DU Test Series IV Chemistry

TEST PAPER CODE : CY
TIME: 3:00 HOURS
DU TEST SERIES
Test Series-IV
1. The question-cum-answer booklet has 15 pages and has

54 questions. Please ensure that the copy of the questioncum-answer booklet you have received contains all the
questions.
2. Wri te your Name in the appropriate s pace
provided on the right side.
3. Section-A have objective questions. Each objective
question has 4 choices for its answer: (a), (b), (c) and (d)
only One of them is the correct answer. There will be
negative marking for wrong answers to objective
questions. The following marking scheme for objective
questions shall be used:
(a) For each correct answer, you will be awarded 2 mark in
Section-A.
(b) For each wrong answer, you will be awarded (2/3)
marks in Section-A.
(c) Multiple answers to a question will be treated as a
wrong answer.
(d) For each un-attempted question, you will be awarded 0
(zero) mark.
4. Section-B has descriptive questions. Write your answer
in the space provided. Maximum marks are given along
with questions.
5. Do not write more than one answer for the same question.
In case of you attempt a subjective question more than
once, please cancel the answer(s) you consider wrong.
Otherwise, the answer appearing last only will be
evaluated.
6. All answers must be written in blue/black/blue-black ink
only. Sketch pen, pencil or ink of any other color should
not be used.
7. For rough work blank sheets are attached in the end of
the question paper.
8. No supplementary sheets will be provided to
the candidates.
9. Clip board, log tables, slide rule, calculator,
cellular phone or electronic gadgets in any
form are NOT allowed.
Date: 01-06-2014
M.M.: 225
2
SECTION-A
1.
Which one among the following is a paramagnetic complex?

(a) K 2 Mo CN 4
(b) Ni H 2 O 6 NO 3 2
(c) Co NH 3 6 Cl3
(d) Pt NH 3 4 Cl2
2.
The coordination compound cis-platin is a medicine for treatment of which one of the following?
(a) Malaria
(b) Cancer
(c) Anaemia
(d) Diabetes
3.
Which of the following are not acceptable sets of quantum numbers for an electron in an atom?
4.
(a) n 3, 0, m 1, ms
1
2
(b) n 3, 1, m 1, ms
(c) n 3, 2, m 0, ms
1
2
(d) n 3, 1, m 2, ms
1
2
Which of the following systems are isoelectronic?

(a) CN , CO , NO
5.
1
2
(b) CN , CO, NO
(c) F2 , OF, S2
(d) OH , HF, NH3
Consider the following reaction

P4 3OH 3H 2O
X Y
What are the oxidation states of phosphorus in X and Y respectively in the above reaction
(a) 3, +3
(b) 3, +1
(c) +3, 1
(d) 3, +5
6.
7.
The ionic radii of K+, Ca2+, Cl and S2 ion decreases in the order
(a) Cl S2 K Ca 2
(b) K Ca 2 Cl S2
(c) S2 Cl K Ca 2
(d) Ca 2 K Cl S2
How many and -particles are emitted in passing from 90 Th 232 to

(a) 4, 4
(b) 4, 6
(c) 6, 4
82 Pb
208
(d) 6, 6
8.
Solution of Na metal in liquid NH3 is a strong reductant due to th presence of

(a) sodium atoms
(b) sodium hydride
(c) sodium amide
(d) solvated electrons
9.
In terms of polar character, which one of the following order is correct

(a) NH 3 H 2O HF H 2S
(b) H 2S NH 3 H 2 O HF
(c) H 2O NH 3 H 2S HF
(d) HF H 2O NH 3 H 2S
10.
Which one of the following is NOT true for diborane?

