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Test - 4 (Paper-I) (Answers & Hints)
All India Aakash Test Series for JEE (Main)-2014
TEST - 4 (Paper-I)
ANSWERS
PHYSICS
CHEMISTRY
MATHEMATICS
1.
(4)
31.
(1)
61.
(2)
2.
(3)
32.
(4)
62.
(1)
3.
(1)
33.
(1)
63.
(3)
4.
(1)
34.
(3)
64.
(2)
5.
(2)
35.
(4)
65.
(2)
6.
(4)
36.
(2)
66.
(1)
7.
(3)
37.
(3)
67.
(1)
8.
(3)
38.
(2)
68.
(2)
9.
(1)
39.
(1)
69.
(4)
10.
(3)
40.
(1)
70.
(3)
11.
(2)
41.
(2)
71.
(2)
12.
(3)
42.
(1)
72.
(2)
13.
(3)
43.
(2)
73.
(4)
14.
(3)
44.
(1)
74.
(3)
15.
(3)
45.
(3)
75.
(3)
16.
(4)
46.
(3)
76.
(2)
17.
(3)
47.
(3)
77.
(4)
18.
(4)
48.
(4)
78.
(3)
19.
(3)
49.
(3)
79.
(2)
20.
(1)
50.
(1)
80.
(2)
21.
(3)
51.
(1)
81.
(2)
22.
(3)
52.
(3)
82.
(2)
23.
(3)
53.
(2)
83.
(2)
24.
(4)
54.
(3)
84.
(1)
25.
(4)
55.
(4)
85.
(1)
26.
(3)
56.
(2)
86.
(4)
27.
(3)
57.
(4)
87.
(4)
28.
(4)
58.
(4)
88.
(3)
29.
(4)
59.
(1)
89.
(2)
30.
(3)
60.
(1)
90.
(3)
1/11
PART - A (PHYSICS)
1.
For pure rolling,
Answer (4)
( 3 1)mg
Spring force : kx = R ( 3 1)
R
Total force along centre of circle
= 2mg cos 30 + mg cos 30

6.
3 3mg
2
90
v2
ai
R
i
2
2R
( j)
2
3
ai
2
v2
( j)
2R
Ml
12
dF
l /2
2
dm
...(i)
BC
AC
x dx
...(ii)
Also,
v1
Now, v sin = v1
...(i)
and v sin( ) = v2
...(ii)
7.
v 22
2v1v 2 cos
f R
2/11
8.
f
m
mR
2
ft
m
at
...(i)
1
sin
2
1
cos
...(i)
...(ii)
AC
AB
t v12
v 22
...(iii)
v1v 2 2
v1 v 2
Answer (3)
G
G
G
mu mv1 mv 2
...(i)
2ft
mR
...(ii)
Answer (3)
Velocity of BALL w.r.t. ground (after collision)
= (v u) + v = 2v u
K = Kf Ki
2f
mR
t
OC
u2 = v12 + v22 = v12 + v22 + 2v1v2 cos 90 ...(iii)

G G
Thus, v1 v 2 0
sin
Answer (2)
a
1
1
1
mu 2
mv12
mv 22
2
2
2
From equations (i) and (ii), we get
Solving (i) and (ii), we get
v12
Solving equations (i), (ii) and (iii), we get
Answer (1)
cot
v2
Also, BC
9m 2u 2
8M l
Let point P moves with velocity v and its direction

makes angle with l1.
5.
cos
OC
AC
l /2
sin
l
4
v
45
v1
OC
BC
Answer (1)
mu
4.
3.
...(iii)
3f
18 g
Answer (4)
Answer (3)
G
ap
2 2
R
0
= NB
2.
1 2
at
2
Now, s
= 2mg
1
m[(2v u )2 ]
2
= 2mv(v u)
=
...(ii)
m 2
u
2

