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Sri Chaitanya IIT Academy., India.

A right Choice for the Real Aspirant


Central Office , Madhapur Hyderabad
Sec: Sr. IPLCO
Dt: 02-08-14
Time : 3 Hours
Marks : 360

JEE MAIN 2013


PTM-1

Max

KEY SHEET

KEY SHEET
PHYSICS
Q.NO
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30

ANSWER
4
1
2
1
3
1
3
2
3
2
1
3
4
2
3
1
2
3
1
4
1
3
2
1
3
2
1
4
2
3

CHEMISTRY
Q.NO
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60

ANSWER
1
3
2
1
3
1
3
1
3
1
1
1
1
3
3
2
1
4
3
3
3
4
2
4
3
2
4
4
4
2

MATHS
Q.NO
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90

ANSWER
2
1
4
3
2
1
1
4
1
3
2
1
3
1
2
1
3
2
1
1
1
3
4
3
2
4
3
2
4
4

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MAIN_(2013)_PTM-1

02-08-14_Sr.IPLCO_JEE

HINTS
PHYSICS
1.
2.
3.
4.
5.

Conceptual
Conceptual
Conceptual
Conceptual
Let the particles meet after a time t1 after the projection of the second particle. Then for their motion
upto their meeting, we have;
first particle
second particle
Initial velocity
u
u
acceleration
-g
gtime of motion
t+t1
t1
u g t t1
u tg1
final velocity
The particle will meet, when first particle is comparing down and second particle is going up. Their
final velocity must be equal in magnitude, so
u tg1 u g t t1

u t

g 2

t1

In this time, height


1
h ut1 gt12
2
u t
g u t
u
g 2
2 g 2

u 2 gt 2
or h

8
2g
Thus

u t

g 2

t t1 t
u t

g 2

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6.

02-08-14_Sr.IPLCO_JEE

Consider motion of stones with respect to the balloon. At the instant of release of stones, the initial
velocity of both stones w.r.t. the balloon is zero. The acceleration of stone w.r.t. the ballon

astone balloon g a g a
Where a is the acceleration of balloon which is = 15.7 m/s2
1
s1 0 astone balloon t12
Now
2
t1 4 6 10 s

s1

1
g a X 102
2

1
9.8 15.7 X 102 m
2
1
s2 0 g a t22
2

and

Where t2 6s

1
9.8 15.7 X 62
2
s
and
s2 :
The distance between 1
s s1 s2
1
9.8 15.7 102 62
2
= 816 m
The displacement, s 2 R cos and acceleration, a g cos

7.

s2

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02-08-14_Sr.IPLCO_JEE

1
2

s at 2
or

8.

2 R cos

1
g cos t 2
2

R
g
if u is the velocity of projection, then
0 u a X 3.5
u 3.5a 3.5 X 7.5
or
=26.25m/s

t2

Now

1
y u X 1 a X 12
2
26.25

Also

yh u X 2
26.25 X 2

9.
10.
11.

1
X a X 22
2

1
X 7.5 X 22
2

Conceptual
Conceptual
dv
2.5 v
dt

dv
2.5dt
v

2.5 t 0 2 v1/ 2
t 2s

12.

h 15m

1
X 7.5 X l 2 22.5m
2

6.25

v 1/2 dv 2.5 dt
0

0
6.25

1 2
gt
2
v gt and after the collision, v gt (straight line)
Collison is perfectly elastic then ball reaches to same height again and again with same velocity.
h

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MAIN_(2013)_PTM-1

13.

2
0
R u sin 2 60

2
2g

02-08-14_Sr.IPLCO_JEE

3u 2

4g
u 2 sin 2 600 3u 2
H

2g
8g
2

21u 2
R
AB H 2
8g
2

14.

From the graph,


22.5
a 22.5
.s or
150
v
60
22.5
0 v.dv 0 22.5 150 X

s ds

2
v 22.5 X 60 22.5 X 60
2
150
2
v 46.47 m / s
Relative velocity of P with respect to S should be along PS or absolute velocity components
perpendicular to PS should be same.
2u

sin u sin 300


3
3
sin 1
4
dv
f v. a bx
dx
2

15.

16.

or

vdv a bx dx
0

v 2ax bx 2

At other station, v=0


2a
x
b
Further acceleration will change its direction when,
a
f=0 or a-bx=0 or x
b
At this x, velocity is maximum.

