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Apparatus
Conveying extruder
Rubber sheet
Die
Burner
Oven
Cutter
Procedure
Precautions
Do not heat the die as much that the elastomeric get cured in the die.
Temperature in the oven is not above the degradation temperature of
natural rubber.
Observations
Before curing the rubber sheet is flexible, soft and stretchable but after
curing, rubber become hard and less stretchable.
Experiment # 2
Curing of Elastomer Using Electric Press.
Apparatus
Electric press
Mold
Cutter
Uncured rubber sheet
Safety gloves
Procedure
Observations
Before curing, the natural rubber is soft, shiny and stretchable but after
curing in the electric press, the rubber become hard and less stretchable.
Experiment # 3
Make a Blend Of two different Elastomers using Twin Blade Melt Mixer.
Formulation
Ingredients
Chloroprene
Styrene Butadiene
Silica
ZnO
Stearic Acid
MBTS
TMTD
Sulphur
Processing Aid
Antidegradent
Amount
(phr)
30
70
30
2
1
2
1
1.5
5
2
Procedure
Observations
Before blending the chloroprene is in light brown color and SBR in light grey.
Chloroprene is in the form of flakes and less stretchable. And SBR is relatively
stretchable and shiny. After blending, the blend is in dark gray color and has
bouncy effect due to pre mature curing.
Experiment # 4
Compounding of an Elastomer using Two Roll Mill.
Formulation
Ingredients
Natural Rubber
Carbon Black
Silica
Sulphur
MBTS
TMTD
Antidegradent
ZnO
Stearic Acid
Processing Oil
Amount
(phr)
100
60
50
2
2
2
1
2
1
10
Procedure
minutes.
Then take all the other ingredients and sprinkle them on the rubber
and mix for 10 minutes.
After this elastomeric sheet is formed.
Cover the rubber sheet in plastic sheet and put it in the freezer so that
the curing does not start.
Water is circulated from the rollers to maintain the temperature of the
rollers.
Observations
The color of the compounded material is black due to carbon black. Mixing is
good if carbon black does not stick to the hands on touching. The surface of
the sheet is also shiny.
Experiment # 5
Blending of Thermoplastic and Elastomer using twin blade melt mixer.
Formulation
Ingredients
Polypropylene
Polychloroprene
Silica
Sulphur
MBTS
TMTD
ZnO
Stearic Acid
Processing Oil
Amount
(phr)
60
40
25
0.6
0.8
0.4
0.8
0.4
4
Procedure
First set the temperature of the heaters of melt mixer at 160 C and
rpm as 45 revolutions per minutes.
Then take polypropylene and put it into the mixer and mix for 1
minute.
And polychloroprene and mix for 1 minute.
After this add silica and wait for 5 minutes and then add all other
ingredients.
And mix it for further 2 minutes and take the blend out of the mixer.
Observations
Before blending the polypropylene is in the form of grains and white it color.
And polychloroprene is in the form of flakes and brown in color and its
stretching is less. The blend was burnt due to high temperature. The color of
the blend is dark brown.
Experiment # 6
To get the Mechanical Properties of Polymer Sample Using Universal Testing
Machine (UTM).
Material
Material Dimensions
ASTM D638
ASTM D638 is used for the tensile testing of polymer sample. The type of test
is used for sample having thickness less than 14 mm. if not then reduce the
thickness by machining. The sample given is of type IV so strain rate for
which is 1.5 mm/mm.min and the speed of testing is 50 mm/min.
Procedure
Results
The properties that are obtained from the graph are yield stress, fracture
stress, ultimate tensile strength (UTS), toughness (Strain energy function).
Yield Stress = 1MPa
Fracture Stress = 3.5 MPa
UTS = 4.8 MPa
Modulus = 166.7 MPa
Toughness (Strain Energy Function) = 117.9 J
Experiment # 7
Make the formulations of Different Products.
Amount
(phr)
100
60
2
2.5
5
3
1.5
1.5
1.5
2
Amount
Natural Rubber
(g)
Toluene (ml)
Phenol
Formaldehyde (g)
5
30
5
Procedure
Amount
(phr)
100
50
2
20
1
2
1.5
2
Amount
(phr)
100
15
40
2
10
Experiment # 8
Determine the Bound Rubber Contents and Crosslink Density of a rubber.
Procedure
First take the small piece of cured natural rubber 1x1 inch.
Weight the sample in weight balance.
Put the sample in 35 ml of toluene in a glass jar. So that the sample is
completely dipped in the toluene.
After 3 hours, take the sample out of the glass jar, clean it with tissue
paper, weight the sample and note the reading.
Put the sample back in the jar and place it for one day.
Take the weight of sample as discussed above.
Repeat the procedure every day until weight of the sample become
constant.
After this place the sample in the oven for one day at 85 C.
Draw the graph between time and weight of the sample.
Calculate the bound rubber contents and cross link density by the
formulae given below.
Crosslink Density
=
1
ln ( 1Vr )+Vr + XV r 2
Vs
1
V r 3 0.5Vr
Where, is the no. of crosslink per unit volume, Vs is the molar volume of
swelling solvent, Vr is the volume fraction of rubber in the swollen gel and
is the polymer/rubber solvent interaction parameter.
( mfmf+ mr )
mr
Wt (
mf + mr )
100WfgWt
Rb =
Where, Rb is the rubber bound content, Wfg is the weight of filler and gel, Wt is
the weight of the sample, mf is the fraction of filler in the compound and mr
is the fraction of rubber in the compound.
Result
The graph between time and Weight of the sample as shown below,
Time (hr)
( mfmf+ mr )
mr
Wt (
mf + mr )
100WfgWt
Rb =
Where,
Wfg = 5.01 g, Wt = 4.96 g, Mf = 0.4673, Mr = 0.4032
Rb % = 78.9 %
Crosslink density is calculated as,
1
ln ( 1Vr )+Vr + XV r 2
Vs
1
V r 3 0.5Vr
Where,