9.
Answer (1)
13. Answer (3)
The impact should be inelastic.
2u
3v
WE theorem,
2
u
3
14. Answer (3)
1
2
KE = (2 1) v
2
1
2
F 30 = 1(m1 + m2)g
F 30 = 0.5 15 10
3 v2
F = 105 N
=3
Here, friction (limiting and kinetic) between 10 kg

and horizontal surface is 30 N.
v
2
4 2
v
9
15. Answer (3)
3
ms
2
10. Answer (3)
W
=
t
mxrel = (m + M)x
1
3
2 ms
200
N
3
MA
t
2
m
gh
t
v
2
m
gh
=
t
1
2
d
v
dt rel
m M
1
2
mv
2
mgh
xrel
m M
JG JG
F d
work done =
= V
V
A
1 V
2 A
P gh
11. Answer (2)

yCM =
m1y1
m1
m2 y 2
4R
3
m m
5R
=
3
12. Answer (3)
dv
dt
t
dv
0
20t 100
10
20t 100
dt
10
v = 25 + t 2 10t
dh
dt
10 10
25 t
10
10
1 2
2
16. Answer (4)
a
2
[m
a
4
Hence, d
m][ x ]
a
2
3a
a
4
13a
4
17. Answer (3)

Forward journey :
10 2
2
10t
y
125
m
3
1
2
= 15 kW
The block leaves the surface at t = 5 s.

Now, a
10
m2
2R
= 10
10 2
2
5
1
2
t
1
10
2
1
s
2
1
4
15
m
4
vx = 10 ms1, vy = 5 ms1
3/11

Backward journey :
15
4
20. Answer (1)
1
10 t
2
5 t
3
s
2
e vx t = 5
3
2
e 10
1
3
v
R
t=ts
18. Answer (4)
l
N1
0 R
G
mg
N2
v
f2
f1
2v 0
mR
2
mg
Here, v max is the maximum safe speed for no

skidding.
...(iv)
R = 0R + Rt
...(v)
2f
t
m
...(vi)
N1 + N2 = mg
l
f h
2
From (ii) and (iii),
l = 2a
fh
a
...(iii)
v
2fh
l
v max
gra
h
mg
mv
r a
...(iv)
v max , then
rg
gra
h
a
h
mv
3v
2
2mv
mv
3v
2
4/11
3f
v
4
7v
4
v
3v
v
v
4L
3v
2v 0
3ft
m
mv 0
5
3
ft
m
2v 0
mg T = mA
T
I
2
mI
6
v0
2ft
m
3ft
m
5v 0
9 g
v
4
7v
4
...(i)
...(ii)
I
A =
2
Now, at a
19. Answer (3)

2mv
2v 0
21. Answer (3)
v max is the maximum safe speed for no toppling.
If v max
For pure rolling,
l
2
N2
N1 = 0
When mg
...(ii)
N1
1
mg
2
...(ii)
= 0 + t
For no overturning :
N1
...(iii)
...(i)
rg
...(i)
2f
mR
v max
f
t
m
For no skidding :
mv
r
t=0
v
0 = 0
3
2v0
3
I
2
mg
A ...(iii)
Solving A = 6 ms2
22. Answer (3)
I2=5
R=7
7
rad/s2
3
KE about P = T KE about P + R KE about P
4
[ i 2 j]
5
T KE about point P = 0, because point P translates

with VCM
1
I
2 P
R KE about point P =
1 mR
=
2
2
mR
16
2
I1
ICM
I3
ICM
5
j ) along ( i 2 j) , is
mR
16
1
[ i 2 j]
5
1
5
Speed of separation =
1
5
1
4
26. Answer (3)

Nett work done by friction is non-zero.
24. Answer (4)

2
mR 2
5
Component of (i
9
2
mv
32
Speed of approach =
1
I
2 CM
I1
j) along ( i 2 j) , is
Component of (2i
23. Answer (3)
27. Answer (3)
3R
8
m R
Limiting friction is insufficient for rolling of disc and

ring.
ICM
3R
8
2
2
mR
I1
5
25. Answer (4)
G
pball m[ i j] m[2i
G
psurface (i 2 j) Ns
83
2
mR
320
28. Answer (4)