17.

a
a
Using Eq. (i) vmax 2a b
b b
Conceptual

Sr.IPLCO_JEE-MAIN_Solutions

a
b
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MAIN_(2013)_PTM-1

18.

19.
20.

See the hint of example 1.9


Least count of vernier calipers
a
1mm

0.1mm 0.01cm
N 1 10
Side of cube = (10) (1 mm) + (1) (LC)
or
a=10 mm+0.1 mm
or
a=10.1 mm
or
a=1.01 cm
mass
m

3
volume a
2.736

3
1.01
= 2.65553 g/cm3
= 2.66g/cm3

2
.x is dimensionless

v.dv ads

22.

0
2

vdv

12 m

ads

v
= area under a-s graph from s=0 to s=12m.
2
2 12 6 4
24m 2 / s 2
or
v 48m / s 4 4m / s
v A0 0
l1 3

l2 2
VA1
3
3

VA2 3 2 5
v
v A1 3x 0.6v
5
t =78.4 - 40.6 =37.8
Dt =Dt2 +Dt1 =0.2 +0.4 =0.6

21.

02-08-14_Sr.IPLCO_JEE

t Dt =( 37.8 0.6) C
0

23.
24.

Conceptual
dv
dv
kvdt
dt
v
ds
dv
k dt
dt
v
dv
kds v log v ks
kv 2

v ue ks
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MAIN_(2013)_PTM-1

25.

Conceptual

26.

da
5/6
From the graph
dt

27.

02-08-14_Sr.IPLCO_JEE

d d 2 s

5/6
dt dt 2
d 2s 5
Integrate the above
t
dt 2 6
ds 5t 2
Integrate again

dt 12
5t 3
Integrate again s
36
5
3
Distance travelled from 0 to 6s = s1 6 30m
36
5 2
Velocity at t 6s v t 15 m / s
12
From 6 to 12 s, u 15 m / s a 5 m / s 2
1
s2 ut at 2 180m
2
Total distance travelled = 30 180 210 m
dv
dv
k
2
2
v2
Resistance force v m kv
dt
dt
m
v
h
dv
k
dv
v
kh
dx
k / m
log 0

, v0 v
m0 ,
v
v m
m
v
k log 0
h
v

k
dv
k
2
dt
Also 2 dt v dv
m 0
v
m
v0

h v0 v
t
.
v
vv0 ln 0
v

28.

x u2 cos 2t u1 cos 1t

x
also u1 sin 1 u2 sin 2
u1 cos 1 u2 cos 2
x sin 2
After solving we get t
u1 sin 2 1
t

29.

Conceptual

30.

M 30, f e 5.0cm and D 25cm. We know

D
25

M m0 X me m0 1 or 30 m0 1
f e
5.0

Which gives m0 5.0


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02-08-14_Sr.IPLCO_JEE

CHEMISTRY

31.

32.

(I) 0.5 mole O3 24 g O3 ;


(ii) 0.5g atom of oxygen = 8g
3.011X 10 23
(iii)
X 32 16 g O2
6.022 X 1023
5.6
X 44 g CO2 11g CO2
(iv)
22.4
No.of moles of CO2 in 100 g mixture
66

1.5
44
No.of moles of H2 in 100g mixture
34

17
2
100
M average
5.40
18.5
5.4
V .D.
2.7
2

33.

Let 1 mole of mixture has x mole N 2O4


2 x 27.6= x 92 1 x 46; x 0.2

34.
35.

Conceptual
1 mole N 2 H 4 loses 8 mole e ; 1 mole N loses 4 mole of e
New oxidation state of N is 2 4 2
K 2Cr2O7 X n X 5O3 Cr 3

36.

6 X 103 X 6 5 n X 9 X 103 n 1

37.

38.
39.
40.

2 BrO3 12 H 10 Br 6 Br2 6 H 2O

10 mole e required for formation of 6 moles of Br2


10 5
n factor of Br2
6 3
mol.wt.
m
3M

eq. wt.
n
5/3
5
Balancing the equation, we have
K 2Cr2O7 H 2 SO4 3SO4 K 2 SO4 Cr2 SO4 3 H 2O

N1V1 N 2V2
0.5 X 20 0.4 X 25
Since, phenolphthalein indicates only conversion of Na2CO3 into NaHCO3 hence, x mL , of HCl
will be further required to convert NaHCO3 to H 2CO3 . So, total volume of HCl required to convert
Na2CO3 into H 2CO3 x x 2 x mL H 2CO3 .

