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p1
No. 1
p1
Oblique
Patterson symmetry p 2
Origin arbitrary
Asymmetric unit
0 x 1;
0y1
Symmetry operations
(1) 1
Multiplicity,
Wyckoff letter,
Site symmetry
Reection conditions
General:
(1) x, y
no conditions
92
Copyright 2006 International Union of Crystallography
Oblique
p2
Patterson symmetry p 2
p2
No. 2
Origin at 2
0 x 12 ;
Asymmetric unit
0y1
Symmetry operations
(1) 1
(2) 2 0, 0
Multiplicity,
Wyckoff letter,
Site symmetry
Reection conditions
General:
(1) x, y
(2) x,
y
no conditions
Special: no extra conditions
1
2
, 12
1
2
,0
0, 12
0, 0
93
Copyright 2006 International Union of Crystallography
pm
No. 3
p1m1
Rectangular
Patterson symmetry p 2 m m
Origin on m
0 x 12 ;
Asymmetric unit
0y1
Symmetry operations
(1) 1
(2) m 0, y
Multiplicity,
Wyckoff letter,
Site symmetry
Reection conditions
General:
(1) x, y
.m.
1
2
.m.
0, y
(2) x,
y
no conditions
Special: no extra conditions
,y
94
Copyright 2006 International Union of Crystallography
Rectangular
Patterson symmetry p 2 m m
p1g1
pg
No. 4
Origin on g
Asymmetric unit
0 x 12 ;
0y1
Symmetry operations
(1) 1
(2) b 0, y
Multiplicity,
Wyckoff letter,
Site symmetry
Reection conditions
General:
(1) x, y
(2) x,
y + 12
0k: k = 2n
95
Copyright 2006 International Union of Crystallography
cm
No. 5
c1m1
Rectangular
Patterson symmetry c 2 m m
Origin on m
0 x 12 ;
Asymmetric unit
0y
1
2
Symmetry operations
For (0, 0)+ set
(1) 1
(2) m 0, y
For ( 12 , 12 )+ set
(1) t( 21 , 12 )
(2) b
1
4
,y
Reection conditions
Coordinates
Multiplicity,
Wyckoff letter,
Site symmetry
(0, 0)+ ( 12 , 12 )+
(1) x, y
General:
hk: h + k = 2n
h0: h = 2n
0k: k = 2n
(2) x,
y
.m.
0, y
[2] p m (3)
none
1; 2
96
Copyright 2006 International Union of Crystallography
Rectangular
2mm
Patterson symmetry p 2 m m
p2mm
p2mm
No. 6
Origin at 2 m m
0 x 12 ;
Asymmetric unit
0y
1
2
Symmetry operations
(1) 1
(2) 2 0, 0
(3) m 0, y
(4) m x, 0
Multiplicity,
Wyckoff letter,
Site symmetry
Reection conditions
General:
(1) x, y
(2) x,
y
(3) x,
y
(4) x, y
no conditions
Special: no extra conditions
.m.
1
2
.m.
0, y
0, y
..m
x, 12
x,
12
..m
x, 0
x,
0
2mm
1
2
, 12
2mm
1
2
,0
2mm
0, 12
2mm
0, 0
,y
1
2
, y
[2] p 1 1 m (p m, 3) 1; 4
[2] p 2 1 1 (p 2, 2)
1; 2
none
[2] p 2 m g (a = 2a) (7); [2] p 2 g m (b = 2b) (p 2 m g, 7); [2] c 2 m m (a = 2a, b = 2b) (9)
97
Copyright 2006 International Union of Crystallography
p2mg
2mm
No. 7
p2mg
Rectangular
Patterson symmetry p 2 m m
Origin at 2 1 g
0 x 14 ;
Asymmetric unit
0y1
Symmetry operations
(1) 1
(2) 2 0, 0
(3) m
1
4
,y
(4) a x, 0
Multiplicity,
Wyckoff letter,
Site symmetry
Reection conditions
General:
(1) x, y
(2) x,
y
(3) x + 12 , y
(4) x + 12 , y
h0: h = 2n
Special: as above, plus
.m.
1
4
,y
3
4
, y
no extra conditions
2..
0, 12
1
2
, 12
hk: h = 2n
2..
