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SOLID FILM
LUBRICANTS
THE DRY LUBRICATION

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I
CONTENTS
INTRODUCTION...................................................................................................................... 3
STRUCTURE AND FUNCTION OF SOLID FILM LUBRICANTS...................................................... 4
PERFORMANCE RANGE OF SOLID FILM LUBRICANTS.............................................................. 6
PRE-TREATMENT AND APPLICATION....................................................................................... 7
TYPICAL TEST METHODS FOR SOLID FILM LUBRICANTS.........................................................10
SELECTION AND USE OF SOLID FILM LUBRICANTS.................................................................12
USING SOLID FILM LUBRICANTS ON VARIOUS AUTOMOTIVE APPLICATIONS......................... 13
FUCHS LUBRITECH'S SOLID FILM LUBRICANT CONCEPT.........................................................14

APPENDIX
APPLICATIONS.......................................................................................................................16
CHARACTERISTIC DATA........................................................................................................ 17
CHECK-LIST SOLID FILM LUBRICANT COATING...................................................................18

2 SOLID FILM LUBRICANTS - THE DRY LUBRICATION

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INTRODUCTION

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INTINTRODUCTION
RODUCTION
In many instances, if it's a question of dry film
lubrication, solid film lubricants are the optimum
choice. Solid lubricant coating has proved its
worth many times over and today provides a reliable and indispensable design element.
Increases in automated production and assembly makes
solid film lubricants ever more important. They make it
possible to provide many structural components with
dry, efficient lubrication and, compared with conventional lubricants, permit designs to be simpler. They
improve the running-in of highly-stressed machinery
components,
in

many

simplify

instances,

installation
guarantee

processes

and,

maintenance-free

lifetime lubrication.
Solid film lubricants manufactured by FUCHS LUBRITECH
are "state-of-the-art" and meet the increasing technical
demands made by diverse sectors such as industrial and
plant technology, metal-processing industry, machinery
construction and the commodity goods and automotive
industries.
In addition to their outstanding technical properties, the
solid film lubricants made by FUCHS LUBRITECH also
comply with the ever-increasing demands to address
environmental issues.

FUCHS LUBRITECH GMBH

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STRUCTURE AND FUNCTION OF SOLID FILM LUBRICANTS

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STSTRUCTURE
RUCTANDUFUNCTION
RE
OF SOLID FILM LUBRICANTS
AND FUNCTION
Solid film lubricants are carefully selected solid lubricants combined with organic or inorganic binders dispersed in solvents.

The fundamental difference compared with normal industrial varnishes


is that they contain solid lubricants instead of colour pigments.
Apart from the main components binders, solid lubricants and
solvents solid film lubricants may also contain functional additives
such as corrosion inhibitors or UV active components.

COMPOSITION OF SOLID FILM LUBRICANTS


Solid Lubricants
MoS2, graphite, PTFE ...
Binders
Epoxy-, polyurethane-, amide-imide-, silicone resin
Solvents
Organic solvents, water
Additives
Corrosion protection, wetting, preservatives, UV additive ...

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INDUSTRIAL VARNISH

STRUCTURE AND FUNCTION OF SOLID FILM LUBRICANTS

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...........

After drying and curing, solid film lubricants form a


strong dry coating several microns thick, by adhe-

30 m

ring firmly to the substrate. The film reduces both


wear and friction as well as acting as a parting
agent and provides lubrication between the opposing surfaces.
SOLID FILM LUBRICANT

10 m

10m

10-15 m

SOLID FILM LUBRICANT


ON PHOSPHATED METAL

Solid lubricant
deposited on
surface

Solid lubricant impregnated into surface

Scanning electron micrograph of the surface of a MoS2 solid film lubricant layer
before applying frictional load.

10m

Binder

Colour pigment

Metal

Solid lubricant

Phosphate layer

Scanning electron micrograph of the surface of a MoS2 solid film lubricant layer
after frictional loading smoothing of the surface of the solid film lubricant.

FUNCTION OF A SOLID FILM LUBRICANT

Initial smoothing of the surface of the solid film


lubricant takes place as a result of the relative

Opposing surface

Opposing surface

Opposing surface

movement of the opposing surfaces.