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MAIN_(2013)_PTM-1

41.

42.
43.

44.

45.
46.

47.
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.

02-08-14_Sr.IPLCO_JEE

1
6.8
P.E.
3.4eV
2
2
13.6
Q En 2 3.4
n
n=2 or first excited state
Conceptual
m 1010 g 1013 kg ;
0.0001
V
X 10 6 X 10 2 1014 m sec 1
100
h
x.p
4
h
h
x

;
4p 4 .mv
6.62 X 1034
x
4 X 3.14 X 1013 X 1014
6.62 10 34
x
X 27 ; x 5.2 X 108 m
12.56 10
1 1
1
1
1
RZ 2 2 2 RX 32 2 2

3
n1 n2
1
3R;
3R
Conceptual
l =2;
number of degenerate orbitals = 2l 1 9;
1
maximum total spins = 9 X
2
maximum multiplicity = 2 S 1
9
2 X 1 10
2
minimum total spins =0
minimum multiplicity = 2 0 +1 =1
Conceptual
h
; l 1 for p-orbital.
Orbital angular momentum l l 1
2
Conceptual
Conceptual
Conceptual
Conceptual
Conceptual
Conceptual
Conceptual
Conceptual
Conceptual
Conceptual
Conceptual
En

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MAIN_(2013)_PTM-1

60.

02-08-14_Sr.IPLCO_JEE

Mass of acetic acid adsorbed by 2g charcoal = 100 X 10-3 X(0.6-0.5) X 60


x 0.6
0.6;

0.3
m
2

MATHEMATICS
61.

The equation of the line L be y 2 m x 8 , m 0


2

coordinates of P and Q are P 8 , 0 and Q 0, 2 8m .


m

So OP OQ 8

62.

63.

2
2
2 8m 10
8 m 10 2
m
m

2
X 8 m 18
m

So, absolute minimum value of OP OQ 18


5
Solving given equations we get x
3 4m
x is an integer, if 3 4m 1, 5
2 4 2 8

m , , ,
4 4 4 4
So m has two integral values.
If p1 and p2 be the distance between parallel sides and be the angle between adjacent sides, then

Required area= p1 p2 cos ec


1
p2
Where p1
2 ,
1 m

1 n
2

(distance between | | lines)


mn
tan
and
1 mn
Re quired area

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64.

02-08-14_Sr.IPLCO_JEE

Image of the point P about the line y x is Q 1, 4


Transformation through a 2 units along the positive direction of x axis , then new point

R 1 2, 4 ie, R(3, 4)

OR OR ' 5
and tan 4 / 3
4
3
sin
and cos
5
5

Then , final position of the point is OR ' cos / 4 , OR 'sin / 4


1
1
1
1

5
cos
sin ,5
cos
sin
2
2
2

2

1
7


,
2
2

65.

x y
1 and let the axis be rotated through an angle and let X , Y be the new
a b
coordinates of any point P x, y in the plane, then
x X cos Y sin , y X sin Y cos , the equation of the line with reference to original
x y
coordinates is 1
a b
X cos Y sin X sin Y cos

1
ie,
(i)
a
b
and with reference to new coordinates is
X Y
1
(ii)
p q
Equation of L is

Comparing Eqs. (i) and (ii), we get


cos sin 1

.(iii)
a
b
p
sin cos 1

.(iv)
a
b
q
Squaring and adding Eqs. (iii) and (iv), we get
1 1
1
1
2 2 2
2
a b
p
q

66.

Let the coordinates of A be (a, 0). Then the slope of the reflected ray is
30
tan say
..(i)
5a

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02-08-14_Sr.IPLCO_JEE

Then the slope of the incident ray


20

tan (ii)
1 a
From Eqs. (i) and (ii),
tan tan

3
2

0
5 a 1 a

13
5
13
, 0
Thus, the coordinate of A is
5

3 3a 10 2a 0; a

2
2
1
2m
67.
Q

1!9! 3!7! 5!5! n !


1 2 X 10! 2 X 10! 10!
2m

10! 1!9!
3!7! 5!5!
n!
1
2m

2 10C1 2 10C3 2 10C5

10!
n!
1 10
2m
C1 10 C3 10 C5 10 C7 10 C9

10!
n!
m
1
2
10 1

2
10!
n!

m 9 and n 10
Hence, x-y+1=0 and x y 3 0 are perpendicular to each other, then orthocenter is the point of
intersection which is (-2, -1)

-2=2m-2n
and
-1=m-n

Point is 2m 2n, m n
68.

