Professional Documents
Culture Documents
14
Calcium, Copper, Iron, Magnesium, Manganese,
Potassium, Phosphorus, Sodium, and Zinc
in Fortified Food Products
Microwave Digestion and
Inductively Coupled Plasma-Optical Emission Spectrometry
First Action 2011
Final Action 2013
Test portion is heated at 200C either with nitric acid in a closedvessel microwave digestion system (MDC) or with a combination
of hydrogen peroxide, nitric acid, and hydrochloric acid in an openvessel microwave digestion system (MDO).
B. Apparatus
C. Reagents
Rec., %
Sra
RSDrb, %
SRc, ng/g
RSDRd, %
HorRat
9732.17
99
152.10
1.56
264.03
2.71
0.68
NSg
5678.58
98
75.93
1.34
184.11
3.24
0.74
NS
Infant cereal
5983.54
100
210.58
3.52
251.67
4.21
0.97
NS
409.90
(411)h
100
13.37
3.26
28.20
6.88
1.06
NS
367.56
(369)h
100
3.51
0.95
12.90
3.51
0.53
2, 4C
Matrix
NS = Not significant.
Table 2011.14B.
Matrix
Mean, mg/kg
Sra
RSDrb, %
SRc, ng/g
RSDRd, %
HorRat
0.09
1.57
0.29
4.97
0.41
NSg
Rec., %
5.92
NA
6.19
101
0.19
3.06
0.38
6.12
0.50
NS
Infant cereal
2.01
NA
0.10
4.98
0.24
11.72
0.81
NS
4.98
(4.93)i
101
0.19
3.84
0.35
7.08
0.56
NS
5.64
(5.94)i
95
0.13
2.27
0.27
4.77
0.39
NS
NS = Not significant.
NA = Not available.
Rec., %
Sra
RSDrb, %
SRc, ng/g
RSDRd, %
HorRat
164.77
97
6.72
4.08
11.25
6.83
0.92
NSg
83.11
102
2.51
0.02
4.62
5.56
0.68
NS
Infant cereal
75.18
94
1.36
1.81
3.32
4.42
0.53
NS
15.65
(16.4)h
95
0.65
4.17
1.95
12.45
1.18
6C
49.29
(54.3)h
91
0.93
1.89
1.54
3.12
0.35
2C
Matrix
NS = Not significant.
Table 2011.14D.
Rec., %
Sra
RSDrb, %
SRc, ng/g
RSDRd, %
HorRat
8996.74
99
135.82
1.51
208.98
2.32
0.57
NSg
6443.79
100
65.17
1.01
130.04
2.02
0.47
NS
Matrix
Infant cereal
6438.19
99
119.83
1.86
135.78
2.11
0.49
6SG
6200.24
(6070)h
102
148.84
2.40
187.59
3.03
0.70
NS
411.08
(472)h
87
10.19
2.48
31.31
7.62
1.18
NS
NS = Not significant.
Rec., %
Sra
RSDrb, %
SRc, ng/g
RSDRd, %
HorRat
1746.74
98
38.46
2.20
51.03
2.92
0.56
2SG
439.31
99
5.57
1.27
13.37
3.04
0.48
NSg
Matrix
Infant cereal
859.48
98
33.62
3.91
35.38
4.12
0.71
2, 6DG
1714.02
(1680)h
102
56.83
3.32
73.68
4.30
0.82
2SG
482.05
(510)h
95
8.52
1.77
16.53
3.43
0.54
NS
NS = Not significant.
Table 2011.14F.
Matrix
Mean, mg/kg
Rec., %
h
Sra
RSDrb, %
SRc, ng/g
RSDRd, %
HorRat
0.14
1.88
0.67
8.82
0.75
NSg
7.54
NA
0.40
99
0.01
2.56
0.0197
4.89
0.27
2C
Infant cereal
16.74
NA
1.14
6.79
1.44
8.61
0.82
NS
15.85
(16.0)i
99
0.45
2.86
1.32
8.31
0.79
NS
12.87
(14.3)1
90
0.23
1.75
1.13
8.75
0.80
NS
NS = Not significant.
NA = Not available.
Rec., %
Sra
RSDrb, %
SRc, ng/g
RSDRd, %
HorRat
1927.84
97
43.30
2.25
51.07
2.65
0.52
NSg
1769.19
96
18.64
1.05
33.39
1.89
0.36
NS
Matrix
Infant cereal
992.41
95
37.67
3.80
39.72
4.00
0.71
6SG
4924.12
(4890)h
101
158.61
3.22
158.61
3.22
0.72
NS
1346.82
(1420)h
95
19.56
1.45
26.85
1.99
0.37
6SG
NS = Not significant.
Table 2011.14H.
Rec., %
Sra
RSDrb, %
SRc, ng/g
RSDRd, %
HorRat
4138.12
101
84.53
2.04
115.22
2.78
0.61
NSg
3729.50
100
46.37
1.24
101.72
2.73
0.59
NS
Infant cereal
4341.81
101
60.56
1.39
111.79
2.57
0.57
NS
3444.06
(3378)h
102
98.10
2.85
111.97
3.25
0.69
NS
2050.02
(2190)h
94
37.86
1.85
67.15
3.28
0.65
NS
Matrix
NS = Not significant.
Matrix
Mean, mg/kg
Rec., %
h
Sra
RSDrb, %
SRc, ng/g
RSDRd, %
HorRat
18.06
NA
0.396
2.19
0.95
5.24
0.51
5SG
53.65
105
1.43
2.66
2.36
4.40
0.50
NS
Infant cereal
36.51
NA
0.92
2.25
1.27
3.44
0.37
NS
26.64
(26.3)i
101
1.06
3.96
1.78
6.69
0.69
NS
49.30
(53.8)i
92
0.96
1.95
3.19
6.46
0.73
NS
NS = Not significant.
NA = Not available.
Std0
Std1
Std2
Std3
Std4
Std5
Std6
Ca
7.5
15
30
75
150
225
Cu
0.05
0.1
0.2
0.5
1.0
1.5
Fe
0.25
0.5
1.0
2.5
7.5
G. Reagents
10
20
40
100
200
300
Mg
2.5
10
25
50
75
Mn
Na
10
20
50
100
150
10
20
50
100
150
Zn
0.1
0.2
0.4
1.0
2.0
3.0
aVF
m