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g) 500 mL 100 ppm Ag+ from pure reagent solid silver nitrate (answer : 0.05 g) (Oct
2006 & Oct 2007)
6. The density of commercial concentrated HNO 3 is 1.41 g/mL. The concentrated acid contains
69% (wt/wt) of pure acid. Determine:
a) the quantity in gram of pure HNO3 in 1000 mL of the concentrated HNO 3(answer :
972.9 g)
b) the molarity of the commercial concentrated acid (answer : 15.44 M)
c) the volume (in mL) of concentrated acid needed to prepare 500 mL 0f 2.50 M HNO 3
solution (answer : 80.96 mL)
d) How mililiters of KOH solution, prepared by dissolving 60.0 g of KOH in 100 mL of
solution, are needed to prepare 450 mL of a 0.70 M solution (answer : 29.41 mL)
7. A student wishes to prepare 500 mL of 25 ppm solution of barium. Calculate:
a) How many mililiters of 1000 ppm barium would be required if he/she were to prepare
this by dilution? (answer : 12.5 mL)
b) If he/she were to prepare this from pure solid BaCl 2.2H2O, how many grams would be
required? (answer : 22.4 mg)
8. Tell how you would prepare 250 mL of a 5.00 M solution of H3PO4 from its commercial reagent
(purity of 85% w/w with specific gravity of 1.69) (answer : 85.27 mL)
9. The density of concentrated HCl is 1.19 g/mL. This concentrated acid contains 36% (w/w)
pure acid. Calculate:
a) the number of grams of pure HCl in 1.0 L the concentrated HCl (answer: 428.4 g/L)
b) the molarity of concentrated acid (answer: 11.74 M)