2
We have y cos x cos x 2 cos x 1
1
y 2 cos x cos x 2 2 cos 2 x 1
2
1
cos 2 x 2 cos 2 1 cos 2 x 2
2
1
cos 2 1
2
1
1 2sin 2 1 1
2
sin 2 1

2
Which is a straight line passing through , sin 1 and parallel to the x axis
2

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69.

70.

Q P 1
, 2 lies between the parallel lines x 2 y 1 and 2 x 4 y 15 , then
2
2

1 2 2 1
2

2
0

2 1 4 2 15
2

4 2
3

4
3
2

0
6

5
2
5

2
6

4 2
5 2


3
6
a, a fall between the lines x y 2 , then
aa2
0
aa2
a 1

0 or 1 a 1
a 1

71.

72.

02-08-14_Sr.IPLCO_JEE

a 1

Since Distance between parallel lines are same


Parallelogram is a rhombus
In rhombus diagonals are perpendicular to each other.
Hence, angle between diagonals / 2
When x is rotational :

let x
q
p
Then, n ! x 1.2.3.......n . an int eger
q

cos 2 n ! x 1 Q cos n 1

lim lim cos 2 m n ! x 1 1

m n

When x is irrational
Then, n ! x is not an integer
0 cos 2 n ! x 1

lim lim cos 2 m n ! x 0


m n

Thus, points are 2, 1 , 2,


2
1 2
Required area |
2 1
2

Sr.IPLCO_JEE-MAIN_Solutions

1 and 1, 0

1
1 1
| 4 2 sq unit.
0 2
1

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1 a a

73.

Q b 1 b 0
c

Applying C2 C2 C1 and C3 C3 C1
Then,
1 a 1 a 1
b 1 b
0 0
c
0
1 c
Let a 1 A, b 1 B and c 1 C , then
1
A
A
1 B B 0 0
1 C 0 C
1 BC 0 A C BC A B BC 0

or

1 1 1
2
.(i)
A B C
a
b
c
1 A 1 B 1 C

a 1 b 1 c 1
A
B
C
1 1 1
3
A B C
from eq. i
2 3
=1

74.

We have,

a 2 2a
0
a 2 4a

a2
0
a4

a 2, 4

75.

Q Equation AB is x y 1 , then coordinates of A and B are (1, 0) and (0, 1) respectively.


Coordinate of P is 1 , 1
2 2

PP1 is perpendicular to OA

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Equation of OP is y x
Then, OP1 PP1 1/ 2
We have, OM n 1 OPn Pn M n 1
2

2 OPn

Also,

Q y x
2 say
2
2
2
OPn1 OM n1 Pn1 M n 1

76.

1
n21 2 n2 n21
2
1 2
n 1 2 n2
2
1
n n 1
2
1
OPn n n 1
2
1
1
2 n 2 3 n 3
2
2
.
.
.
1
n 1 1
2
1 1
1
n 1 n
2 2
2
From figure

2
n

RS RS

........ i
PR 2r
PQ PQ

tan

........ ii
PR 2r
2
Multiplying Eqs. (i) and (ii),
tan

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tan cot

77.

02-08-14_Sr.IPLCO_JEE

RS .PQ

2r
RS PQ
2

2r

Let C h, k be the centre of the circle passing through the end points of the rod AB and PQ of
lengths a and b respectively, CL and CM be perpendiculars from C on AB and PQ respectively. Then
CA=CP (radii of the same circle)

a2
b2
h2
( AL a / 2 and MP b / 2)
4
4
4 h2 k 2 a 2 b2
k2

78.

Let AOL
A a cos , a sin

M a a cos , a sin

x a a cos

x a a cos
and

y a sin

.......... i

.......... ii

From Eqs. (i) and (ii),


2
x a y2 a2

x 2 y 2 2ax 0

x 2 y 2 2ax

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79.

02-08-14_Sr.IPLCO_JEE

Let h, k be any point in the set, then equation of circle is x h y k 9


2

2
2
But h, k lie on x y 25
then h 2 k 2 25
2 Distance between the centres of two circles 8

k2 8

4 h k 64
locus of h, k is 4 x 2 y 2 64
2

80.

