Apendices

Constante de Boltzmann
Constante de Faraday

0.082054 It atm' oK-I. mol-1

82.057 em3. atm' K-1 . mol-1
8.3144 J .oK-l. mol-1
8.3144 x 107 erg' K-1 . mol-1
1.9872 eal K-1 . mol-1
1.38044 x 10-16 erg' K-1
23040 eal volt-1

Aeeleraeion de Ia gravedad
Carga eleetroniea
Numero de Avogadro
Veloeidad de la luz

96 400 J . volt-1
6.6252 x 10-27 erg' seg
1.58346 x 10-37 Keal . seg
980.665 em . seg-2
4.80286 x 10-10 ues
6.023 x 1023
299793 Km' seg-1

Longitud
Masa
Volumen
Fuerza
Presion

1 Kg
1 It
1N
1 atm

g=
e=

N=

e=

=
=
=

3.28084 pies = 39.3701 pulg

2.204621b
0.0353147 pies3 = 0.264172 gal
= 1 Kg' m . seg-2 = 105 dinas = 0.224809 Ib fuerza
= 760 mm Hg = 1.01325 x 106 dina . em-2 = 1.01325 bar
= 14.696 Ib . pulg-2
= 0.239006 eal = 1 Kg' m2 . seg-2 = 1 N . m = 1 W' seg
= 107 dina . em = 107 erg = 10 em3 . bar = 9.86923 em3 . atm
= 0.00987 It atm = 9.47831 x 10-4 Btu
= 103 J . seg-1 = 1.34102 HP = 103 V' A = 103 Kg' m2 . seg3
= 239.006 eal seg-1 = 737.562 pie Ibf 'seg-1
= 56.8699 Btu . min-1

Termodinamica

208

bio/6gica

Datos termodinamicos de elementos y compuestos inorganicos a

condiciones de 298 oK y 1 atm.

Apendice 3.

Sustancia

Ag
Ag+
Agel
AgBr
Agi
AgN03
AI
AP+
AI203
Ar
As
AS043AsH3
H3As04
Au
AU203
AuCI
AuCI3
B
B203
H3B03
Ba
Ba2+

BaO
BaCI2
BaS04
BaC03
Be
BeO
Br2
BrHBr
C
CO
CO2
C032HC03-

Estado

sol
aq
sol
sol
sol
sol
sol
aq
sol
gas
sol
aq
gas
sol
sol
sol
sol
sol
sol
sol
sol
aq
sol
aq
sol
sol
sol
sol
sol
sol
1iq
aq
gas
sol (grafito)
sol (diamante)
gas
gas
aq
aq
aq

~HO
(kJ mol-I)

~GO
(kJ mol-I)

0
105.90
-127.04
-99.50
-62.38
-123.14
0
-524.67
-1669.79
0
0
-870.27
171.54
-900.40

0
77.11
-109.72
-95.94
-66.32
-32.18
0
-481.16
-1576.41

0
80.75

0
0
-635.97

so

cpo

(J mol-10K-I)

(J mol-10K-I)

42.71

25.49

73.93
96.11
107.11
114.22
140.92
28.32

37.66
50.79
52.38
54.43

- 313.38
50.99
154.7 4

93.05
24.34
78.99
20.79

35.15
-144.77

24.98

0
163.18

47.70
125.52

25.23

0
1184.07
-963.16
-963.32

6.53
54.02
89.58
159.83
66.94
12.55
70.29
125.52
132.21
112.13
9.54
14.10
152.30
80.71
198.48

11.97
62.26
82.05

-35.15
-118.41
0
1263.57
-1087.84
-1067.76
0
-538.36
-558.15
-860.06
-1464.4
-1218.80
0
-610.86
0
-120.92
-36.23
0
1.90
-110.52
-393.51
-412.92
-676.26
-691.11

0
-560.66
-528.44
-810.86
-1353.11
-1138.88
0
-581.58
0
102.82
-53.22
0
2.87
-137.27
-394.38
-386.23

197.91
213.64
121.34

-528.10
-:587.06

-53.14
94.98

5.69
2.44

26.36
47.45
75.31
101.75
85.35
17.82
25.40
-128.45
29.12
8.64
6.06
29.14
37.13

Apendices

Sustancia
H2C03
CS2
HCN
CNCNONH4HC03
CO(NH2h
Ca
Ca2+
CaO
Ca(OHh
CaF2
CaCb
CaS04
CaC03
Cd
Cd2+
CdO
CdCI2
CdS04
Cb
HCI
Co
C02+
CoO
Cr
Cr2+
Cr203
Cr042Cr2072Cs
Cs+
Cu
Cu+
Cu2+
CuO
CU20
CuCI
CuCb
CuS
CUS04
F2

Estado
aq
gas
1iq
aq
aq
aq
sol
sol
aq
sol
aq
sol
sol
sol
sol
sol
sol (calcita)
sol
aq
sol
sol
sol
gas
gas
sol
aq
sol
sol
aq
sol
aq
aq
sol
aq
sol
aq
aq
sol
sol
sol
sol
sol
sol
gas

~HO
(kJ mol-1)
-699.65
115.27
87.86
105.44
151.00
-140.16
-852.28
-333.19
-319.24

