Professional Documents
Culture Documents
2
Natural Laws
Law of Conservation of Mass – total
amount of mass remains constant
during a chemical change
Law of Definite Proportions – in a given
chemical compound, the elements are
always combined in the same
proportions by mass
3
Scientific Method
Observation - statement that accurately describes
something seen, heard, tasted, felt, or smelled
5
Phase Diagram
6
Chemical and Physical Properties
Chemical Properties - chemical changes
rusting or oxidation
chemical reactions
Physical Properties - physical changes
changes of state
density, color, solubility
Extensive Properties - depend on quantity; i.e.,
volume
Intensive Properties - do not depend on
quantity; i.e., color, temperature, density
7
8
Mixtures, Substances,
Compounds, and Elements
Pure Substance
matter in which all samples have identical
composition and properties
Compounds: substances composed of atoms
of two or more elements chemically united in
fixed proportions
Elements: substances that cannot be
decomposed into simpler substances via
chemical reactions
9
Mixtures, Substances,
Compounds, and Elements
Compounds
substances composed of two or more
elements in a definite ratio by mass
can be decomposed into the constituent
elements
Water is a compound that can be decomposed
into simpler substances – hydrogen and oxygen
2 H2 O 2 H2 + O 2
10
Mixtures, Substances,
Compounds, and Elements
Mixtures
composed of two or more substances
homogeneous mixtures - possess the same
properties throughout the mixture
heterogeneous mixtures - consists of two
or more regions that differ in properties
11
Rounding
Rules
Off Numbers
Example
1. If the next digit is less than 5, 1.294 1.29
then the previous digit remains the same
N. x 10x
General Formula
13
To convert numbers into Scientific
Notation
19
Multiplying and Dividing Numbers
When multiplying or dividing numbers, your final
answer should have the same number of
significant digits as number from the calculation
with the fewest significant digits
20
Significant Figures
Multiplication or Division
The number of significant figures in the result is set by the
original number that has the smallest number of significant
figures
4.51 x 3.6666 = 16.536366= 16.5
22
Mixing addition/subtraction with
multiplication and division
Complete all of the addition/subtraction first, then
complete the multiplication/division (round after the
add/sub and after the mult/divs)
1.3456778 +2.8765
1.8
15.755 x 10205
1.58 x 10206
25
SI Base Units
Quantity Unit
Symbol
length meter m
mass kilogram kg
time second s
current ampere
A
temperature Kelvin K
amt. substance mole mol
26
Derived SI Units
Quantity Definition of Quantity SI unit
Area Length squared m2
28
Relationships of Some U.S. and Metric
Units
Length
1 m = 39.37 inches
2.54 cm = 1 inch
1 mile = 5280 ft
Volume
1 liter = 1.06 qt
1 qt = 0.946 liter
4 qt = 1 gal
31
The speed of sound in air is about 343 m/s. What is
this speed in miles per hour?
meters to miles
seconds to hours
m 1 mi 60 s 60 min mi
343 x x x = 767
s 1609 m 1 min 1 hour hour
32
The Factor Label Method
9.32 yd ? mm
3ft 12in 2.54cm 10mm
9.32 yd x x x x 8.52 10 3 mm
1yd 1ft 1in 1cm
33
The Factor Label Method
Express 627 milliliters in gallons.
1L 1.06qt 1gal
627 mL x x x 0.16615 5
1000 mL 1L 4qt
0.166 gal
34
The Factor Label Method
Express 3.50 (short) tons in grams.
2000 lb 454 g
3.50 tons 3178000 g
ton lb
3.18 x 10 6 g
35
The Factor Label Method
Express 2.61 x 104 cm2 in ft2.
1in 2 1ft
? ft 2.61 10 cm (
2 4 2
) ( ) 2
2.54 cm 12in
28.0938061 9 ft 2 28.1 ft 2
36
The Factor Label Method
Express 2.61 ft3 in cm3.
12 in 3 2.54 cm 3
? cm 2.61 ft (
3 3
) ( )
1 ft 1 in
73906.9696 cm 7.39 10 cm
3 4 3
37
Density and Specific Gravity
density = mass
volume
m
d v
1 cm 1 mL 97.3 cm 97 .3 mL
3 3
density m
V
39
Density and Specific Gravity
Calculate the density of a substance if
742 grams of it occupies 97.3 cm3.