Force of friction becomes the internal force for the
system of truck and earth.
13
2
mR
20
29. Answer (4)
K
j]
G G
1 m1m2
2
(v1 v 2 )(1 e )
2 (m1 m2 )
30. Answer (3)
m[ i 2 j] Ns
Total work done upon spring is
1 2
kx .
2
PART - B (CHEMISTRY)
32. Answer (4)
31. Answer (1)

According to Bent's rule, more electronegative atom
prefers to occupy axial position so as to have
minimum repulsion.
KE per mole =
Cl
II. F
Cl
Cl
F
=0
F
0
CF3
P
Entropy is a state function
CH3
IV. CH3
CH3
CF3
=0
34. Answer (3)
CF3
CH3
III. CH3
33. Answer (1)

3
RT
2
3
2 300
=
2
= 900 cal
F
Cl
I. Cl
YS has least value of Ksp. Precipitation occurs when

ionic product > solubility product.
CH3
CF3
0
S(X P) = S(X Y) + S(Y Z)

+ S(Z
Q)
+ S(Q P)
= 20 e.u. + 40 e.u. + (30 e.u.) + 10 e.u.

= 40 e.u.
5/11

35. Answer (4)

40. Answer (1)
12
On increasing temperature, water dissociates more

and hence value of K w increases from 1014 to
1012. Thus, pH scale now becomes smaller and
neutral pH is 6.
Spin quantum number is not derived from solution of

Schrodinger wave equation. Cr(Z = 24)
Total spin =
1
number of unpaired e
2
1
6
2
Also, pH + pOH = 12
So, pOH also becomes 6.
=3
Orbital angular momentum of an e in 5s
But, water will still remain neutral.

36. Answer (2)
He gas shows positive deviation only.
At high temperature and low pressure, a real gas
behaves like an ideal gas. For other gases at
moderate pressure range, attractive forces dominate.
37. Answer (3)
hc
0
mv 2
2hc
l(l 1)
0(0 1)
=0
41. Answer (2)
S = 1.65 104 mol/L
E = + KE
hc
Ksp = 4S3 = 4 (1.65 104)3 = 1.8 1011
1
mv 2
2
pOH = 14 9 = 5
[OH] = 105
[Mg2+][OH]2 = Ksp
2hc
m
[Mg2+] =
11
1.8 10
= 1.8 101 = 0.18
(10 5 )2
42. Answer (1)
38. Answer (2)
When CH3OH is added, equilibrium shifts backward

and a new equilibrium state is established.
n + p = 45
Addition of catalyst or inert gas at constant volume

will have no effect.
n = 1.14p
On solving, p = 21 and n = 24.
43. Answer (2)
So, atomic number of atom is 21.

Electronic configuration of ion (21 3)
ZZZ
X
H2O YZZ
Z H3 O
HA
C1
= 1s22s22p63s23p6
So, outermost shell of ion has 8 electrons.
39. Answer (1)
Since 1 and 2 are very small, so
Cl
C1 1 C1 and C2 2 C2
Xe
K a (HA)
Cl
K a (HB)
C1
(
C2
B
1
Both are linear molecules.
6/11
ZZZ
X
H2O YZZ
Z H3 O
HB
C2
A
2

Divide,
1
2

51. Answer (1)
C2
C1
4 10
6 10
a
V2
(V
b)
RT
If 'a' is negligible, then
[A ]
[B ]
2
3
0.2
0.4
1
3
P(V b) = RT
PV = RT + Pb
44. Answer (1)
52. Answer (3)
In solid form, XeF6 exist as
XeF5+F.
F
F
F
Xe
3d z2 has two nodal cones.