A partial discharge of material from the solid film
lubricant layer creates a "transfer" film on the

1) Partial separation of
the solid lubricant
from the coating

2) Transfer of the solid


lubricant onto the
opposing surface

3) Formation of the
transfer film

opposite surface. The build-up of lubricating film


between the two surfaces leads to a reduction in
the coefficient of friction.

STRIBECK DIAGRAM: MODEL OF THE FRICTION AREAS


DURING FLUID LUBRICATION

of dry and clean lubrication and in many instances


can replace the use of greases and fluid lubricants,
particularly where slow sliding movements are
involved. In addition solid film lubricants can be

Hydrodynamic friction
(Fluid lubrication)

Mixed friction

Boundary friction
Boundary friction

Coefficient of Friction

Static friction

The solid film lubricant provides the dual advantage

used in combination with fluid or pastes. Solid film


lubricants enhance the lubrication of components

Mixed friction

in the boundary friction region, when there is


no hydrodynamic lubrication and direct contact
between the surfaces occurs.

Hydrodynamic
friction
Rotational speed n

FUCHS LUBRITECH GMBH

Solid film lubricant


Oil

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PERFORMANCE RANGE OF SOLID FILM LUBRICANTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

PEPERFORMANCE
RFORM
AN
E FILM
RALUBRICANTS
NGE
RANGE
OF C
SOLID
Solid film lubricants enable to pre-treat and store lubricated parts ready for assembly.
They are characterised by extremely high resistance to pressure and to temperatures; they neither age nor become
resinous and at the same time are clean to handle. FUCHS LUBRITECH's solid film lubricants possess outstanding
lubricating and protective properties:
ADVANTAGES

FIELDS OF APPLICATION

SOLID FILM LUBRICANTS

SOLID FILM LUBRICANTS

Q make dry and clean lubrication possible

Q make assembly and dismantling of fitted parts simpler

Q are resistant to contamination

Q optimise the running-in performance of highly-stressed components

Q protect against corrosion

Q make maintenance-free lifetime lubrication possible

Q lubricate under extreme conditions

Q prevent the occurrence of "stick-slip" and thus reduce noise

(high and low temperatures, vacuum, radiation)


Q are suitable for the surface refinement of a number

of materials (metals, plastics, elastomers, ceramics,

Q attain precise coefficients of friction with low variables for fasteners


Q when combined with oil and grease lubrication guarantee additional

safety through emergency lubrication.

glass etc.)

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PRE-TREATMENT AND APPLICATION

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PRPRE-TREATMENT
E-TREAANDTM
ENT
APPLICATION
& APPLICATION
The application of solid film lubricants is a complex subject and should be done by specialists.

METAL PARTS:

PRE-TREATMENT
Surface preparation of the parts to be coated plays an
important role during solid film lubricant coating.
Good adhesion and therefore long lifetime can only be
achieved with a pre-treatment which is customised for
the particular part and solid film lubricant. Thorough
removal of all grease residues, dust, dirt, rust and scale is
a fundamental part of the pre-treatment of the work
piece surface.

De-greasing can usually be done by using organic


solvents, such as, for example, hydrocarbon, acetone etc.
A more environmentally and user-friendly result can be
achieved by using alkaline or neutral aqueous cleaners.
The effectiveness of the cleaners can usually be intensified when combined with ultrasound or heat.
Rust and scale can be removed mechanically or chemically. Grinding or blasting are suitable mechanical
pre-treatment methods. Rust and scale can be removed
chemically through pickling in acids or lyes.

PLASTIC PARTS:
De-greasing of plastics and elastomers can be achieved
with aqueous cleaners or solvents. When using solvents,
however, attention should be paid to compatibility with
the plastics to be cleaned.

Phosphatising can give significantly improved adhesion


of the solid film lubricant onto the metal surface.
Phosphating improves both the mechanical properties
and corrosion protection of the parts to be coated.
Normally, zinc or manganese phosphating is used.

