StoreCard

Mixed storage
of chemicals

Merck KGaA Germany

64271 Darmstadt
Tel
+49 (0) 61 51/72-0
Fax
+49 (0) 61 51/72-20 00
e-mail contact@merck-chemicals.com
www.merck-chemicals.com/safety

StoreCard

Mixed storage of chemicals

Hazardous materials must be stored in such a way
that:

When the recommendations for mixed storage of chemicals of

StoreCard are used, national regulations for separate and segregated
storage must also be adhered to.

risks involved in storing incompatible materials together are

minimized.

in the event of re, toxic smoke is avoided.

Explosive substances

The term separate storage means locating products in different

storage areas. A storage area is a section of a warehouse is separated
from other rooms by either by re-resistant walls and ceilings or
safety cabinets or both. Separate storage may be necessary to avoid
the increased risk which may happen if contact occurs between
products of different storage classes.

Segregated storage:

The term segregated storage means storage in the same storage area
where the products are separated from one another by gaps or barriers

Hazard labels*

10-13 13

2A

Aerosols

2B

11

10

8B

8A

6.2 6.1 D 6.1 C 6.1 B 6.1 A 5.2 5.1 C 5.1 B 5.1 A 4.3

5
1

4.1 A
4.1 B

Substances liable to
spontaneous combustion

4.2

Substances that form ammable

gases in contact with water

4.3

2B

5
1

2A

5.1 A

Oxidizing substances

5.1 B

Oxidizing substances
(ammonium nitrate)

5.1 C

6
1

5.2

Combustible acute toxic

substances

6.1 A

Non-combustible acute toxic

substances

6.1 B

INFECTIOUS SUBSTANCE

RADIOACTIVE I
CONTENTS _ _ _ _ _ _ _ _ _ _ _
ACTIVITY _ _ _ _ _ _ _ _ _ _ _ _

RADIOACTIVE II
CONTENTS _ _ _ _ _ _ _ _ _ _ _
ACTIVITY _ _ _ _ _ _ _ _ _ _ _ _

RADIOACTIVE III
CONTENTS _ _ _ _ _ _ _ _ _ _ _
ACTIVITY _ _ _ _ _ _ _ _ _ _ _ _

TRANSPORT INDEX

TRANSPORT INDEX

1. A risk
assessment is
necessary. Are there
no signi cant risks a
mixed storage is permitted.
2. Combustible substances,
4
4
1
1
with the exception of ammable
liquids, may be stored in storage
areas in which there are no more
than 50 full compressed-gas cylinders
of which a maximum of 25 of them
contain ammable, oxidizing or toxic gases
provided the storage area for compressed-gas
cylinders is separated by an at least two-metre high
wall made of non-combustible building materials.
Alternatively, there must be at least ve-metres distance
between the gas cylinders and the combustible substances.
3. Up to 150 compressed-gas containers containing
ammable, oxidising and inert gases may be stored together. In
addition 15 compressed-gas containers with toxic and highly toxic
gases may be stored together with them at the same time.
4. Mixed storage is permitted if the following restrictions and quantities
are adhered to:

Non-combustible toxic substances

6.1 D
or substances wit chronic effect
6.2

Combustible toxic substances or

6.1 C
substances wit chronic effect

Oxidizing substances (strong

oxidizer)

Radioactive substances

Flammable solids (explosive)

Infectious substances

4.2 4.1 B 4.1 A

Flammable solids and

desensitized substances

Organic peroxides and selfreactive substances

12

Gases

Flammable liquids

Segregated storage within one area may also be necessary

if certain products are in the same storage class, but have
special properties. This is also the case for products in differing
storage classes, with particular properties, for which mixed
storage in accordance with the mixed storage table is normally
permitted (Example: cyanides must not be stored together with
substances, such as acids, with which they can form hydrogen
cyanide.). Information on this is available in the hazard and
precautionary statements (e.g. H271, H272, H 304 EUH029,
EUH031, EUH032, P220, P223 or P420). However, chapter 10
(stability and reactivity) of the MSDS is of no use.

Separate storage:

For safety reasons, all products to be stored must be classi ed in

the storage class relevant to their speci c hazard characteristics.
A chemical can only be classi ed in one storage class. Chemicals having more than one hazardous property are assigned to
a class based on a ranking system for the hazard involved. This
guarantees that chemicals with the same or similar hazardous
properties can be treated similarly with regard to the necessary
safety measures, in particular re and explosion protection. All
Merck reagents and chemicals are assigned to the storage class
stated in their respective Material Safety Data Sheets (MSDS)
and online in ChemDat (http://www.merck-chemicals.com).
GHS-pictogram*

The mixed storage of products of differing storage classes

is only permitted if certain conditions are met (e.g. identical
extinguishing agent for all products, identical temperature
conditions -> see MSDS).

The mixed storage table indicates whether a product in a particular

storage class may be stored together with one in another class,
whether such mixed storage together is prohibited (separate storage
required) or whether there are restrictions on mixed storage that have
to be observed (segregated storage in the same storage area required).

dangerous, violent reactions, such as the generation of

ammable gases or very toxic gases are prevented.