1 cm 1 mL 97.3 cm 97 .3 mL
3 3
density m
V
density 742 g
97.3 mL
density 7.63 g/mL
40
Density and Specific Gravity
Suppose you need 125 g of a corrosive
liquid for a reaction. What volume do
you need?
liquid’s density = 1.32 g/mL
m m
density V
V density
125 g
V 94.7 mL
1.32 g mL 41
Density and Specific Gravity
A 31.10 gram piece of chromium is dipped into a
graduated cylinder that contains 5.00 mL of
water. The water level rises to 9.32 mL. What is
the specific gravity of chromium?
31.10 g
density of Cr
4.32 mL
7.19907 g 7.20 g
mL mL
7.20 g mL
Specific Gravity of Cr g
7.20
1.00 mL
42
Heat and Temperature
Heat and Temperature
are not the same thing
T is a measure of the
intensity of heat in a
body
3 common temperature
scales - all use water as
a reference
43
Relationships of the Three
Temperature Scales
Kelvin and Centigrade Relationsh ips
K C 273
o
or
o
C K 273
44
Relationships of the Three
Temperature Scales
Fahrenheit and Centigrade Relationsh ips
180 18 9
1.8
100 10 5
o
F 1.8 o C 32
or
F 32
o
o
C
1.8
45
Convert 172.9 0F to degrees Celsius.
0F = (1.8 x 0C) + 32
0F – 32 = (1.8 x 0C)
(0F – 32) = 0C
1.8
46
Chapter 2
Atoms, Molecules, and Ions
Periodic Table: Elements
Atomic number =
the number of protons
6
Atomic mass =
Weight relative to C
one mole
12.011 Chemical symbol
Isotopes
– atoms whose nuclei have the same atomic number
but different mass numbers
Mass number =
Protons +neutrons
50
Cr
24
Atomic number
52 53 54
Cr Cr Cr
24 24 24
Calculating Average Atomic Mass
Mass number Isotope Mass
%Abundance
50 49.9461
4.35%
52 51.9405
83.79%
53 52.9407
9.50%
49.9461 x 0.0435 = 2.17
54 53.9389
51.9405 x 0.8379 =43.52
2.36%
52.9407 x 0.0950 = 5.03
53.9389 x 0.0236 = 1.27
51.99
• Essentially all elements combine to form
compounds
• Compounds are of two types:
– Molecular, which involve shared electrons and consist
of electrically neutral, discrete particles called
molecules
– Ionic compounds, which involve electron transfer and
charged particles called ions
• Chemical formulas are collections of
chemical symbols that are used to describe
elements and compounds
– Free elements are not combined with other elements in
a compound
• Examples: Fe (iron), Na (sodium), and K
(potassium)
– Many nonmetals occur as diatomic molecules
A molecule is an aggregate of two or more atoms in a definite
arrangement held together by chemical bonds
2 atoms of Al 1 atom Co
2 atoms Cl
3 atoms of S
12 atoms H
12 atoms of O
6 atom O
• Chemical equations describe what happens
in a chemical reactions
• Hydrogen and oxygen combine to form
water
• Hydrogen and oxygen are called reactants
• Water is called the product
• Reactants are separated from products with “”
– 2 H 2 + O2 2 H 2 O
• Note that the “” is like an equal sign because both
sides of the equation have the same number of each
type of atom
• This can be represented as:
Note: Mass is conserved because the
number of atoms of each type remains
the same on each side of the arrow.
(Both sides of the arrow show 4 H and
2 O atoms.) This equation is said to be
balanced.
Space-filling models:
Black atoms = carbon
White atoms = hydrogen
• Other classes of hydrocarbons exist
• Different classes of organic compounds are
derived from hydrocarbons by replacing
hydrogen
• For example alcohols result when a H is
replaced by OH in a hydrocarbon
Methanol (wood alcohol),
CH3OH, is related to methane,
CH4, by replacing one H with
OH.
An ion is an atom, or group of atoms, that has a net positive
or negative charge.
11 protons 11 protons
Na Na+
11 electrons 10 electrons
17 protons 17 protons
Cl Cl-
17 electrons 18 electrons
Ions
-e -e -e -e -e -e
-e -e -e -e -e -e
Mg 2+
A monatomic ion contains only one atom
Na+, Cl-, Ca2+, O2-, Al3+, N3-
name
(2) Name the nonmetal with the suffix “–
ide”
Chemical Nomenclature
Examples
+2 +3 ±4 -3 -2 -1
Ionic Charges
Transition metal ionic compounds
indicate charge on metal with Roman numerals
Al2O3
Ca2+ Br-
CaBr2
Na+ CO32-
Na2CO3
Some Polyatomic Ions
NH4+ ammonium SO42- sulfate
CO32- carbonate SO32- sulfite
- -
HCO3 bicarbonate NO3 nitrate
ClO3- chlorate NO2- nitrite
Cr2O72- dichromate SCN- thiocyanate
2- -
CrO4 chromate OH hydroxide
Problems
Name the following compounds:
LiF
NH4NO3
MgCl2
FeO
NaOH
Al2(SO4)3
Problems
Give the correct chemical formula for
the following compounds
Calcium bromide
Strontium phosphide
Potassium sulfate
Carbon tetrachloride
Lithium selenide
Molecular Compounds
HI
NF3
SO2
N2Cl4
NO2
N2O
An acid can be defined as a substance that yields
hydrogen ions (H+) when dissolved in water.