0, 0
1
2
,0
hk: h = 2n
[2] p 1 m 1 (p m, 3) 1; 3
[2] p 2 1 1 (p 2, 2)
1; 2
none
[2] p 2 g g (b = 2b) (8)
98
Copyright 2006 International Union of Crystallography
Rectangular
2mm
p2gg
Patterson symmetry p 2 m m
p2gg
No. 8
Origin at 2
0 x 12 ;
Asymmetric unit
0y
1
2
Symmetry operations
(1) 1
(2) 2 0, 0
(3) b
1
4
,y
(4) a x, 14
Multiplicity,
Wyckoff letter,
Site symmetry
Reection conditions
General:
(1) x, y
(2) x,
y
(3) x + 12 , y + 12
(4) x + 12 , y + 12
h0: h = 2n
0k: k = 2n
Special: as above, plus
2..
1
2
2..
0, 0
,0
0, 12
hk: h + k = 2n
, 12
hk: h + k = 2n
1
2
[2] p 1 1 g (p g, 4)
[2] p 2 1 1 (p 2, 2)
none
none
1; 4
1; 2
99
Copyright 2006 International Union of Crystallography
c2mm
2mm
No. 9
c2mm
Rectangular
Patterson symmetry c 2 m m
Origin at 2 m m
0 x 14 ;
Asymmetric unit
0y
1
2
Symmetry operations
For (0, 0)+ set
(1) 1
(2) 2 0, 0
For ( 12 , 12 )+ set
(1) t( 21 , 12 )
(2) 2
1
4
, 14
(3) m 0, y
(4) m x, 0
,y
(4) a x, 14
(3) b
1
4
Reection conditions
Coordinates
Multiplicity,
Wyckoff letter,
Site symmetry
(0, 0)+ ( 12 , 12 )+
(1) x, y
(2) x,
y
(3) x,
y
General:
(4) x, y
hk: h + k = 2n
h0: h = 2n
0k: k = 2n
Special: as above, plus
.m.
0, y
0, y
no extra conditions
..m
x, 0
x,
0
no extra conditions
2..
1
4
2mm
0, 12
no extra conditions
2mm
0, 0
no extra conditions
, 14
3
4
, 14
hk: h = 2n
IIb
[2] c 1 1 m (c m, 5)
[2] c 2 1 1 (p 2, 2)
[2] p 2 g g (8)
[2] p 2 g m (p 2 m g, 7)
[2] p 2 m g (7)
[2] p 2 m m (6)
none
(1; 4)+
(1; 2)+
1; 2; (3; 4) + ( 12 , 12 )
1; 4; (2; 3) + ( 12 , 12 )
1; 3; (2; 4) + ( 12 , 12 )
1; 2; 3; 4
International Tables for Crystallography (2006). Vol. A, Plane group 10, p. 101.
Square
Patterson symmetry p 4
p4
p4
No. 10
Origin at 4
0 x 12 ;
Asymmetric unit
0y
1
2
Symmetry operations
(1) 1
(3) 4+ 0, 0
(2) 2 0, 0
(4) 4 0, 0
Multiplicity,
Wyckoff letter,
Site symmetry
Reection conditions
General:
(1) x, y
(2) x,
y
(3) y,
x
(4) y, x
no conditions
Special:
2..
1
2
,0
hk: h + k = 2n
4..
1
2
, 12
no extra conditions
4..
0, 0
no extra conditions
0, 12
101
Copyright 2006 International Union of Crystallography
International Tables for Crystallography (2006). Vol. A, Plane group 11, p. 102.
p4mm
4mm
No. 11
p4mm
Square
Patterson symmetry p 4 m m
Origin at 4 m m
0 x 12 ;
Asymmetric unit
0 y 12 ;
xy
Symmetry operations
(1) 1
(5) m 0, y
(3) 4+ 0, 0
(7) m x, x
(2) 2 0, 0
(6) m x, 0
(4) 4 0, 0
(8) m x, x
Generators selected (1); t(1, 0); t(0, 1); (2); (3); (5)
Positions
Coordinates
Multiplicity,
Wyckoff letter,
Site symmetry
Reection conditions
General:
(1) x, y
(5) x,
y
(2) x,
y
(6) x, y
(3) y,
x
(7) y, x
(4) y, x
(8) y,
x
no conditions
Special:
..m
x, x
x,
x
.m.
x, 12
x,
12
1
2
.m.
x, 0
x,
0
0, x
2 m m.