Storage class

(e.g. walls, non-combustible substances of storage class 10-13)

or in safety cabinets made of non-combustible material.

maximum quantity (tonnes)

Combustible corrosive
substances

8A

Non-combustible corrosive
substances

8B

Other combustible liquids

10

Other combustible solids

11

1) These quantities apply only to the mixed storage of store class 4.1 B with store class 6.1 A.

Other non-combustible liquids

12

Other non-combustible solids

13

Other combustible and noncombustible substances

10-13

5. Materials that ignite easily or cause a re to spread rapidly, such as packaging

materials, must not be stored together with toxic substances or ammable liquids.
6. Products which do not react with one another in the event of an incident may be
stored together. This can be achieved by segregated storage, e.g. physical separation,
large gaps between containers, separate containment basins, or storage in safety
cabinets.
7. Mixed storage with non-combustible substances is permitted. For mixed storage
with combustible substances see point 4.

*Only if relevant for allocation for storage class y Mixed storage is permitted in principle
y Mixed storage is permitted only with restrictions (see number) y Separate storage is required

Protective measures and rules of conduct

The potential harm that may arise in the storage

of chemicals depends not only on the quantities
involved, but also on the particular hazards they
pose. Uncontrolled storage is not permitted. The
following requirements apply to all hazardous
chemicals.
1. Safety instructions, which relate either to
individual chemicals or to classes of chemicals
with the same hazardous properties, need to be
compiled.
2. Chemicals must be stored strictly according to
the warehousing plan.
3. Workers must wear suitable protective clothing
(overalls, safety shoes and as needed, also
safety goggles and protective gloves) within the
warehouse.
4. There must be a strict ban on naked ames,
unshielded lights and smoking.
5. Stored goods must be handled in a way that
prevents damage to packaging and the escape
of chemicals.
6. Escape routes, emergency exits and access
routes for the emergency services must be kept
free at all times.
7. Suitable re extinguishers (ABC powder
extinguishers), rst-aid boxes and eyewash
bottles must be close at hand.
8. Written permission must be obtained before any
welding is undertaken. The same applies to the
use of power tools (for drilling, grinding, etc).
9. There must be a strict ban on smoking, eating
and drinking in areas where chemicals are
stored.

restrictions

4.1 B

5.1 B

6.1 A

no restrictions

101)

only with a functioning automatic re-alarm system

20

only with a functioning automatic extinguisher system

20

1001)

20

20

20

Special rules for the storage of small quantities

These regulations apply to storage rooms with a capacity of less than one tonne
or to safety cabinets. The storage table for small quantities shows, by means of
GHS-pictograms, combinations of products may be stored together (+) or not
(-). There are no exceptions for explosive substances, gases, organic peroxides,
self-reactive substances and radioactive substances; the mixed storage table (see
above) still applies.
none

none

y Flammable liquids and aerosols y Substances liable to spontaneous combustion

y Substances that form ammable gases in contact with water y Flammable solids

Example for a warehousing plan

I store class 3 + 8 A

II store class 3 + 6.1 A

III store class 8 B + 10-13

6.1 B

Warehousing plan
total storage
quantity:

50 t

maximum storage
quantity of store
class 3 in Room I
and II:
15.000 l
store class 8 A in
Room I
Only in unbreakable packaging

Example for a safety instruction see on the back side

Hazard Statements
Hazard Statements
Unstable explosives.

H330

Explosive; severe projection hazard.

H332

H201

Explosive; mass explosion hazard.

H203

Explosive; re, blast or projection hazard.

H202
H204
H205

Fire or projection hazard.

May mass explode in re.

H220

Extremely ammable gas.

H222

Extremely ammable aerosol.

H221

Flammable gas.

H223

Flammable aerosol.

H225

Highly ammable liquid and vapour.

H224
H226
H228
H240
H241
H242
H250
H251
H252
H260
H261
H270
H271
H272
H280
H281

Extremely ammable liquid and vapour.

Heating may cause an explosion.

In contact with water releases ammable

gases.

May cause or intensify re; oxidiser.

May cause re or explosion; strong oxidiser.

May intensify re; oxidiser.

Contains gas under pressure; may explode

if heated.

H301

H301 +
H311
H301 +
H331
H301 +
H311 +
H331
H302

H302 +
H312
H302 +
H332
H302 +
H312 +
H332
H304

H350

H360
H360D
H360Df
H360F
H360FD

H361

Fatal if swallowed or in contact with skin.

H300 +
H310 +
H330

H341

Fatal if swallowed.

H300 +
H310
H300 +
H330

H340

H360Fd

May be corrosive to metals.

H300

EUH 044

H336

Contains refrigerated gas; may cause

cryogenic burns or injury.

H290

Fatal if swallowed or if inhaled.

Fatal if swallowed, in contact with skin or
if inhaled.
Toxic if swallowed.
Toxic if swallowed or in contact with skin.

May be fatal if swallowed and enters

airways.

H362
H370

H371

H372

H373

Causes skin irritation.