HCl
•Pure substance, hydrogen chloride
•Dissolved in water (H+ Cl-), hydrochloric acid
89
Atomic Weights
Weighted average of the
masses of the constituent
isotopes if an element.
Tells us the atomic masses of
every known element.
Lower number on periodic
chart.
90
The Mole
A number of atoms, ions, or molecules
that is large enough to see and handle.
A mole = number of things
Just like a dozen = 12 things
One mole = 6.022 x 1023 things
Avogadro’s number = 6.022 x 1023
Symbol for Avogadro’s number is NA.
91
The Mole
92
Mole and Avogadro’s Number
1 mol Na = 6.02 x 10 23 Na atoms
1 mol H2 = 6.02 x 10 23 H2 molecules
1 mole NaCl = 6.02 x 10 23 NaCl Formula Units
1 mole Na+1 = 6.02 x 10 23 Na+1 ions
93
The Mole
Example: Calculate the mass of a single
Mg atom, in grams, to 3 significant
figures.
1 mol Mg atoms
? g Mg 1 Mg atom
6.022 10 23
Mg atoms
24.30gMg
4.04 10 23 g Mg
1 mol Mg atoms
94
The Mole
Example: How many atoms are
contained in 1.67 moles of Mg?
6.022 10 23 Mg atoms
? Mg atoms 1.67 mol Mg
1 mol Mg
1.0110 24 Mg atoms
95
The Mole
Example: How many moles of Mg atoms are
present in 73.4 g of Mg?
You do it!
96
The Mole
Example 2-4: How many moles of Mg atoms
are present in 73.4 g of Mg?
1 mol Mg atoms
? mol Mg 73.4 g Mg
24.30 g Mg
3.02 mol Mg
IT IS IMPERATIVE THAT YOU KNOW
HOW TO DO THESE PROBLEMS
97
Formula Weights, Molecular
Weights, and Moles
How do we calculate the molar mass of
a compound?
add atomic weights of each atom
The molar mass of propane, C3H8, is:
3 C 3 12.01 amu 36.03 amu
8 H 8 1.01 amu 8.08 amu
Molar mass 44.11 amu
98
Formula Weights, Molecular
Weights, and Moles
99
Formula Weights, Molecular
Weights, and Moles
Example: Calculate the number of C3H8
molecules in 74.6 g of propane.
? C3 H 8 molecules 74.6 g C3 H 8
1 mole C3 H 8 6.022 10 23 C3 H 8 molecules
44.11 g C3 H 8 44.11 g C3 H 8
1.02 10 molecules
24
100
Percent Composition and
Formulas of Compounds
% composition = mass of an individual
element in a compound divided by the
total mass of the compound x 100%
Determine the percent composition of C
in C3H8.
mass C
%C 100%
mass C3 H 8
3 12.01 g
100%
44.11 g
81.68% 101
Percent Composition and
Formulas of Compounds
Example: Calculate the percent
composition of Fe2(SO4)3 to 3 significant
figures.
You do it!
102
Percent Composition and
Formulas of Compounds
Example: Calculate the percent
composition of Fe2(SO4)3 to 3 sig. fig.
2 Fe 2 55.8 g
% Fe 100% 100% 27.9% Fe
Fe 2 (SO 4 ) 3 399.9 g
3 S 3 32.1 g
%S 100% 100% 24.1% S
Fe 2 (SO 4 ) 3 399.9 g
12 O 12 16.0 g
% O 100% 100% 48.0% O
Fe 2 (SO 4 ) 3 399.9 g
Total 100%
103
Derivation of Formulas from
Elemental Composition
Empirical Formula - smallest whole-number ratio of
atoms present in a compound
CH2 is the empirical formula for alkenes
No alkene exists that has 1 C and 2 H’s
Molecular Formula - actual numbers of atoms of each
element present in a molecule of the compound
Ethene – C2H4
Pentene – C5H10
We determine the empirical and molecular formulas of a
compound from the percent composition of the
compound.
percent composition is determined experimentally
104
Derivation of Formulas from
Elemental Composition
Example: A compound contains 24.74% K,
34.76% Mn, and 40.50% O by mass. What is
its empirical formula?