1
2
,0
0, 12
4mm
1
2
, 12
no extra conditions
4mm
0, 0
no extra conditions
x,
x
,x
x, x
no extra conditions
, x
no extra conditions
0, x
no extra conditions
1
2
hk: h + k = 2n
[2] p 2 1 m (c 2 m m, 9)
1; 2; 7; 8
[2] p 2 m 1 (p 2 m m, 6) 1; 2; 5; 6
none
[2] c 4 m g (a = 2a, b = 2b) (p 4 g m, 12)
International Tables for Crystallography (2006). Vol. A, Plane group 12, p. 103.
Square
4mm
Patterson symmetry p 4 m m
p4gm
p4gm
No. 12
Origin at 4 1 g
0 x 12 ;
Asymmetric unit
0 y 12 ;
y 12 x
Symmetry operations
(1) 1
(5) b
1
4
,y
(3) 4+ 0, 0
(7) g( 12 , 12 ) x, x
(2) 2 0, 0
(6) a x, 14
(4) 4 0, 0
(8) m x + 12 , x
Generators selected (1); t(1, 0); t(0, 1); (2); (3); (5)
Positions
Coordinates
Multiplicity,
Wyckoff letter,
Site symmetry
Reection conditions
General:
(1) x, y
(5) x + 12 , y + 12
(2) x,
y
(6) x + 12 , y + 12
(3) y,
x
(7) y + 12 , x + 12
(4) y, x
(8) y + 12 , x + 12
h0: h = 2n
0k: k = 2n
Special: as above, plus
..m
x, x + 12
2 . mm
1
2
4..
0, 0
,0
x,
x + 12
x + 12 , x
x + 12 , x
0, 12
hk: h + k = 2n
, 12
hk: h + k = 2n
1
2
[2] p 2 1 m (c 2 m m, 9)
[2] p 2 g 1 (p 2 g g, 8)
none
none
no extra conditions
1; 2; 7; 8
1; 2; 5; 6
103
Copyright 2006 International Union of Crystallography
International Tables for Crystallography (2006). Vol. A, Plane group 13, p. 104.
p3
No. 13
p3
Hexagonal
Patterson symmetry p 6
Origin at 3
0 x 23 ;
0, 0 12 , 0
Asymmetric unit
Vertices
2
3
0 y 23 ; x (1 + y)/2;
, 13 31 , 23 0, 12
y min(1 x, (1 + x)/2)
Symmetry operations
(2) 3+ 0, 0
(1) 1
(3) 3 0, 0
Multiplicity,
Wyckoff letter,
Site symmetry
Reection conditions
General:
(1) x, y
(2) y,
xy
(3) x + y, x
no conditions
Special: no extra conditions
3..
2
3
, 13
3..
1
3
, 23
3..
0, 0
104
Copyright 2006 International Union of Crystallography
International Tables for Crystallography (2006). Vol. A, Plane group 14, p. 105.
Hexagonal
3m
Patterson symmetry p 6 m m
p3m1
p3m1
No. 14
Origin at 3 m 1
0 x 23 ;
0, 0 23 , 13
Asymmetric unit
Vertices
1
3
0 y 23 ;
, 23
x 2y;
y min(1 x, 2x)
Symmetry operations
(1) 1
(4) m x, x
(2) 3+ 0, 0
(5) m x, 2x
(3) 3 0, 0
(6) m 2x, x
Multiplicity,
Wyckoff letter,
Site symmetry
Reection conditions
General:
(1) x, y
(4) y,
x
(2) y,
xy
(5) x + y, y
(3) x + y, x
(6) x, x y
no conditions
Special: no extra conditions
.m.
x, x
3m.
2
3
, 13
3m.
1
3
, 23
3m.
