Professional Documents
Culture Documents
Ho Nam Chang
Professor of Biochemical Engineering
Department of Chemical & Biomolecular Engineering, Korea Advanced Institute of
Science and Technology KAIST), 373-1, Guseong-dong, Yuseong-gu, Daejeon,
305-701, Republic of Korea
E-mail: hnchang@kaist.edu, Tel: +82-42-350-3912, Fax: +82-42-350-3910
Biofuel
Protein
Carbohydrate
Lipid
Hydrolysis
Amino acids
Sugars
No need sterilization
No additional hydrolysis
enzyme
Mixed culture
Acidogenesis : fast
Methanogenesis : slow
Acidogenesis
Ammonia
OH
Acetogenesis
Hydrogen,
carbon dioxide
Acetic acid
Acetic acid
Propionic acid
Butyric acid
Valeric acid
Caproic acid
(C2)
(C3)
(C4)
(C5)
(C6)
Methanogenesis
OH
Biogas
(Methane, carbon dioxide)
Biofuel
VFAVFA-based Biofuels
1. Pretreatment (lignin: little, regular)
2. VFA (slow high rate)
3. Concentration of VFAs (30g/L
(30g/L 400g/L)
Evaporation (25kwh/m3 ton of water)
Solvent extraction (efficiency durability)
4. Hydrogenation (catalytic, 200oC, 20 atm)
atm)
CH3COOH + 2H2 C2H5OH + H2O
Propionic acid + 2H2propanol + H2O
Butyric acid + 2H2butanol +H2O
5. Separation to ethanol, propanol,
propanol, butanol
Biofuel
VFA Platform
Principle
Disintegration
Hydrolysis
Application
Oct. 2008, presented in International
Workshop on Defining Issues in Biofuels
R&D
VFAs
Biofuel
Acetate
C3
Propionate
C4
Butyrate
C5
Valerate
C6
Caproate
Biological
and
chemical
processes
BioChemicals
Biological &
thermochemical process
C2
Methane
Liquid
Anaerobic digestion
VFAs
BioFuels
Fermentation
&
Anaerobic Oxidation
Raw Materials
Gas
Ethanol
BioHydrogen
Butanol
Microbial Biodiesel
Bioplastics
Bulk chemicals(C3 ~C6)
Pharmaceuticals
Textiles
Other value added
chemicals
4
Acetate
Thermal conversion,
Catalysis
Fermentation
Hydrolysis
Biomass
Sugars
Fermentation
(80 gal/ton)
Ethanol
(56 gal/ton)
(85 gal/ton)
Syngas
Catalysis
Biological Process
Chemical Process
Mixed
alcohol
(120 gal/ton)
VFA
Biofuel
Whole-sale
sale Petroleum Product Price ($/L, 2005
2005-2006)
Ethanol
Diesel
Biofuel cost
(2006~2030)
$130/bbl
$100/bbl
Fischer Tropsch
Wheat
Beet
$50/bbl
Corn
Sugar cane
Biofuel
Vegetable oils
Anima fats
Ligno cellulose
Source:
Cost Comparison
1.1
Bioethanol present cost range
1.0
(Sugar platform) 1)
Sugarcane 1) Corn 1)
1) Estimated
Biofuel
2)
(VFA platform) 2)
Lignocellulose
by IEA/OECD, 2006
Organic wastes
Agricultural wastes
Forest residues
Energy crops
Marine biomass
MSW
No sterility
No GMOs
Adaptable
No pure cultures
Low capital
No enzymes
High product yields
No vitamin addition
Co-products not required
Biofuel
Mass
Cellulosic
Ethanol
(Sugar platform)
C6
38%
C5
27%
Lignin
Ash
Others
20%
3%
12%
(VFA platform)
C6
C5
Lignin
Ash
Others
38%
27%
20%
3%
12%
Hydrolysis
90%
90%
90%
90%
C6
ferment.
51%
90%
90%
90%
30%
Pretreat.
C5
Recovery Sum EtOH
ferment.
95%
14.91%
51%
Anaerobic
digestion
76%
76%
Composition
Mixed
Alcohol
Pretreat.
95%
10.60%
95%
95%
Hydrogen
Rxn
77%
77%
Sum
Alcohol
19.01%
13.51%
95%
77%
2.37%
VFA recovery
Total
EtOH
25.51%
(319 L/t)
Total
Alcohol
34.89%
(436 L/t)
Money
Cellulosic Ethanol Return $ = $0.3/kg(EtOH) * 0.2551/kg biomass = $ 0.0765/kg biomass (Biomass cost = 52.3%)
Mixed Alcohol
Energy
Cellulosic Ethanol Y= 25.51% 26.84 MJ/kg * 0.2749 kg/kg = 7.28 MJ/kg biomass
Mixed Alcohol
Y= 34.89% 30.2 MJ/kg1 * 0.3489 kg/kg = 10.54 MJ/kg biomass (9.28 MJ/kg) 2
1
2
Biofuel
Ethanol:Propanol:Butanol = 6:1:3
H2 consumption = - 120 MJ/kg*0.3489*0.03 g H2/g alcohol = - 1.256 MJ
10
Korean Foodwastes
Foodwastes Composition
Item
Content
Sugar platform
VFA platform
21
(% of TS)
(% of TS)
83
7.05
15.5
9.9
17
6.4
40
4.0
3.5
22.5
20
Sum : 23.5
<<
42.8
Biofuel
11
VFA Fermentation
VFAs production from foodwates at HRT = 12 days
Biofuel
12
pH
Biofuel
13
Treatable Biomass
Low lignin biomass
Sludge
Food wastes
Manure
Marine biomass
All biodegradables
Biofuel
(need pretreatment)
Agricultural wastes
Energy crops
14
Raw Materials
Pretreatment
Carbohydrate
Lipid
Protein
Enzyme
hydrolysis
Carbohydrate
Sugars
Other use
Lipid
Protein
Amino acids
VFAs
Microbial
Fermentation
Sugars
Biomass is mainly composed of carbohydrates, lipids, and proteins. And many biomasses are the complex of biomass
with various composition. Using the sugar part of biomass mixture, especially wetted organic wastes, is wasteful and
needs the large wastewater treatment facilities. The VFA platform may be a modified form of biogas platform to diversify
producible products, most part of biomass is converted to simple acids, and do not need additional enzymes.
Biofuel
15
Advantage
Sugar
platform
VFA
platform
Biofuel
Disadvantage
16
Chemical route
Biological route
Biofuel
Biofuel
Fermentation Productivity
Qp (g-product/L.h)
Specific cell productivity
Cell concentration
Substrate
availability
Inhibitor
removal
qP/X : (g-product/g-cellh)
X (g-cell/L)
YP/S
(g-p/g-s)
KI
Strain Development
HCDC
Feeding
Separation
Mutation, Screening
Metabolic engineering
Directed Evolution
Impact : variable
Biofuel
Cell recycle
Immobilization
Perfusion
Batch, fed-batch
Continuous
Air
Oxygen recycle
in situ separation
Impact : variable
19
Biofuel
20
Membrane
Water extraction
Amine dewatering
VFA purification
Biofuel
MED:: MultiMED
Multi-Effect Distillation
Source : www.roplant.org
(Mechanical VC)
Source : www.roplant.org
Biofuel
22
Biofuel
Copper chromite
- high temperatures (> 200C )
- high pressures (> 600 psi) (> 40.8 atm)
- widely used in industry (e.g., for making detergent alcohols
from fatty acids)
Biofuel
24
Biofuel