The adhesion of the solid film lubricants can be improved by roughing the surface, for example. Suitable
methods are grinding or blasting with CO2 or sand.
avoided. Alternatively, physical methods such as plasma
activation, corona or flame treatment can be used for
the pre-treatment of plastics.

Relative service life

Deformation of the parts or surface damage must be

Relative service life of solid film lubricants is dependent upon


roughness of the substratum and pre-treatment methods

sandblasted and phosphated


sandblasted
ground
2

FUCHS LUBRITECH GMBH

10

12

14
16
18
Surface roughness [m]

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PRE-TREATMENT AND APPLICATION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Drum

Spraying

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Sand blasting
Continuous drum
Chemical pre-treatment

Using robots

CLEANING

PRE-TREATMENT

APPLI CA

APPLICATION
Decisive for the application of the solid film lubricant are

Higher temperatures lead to partial accumulations of

primarily the geometric shape of the parts and the tech-

varnish and rough surfaces, lower temperatures only

nical application properties of the selected coating.

give rise to very thin layers. The ideal degree of filling of

Application is principally undertaken using traditional

the centrifuge depends on the plant and usually has to

processes found in coating technology, such as, dipping,

be determined empirically (guideline: 60-70%). Using

tumbling, dip-centrifuging and spraying.

this method of application varnish utilisation can


amount to up to 90%.

SPRAY-COATING

It is, however, difficult to achieve homogenous layers

For most products it has been shown that the "non vola-

over 10m thick. With dip-centrifuging there is the dan-

tile part" of the solid film lubricant should be set at

ger that the parts will stick together (particularly parts

about 26-30% for spray application. The non-volatile

with flat surfaces). The parts should, therefore, be

part corresponds to the dry residue, i.e. the dry lubricant

moved continuously during dipping and also when

coating after the solvent has evaporated.

drying or curing afterwards.

Any standard spray gun may be used. HVLP spray guns,


with a circular/spread jet setting and a nozzle diameter
of 0.5-0.8 mm, have proved to be particularly suitable.
The specific design of the HVLP spray technology allows
varnish utilisation of up to 60%.
In many usages pre-heating of the parts to be coated to

SUMMARY OF THE COATING METHODS


AND AREAS OF APPLICATION

60-80C is an advantage. This also allows the application


of layers with a thickness greater than 20m
without intermediate ventilation. Spray-coating usually

very suitable

achieves layer thicknesses of 10-30 m.

conditionally suitable

Spray coating
Drum coating

DIP-CENTRIFUGING
During centrifuge coating, it is recommended to set the
non-volatile part to 22-28%, in order to achieve an
optimum coating result. Here, too, it can be an advantage to pre-heat the parts to be coated to 80-85 C.

8 SOLID FILM LUBRICANTS - THE DRY LUBRICATION

Dip Coating
Dip/centrifugal coating
Spray drum coating

FUCHS LUBRITECH GMBH

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PRE-TREATMENT AND APPLICATION

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Centrifuge

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Dipping

Baking

Rotary cycling table

LI CATION

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UV light

Layer thickness
testing
Drying

HARDENING

QUALITY CONTROL

PACKING

DRUM COATING

Normal curing temperatures are in the region of approx.

Coating in drums is particularly suitable for bulk goods,

100-200C. More detailed information about the solid

which have simple shapes (e.g. washers, bolts, pins,

film lubricants made by FUCHS LUBRITECH can be

O-rings). An advantage of this process is the surface

obtained from the relevant product information sheets.

smoothing that occurs due to the friction between the


coated parts in the drum and so homogenous layer
surfaces can be achieved. By combining it with a spray

QUALITY CONTROL

coating in so-called "spraying drums" the thickness of

The general criteria used for the quality control of solid

product deposited can be controlled precisely, thereby

film lubricant layers are the surface finish, the coating

giving an improved coating.

thickness and adhesion to the surface of the component.