(a) It has two bridging hydrogen
(b) When methylated, the product is Me4B2H2
(c) The bridging hydrogens are in a plane perpendiculars to the rest.
(d) All the six BH bond distances are equal
11.
The bond angle of given hydrides are such that

(a) TeH2 SeH 2 SH2 OH 2
(b) OH2 SH 2 SeH2 TeH 2
(c) SH 2 SeH2 TeH 2 OH 2
(d) TeH2 OH2 SH 2 SeH 2
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12.
Borax on heating strongly above its melting point melts to liquid, which then solidifies to a transparent mass
commonly known as borax bond. The transparent glassy mass consists of
(a) Sodium pyroborate
(b) Boric anhydride
(c) Sodium metaborate
(d) Mixture of sodium metaborate and boric anhydride
13.
A solution containing As3+, Cd2+, Ni2+ and Zn2+ is made alkaline with dil. NH4OH and treated with H2S. The
prceipitate obtained will consists of
(a) As2S3 and CdS
(b) CdS, NiS and ZnS
(c) NiS and ZnS
(d) NiS
14.
If a solution containing Cu(II) and Cd(II) salts [sulphates or chlorides] is treated with excess KCN and H2S is
passed through the solution, then
(a) No change will be observed
(b) CdS will be precipitated
(c) CuS will be prcipitated
(d) Both CdS and CuS will be precipitated
15.
In the extraction of nickel by Mond process, the metal is obtained by

(a) electrochemical reduction
(b) thermal decomposition
(c) chemical reduction by Al
(d) Reduction by carbon
16.
In the reaction,
O
O
CH3
+
O
How is the product formed?

(a) Michael addition followed by Mannich reaction
(b) Michael addition followed by Knoevenagel reaction
(c) Michael addition followed byAldol condensation
(d) Aldol condensation followed by Michael addition
Cl
17.
NH2
liq. NH3
NaNH2
What is the mechanism of the reaction given above called?

(a) SN1
(b) SN2
(c) Addition-elimination
(d) Elimination-addition
O
18.
EtONa/EtOH
Product
The product will be

Me
C
(a)
Me
(b)
C
Me
Me
OH
Me
(c)
19.
(d) None of these
Me
Which one amongst the following carbocation is most stable?

(a)
H
C
(b)
CH2
(d) H3C
(c)
CH3
CH3
20.
In the reaction,
O
[X]
NH2OH
H3O+
[Y]
The product [Y] is

O
OH
(a)
21.
(b)
(d)
NH
Which one of the following transitions would NOT be observed in the UV visible spectrum of vinyl chlorides
(b) *
(a) n *
22.
(c)
(c) n *
(d) *
Which one of the following reactions will not yield a carboxylic acid
(b) PhCN H3O
(a) RMgX CO2

23.
(c) PhOH CHCl3 NaOH

(d) PhOH NaOH CO 2
2-phenylethanol can be prepared by searching PhMgBr with
(a) ethanol
(b) ethyl ocetate
(c) ethylenoxide
(d) azisidine
24.
Which one of the following would readily gives tollens test

O
(a)
25.
26.
(b)
(c)
(d) H2
How many signals in NMR spectra will be obtained from the following compounds respectively?
(1) H3C
CH3
O CH3
(2) H3C
Si
(a) 2, 1, 3
CH3
(3) H3C
OCH3
CH3
CH3
(b) 2, 1, 4
(c) 1, 1, 3
(d) 1, 1, 4
The rotational constant (B) of a diatomic molecule is

(a)
28.
OCH3
(d)
Which of the following molecules will not show IR spectrum?

(a) HCl
(b) CH4
(c) H2O
CH3
27.
OH
h
4 2 I
(b)
h2
4 2 I
(c)
h2
82 I
(d)
h
82 I
Which of the following molecule has the lowest vibrational stretching frequency?
(a) 1 H
35
Cl
(b) 2 H
35
Cl
(c) 1 H
36
Cl
(d) 1 H
39
Cl
29.
The source of UV radiation used in UV-visible spectrophometes is

