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Tar-Analyser TA 120-3
Norman Poboss
Process monitoring before gas engines to enlarge motor life and decrease
maintenance costs
II. Monitoring of the efficiency of tar scrubber and catalytic tar reformer
III. Optimization of tar scrubber facilities and therefore waste water and solvent
optimization
IV. Monitoring for general gasification process (tar peak tracing)
V. Fundamental tar research projects
80
Signal
Detector (FID)
100
N2
Oven
300C
Tar
Filters
20 - 100C
60
40
20
0
Sample
Loop 1
Sample
Loop 2
Loading
Sample
Loop 3
20
40
60
80
Time / sec
100
Producer-Gas
Sample gas is sucked into the analyzer by three injection pumps/venturi nozzels
3 sample loops are laden simultaneously
Tar filters are backflushed during loading phase
120
Detector (FID)
N2
Oven
300C
Tar
Filters
20 - 100C
Sample
Loop 2
Analysis 2
Filter 2
Analysis 3
No Filter
60
40
20
0
Sample
Loop 1
Analysis 1
Filter 1
Sample
Loop 3
20
40
60
80
Time / sec
100
Producer-Gas
120
different Filtermaterials
different Filtertemperatures
Possible Filtermaterials
Heat Sink
Activated Carbon
LC-NH 2 / SPA-Material
Peltierelements
Filter
Silica Gel
Quarz Whool
User Defined
Thermocouple
Filtermaterial
Isolation
norman.poboss@ifk.uni-stuttgart.de
10
100
Signal
80
Loading
Analysis 1 Analysis 2
Filter 1
Filter 2
Measurable Values
Analysis 3
No Filter
60
40
20
20
40
60
Time / sec
80
100
120
Tar Filter
1
Fuel
5
3
6
8
Tar Filter
Combustion Air
Carrier
Loop 3
Loop 2
Compressed Air
4
5
3
1
1
6
8 7
Sample
2 Sample Lines
Calibration
2 Calibration Lines
Loop 1
Oven
Specifications
Effective Range:
Measurement Limit:
Reproducibility:
minimum of 60 seconds
+5 to + 35 C
60 minutes
Sample Pressure:
- 30 to 50 mbar
Calibration
Signal of an FID is almost directly proportional to the amount of organically bound carbon.
Substance
Response
relative to
propane
Propane
1.00
Benzene
0.99
Toluene
1.00
Ethylbenzene
0.92
o-Xylene
0.97
Trimethylbenzene
0.96
Phenol
1.00
Indene
0.92
Naphthalene
1.00