Make the simplifying assumption that we
have 100.0 g of compound.
In 100.0 g of compound there are:
24.74 g of K
34.76 g of Mn
40.50 g of O
105
Derivation of Formulas from
Elemental Composition
1 mol K
? mol K 24.74 g K 0.6327 mol K
39.10 g K
1 mol Mn
? mol Mn 34.76 g Mn 0.6327 mol Mn
54.94 g Mn
1mol O
? mol O 40.50 g O 2.531 mol O
16.00 g O
obtain smallest whole number ratio
106
Derivation of Formulas from
Elemental Composition
1 mol K
? mol K 24.74 g K 0.6327 mol K
39.10 g K
1 mol Mn
? mol Mn 34.76 g Mn 0.6327 mol Mn
54.94 g Mn
1mol O
? mol O 40.50 g O 2.531 mol O
16.00 g O
obtain smallest whole number ratio
0.6327 0.6327
for K 1K for Mn 1 Mn
0.6327 0.6327
107
Derivation of Formulas from
Elemental Composition
1 mol K
? mol K 24.74 g K 0.6327 mol K
39.10 g K
1 mol Mn
? mol Mn 34.76 g Mn 0.6327 mol Mn
54.94 g Mn
1mol O
? mol O 40.50 g O 2.531 mol O
16.00 g O
obtain smallest whole number ratio
0.6327 0.6327
for K 1K for Mn 1 Mn
0.6327 0.6327
2.531
for O 4O
0.6327
thus the chemical formula is KMnO 4
108
Derivation of Formulas from
Elemental Composition
Example: A sample of a compound
contains 6.541g of Co and 2.368g of O.
What is empirical formula for this
compound?
You do it!
109
Derivation of Formulas from
Elemental Composition
Example: A sample of a compound
contains 6.541g of Co and 2.368g of O.
What is empirical formula for this
compound?
1 mol Co
? mol Co 6.541 g Co 0.1110 mol Co
58.93 gCo
1mol O
? mol O 2.368 g O 0.1480 mol O
16.00 g O
find smallest whole number ratio
110
Derivation of Formulas from
Elemental Composition
Example: A sample of a compound
contains 6.541g of Co and 2.368g of O.
What is empirical formula for this
compound?
0.1110 0.1480
for Co 1 Co for O 1.333O
0.1110 0.1110
multipy both by 3 to turn fraction to whole number
1 Co 3 3 Co 1.333 O 3 4 O
Thus the compound' s formula is :
Co3O 4
111
Some Other Interpretations of
Chemical Formulas
Example: What mass of ammonium
phosphate, (NH4)3PO4, would contain
15.0 g of N?
112
Some Other Interpretations of
Chemical Formulas
Example: What mass of ammonium
phosphate, (NH4)3PO4, would contain
15.0 g of N?
molar mass of (NH 4 )3 PO 4 149.0 g/mol
1 mol N
? mol N 15.0 g of N 1.07 mol N
14.0 g N
1 mol (NH 4 ) 3 PO 4
1.07 mol N 0.357 mol (NH 4 ) 3 PO 4
3 mol N
113
Some Other Interpretations of
Chemical Formulas
Example: What mass of ammonium
phosphate, (NH4)3PO4, would contain
15.0 g of N?
molar mass of (NH 4 )3 PO 4 149.0 g/mol
1 mol N
? mol N 15.0 g of N 1.07 mol N
14.0 g N
1 mol (NH 4 )3 PO 4
1.07 mol N 0.357 mol (NH 4 )3 PO 4
3 mol N
149.0 g (NH 4 )3 PO 4
0.357 mol (NH 4 )3 PO 4 53.2 g (NH 4 )3 PO 4
1 mol (NH 4 )3 PO 4
114
Purity of Samples
The percent purity of a sample of a
substance is always represented as
mass of pure substance
% purity = 100%
mass of sample
mass of sample includes impurities
115
Purity of Samples
Example 2-18: A bottle of sodium
phosphate, Na3PO4, is 98.3% pure Na3PO4.
What are the masses of Na3PO4 and
impurities in 250.0 g of this sample of
Na3PO4?
98.3 g Na 3 PO 4
unit factor
100.0 g sample
116
Purity of Samples
Example 2-18: A bottle of sodium
phosphate, Na3PO4, is 98.3% pure Na3PO4.