Hybridisation state is sp3d 2.
53. Answer (2)
45. Answer (3)
54. Answer (3)

Cl
Cl
I
Cl
Cl
55. Answer (4)
I
Cl
Cl
8 I Cl bonds are present.
CaCO3
CaO CO2 (X)
X is CO2
Na2CO3 + H2O + CO2 2NaHCO3
46. Answer (3)

At boiling point, temperature remain constant. So,
the total energy remain same for them.
47. Answer (3)
Moles of CaCO3 =
10
= moles of CO2
100
Moles of Na2CO3 = 1 mole
Since Kp depends only on temperature, if the volume

is doubled, equilibrium is disturbed and more
products would be formed. So, will change while
Kp will not change.
48. Answer (4)
Pure element has zero standard enthalpy of
formation in its standard stable state.
Number of moles of NaHCO3 formed is 0.2 mole

because CO2 is limiting reagent.
56. Answer (2)
It is the drawback of first law of thermodynamics
that it fails to predict the direction of reaction taking
place.
57. Answer (4)
49. Answer (3)

Molar heat capacity is intensive property.
50. Answer (1)
KE per molecule =
3
kT, where 'k' is Boltzman's
2
constant.
ZZZ
X
H2O(s) YZZ
Z H2O(l )
273 K is melting point of water and the process is
at equilibrium, so G = 0 while S = +ve, since
solid is changed to liquid phase.
58. Answer (4)

Dipole moment of CH3Cl > CH3F.
59. Answer (1)
60. Answer (1)
7/11
PART - C (MATHEMATICS)
61. Answer (2)
66. Answer (1)
0 cos2x 1
0
0
As, (a + b) cos C + (b + c) cos A + (c + a) cos B

= a+b+c
cos2 x
67. Answer (1)
tan
(Using projection formulae)
cos x
Period of cos 2{2x} =
1
2
Period of sin 2{2x} =
1
2
62. Answer (1)

sin x
a
sin y
b
(a b ) sin x
,b
sin x sin y
sin x sin y
a b
a cot x + b cot y =
Also, sin 3x cos[3x] cos 3x sin[3x] = sin(3x [3x])
(a b ) sin y
sin x sin y
= sin{3x}
(a b )(cos x cos y )
sin x sin y
= (a
b ) cot
+ = 5, = 5
a sin 2 + b cos 2 =
1 tan2
a
b
b
1
b b tan2
2a tan
2a
(2a2
b2
(a 2
1
(
a2
b2
[(
b2 )
b2 )
(a 2
= b
b2 )
1)]3
1)(
3
3(
) 3(
)3 3
) 2
(1
)2 6(
) 3(
(1 (
) 3(
) 2
125 15( 5) 3( 5)2
6( 5) 3( 5) 2
3
(1 5 5)
sec2
( 9)3
3 tan2 8 tan + 3 = 0
tan
3
3
108
9 9 9
4
27
65. Answer (2)

13 12 sin x 5 cos x 13
max(12 sin x 5 cos x) = 13
14 < 13 {2x} 13
max(13 {2x}) = 13
max(13, 13) is 13
8/11
1)3
125 75 75 30 15 2
2)2
1)3
1)3
64. Answer (2)
tan
1)
a2 )
1
3
a2
b2
(a 2
=1
68. Answer (2)
a
b
(2 tan
1 1 1
, ,
2 2 3
So, required period = LCM of
63. Answer (3)
tan
1
3
Its period =
69. Answer (4)
(sin x cos x )
(sin x
1
sin x cos x
cos x ) 1
sin x cos x
sin x cos x
1
sin x cos x
1
sin x cos x
2
(1 sin 2 x ) 1
sin 2 x
2
sin 2 x
73. Answer (4)

Simplifying the equation becomes,
(2a + b)x 2 (a b)x (a + 2b) = 0
(1 + t)(t + 2)2 = (7t 2)2, where t = sin 2x
The sum of the coefficients = 0.
t 3 44t 2 + 36t = 0
t 2 44t + 36 = 0
t
x = 1 = is a root.
(sin 2x 0)
Product of the roots = =
22 8 7
sin 2 x
(a 2b)
2a b
(a 2b)
2a b
74. Answer (3)
=
22 8 7
| a | = 22, b = 8
sec2(a + 2)x 1 + a2 = 0
a = 22, b = 8
tan2(a + 2)x + a 2 = 0
70. Answer (3)

n(A A B B) = n(A) n(A) n(B) n(B)
tan(a + 2)x = 0 and a2 = 0

tan 2x = 0
= (4 3)2
0,
a=0
= 144
71. Answer (2)

