1. At298K,theHenry\'slawconstantforoxygenis0.

00130
M/atm.Airis21.0%oxygen.
a. At298K,whatisthesolubilityofoxygeninwater
exposedtoairat0.890atm?
b. Ifatmosphericpressuresuddenlychangesfrom1.00
atmto0.890atmat298K,howmuchoxygenwillbe
releasedfrom3.90Lofwaterinanunsealedcontainer?
2. Whentwovolatileliquids(XandY)aremixed,thesolution
processinvolves1.breakingtheintermolecularXXand
YYattractions,and2.formingnewXYattractions.
3. At25Cand775Torr,carbondioxidehasasolubilityof
0.0347Minwater.Whatisitssolubilityat25Cand1630
Torr?
4. Biphenyl,C12H10,isanonvolatile,nonionizingsolutethat
issolubleinbenzene,C6H6.At25C,thevaporpressureof
purebenzeneis100.84torr.Whatisthevaporpressureofa
solutionmadefromdissolving18.4gofbiphenylin34.0gof
benzene?
5. Asolutionismadebymixing45.0mLofethanol,C2H6O,
and55.0mLofwater.Assumingidealbehavior,whatisthe
vaporpressureofthesolutionat20C?
6. Asolutionismadebydissolving0.583molofnonelectrolyte
solutein883gofbenzene.Calculatethefreezingpointand
boilingpointofthesolution.Constantsmaybefoundhere.
7. Theboilingpointofanaqueoussolutionis101.76C.What
isthefreezingpoint?Constantscanbefoundhere.
8. Quinineisanaturalproductextractedfromthebarkofthe
cinchonatree,whichisnativetoSouthAmerica.Quinineis
usedasanantimalarialagent.When2.11gofquinineis
dissolvedin25.0gofcyclohexane,thefreezingpointofthe
solutionisloweredby5.42C.ThefreezingpointandKf
constantforcyclohexanecanbefoundhere.Calculatethe
molarmassofquinine.

A50/50blendofenginecoolantandwater(byvolume)is
usuallyusedinanautomobile\'senginecoolingsystem.If
yourcar\'scoolingsystemholds5.50gallons,whatisthe
boilingpointofthesolution?Makethefollowing
assumptionsinyourcalculation;atnormalfillingconditions,
thedensitiesofenginecoolantandwaterare1.11g/mLand
0.998g/mLrespectively.Assumethattheenginecoolantis
pureethyleneglycol(HOCH2CH2OH),whichisnon
ionizingandnonvolatile,andthatthepressureremains
constantat1.00atm.Also,you\'llneedtolookupthe
boilingpointelevationconstantforwater.
10.
Calculatetheosmoticpressureofa0.239Maqueous
solutionofsucrose,C12H22O11,at37C
11.
When4.62gofanonelectrolytesoluteisdissolvedin
405mLofwaterat26C,theresultingsolutionexertsan
osmoticpressureof895torr.
9.

a. Find Molar concentration of the solution.

b. How many moles of solute are in the solution
c. What is the molar mass of the solute

12.
Assuming100%dissociation,calculatethefreezing
pointandboilingpointof1.81mNa2SO4(aq).Constants
maybefoundhere.
13.
fan0.810maqueoussolutionfreezesat3.30C,what
isthevan\'tHofffactor,i,ofthesolute?Kfvaluescanbe
foundhere.
Intravenous,orIVsolutionsusedinmedicinemust
exertthesameosmoticpressureasbloodtopreventanet
flowofwaterintooroutofthebloodcells.Theproper
concentrationforanintravenousNaClsolutionis0.90g
NaClper100.mLofwater(sometimesreferedtoas0.90%
m/v).Ifthevan\'tHofffactorofNaClisi=1.8,whatisthe
osmoticpressureofbloodatbodytemperatrue,37C?

14.

ForanaqueoussolutionofHF,determinethevan\'t
Hofffactorassuming...0%ionization&100%ionization

15.

Asolutionismadebydissolving0.0100molofHFin
enoughwatertomake1.00Lofsolution.At26C,the
osmoticpressureofthesolutionis0.311atm.Whatisthe
percentionizationofthisacid?

16.

17.