H411

H317

May cause an allergic skin reaction.

H319

Causes serious eye irritation.

H318

Causes serious eye damage.

May damage the unborn child.

May damage the unborn child. Suspected of

damaging fertility.

May damage fertility.

May damage fertility. May damage the

unborn child.
May damage fertility. Suspected of
damaging the unborn child.

Contact with acids liberates very toxic gas.

EUH 066

Contact with acids liberates toxic gas.

Repeated exposure may cause skin dryness

or cracking.

EUH 070

Toxic by eye contact.

EUH 059

Hazardous to the ozone layer.

EUH 071

EUH 201

Corrosive to the respiratory tract.

Contains lead. Should not be used on
surfaces liable to be chewed or sucked by
children.

EUH 201A Warning! Contains lead.

EUH 202
EUH 203
EUH 204
EUH 205
EUH 206

Cyanoacrylate. Danger. Bonds skin and

eyes in seconds. Keep out of the reach of
children.
Contains chromium (VI). May produce an
allergic reaction.
Contains isocyanates. May produce an
allergic reaction.

Contains epoxy constituents. May produce

an allergic reaction.
Warning! Do not use together with other
products. May release dangerous gases
(chlorine).

Warning! Contains cadmium. Dangerous

fumes are formed during use. See
information supplied by the manufacturer.
Comply with the safety instructions.

Suspected of damaging fertility or the

unborn child <state speci c effect if
known> <state route of exposure if it is
conclusively proven that no other routes of
exposure cause the hazard>.

EUH 207

Suspected of damaging fertility.

EUH 209A Can become ammable in use.

May cause harm to breast-fed children.

EUH 401

EUH 208

Contains <name of sensitising substance>.

May produce an allergic reaction.

Safety data sheet available on request.

H410

H315

May damage fertility or the unborn child

<state speci c effect if known > <state
route of exposure if it is conclusively proven
that no other routes of exposure cause the
hazard>.

EUH 032

EUH 210

Harmful in contact with skin.

Causes severe skin burns and eye damage.

Suspected of causing cancer <state route of

exposure if it is conclusively proven that no
other routs of exposure cause the hazard>.

Contact with water liberates toxic gas.

EUH 031

Suspected of damaging fertility. Suspected

of damaging the unborn child.

H312
H314

May cause cancer by inhalation.

EUH 029

H361fd

H361f

Fatal in contact with skin.

Toxic in contact with skin.

May cause cancer <state route of exposure

if it is conclusively proven that no other
routes of exposure cause the hazard>.

Risk of explosion if heated under

con nement.

Can become highly ammable in use.

H310
H311

Suspected of causing genetic defects <state

route of exposure if it is conclusively proven
that no other routes of exposure cause the
hazard>.

May form explosive peroxides.

EUH 209

Harmful if swallowed or if inhaled.

Harmful if swallowed, in contact with skin
or if inhaled.

May cause genetic defects <state route of

exposure if it is conclusively proven that no
other routes of exposure cause the hazard>.

EUH 019

In use may form ammable/explosive

vapour-air mixture.

Suspected of damaging the unborn child.

Harmful if swallowed.

Harmful if swallowed or in contact with

skin.

May cause respiratory irritation.

Explosive with or without contact with air.

H361d

Toxic if swallowed or if inhaled.

Toxic if swallowed, in contact with skin or
if inhaled.

Reacts violently with water.

May cause drowsiness or dizziness.

H335

H351

In contact with water releases ammable

gases which may ignite spontaneously.

EUH 014
EUH 018

Catches re spontaneously if exposed to air.

Self-heating in large quantities; may catch
re.

Harmful if inhaled.

H334

H350i

Self-heating: may catch re.

Explosive when dry.

EUH 006

May cause allergy or asthma symptoms or

breathing dif culties if inhaled.

Heating may cause a re or explosion.

Heating may cause a re.

EUH 001

Toxic if inhaled.

Flammable liquid and vapour.

Flammable solid.

Fatal if inhaled.

H331

H400

H412
H413

Causes damage to organs <or state all

organs affected, if known> <state route of
exposure if it is conclusively proven that no
other routes of exposure cause the hazard>.
May cause damage to organs <or state all
organs affected, if known> <state route of
exposure if it is conclusively proven that no
other routes of exposure cause the hazard>.

To avoid risks to human health and the

environment, comply with the instructions
for use.

Hazard statements coming into force with the first adaptation (2010).

Example for a safety instruction

Causes damage to organs <or state all

organs affected, if known> through
prolonged or repeated exposure <state
route of exposure if it is conclusively proven
that no other routes of exposure cause the
hazard>.
May cause damage to organs <or state
all organs affected, if known> through
prolonged or repeated exposure <state
route of exposure if it is conclusively proven
that no other routes of exposure cause the
hazard>.

Very toxic to aquatic life.

Very toxic to aquatic life with long lasting

effects.
Toxic to aquatic life with long lasting
effects.

Harmful to aquatic life with long lasting

effects.

May cause long lasting harmful effects to

aquatic life.

W280124 Stand 3/2010

H200

EU Hazard Statements