Transparent solid film lubricants usually contain

HARDENING

a special UV indicator which can be made visible with a

Air-drying solid film lubricants are dried at room tem-

UV lamp and allows "Yes/No" control.

perature before being subjected to frictional load, while

Further control parameters are determined by the shape

heat-cured solid film lubricants are cured after coating.

of the component and the requirements of the coating


applied. Quality control statistical analysis using

FUCHS LUBRITECH GMBH

Costs

Complex shapes

Reduced consumption of coating

Greater coating
thickness

Ensure coating
quality

Eliminate components sticking

Bulk components

Individual
components

appropriate test rigs is rarely required.

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TYPICAL TEST METHODS FOR SOLID FILM LUBRICANTS

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T YTYPICAL
P I C ATEST
L METHODS
TEST METHODS FO
FOR SOLID FILM LUBRICANTS

Various methods are used to test the performance of solid film lubricants. The individual charac-

ALMEN WIELAND TEST METHOD

3500

350

RLV1) 060

3000

300

Rotating shaft (coated) fixed in

2500

250

two bearing shells

2000

200

1500

150

1000

100

coefficient of friction

500

50

Measurement at slow

Q
Q

Contact geometry: flat surface


n

Test criteria: fretting load,


F

00:00

sliding speeds

SRV TEST METHOD


DIN 51834-8

Oscillating counterpart
on a plate (coated)

Time [min]

18:00

0,250

F
Coefficient of Friction,

Contact geometry: line


(alternatively flat surface or point)

0,200

0,150

0,100

Test criteria: coefficient of friction, wear

0,050

Service life testing at high sliding speeds

and varying surface pressures

10

20

30

40

50

60
70
Time [min]

80

90

100

110

120

LFW1 TEST METHOD


ASTM D 2714 (RLV1) 119)

Oscillating ring on block (coated)

Contact geometry: line

Test criteria: coefficient of friction, wear

Service life testing at slow sliding speeds

Coefficient of Friction,

0,20

0,10

-0,10

-0,20
0

00:30

01:00

01:30
Time [h:min]

02:00

02:30

1) RLV: LUBRITECH Laboratory Specifications

10 SOLID FILM LUBRICANTS - THE DRY LUBRICATION

FUCHS LUBRITECH GMBH

Temperature T [C]

teristics of a solid film lubricant can be established by selecting the correct test method.

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. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .TYPICAL TESTING

METHODS FOR SOLID FILM LUBRICANTS

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OR SOLID FILM LUBRICANTS


8

COEFFICIENT OF FRICTION TESTING ON ELASTOMERS

uncoated
7

DIN 52375 (RLV1) 142)

Oscillating counterpart on a

coated elastomer plate

Contact geometry: flat surface

Test criteria: friction force

Measurement at slow speeds

coated with
solid film lubricant

1
0

and under low loads

10

20

30

40

Sliding track [mm]

DIN EN ISO 16047 (DIN 946)

Determination of coefficients
of friction on bolted connections

Contact geometry: flat surface


(thread and bolt head)

Test criteria: coefficient of friction,


clamping force

Measurement of thread friction,

100

Tightening torque MA [Nm]

SCREW TEST

80

60

40

20

0
0

10.000

20.000

30.000

40.000

Clamping force Fv [Nm]

friction under head and total coefficient


of friction

CORROSION TESTS
Q

DIN 50021 (salt spray test),


DIN 50017 (condensed water test),
VDA 621-415 (alternating cycles test)

Determination of the corrosion resistance


of coated test plates or components
uncoated

coated with
solid film lubricant

1) RLV: LUBRITECH Laboratory Specifications

FUCHS LUBRITECH GMBH

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SELECTION AND USE OF SOLID FILM LUBRICANTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

The special demands placed on a solid film lubricant coating are as numerous as the possible
applications.
The selection of a suitable solid film lubricant requires a

Coefficient of Friction,

SESELECTION
LECTAND
ION
&SOLID
USFILM
E LUBRICANTS
USE OF
0,24

Running-in phase
0,21
0,18
0,15

high degree of professional competence and is mainly


determined by these factors: type of component,

0,12

purpose of the coating, surrounding conditions and

0,09

Stationary phase

quality management requirements.