What are the masses of Na3PO4 and
impurities in 250.0 g of this sample of
Na3PO4?
98.3 g Na 3PO 4
unit factor
100.0 g sample
98.3 g Na 3 PO 4
? g Na 3 PO 4 250.0 g sample
100.0 g sample
= 246 g Na 3PO 4
117
Purity of Samples
Example: A bottle of sodium phosphate,
Na3PO4, is 98.3% pure Na3PO4. What are
the masses of Na3PO4 and impurities in
250.0 g of this sample of Na3PO4?
98.3 g Na 3 PO 4
unit factor
100.0 g sample
98.3 g Na 3 PO 4
? g Na 3 PO 4 250.0 g sample
100.0 g sample
= 246 g Na 3 PO 4
? g impurities = 250.0 g sample - 246 g Na 3 PO 4
118
= 4.00 g impurities
Reaction Stoichiometry
Given the following balanced equation, how
many moles of O2 are required to react with 6.0
moles C6H6?
119
Reaction Stoichiometry
Given the following balanced equation, how
many grams of O2 are required to react with 6.0
moles C6H6?
120
Reaction Stoichiometry
Given the following balanced equation, how
many grams of O2 are required to react with 0.50
grams C6H6?
121
Limiting Reactant
Given the following balanced equation, how
many grams of H2O are required to react with
0.50 g C6H6 and 0.50 g O2?
123
Reactions in Aqueous
Solution
Chapter 4
A solution is a homogenous mixture of 2 or more
substances
H2O
C6H12O6 (s) C6H12O6 (aq)
d
d
H2O
The Solubility of Ionic Compounds in Water
The solubility of ionic compounds in water depends upon the relative
strengths of the electrical forces between ions in the ionic compound
and the attractive forces between the ions and water molecules in the
solvent. There is a tremendous range in the solubility of ionic
compounds in water! The solubility of so called “insoluble” compounds
may be several orders of magnitude less than ones that are called
“soluble” in water, for example:
Have a sour taste. Vinegar owes its taste to acetic acid. Citrus
fruits contain citric acid.
React with certain metals to produce hydrogen gas.
React with carbonates and bicarbonates to produce carbon
dioxide gas
Bases
Have a bitter taste.
Diprotic acids
H2SO4 H+ + HSO4- Strong electrolyte, strong ac
HSO4- H+ + SO42- Weak electrolyte, weak acid
Triprotic acids
H3PO4 H+ + H2PO4- Weak electrolyte, weak acid
H2PO4- H+ + HPO42- Weak electrolyte, weak acid
HPO42- H+ + PO43- Weak electrolyte, weak acid
Neutralization Reaction
2Mg + O2 2MgO
Oxidation number: the charge an
atom would have if the shared
electrons were transferred
completely to the atom with the
greater attraction for the
electrons.
Combination Reaction
A+B C
0 0 +4 -2
S + O2 SO2
Oxidized? Reduced? Oxidizing agent? Reducing agent?
Decomposition Reaction
C A+B
+1+5 -2 +1 -1 0
2KClO3 2KCl + 3O2
Types of Oxidation-Reduction Reactions
M + BC MC + B
Reaction will occur only
if M is above B.
Ca + 2H2O Ca(OH)2 + H2
Pb + 2H2O Pb(OH)2 + H2
Zn (s) + CuSO4 (aq) ZnSO4 (aq) + Cu (s)
Zn Zn2+ + 2e- Zn is oxidized Zn is the reducing agent
Chlorine Chemistry
Classify the following reactions.
Dilution
Add Solvent
MiVi = MfVf
How would you prepare 60.0 mL of 0.20 M
HNO3 from a stock solution of 4.00 M HNO3?
MiVi = MfVf
P1 x V1 = P2 x V2
P1 = 726 mmHg P2 = ?
V1 = 946 mL V2 = 154 mL
619 torr
Amedeo Avogadro studied this and devised Avogadro’s
principle:
When measured at the same temperature and
pressure, equals volumes of gases contain equal
number of moles
The volume of a gas is directly proportional to its
number of moles, n
V n (at constant T and P)
At constant T and P
P = 1 atm
PV = nRT
1 mol HCl
nRT n = 49.8 g x = 1.37 mol
V= 36.45 g HCl
P
L•atm
1.37 mol x 0.0821 mol•K
x 273.15 K
V=
1 atm
V = 30.6 L
Argon is an inert gas used in lightbulbs to retard the
vaporization of the filament. A certain lightbulb
containing argon at 1.20 atm and 18 0C is heated to
85 0C at constant volume. What is the final pressure of
argon in the lightbulb (in atm)?