x 6 + y 6 + 3x 4y 2 + 3x 2y4 = x 6 + y6 + 2x 3y 3
(0, 0), 0,
abcdefg
x
y
y
x
9 10 10 10 1 1 1
b, c and d can be selected in 10 ways.
2
3
xy
a in 9 ways.
2
3
Now, when a, b, c and d are fixed, e, f and g will

themselves be fixed and can be selected in 1 way
only.
72. Answer (2)

sin3
sin2
+
2 cos = 0
are the ordered pairs
satisfying the equation.
3(x 2 + y2) = 2xy
Let the 7-digit number is
3x 2y 2(x 2 + y 2) = 2x 3y3
y2
, 0,
75. Answer (3)
3(x 4y2 + x 2y4) = 2x 3y3
x2
+ sin 2
sin2
cos sin 2
(sin3 2 sin2 cos ) + (sin2 2 sin cos )

+ (sin 2 cos ) = 0
(sin2 + sin + 1)(sin 2 cos ) = 0
Number of 7-digit numbers = 9 103.

76. Answer (2)
Required divisors are 1, 5, 32, 3 7, 72, 32 5,
3 7 5, 5 72, 32 72, 32 5 72.
77. Answer (4)
Since sin2 + sin + 1 0
z z
is a purely imaginary number.
1 zz
sin 2 cos = 0
tan = 2
From figure, the number of solution is 1.
z z
1 zz
is
or
5
.
9
z lies in second quadrant.
Now, arg z is
arg
y=2
Im(z) is positive.
arg
z z
1 zz
9/11

78. Answer (3)
82. Answer (2)
cos45 + icos135 cos(180 + 45) icos315 +

...... + cos(3645)
=
21
2
1
10!
3! 7!
1 10
[ C1
10!
29
10!
...... 20 terms
20
1 10!
10! 1! 9!
...... 21 terms
i
As, r
A
= (b c ) 2 2bc sin
2
A
A
4k 2 sin2
= (b c )2 4k 2 sin2
2
2
A
i.e., a 2k sin
2
80. Answer (2)
2
2R
9
4R sin
A
tan
2
2
As, A
3
b
a
81. Answer (2)
C
A B
cos
2
2
sin
C
A B
cos
2
2
C9 ]
sin
C
2
1 2 sin2
a + b = x2
sin
C
2
sin
C
2
1
9
1
9
C
2
1
3
1
9
1 2
( x 1)( x
Let a = x 2 + 2, b
(s b )(s c )
s(s a )
c
1
3
A B
2
cos
7
9
84. Answer (1)
1
3
A
tan
2
2
1
,1
3
x = 2 + 4 6 + 8 ...... 46 + 48
y = 1 3 + 5 ...... 47
i(1 3 + 5 7 ...... 47)

+ (2 + 4 6 + 8 ...... + 48) = x + iy
x4
x
x
3)
x2
4x
x
4x
x2
3x 2
x
4x
i.e., | a + b | = | a | + | b |
So, ab 0
(x2
2)( x 1)( x
3)
0
x
x (, 0) (0, 1] [3, )
2
85. Answer (1)
x = (2 + 2 + 2 + ...... + 2) = 2 12 = 24
We are given 2m 2n = 120
y = [(2) + (2) + ...... + (2)] = 24
By trail, m = 7, n = 3
3x + 2y = 3(24) 2(24) = 24
10/11
10
C7
A
B
C
sin sin
2
2
2
sin
cos C
10
C5
A
B
C
sin sin
2
2
2
4R sin
= (b c)2 2bc cos A + 2bc
1
s
10
C3
83. Answer (2)
a2 = b 2 + c2 2bc cos A
10
10!
9! 1!
5m + n = 45 + 10 = 55
(21 20i )
2
(21 20i )
2
79. Answer (2)
10!
7! 3!
m = 9, n = 10
10!
5! 5!
3m 7n = 21 21 = 0
(x 0)
86. Answer (4)
88. Answer (3)
Vertex of f(x) will be at x =
Total number of functions = nm.
a
2
Case 1 : a > 2, then minimum value of f(x) is at

x = 1.
f(1) = 5
Statement-1 is correct and statement-2 is false.