0,06

Solid film lubricants manufactured by FUCHS LUBRITECH


0,03

have proved themselves in many fields and represent the


optimum solution for dry and clean lubrication. Thus, for

Test duration

example, they can provide installation-compatible

Characteristic slope of the coefficient of friction


of a MoS2-based solid film lubricant depending on the test duration.

lubrication for screw connections, fitted parts and


O-rings, help to minimise wear on gear components
Service life (relative)

and provide lifetime lubrication for components


essential to safety.

SELECTION CRITERIA FOR COATINGS


COMPONENT

COATING PURPOSE

Running-in lubrication Q
Assembly Q
Lifetime lubrication Q
Corrosion protection Q
Wear reduction Q
Decorative appearance Q
Increase in value Q

Geometry
Weight
Q Material
Q Surface
Q Coating costs
Q
Q

20 min-1

60 min-1
100 min-1

TYPE
OF COATING

Component testing
Model testing
Q Statistical process
control
Q Documentation
Q
Q

QUALITY CONTROL REQUIREMENTS

ENVIRONMENTAL CONDITIONS

40

60

80
Load [N/mm2]

Influence of load and speed on the service life


of a MoS2-based solid film lubricant.

Coefficient of Friction,

Temperature range Q
Environmental conditions Q
Friction conditions Q
Load Q
Type of movement Q
Load cycle Q

20

0,15

0,10

The assessment as to whether a solid film lubricant is suitable for providing lifetime lubrication for a component
must usually be proved through trials on suitable test
rigs. Generally solid film lubricants have a limited service

0,05

life, which will be indicated in the trial by an increase in


the coefficient of friction and the appearance of wear
phenomena. Thus, it should be noted that load and
sliding speed of the component can have a great
influence on the performance of the solid film lubricant.

12 SOLID FILM LUBRICANTS - THE DRY LUBRICATION

200

400

600

Influence of load on the coefficient of friction


of a MoS2-based solid film lubricant.

800
Load [N/mm2]

FUCHS LUBRITECH GMBH

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USING SOLID FILM LUBRICANTS ON VARIOUS AUTOMOTIVE APPLICATIONS

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UUSING
SINSOLID
G SFILM
OLUBRICANTS
LID FILM
ON VARIOUSL
AUTOMOTIVE
UBRICAPPLICATIONS
ANTS
11

10

2
3

12
4
9

e:

urc

So

ler

rys

Ch

ler

AG

im

Da

AREAS OF APPLICATION
1

Coating of profile gaskets

Various plastic parts in the car interior

Connecting parts in the engine compartment

Elements of the fuel injection system

Reduced coefficient of friction of O-rings

Apart from numerous industrial applications, the

Wear reduction of gaskets

versatility of solid film lubrication can be seen

Coating of wheel bolts

from the automotive applications outlined below.

High temperature solid film lubricants for exhaust systems

Wear reduction of seat adjustment mechanisms

Solid film lubricants ease the assembly of sealing and

10

Closure mechanisms of the safety-belt systems

bolting elements, contribute to interior noise reduction,

11

Sliding components in the boot lid

provide the best possible performance under extreme

12

Sections of the door locking system

conditions (e.g. engine compartment, exhaust system)


and guarantee safe and reliable lubrication of

Installation lubrication / running-in conditions

components.

Lifetime lubrication
Noise reduction

FUCHS LUBRITECH GMBH

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THE SOLID FILM LUBRICANT CONCEPT . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

THTHEE CUSTOMER
SOLIDIS PARAMOUNT
FILM
LUBRICANT CONCEPT
Our professional and experienced lubrication technology team will
help you find solutions to your technical requirements.
With our sample coating service we offer you the

We offer you the opportunity to have coating work

opportunity to test the efficiency of our products on

carried out at one of our coating centres (FLT Surface

your components. If necessary we will develop tailor-

Technology).

made solutions especially for your application. In addition we will assist you with the implementation

In addition, through the know-how transfer of the

of a solid film lubricant coating system up to the

application technology, we make it possible for

production stage.

implementation to take place at your own premises or


at those of one of our numerous external partners.

