Professional Documents
Culture Documents
Interatomic Bonding
ISSUES TO ADDRESS...
What promotes bonding?
What types of bonds are there?
What properties are inferred from bonding?
Review of Atomic Structure
Chapter 2 - 1
Ionic Bonding
Balance of attractive and repulsive forces between
two atoms
State of equilibrium at r0 no net force
Bonding energy:
E required to separate
two atoms from this
equilibrium state to an
infinite separation
Adapted from Fig.
2.10(a), Callister &
Rethwisch 9e.
Chapter 2 - 2
Atomic Structure
Subatomic particle mass: electrons 9.11 x 10-31 kg
protons
-27
neutrons 1.67 x 10 kg
12.011 g/mol
1.008 g/mol etc.
Chapter 2 - 3
Fig_2-1
Chapter 2 - 5
Chapter 2 - 5
Designation
K, L, M, N, O (1, 2, 3, etc.)
s, p, d, f (0, 1, 2, 3,, n-1)
Chapter 2 - 6
s orbital
p orbital
Chapter 2 - 7
Quantum #
Designation
K, L, M, N, O (1, 2, 3, etc.)
s, p, d, f (0, 1, 2, 3,, n-1)
Number of orbitals 1, 3, 5, 7
Number of electrons 2, 6, 10, 14
Table_2-1
Chapter 2 - 8
Chapter 2 - 9
SURVEY OF ELEMENTS
Most elements: Electron configuration not stable.
Atomic #
Element
Hydrogen
1
Helium
2
Lithium
3
Beryllium
4
Boron
5
Carbon
6
...
Neon
10
Sodium
11
Magnesium
12
Aluminum
13
...
Electron configuration
1s 1
1s 2
(stable)
1s 2 2s 1
1s 2 2s2
1s 2 2s 2 2p 1
1s 2 2s 2 2p 2
...
Argon
...
Krypton
1s 2 2s 2 2p 6 3s 2 3p 6
(stable)
...
1s 2 2s 2 2p 6 3s 2 3p 6 3d 10 4s 2 4p 6 (stable)
18
...
36
1s 2 2s 2 2p 6
(stable)
1s 2 2s 2 2p 6 3s 1
1s 2 2s 2 2p 6 3s 2
1s 2 2s 2 2p 6 3s 2 3p 1
...
Electron Configurations
Valence electrons those occupy the outmost shell.
Many physical and chemical properties of solids are
based on these valence electrons.
Valence electrons are most available for bonding and
tend to control the chemical properties
example: C (atomic number = 6)
1s2 2s2 2p2
valence electrons
Chapter 2 - 11
K Ca Sc
Se Br Kr
He
Li Be
F Ne
Na Mg
Cl Ar
Rb Sr
Cs Ba
Te
Adapted from
Fig. 2.8,
Callister &
Rethwisch 9e.
Xe
Po At Rn
Fr Ra
Electropositive elements:
Readily give up electrons
to become + ions.
Electronegative elements:
Readily acquire electrons
to become - ions.
Chapter 2 - 12
Electronegativity
Ranges from 0.9 to 4.1,
Large values: tendency to acquire electrons.
Smaller electronegativity
Larger electronegativity
Chapter 2 - 13
donates
electrons
nonmetal
accepts
electrons
Dissimilar electronegativities
ex: MgO
Mg
Chapter 2 - 14
Ionic Bonding
Cl (nonmetal)
unstable
electron
Na (cation)
stable
+
Coulombic
Attraction
Cl (anion)
stable
Chapter 2 - 15
Chapter 2 - 16
Give up electrons
Acquire electrons
Chapter 2 - 17
Covalent Bonding
similar electronegativity: share electrons
bonds determined by valence s & p orbitals
dominate bonding
Directional
H2
Example: H2
Each H: has 1 valence e-,
needs 1 more
Electronegativities
are the same.
shared 1s electron
from 1st hydrogen
atom
shared 1s electron
from 2nd hydrogen
atom
Bond Hybridization
Carbon can form sp3 hybrid
orbitals
Tetrahedron
Electronegativities of C and H
are comparable so electrons
are shared in covalent bonds.
Chapter 2 - 20
Methane sp3
C-H bonds
Diamond - sp3
C-C bonds
Extremely strong
High melting T
Very hard material
Chapter 2 - 21
Fig_2-16
Chapter 2 - 22
http://www.eatwriteteach.com/
http://www.swissdiamond.com/
Chapter 2 - 24
Methane sp3
Graphite sp2
Diamond, sp3
www2.warwick.ac.uk
Chapter 2 - 25
Metallic Bonding
Metallic Bonding -- delocalized as electron cloud
electrons not bound to any particular atom
or
electron cloud
Bonding
Primary Bonding
types: ??
Chapter 2 - 27
Bonding
Primary Bonding
types: ??
Secondary Bonding
weak compared to primary bonds
van der Waals bonds: from interaction between dipoles
hydrogen bonding
Chapter 2 - 28
Chapter 2 - 29
Bonding
unusual, most substances experience an increase in
density upon transforming from liquid to solid
ice formation => expansion of approximately 9 pct
4 hydrogen bonds form per H2O molecule
open structure => lower density
upon melting
structure partially destroyed
molecules closer packed
Chapter 2 - 30
Mixed Bonding
For many real materials, the atomic bonds are mixtures
bonding tetrahedron
electronegativity
Chapter 2 - 31
Mixed Bonding
Covalent-Ionic Mixed Bonding: percent ionic character (%IC)
Ex: MgO
XMg = 1.3
XO = 3.5
Chapter 2 - 32
Read Chapter 2
Chapter 2 - 33