(a) Xenon vapour lamp
(b) Sodium vapour lamp
(c) Halogen vapour lamp
(d) Hydrogen vapour lamp
30.
Predict the number of translational, rotational and vibrational degree of freedom in Neon (Ne).
(a) 3, 0, 0
(b) 3, 1, 0
(c) 3, 0, 1
(d) 3, 1, 1
5
31.
The mechanism for photochemical decomposition of HI into H2 and I2 is
HI h H I
H HI H 2 I
I I I 2
What is the overall quantum yield of the reaction?
(a) 0.5
(b) 1
(c) 2
(d) 4
32.
For which one of the following process is Inter System Crossing (ISC) essential?
(a) Fluorescence
(b) Phosphorescence (c) Chemiluminescence (d) Radioactive decay
33.
At which pressure and temperature conditions is the behaviour of a real gas closest to that of an ideal gas?
(a) 15 atm and 200K (b) 1 atm and 273 K (c) 0.5 atm and 500K (d) 15 atm and 500K
34.
The heat of formation of SiO2 and MgO are 48.4 KJ and 34.7 KJ respectively. What is the heat of reaction
for
2Mg SiO2
2MgO Si
(a) 13.62 KJ
35.
36.
(b) 21.0 KJ
(c) 21.16 KJ
(d) 13.60 KJ
The temperature of 4 moles of an ideal gas is raised from 300K to 350K. What is the value of H E for
this process.
(a) 1660J
(b) 415J
(c) 41.5J
(d) 16.6 J
The phase diagram for a one compound system is shown below.
What are the number(s) of degree of freedom at the point B, X and Y respectively
(a) 0, 1 and 2
(b) 0, 2 and 1
(c) 2, 0 and 1
(d) 1, 0 and 2
37.
The conc. of OH ions at 25C in a saturated solution of Mg(OH)2 , a sparingly soluble electrolyte, is
410 4M. What is the solubility product of the salt at 25C
(a) 81012
(b) 4108
(c) 3.21011
(d) 1.251011
38.
The reaction 2H 2 2NO N 2 2H 2O is assumed to proceed by the following mechanism

N 2 O 2
2NO
N2O2 H2 N 2O H 2O
N2O H 2 N 2 H2O
fast
slow
fast
Which is the rate law for the reaction?

2
(a) rate K NO H 2
(b) rate K NO H2
2
(c) rate K NO H 2
(d) rate K NO H 2
6
39.
The equivalent conductivities at infinite dilution of NaCl, HCl and CH3COONa in water at 25C are 128, 425
and 91 cm2/ eq respectively. A solution of CH3COOH shown an equivalent conductance of 38.8 cm2/ eq.
What is the % dissociation of CH3COOH?
(a) 5.0
(b) 10.0
(c) 20.0
(d) 30.0
40.
A gas can be liquified at a temperature (T) K and pressure (P) provided that
41.
42.
(a) T TC and P PC
(b) T TC and P PC
(c) T TC and P PC
(d) T TC and P PC
If the average of N2 molecule at 27C is 515 m/s. The average speed of CO at 327C would be approximately
(a) 515 m/s
(b) 1030 m/s
(c) 258 m/s
(d) 725 m/s
The van der waals equation is given by
n 2a
P 2 V nb nRT
V
The ratio (a/b) has the dimension of

(a) atm lit1
(b) lit atm mol1
43.
44.
45.
(c) lit mol1

(d) lit atm1 mol1
The pH of the solution obtained by mixing 500 ml of 0.1M CH3COOH with 250 ml of 0.1 M NaOH
(pKa of CH3COOH is 4.75) is
(a) 5.75
(b) 3.75
(c) 4.75
(d) 4.05
The volume of the gas liberated at STP when a current of 5.36 A is passed through dil. H2SO4 for 5 hours will
be
(a) 5.6 L
(b) 11.2 L
(c) 16.8 L
(d) 22.4L
At low pressure, the van der waals equation is written as
a
P V 2 V RT
The compossibility factor is then equal to
(a) 1
a
RTV
(b) 1
a
RTV
(c) 1
RTV
a
(d) 1
RTV
a
7
SECTION-B
46.
Complete the following reaction
[15 Marks]
low temp.
B2 H6 2NH3
X
excess NH
3
B2 H 6
Y
high temp
200C
B2 H6 NH3
Z
Write the structure of X also.
8
47.
(a) Draw the M.O. diagram of CO molecule.