2 2
2
v m2
1
or with vi rms
v
2
i
v2 m1
2
v
m2
M2
v
1 rms
2 rms
m1 M1
Note that heavier gases move slower
than lighter gases
The rate of effusion is proportional to
the average molecular speed, thus
effusion rate (gas 1)
v1 rms
M2
effusion rate (gas 2) v2 rms M1
The kinetic theory predicts that
absolute zero is the temperature at
which the average kinetic energy of an
ideal gas is zero
Real gases exhibit non-ideal behavior
Gas Stoichiometry
L•atm
0.187 mol x 0.0821 x 310.15 K
nRT mol•K
V= = = 4.76 L
P 1.00 atm
Ideal Gas Law and Reaction
Stoichiometry
Pi = Xi PT PT = 1.37 atm
0.116
Xpropane = = 0.0132
8.24 + 0.421 + 0.116
Therefore: E=q+w
Thermodynamics
State functions are properties that are determined by the state
of the system, regardless of how that condition was achieved.
energy, pressure, volume, temperature
DE = q + w
q = - 407 J w = -515
J
E = q + w = - 407 J + ( - 515 J) = - 922 J
E = - 922 J x 1 kJ = -0.922 kJ
1000 J
E = - 922 J x 1 cal = - 220 cal
4.184 J
E is a state function, q and w are not.
First Law of Thermodynamics
900C
400C
greater thermal energy
Thermochemistry is the study of heat change in chemical
reactions.
The system is the specific part of the universe that is of
interest in the study. SURROUNDINGS
SYSTEM
DH = qp
Is DH negative or positive?
Endothermic
DH > 0
Is DH negative or positive?
Exothermic
DH < 0
1 mol P4 3013 kJ
266 g P4 x x = 6470 kJ
123.9 g P4 1 mol P4
The specific heat (s) of a substance is the amount of heat (q)
required to raise the temperature of one gram of the
substance by one degree Celsius.
The heat capacity (C) of a substance is the amount of heat (q)
required to raise the temperature of a given quantity (m) of
the substance by one degree Celsius.
C = ms
Heat (q) absorbed or
released:
q = msDt
q = CDt
Dt = tfinal -
tinitial
How much heat is given off when an 869 g iron bar cools
from 940C to 50C?
s of Fe = 0.444 J/g • 0C
Reaction at Constant V
DH = qrxn
DH ~ qrxn
No heat enters or leaves!
Constant-Pressure Calorimetry
Reaction at Constant P
DH = qrxn
aA + bB cC + dD
Example:
Problem: Calculate the energy involved in the oxidation of elemental
sulfur to sulfur trioxide from reactions:
1) S (s) + O2 (g) SO2 (g) H1 = -296.0 kJ
-6535kJ
= - 3267 kJ/mol C6H6
2 mol
The
Quantum Mechanical Atom
Chapter 7
Properties of Waves
Electromagnetic
radiation is the emission
and transmission of energy
in the form of
electromagnetic waves.
E = hn
E = hn
E = hc
l
E = 6.63 x 10-34 (J•s) x 3.00 x 10 8 (m/s)
0.154 x 10-9 (m)
E = 1.29 x 10 -15 J
Bohr’s Model of
the Atom (1913)
1. e- can only have specific
(quantized) energy
values
2. light is emitted as e-
moves from one energy
level to a lower energy
level
1
En = -RH( )
n2
1 1
Ephoton = DE = RH( )
n2i n2f
Ephoton = 2.18 x 10-18 J x (1/25 - 1/9)=1.55 x 10-19 J
Ephoton = h x c / l
l = h x c / Ephoton
= 6.63 x 10-34 (J•s) x 3.00 x 108 (m/s)/1.55 x 10-19J
= 1.28 x 10-6 m
= 1.28 x 10-6 m x 1nm = 1280 nm
10-9m
Problems with the Bohr model.
Bohr’s approach only works for the hydrogen atom. It can not explain the
spectra of atoms with more than one electron.
l = 1 (p orbitals)
l = 2 (d orbitals)
Electron Spin
l=2
Atoms With More Than One Electron
? ?
Li
Be
B5
C 634electrons
electrons
BBe
Li1s1s
1s
2 2s
222s
2s
2 2p
12 1
H
He12electron
electrons
He
H 1s
1s12
Paramagnetic Diamagnetic
unpaired electrons all electrons paired
2p 2p
The most stable arrangement of electrons
in subshells is the one with the greatest
number of parallel spins (Hund’s rule).
