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It does not explain the orientation relationship between initial and final lattices [3]
Does not involve shear a characteristic of martensitic transformation
It does not well establish the existence of habit planes which makes it difficult to
explain the invariant plane strain associated with martensitic transformations [4]
Later, other crystallographic theories like Wechsler Lieberman Read (WLR) and Bowles and
MacKenxie (BM) were developed which explained the habit plane orientation and multidomain
structure of martensite reasonably well [5].
Both the theories are almost similar to each other but mathematically different. They are
characterized by the following features
i. lattice deformation ( > ' Bain distortion)
iii. Lattice rotation (ii. and iii. essential for invariant plane upon transformation) [3]
2. Thermodynamics
The driving force for any microstructural evolution is the possibility to reduce free energy of the
system. In general, free energy (F) of any system can contain the following terms:
F = Fbulk + Fint + Fel + Ffys
Fbulk = Bulk free energy determines the composition and volume fraction of equilibrium phases
In general for martensite, the free energy is given in terms of the following:
F = Fch + Fint + Fel
The first term in the above equation is negative change in chemical free energy which provides
the driving force of the reaction, and the next two terms represent the positive free energy due to
the interface and accommodation of elastic strain (latter may be regarded as an effective stress
acting on the interface to restrict the spontaneous growth of the plate) [1].
i. Chemical free energy
The basic equation of chemical free energy evolved from a basic calculation is given below [3]
= (1 x )
+ x
The evolution of this simple term to more complex forms has been gradually achieved and terms
such as chemical free energy have been incorporated in one of the recent model [7].
ii. Non-Chemical free energy
In general the contribution of non-chemical free energy is not of much significance in other
reactions but in martensitic reaction its contribution is quite significant. Major contributions to
this free energy are discussed below.
a. Interfacial energy
Interfacial energy between matrix and martensite depends on the coherency of the two phases
i. e., on orientations and indices of the interface of two crystals. Initially, with an assumption of
constant interfacial energy per unit area and lenticular shape with negligible thickness, the
interfacial energy was given by the following expression [3]
Fint = 2r2
r is the radius of the martensitic crystal;
Later other interfacial energies were calculated using other theories but after the introduction
micromechanical theory of branching domain walls on the interface (by Kohn and Muller)
between martensite and the parent phase, which is caused by a balance between the stress
energy interfacial energy. [7]
b. Energy for plastic deformation
Slip or twinning occurs in martensitic crystals in order to relax the stress due to the shape change
associated with lattice transformation. The energy needed for occurrence of deformation is very
large but is not properly quantified.
c. Energy for elastic deformation
Elastic distortion occurs within and outside martensitic crystal and this contributes to the elastic
energy. This is the most important factor that contributes to free energy, and the one which has
undergone several changes from a simple equation to complex equations by incorporating
various changes in conditions gradually.
Several conditions have been incorporated into models depending on the dimensions of
transformation modeling, materials, stress conditions etc., Examples of few of the them are given
below;
References:
1. J. W. Christian, The Theory of Transformations in Metals and Alloys, vol. 7, Pergamon
press, Oxford, p 13 & 921;
2. David A. Porter, Kenneth E. Easterling, Phase Transformations in Metals and Alloys, 3rd
edition, CRC Press, New York
3. Z. Nishiyama, Martensitic Transformation, Academic Press, New York, p. 342, 355, 211,
213, 216;
4. T. V. Rajan, Heat Treatment: Principles and Techniques p. 92
5. Y. Wang and A. G. Khachaturyan, Three-Dimensional Field Model and Computer
Simulation of Martensitic Transformation, Acta Metallurgica, vol. 45, 759-773, (1997)
6. Nele Moelans, Bart Blanpain, An Introduction to Phase-field Modeling of Microstructure
Evolution, Computer Coupling of Phase Diagrams and Thermochemistry, 32, 268-294, (2008)
7. A. Artemev, Y. Yin and A. G. Khachaturyan, Three Dimensional Phase Field Model of
Proper Martensitic Transformation, Acta Meteriali, 49, 1165-1177, (2001)