Sample coating on a laboratory- and


semi commercial scale

Tec
on hnica
lub l a
ric dvi
an ce
ts

the
of
er gy
nsf lo
tra no
w tech
-ho g
ow tin
Kn coa
of
tai Dev
lor elo
-m pm
ad en
ep t
rod
uct
s

e
ng tr
ati en
co ng c
act ati
ntr co
Co own
r
ou
in

Service investigations
by our development division

14 SOLID FILM LUBRICANTS - THE DRY LUBRICATION

FUCHS LUBRITECH GMBH

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APPENDIX

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APPLICATIONS AND CHARACTERISTIC DATA


CHECK-LIST
SOLID FILM LUBRICANT COATING

FUCHS LUBRITECH GMBH

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APPENDIX . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

CHECK-LIST SOLID FILM LUBRICANT COATING


Please cross off as appropriate

1. GENERAL CUSTOMER INFORMATION


Company

Contact person

Department

Street

Postal Code/ Location

Phone

Fax

E-Mail

Internet

2. INFORMATION ABOUT THE COMPONENT FUNCTION / AREA OF APPLICATION (if possible enclose drawing or sketch)
Description

To what stresses is the component / the system subjected?


Surface pressure
Surrounding media (e.g. dust, salt water, oil, air etc.)
Type of movement (e.g. rolling, sliding)
Operating temperature

up to

3. INFORMATION CONCERNING THE COMPONENT TO BE COATED


Material

Steel

(alloy/description; e.g. St. 37, 100 Chromium 6)

Plastic/elastomers

Stainless Steel
Miscellaneous

(e.g. PA, PP NBR, EPDM)

Surface finish
blank

Roughness (e.g. Ra value)

Surface finished

(e.g. phosphatised, galvanised)

4. INFORMATION ABOUT THE UNCOATED MATING SURFACE AT 3.


Material

Steel

(alloy/description; e.g. St. 37, 100 Chromium 6)

Plastic/elastomers

Stainless Steel
Miscellaneous

(e.g. PA, PP NBR, EPDM)

Surface finish
blank

Roughness (e.g. Ra value)

18 SOLID FILM LUBRICANTS - THE DRY LUBRICATION

Surface finished

(e.g. phosphatised, galvanised)

FUCHS LUBRITECH GMBH

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APPENDIX

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5. REQUIREMENT PROFILE
Coating specified by the customer : (including pre-treatment)

Water-based

Coating for assembly aid

Durable function lubrication

Running-in lubrication

Solvent-based

Miscellaneous

Low coefficient of friction []

Component testing:

Better wear performance

Load cycles (number of cycles):

Corrosion protection [h]

Test method

Sliding speed in m/s:

Approx. layer thickness in m: (only give details if absolutely necessary)

Sliding track in mm:

Partial coating (please indicate area on the drawing)


Complete coating (standard process)

6. WHAT MUST BE TAKEN INTO ACCOUNT REGARDING THE COMPONENT / ITS USE?
Sand-blasting permissible

Yes

No

Phosphating permissible

Yes

No

Avoid temperatures below

C / above

Miscellaneous

7. INFORMATION NEEDED FOR JOB COATING


As part of our sample coating service we will suggest one or more coating processes. In order to be able to select a suitable process for you at the sample stage
we would ask you for the following information:
Number of items per year
Number of items per delivery
Part weight, if applicable
Other requirements

SEND IN THE CHECK-LIST


Please forward this check-list and supplementary information to:
FUCHS LUBRITECH GMBH
Product Management, Dry Film and Coatings
Hans-Reiner-Str. 7-13
67685 Weilerbach/Germany
E-mail: gleitlacke@fuchs-lubritech.de
NOTE:
This and other check-lists are also available for downloading on the
Internet from www.fuchs-lubritech.com.

FUCHS LUBRITECH GMBH

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FUCHS LUBRITECH GMBH


Hans-Reiner-Str. 7-13
67685 Weilerbach/Germany
www.fuchs-lubritech.com

Phone: +49 (0) 6374 924-5


Fax:
+49 (0) 6374 924-940

E-mail: info@fuchs-lubritech.de

1' PP 03/07 0601787

Lubrication Technology

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