C 967
N
O
F
Ne 810
electrons
electrons
electrons
Ne
N
O
C
F 1s
1s222s
22s222p
22p5
2346
Orbital Diagrams H Be
Element Symbol Electron Orbital Diagrams
Configuration
Hydrogen H 1s1
1s 2s
Helium He 1s2
1s 2s
Lithium Li 1s22s1
1s 2s
Beryllium Be 1s22s2
1s 2s
Orbital Diagrams - II : B Ne
Ti [Ar] 4s 2 3d 2 [Ar] 3d 2 4s
2
V [Ar] 4s 2 3d 3 [Ar]Anomalies
3d 3 4s
2 to Filling
Cr [Ar] 4s 1 3d 5
Mn [Ar] 4s 2 3d 5
Fe [Ar] 4s 2 3d 6 Either order will be OK !
Co [Ar] 4s 2 3d 7 But it’s normally best to
Anomalies
Ni [Ar] 4s 2 3d 8 put the one filling last!!!
to Filling
Cu [Ar] 4s 1 3d 10
2 10
The Periodic Table of the Elements
H Electronic Structure He
Li Be B C N O F Ne
N Mg Al Si P S Cl Ar
aK Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
Rb Sr Y Zr NbM Tc R Rh Pd A Cd In Sn Sb Te I Xe
Cs Ba La Hf Ta oW Re uOs Ir Pt gAu Hg Tl Pb Bi Po At Rn
Fr Ra Ac Rf Ha Sg
1s22s22p63s2 2 + 2 + 6 + 2 = 12 electrons
Abbreviated as [Ne]3s2 [Ne] 1s22s22p6
ns2np1
ns2np2
ns2np3
ns2np4
ns2np5
ns2
d10
d1
d5
4f
5f
Electron Configurations of
Metal Ions
Na+, Al3+, F-, O2-, and N3- are all isoelectronic with Ne
X (g) + e- X-(g)
Li + F Li+ F -
1s22s1 1s22s22p5 [He]
1s2[2Ne]
1s 2s22p6
Li Li+ + e-
e- + F F -
Li+ + F - Li+ F -
F + F F F
7e- 7e- 8e- 8e-
Lewis structure of F2
H + O + H H O H or H O H
2e-8e-2e-
O C O or O C O
8e- 8ebonds
double - 8e- double bonds
N N or N N
8e-8e
triple -
bond
triple bond
Lengths of Covalent Bonds
Bond
Bond Length
Type (pm)
C-C 154
CC 133
CC 120
C-N 143
CN 138
electron rich
electron poor
region
region e- poor e- rich
H F H F
d+ d-
Electronegativity is the ability of an atom to attract
toward itself the electrons in a chemical bond.
X (g) + e- X-(g)
H O H or H O H
Two possible skeletal structures of formaldehyde (CH2O)
H
H C O H C O
H
( )
total number 1 total number
on an atom in of valence
a Lewis
= electrons in - of nonbonding - of bonding
electrons 2 electrons
structure the free atom
-1 +1 H 0 0
H C O H C O
H
FC C1 = 4 – 2 - ½(6) = -1 FC C2 = 4 – 0- ½(8) = 0
FC O1 = 6 – 2- ½(6) = +1 FC O2= 6-4-½(4) =
0
Resonance
+ - - +
O O O O O O
- - - -
O C O O C O O C O
O O O
- -
Exceptions to the Octet Rule
Be – 2e-
BeH2 2H – 2x1e- H Be H
4e-
Odd-Electron Molecules
N – 5e-
NO O – 6e- N O
11e-
The Expanded Octet (central atom with principal quantum number n > 2)
F
F F
S – 6e- 6 single bonds (6x2) = 12
SF6 6F – 42e- S 18 lone pairs (18x2) = 36
48e- Total = 48
F F
F
How the Model Explains the Properties
of Covalent Compounds
Bond Energy
H2 (g) H (g ) + H (g ) DH0 = 436.4 kJ
Cl2 (g) Cl (g)+ Cl (g ) DH0 = 242.7 kJ
HCl (g) H (g ) + Cl (g ) DH0 = 431.9 kJ
O 2 (g ) O (g ) + O (g ) DH0 = 498.7 kJ O O
N2 (g) N (g ) + N (g ) DH0 = 941.4 kJ N N
Bond Energies
Single bond < Double bond < Triple bond
Thus the relationship between bond length, bond strength, and bond energy is :
VS
# of atoms # lone
bonded to pairs on Arrangement of Molecular
Class central atom central atom electron pairs Geometry
B B
10.1
BeCl2
10.1
VSEPR
# of atoms # lone
bonded to pairs on Arrangement of Molecular
Class central atom central atom electron pairs Geometry
10.1
BF3
10.1
VSEPR
# of atoms # lone
bonded to pairs on Arrangement of Molecular
Class central atom central atom electron pairs Geometry
10.1
CH4
10.1
VSEPR
# of atoms # lone
bonded to pairs on Arrangement of Molecular
Class central atom central atom electron pairs Geometry
10.1
PCl5
