Professional Documents
Culture Documents
CHEMISTRY
In organic molecules:
Functional group
CnH2n+2
Successive compounds have physical properties that vary in a regular manner as the
number of carbon atoms present increases.
The boiling point of straight chain alkanes increases when a metalyne group is
added.
Reason:
As the relative molecular mass of the alkane increases the strength of the Van der
Waals forces between molecule increases.
The boiling point of the alcohols(-OH) tend to be higher due to the presence of
hydrogen bonding.
Other functional groups such as carboxylic acid (-COOH), amine(-NH2) and amide(CONH2) also gives rise to hydrogen bonding.
Therefore, they have higher melting and boiling point than non-polar or polar organic
compounds of similar molar masses.
Benzene ring:
Use the prefix from the table to the number of carbon atoms in the longest
continuous carbon chain.
Number the position of these substituent groups using the combination that
includes the lowest individual numbers.
Arrange the number of substituent groups in alphabetical order. eg. di, tri, tetra
pg. 432
INCOMPLETE
COMBUSTION
Example:
eg.
Ethane
Chloroethane
Though double bond are stronger than single bond, they are not
twice as strong:
!
!
Poly(ethene)
POLY(VINYL) CHLORIDE
(PVC)
POLY(PROPENE)
ALCOHOLS
Primary alcohols !