1s22s1 c)
1s22s22p4
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d)