(b) Write the increasing order of bond orders of following molecule/ion.
[9 Marks]
O2 , O2 , O2 , O22
[6 Marks]
9
48.
Write the hybridization, structure, oxidation state of metal ions, CFSE and magnetic moment of following
complexes.
[15 Marks]
2
(i) ZnCl4
(ii) Ni CN 4
(iii) Co NH3 4 Cl2
10
49.
(a) The density of Li metal is 0.53 gcm3 and the separation of the (100) planes of the metal is 350 ppm.
Determine whether the lattice is fcc or bcc.
[09 Marks]
530 kg m 3 6.022 1023 mol1 350 1012 m 3
Given:
1.97
6.941 103 kg mol1
(b) Calculate the pH (approx.) of 1107 M solution of HCl at 25C.
[06 Marks]
11
50.
Calculate the q, w, U and H for the isothermal expansion of one moles of an ideal gas at 27C from a
volume of 10 dm3 to a volume of 20 dm3, against a constant external pressure of 1 atm. [15 Marks]
Given: (10 dm3 atm = 1013J)
12
51.
Calculate S when one mole of steam at 100C is converted into ice at 0C.
Given:
Average specific heat of water = 75.31 J K1 mol1.
Heat of vapporization at B.P. = 44.8 kJ mol1
Heat of fusion at freezing point = 6 kJ mol1.
[15 Marks]
44.8
6
273
0.12,
0.22, Cp ln
0.075
373
273
373
13
52.
(a) In the reaction,
[09 Marks]
(i) CH3I (excess)

(ii) AgOH
N
CH3
(iii) heat
Write the steps for the formation of above product.

(b) Write the mechanism of reaction
[06 Marks]
O
(i) OH
(ii) H+
COOH
Br
14
53.
What are [X], [Y] and [Z].

O
I2
H3C
Ag
Ph
[X]
[Y]
H2O
[Z]
[15 Marks]
15
54.
What are [X], [Y] and [Z].

O
O
SH
H3C
SH
+
[X]
nBuLi
[Y]
HgCl2
[Z]
[15 Marks]
16
Space for rough
17
CHEMISTRY
Date : 01-06-2014
DU Test Series-IV
ANSWER KEY
1. (b)
2. (b)
3. (c)
4. (d)
5. (b)
6. (c)
7. (c)
8. (d)
9. (b)
10. (d)
11. (b)
12. (d)
13. (b)
14. (b)
15. (b)
16. (c)
17. (d)
18.(c)
19. (c)
20. (c)
21. (d)
22. (c)
23. (c)
24. (c)
25. (d)
26. (b)
27. (d)
28. (b)
29. (d)
30. (a)
31. (c)
32. (b)
33. (c)
34. (b)
35. (a)
36. (b)
37. (c)
38. (b)
39. (b)
40. (b)
41. (d)
42. (b)
43. (c)
44. (b)
45. (a)

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TEST PAPER CODE : CY

TIME: 3:00 HOURS

1. The question-cum-answer booklet has 15 pages and has

Which one among the following is a paramagnetic complex?

Which of the following systems are isoelectronic?

(d) OH , HF, NH3

Consider the following reaction

How many and -particles are emitted in passing from 90 Th 232 to

Solution of Na metal in liquid NH3 is a strong reductant due to th presence of

In terms of polar character, which one of the following order is correct

Which one of the following is NOT true for diborane?

The bond angle of given hydrides are such that

(b) OH2 SH 2 SeH2 TeH 2

(c) SH 2 SeH2 TeH 2 OH 2

(d) TeH2 OH2 SH 2 SeH 2

In the extraction of nickel by Mond process, the metal is obtained by

How is the product formed?

What is the mechanism of the reaction given above called?

The product will be

(d) None of these

Which one amongst the following carbocation is most stable?

The product [Y] is

(a) RMgX CO2

(c) PhOH CHCl3 NaOH

Which one of the following would readily gives tollens test

The rotational constant (B) of a diatomic molecule is

Which of the following molecules will not show IR spectrum?

The source of UV radiation used in UV-visible spectrophometes is

The mechanism for photochemical decomposition of HI into H2 and I2 is

The reaction 2H 2 2NO N 2 2H 2O is assumed to proceed by the following mechanism

Which is the rate law for the reaction?

The ratio (a/b) has the dimension of

(c) lit mol1

Complete the following reaction

Write the structure of X also.

(a) Draw the M.O. diagram of CO molecule.

(iii) Co NH3 4 Cl2

(b) Calculate the pH (approx.) of 1107 M solution of HCl at 25C.

(a) In the reaction,

(i) CH3I (excess)

Write the steps for the formation of above product.

What are [X], [Y] and [Z].

What are [X], [Y] and [Z].

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