10.1
VSEPR
# of atoms # lone
bonded to pairs on Arrangement of Molecular
Class central atom central atom electron pairs Geometry
10.1
SF6
10.1
Molecular Shapes
trigonal trigonal
AB3 3 0
planar planar
trigonal
AB2E 2 1 bent
planar
SO2
10.1
SO2
10.1
VSEPR
# of atoms # lone
bonded to pairs on Arrangement of Molecular
Class central atom central atom electron pairs Geometry
10.1
NH3
10.1
VSEPR
# of atoms # lone
bonded to pairs on Arrangement of Molecular
Class central atom central atom electron pairs Geometry
10.1
H2O
10.1
VSEPR
# of atoms # lone
bonded to pairs on Arrangement of Molecular
Class central atom central atom electron pairs Geometry
trigonal trigonal
AB5 5 0
bipyramidal bipyramidal
trigonal seesaw
AB4E 4 1
bipyramidal
SF4
10.1
SF4
10.1
VSEPR
# of atoms # lone
bonded to pairs on Arrangement of Molecular
Class central atom central atom electron pairs Geometry
trigonal trigonal
AB5 5 0
bipyramidal bipyramidal
trigonal distorted
AB4E 4 1
bipyramidal tetrahedro
trigonal n
AB3E2 3 2 T-shaped
bipyramidal
F
F Cl
10.1
BrF3
10.1
VSEPR
# of atoms # lone
bonded to pairs on Arrangement of Molecular
Class central atom central atom electron pairs Geometry
trigonal trigonal
AB5 5 0
bipyramidal bipyramidal
trigonal distorted
AB4E 4 1
bipyramidal tetrahedro
trigonal n
AB3E2 3 2 T-shaped
bipyramidal
trigonal
AB2E3 2 3 linear
bipyramidal
I
I 10.1
ICl2 -
10.1
VSEPR
# of atoms # lone
bonded to pairs on Arrangement of Molecular
Class central atom central atom electron pairs Geometry
10.1
BrF5
10.1
VSEPR
# of atoms # lone
bonded to pairs on Arrangement of Molecular
Class central atom central atom electron pairs Geometry
10.1
ICl4 -
10.1
Predicting Molecular Geometry
What are the molecular geometries of AsH3,
OF2, AlCl4-, H3O+, SnCl5-?
bent
OF2
Trigonal pyramid
H3O+
electron rich
electron poor
region
region
H F
d d
10.2
Polarity of CO2 and H2O
(a) .. .. ..
P P P
H H H H
H H
H H Bond dipoles H Molecular Dipole
Molecular shape
10.2
Which of the following molecules have a dipole moment?
H2O, CO2, SO2, and CH4
O S
H C H
O C O
no dipole moment H
nonpolar molecule no dipole moment
nonpolar molecule
10.2
Valence Bond Theory
Basic Principle of Valence Bond Theory:
a covalent bond forms when the orbitals from
two atoms overlap and a pair of electrons
occupies the region between the nuclei.
Usually this means that each bonding orbital
should contain one electron. The electrons
must have opposite spins.
2 (linear) sp BeCl2
H
O
s bonds = 6 + 1 = 7
H C C O H
p bonds = 1
H
10.5
Skip pages 318-326 molecular orbitals
Resonance implies electron delocalization. This
can be explained by valence bond and molecular
orbital theory.
This occurs when a p orbital overlaps with more
than one other p orbital. The p electrons are free
to move around three or more atoms.
Examples: ozone, benzene, sulfur trioxide.
Structures with delocalized electrons always
have greater stability than similar structures
without delocalized electrons.
Delocalized electrons are not confined between two
adjacent bonding atoms, but actually extend over three or
more atoms.
10.8
Experiments show O2 is paramagnetic
O
O
No unpaired e-
Should be diamagnetic
10.6
Energy levels of bonding and antibonding molecular
orbitals in hydrogen (H2).
10.7
Number of Number of
bond order =
1
2 ( electrons in
bonding
MOs
-
electrons in
antibonding
MOs
)
bond
½ 1 ½ 0
order
10.7