89. Answer (2)
a2 + a 2 = 0
cos(sin x )
a = 2 or 1 which is not possible.
cos
cos x
Case 2 : a < 0, then the minimum value is f(0).

f(0) = 5
a 2 + 2a 3 = 0
sin x
cos x
1
2
2n
a = 3 or 1
a = 3 is possible
a
Now, if 0 < a < 2, then the minimum value is f
2
a
f
2
3a
8a 12
4 2 13
3
4 2 13
is possible
3
or a
Sum of values of a =
|sin 2 x |
4 2 13
3
2 13
3
1 sin 2 x
1
2
2n
2n
1
2
,n I
2
2
2
2
RHS > 2 for all n I

The equation does not possess real roots.
Statement-1 is true, statement-2 is true but it is not
the correct explanation of statement-1.
2 3 13
.
3
90. Answer (3)

|| z z1 | | z z2 || = k is
87. Answer (4)

Statement-2 is correct as period of sin x is 2 and
2
hence period of sin(x) is
= 2.
(b) Two rays if k = | z1 z2 |
Similarly, period of cos x is 2 and hence period of
(c) Empty set if k > | z1 z2 |
cos(
2 x ) is
2
2
2.
Hence, statement-1 is not true as LCM of

2 does not exist.
(a) Hyperbola if k < | z1 z2 |
Here, | z1
2 and
z2 |
2, k
Statement-1 represents a branch of hyperbola

statement-2 is false.
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Test - 4 (Paper-I) (Answers & Hints)

All India Aakash Test Series for JEE (Main)-2014

All India Aakash Test Series for JEE (Main)-2014

Test - 4 (Paper-I) (Answers & Hints)

For pure rolling,

Total force along centre of circle

= 2mg cos 30 + mg cos 30

u2 = v12 + v22 = v12 + v22 + 2v1v2 cos 90 ...(iii)

Solving (i) and (ii), we get

Solving equations (i), (ii) and (iii), we get

Let point P moves with velocity v and its direction

Test - 4 (Paper-I) (Answers & Hints)

All India Aakash Test Series for JEE (Main)-2014

13. Answer (3)

The impact should be inelastic.

14. Answer (3)

Here, friction (limiting and kinetic) between 10 kg

15. Answer (3)

10. Answer (3)

11. Answer (2)

12. Answer (3)

16. Answer (4)

17. Answer (3)

The block leaves the surface at t = 5 s.

All India Aakash Test Series for JEE (Main)-2014

20. Answer (1)

Test - 4 (Paper-I) (Answers & Hints)

18. Answer (4)

Here, v max is the maximum safe speed for no

19. Answer (3)

21. Answer (3)

v max is the maximum safe speed for no toppling.

For pure rolling,

Test - 4 (Paper-I) (Answers & Hints)

All India Aakash Test Series for JEE (Main)-2014

KE about P = T KE about P + R KE about P

T KE about point P = 0, because point P translates

26. Answer (3)

24. Answer (4)

23. Answer (3)

27. Answer (3)

Limiting friction is insufficient for rolling of disc and

28. Answer (4)

29. Answer (4)

30. Answer (3)

Total work done upon spring is

31. Answer (1)

Entropy is a state function

34. Answer (3)

33. Answer (1)

YS has least value of Ksp. Precipitation occurs when

S(X P) = S(X Y) + S(Y Z)

= 20 e.u. + 40 e.u. + (30 e.u.) + 10 e.u.

All India Aakash Test Series for JEE (Main)-2014

Test - 4 (Paper-I) (Answers & Hints)

On increasing temperature, water dissociates more

Spin quantum number is not derived from solution of

So, pOH also becomes 6.

But, water will still remain neutral.

Ksp = 4S3 = 4 (1.65 104)3 = 1.8 1011

= 1.8 101 = 0.18

42. Answer (1)

38. Answer (2)