Let coordinates of A and B are and , respectively.

2a, b 2
and 2 p, q 2
Equation of circle with AB as diameter.
x x y y 0

x 2 y 2 x y 0

x 2 y 2 2ax 2 py b 2 q 2 0
Radius

p2 b2 q2

81.

b2 p 2 q 2

Centre and radius of the circle x 2 y 2 2 gx 2 fy 0 are C1 g , f and r1


2
2
2
2
centre and radius of the circle x y 2 g1 x 2 f1 y 0 are C2 g1 f1

and

r2

2
1

f 2 and

f12

Q Circles touch each other.


C1C2 r1 r2

g g1

f f1
2

f 2

2
1

f12

squaring both sides then

g 2 f 2 g12 f12 2 gg1 2 ff1 g 2 f 2 g12 f12 2

gg1 ff1

g 2 f 2 g12 f12

f 2

2
1

f12

g 2 g12 f 2 f12 2 gg1 ff1 g 2 g12 g 2 f12 f 2 g12 f 2 f12

g 2 f12 f 2 g12 2 gg1 ff1 0

82.

gf1 fg1 0

gf1 fg1
Equation of chord can be written as x y a
So, length of perpendicular from the centre (0, 0) of the circle to the chord<radius
a
8 a 4
ie,
2

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83.

02-08-14_Sr.IPLCO_JEE

Suppose chord bisect at M , 0 , then


other end point of chord is h, q
ph
2
Which lie on x 2 y 2 px qy

where

or h 2 q 2 ph q 2
h 2 ph 2q 2 0
for two chords, B 2 4 AC 0
or p 2 4.1.2 q 2 0
or
84.

p 2 8q 2

Let MN be the diameter of the circle whose equation is


4y x 7
(i)

and coordinates of A and B are (-3, 4) and (5, 4) respectively.


Equation of bisector of AB is L 1, 4

1
x 1
0
x 1

y4

slope of AB 0

(ii)

Solving Eqs. (i) and (ii) we get the coordinates of the centre of the circle as (1, 2)
OL

1 1

4 2 2
2

BC 2OL 4 units
AB 8 units
Area of rec tan gle ABCD 4 X 8
85.

Let the circle be x h y k


lh mk 1
r

then
l 2 m2
2

= 32 sq. unit.
r2

or l 2 h 2 r 2 m 2 k 2 r 2 2lmhk 2lh 2mk 1 0

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02-08-14_Sr.IPLCO_JEE

also 4l 2 5m 2 6l 1 0
Comparing the coefficients of similar terms
h 2 r 2 4, k 2 r 2 5, hk 0
2h 6, 2k 0

k 0, h 3 and 9 r 2 4
r 5

86.

87.

Hence, centre 3, 0 and radius 5 .


OC is the diameter of the circle
0 g 0 f
Circumcentre
,

2
2
f
g
,
2
2

2
2
We have, 2 x 3 xy 2 y 0
ie, x 2 y 2 x y 0, which represents a pair of Perpendicular lines passing through the origin.

2 1
Re quired area

4
4
3

sq unit
4
x y
Let line is a b 1
2

88.

A a, 0 and B 0, b

Equation of circle since AB is diameters is


x a x 0 y 0 y b 0

x 2 y 2 ax by 0
Tangent at (0, 0) is
ax by 0

AM m

a2
a 2 b2

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Sri Chaitanya IIT Academy


MAIN_(2013)_PTM-1

mn

89.

b2

BN n

and

The point

02-08-14_Sr.IPLCO_JEE

a 2 b2

b 2 diameter of circle

p 1 , p

lies inside the circle

x y 2 x 15 0 , then
2

P 1

P 2 P 1 15 0
2

(page no. 815 q.no-91)

P 1 P
2

2 P 1 15 0

2 P 16 0 P 8
.(i)
Circles are concentric.
Point P 1 , P out side the circle
2

x2 y 2 2x 7 0

P 1

P 2 P 1 7 0

P 1 P
2

2 P 1 7 0

2 P 8 0
2

90.

........... ii

From Eqs. (i) and (ii), we get


2
4 P 8 which is impossible
For no value of Pthe point will be within the region.
The image of the circle has same radius but centre different. If centre is , , then
3 2 2 3 2 19

1
1
12 12
3 2 14
17, 16
Required circle is x 17 y 16 1
2

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