0, 0
x, 2x
2x,
x
IIa
IIb
[3] p 1 m 1 (c m, 5)
1; 4
[3] p 1 m 1 (c m, 5)
1; 5
[3] p 1 m 1 (c m, 5)
1; 6
none
[3] h 3 m 1 (a = 3a, b = 3b) (p 3 1 m, 15)
105
Copyright 2006 International Union of Crystallography
International Tables for Crystallography (2006). Vol. A, Plane group 15, p. 106.
p31m
3m
No. 15
p31m
Hexagonal
Patterson symmetry p 6 m m
Origin at 3 1 m
0 x 23 ;
0, 0 12 , 0
Asymmetric unit
Vertices
0 y 12 ;
2 1
1 1
3, 3
2, 2
x (1 + y)/2;
y min(1 x, x)
Symmetry operations
(1) 1
(4) m x, x
(2) 3+ 0, 0
(5) m x, 0
(3) 3 0, 0
(6) m 0, y
Multiplicity,
Wyckoff letter,
Site symmetry
Reection conditions
General:
(2) y,
xy
(5) x y, y
(1) x, y
(4) y, x
(3) x + y, x
(6) x,
x + y
no conditions
Special: no extra conditions
..m
x, 0
3..
1
3
3.m
0, 0
, 23
0, x
2
3
x,
x
, 13
IIa
IIb
[3] p 1 1 m (c m, 5)
1; 4
[3] p 1 1 m (c m, 5)
1; 5
[3] p 1 1 m (c m, 5)
1; 6
none
[3] h 3 1 m (a = 3a, b = 3b) (p 3 m 1, 14)
106
Copyright 2006 International Union of Crystallography
International Tables for Crystallography (2006). Vol. A, Plane group 16, p. 107.
Hexagonal
Patterson symmetry p 6
p6
p6
No. 16
Origin at 6
0 x 23 ;
0, 0 12 , 0
Asymmetric unit
Vertices
2
3
0 y 12 ;
, 13 21 , 12
x (1 + y)/2;
y min(1 x, x)
Symmetry operations
(1) 1
(4) 2 0, 0
(2) 3+ 0, 0
(5) 6 0, 0
(3) 3 0, 0
(6) 6+ 0, 0
Multiplicity,
Wyckoff letter,
Site symmetry
Reection conditions
General:
(2) y,
xy
(5) y, x + y
(1) x, y
(4) x,
y
(3) x + y, x
(6) x y, x
no conditions
Special: no extra conditions
2..
1
2
,0
0, 12
3..
1
3
, 23
2
3
6..
0, 0
1
2
, 12
, 13
[3] p 2 (2)
none
none
1; 4
107
Copyright 2006 International Union of Crystallography
International Tables for Crystallography (2006). Vol. A, Plane group 17, pp. 108109.
p6mm
6mm
No. 17
p6mm
Hexagonal
Patterson symmetry p 6 m m
Origin at 6 m m
Asymmetric unit
Vertices
0 x 23 ;
0, 0 12 , 0
0 y 13 ;
2 1
3, 3
x (1 + y)/2;
y x/2
Symmetry operations
(1)
(4)
(7)
(10)
1
2 0, 0
m x, x
m x, x
(2)
(5)
(8)
(11)
3+
6
m
m
0, 0
0, 0
x, 2x
x, 0
(3)
(6)
(9)
(12)
3
6+
m
m
0, 0
0, 0
2x, x
0, y
108
Copyright 2006 International Union of Crystallography
No. 17
CONTINUED
p6mm
Generators selected (1); t(1, 0); t(0, 1); (2); (4); (7)
Positions
Coordinates
Multiplicity,
Wyckoff letter,
Site symmetry
12
Reection conditions
General:
(1)
(4)
(7)
(10)
x, y
x,
y
y,
x
y, x
(2)
(5)
(8)
(11)
y,
xy
y, x + y
x + y, y
x y, y
(3)
(6)
(9)
(12)
x + y, x
x y, x
x, x y
x,
x + y
no conditions
.m.
x, x
x, 2x
..m
x, 0
0, x
2mm
1
2
,0
0, 12
3m.
1
3
, 23
2
3
6mm
0, 0
2x,
x
x,
x
1
2
x,
x
x,
0
x,
2x
0, x
, 12
, 13
1;
1;
1;
1;
1;
2;
2;
4;
4;
4;
3;
3;
7;
8;
9;
10; 11; 12
7; 8; 9
10
11
12
109
2x, x
x, x