209
SO
(J mol-1 K-l)

~GO
(kJ mol-1)
-623.17
65.06
63.60
112.13
165.69
-98.74
-197.15
-203.84

0
-553.04
-604.17
-896.76
-1161.90
-750.19
-1320.30
-1128.76

-542.96
-635.55
-986.59
-1214.62
-794.96
-1432.69
-1206.88
0

-77.74

-254.64
-389.11
-926.17

-225.06
-342.59
-820.20
0

0
-67.36
-239.32
0

-138.91
-1128.43

-1046.84
-706.26
-1257.29

-863.16
-1460.63
0
-247.69

0
-282.04

0
51.88
64.39
-155.23
-166.69
-134.73

0
50.21
64.98
-127.19
-146.36
-118.83

-205.85
-48.53
-769.86

-48.95
-661.91
0

45.65
75.73

128.87
117.99
130.12
104.60
173.85
41.63
-55.23
39.75

106.69
92.89
51.46
-61.09
54.81
118.41

0
-95.27
0
-51.46
-213.38

-92.31

187.44
237.82
151.04

76.15
68.87
113.81

-72.38

Cpo

(J mol-1 K-l)

93.14
26.28
42.80
84.52
67.03
72.63
99.58
81.88
25.90
43.43

137.24
222.95
186.68
28.45

33.93
29.12
25.56

155.23
43.93
23.77

23.35

81.17
38.49
213.80

118.74

82.84
133.05
33.31
-26.36
98.74

31.05

43.51
100.83
91.63

44.35

66.53
113.39
203.34

47.82
100.83
31.46

24.47

69.87

210

Termodinamica bio/6gica

Sustancia
FHF
Fe
Fe2+
Fe3+
Fe203
Fe(OH12
Fe(OHh
H
H2
H+
OHH2O
H2O
H202
H202
He
Hg
Hg2+
HgO
HgCI2
Hg2C12
HgS
HgS04
Hg2S04
12
1+
HI
K
K+

K20
KOH
KCI
KCI03
KCI04
KBr
KI
KN03
K2C03
Kr
Li
Li+
Li20
LiOH

Estado
aq
gas
sol
aq
aq
sol
sol
sol
gas
gas
aq
aq
gas
1iq
1iq
aq
gas
1iq
aq
sol (rojo)
sol
sol
sol (rajo)
sol
sol
sol
aq
gas
sol
aq
sol
sol
sol
sol
sol
sol
sol
sol
sol
gas
sol
aq
sol
sol

~HO
(kJ mol-I)

~GO
(kJ mol-I)

SO
(J mol-10K-I)

-329.11
-268.61

-276.48
-270.71

-9.62
173.51
27.15
-113.39
-293.30

0
-87.86
-47.70

-84.94
-10.54
-740.99
-483.55

-822.16
-568.19
-824.25
-217.94
0
0
-229.94
-241.83

89.96
79.50

203.24
0
0
-157.30
-228.60
-237.19
-118.11

-285.84
-187.61
-191.13

-230.12
-264.93
-58.16
-704.17
-741.99
0
55.94
25.94
0
-251.21
-361.50
-425.85
-435.87
-391.20
-433.46

69.94

29.08
25.23

104.60

20.79
28.84
0
-133.89
33.58
75.30

20.79

-58.53

71.97

45.73

-210.66
-48.83

196.22
77.82

101.67

-623.92

200.75
116.73
109.37

132.01
54.98
-129.70

206.33
63.60
102.50

29.16
29.16

82.68
142.97
151.04
96.44
104.35

51.51
100.25
110.17
53.64
55.06
96.27

0
51.67
1.30
0
-282.28

-408.33
-289.91
-304.18
-379.20
-322.29
-393.13

-392.17
-327.65
-492.71
-1146.12

-123.43

126.05
77.40

0
0

0
0
-164.38
-90.71

114.61
130.59
0
-10.54
188.72

Cpo

(J mol-10K-I)

132.93

-278.46

-293.80

163.97
28.03
14.23

-595.80
-487.23

-443.92

50.21

0
0

0
0

27.82

20.79
23.64

211

Apendices

Sustancia
Mg
Mg2+
MgO
Mg(OHh
MgCb
MgS04
MgC03
Mn
Mn2+
Mn3+
Mn02
N2
N3NH3
NH4+
NH4C1
NH40H
N2H4
NO
NO~
N204
N20
HN02
HN03
N03Na
Na+
Na20
NaCI
NaBr
Nal
Na2S04
NaN03
Na2C03
NaHC03
Ne
Ni
Ni2+
NiO
Ni(OHh
0
02
03

Estado
sol
aq
sol
sol
sol
sol
sol
sol
aq
aq
sol
gas
aq
gas
aq
sol
aq
1iq
gas
gas
gas
gas
aq
1iq
aq
sol
aq
sol
sol
sol
sol
sol
sol
sol
sol
gas
sol
aq
sol
sol
gas
gas
aq
gas

AHO
(kJ mol-1)
0
-461.96
-601.83
-924.66
-641.83
-1278.21
-1112.94
0
-218.82
-100.42
-520.91
0
245.18
-46.19
-132.80
-315.39
-366.10
50.42
90.37
33.85
9.66
81.56
-118.83
-173.22
-206.57
0
-239.66
-415.89
-411.00
-359.95
-288.03
-1384.49
-466.68
-1130.94
-947.68
0
0
-64.02
-244.35
-538.06
247.52
0
-12.09
142.26

AGo
(kJ mol-1)
0
-456.01
-569.57
-833.75
-592.33
-1173.61
-1029.26

So
(J mol-1 K-l)
32.51
-117.99
26.78
63.14
89.54
91.63
65.69
31.76

Cpo
(J mol-1 K-l)
23.89
37.41
77.03
71.30
96.27
75.52
26.32

0
-223.43

-83.68

-466.10
0

53.14
191.49

54.02
29.12

-16.64
-79.50
-203.89
-263.76

192.51
112.84
94.56
181.17

35.66

86.69
51.84
98.29
103.60
-53.64
-79.90
-110.50
0
-261.87

210.62
240.46

-376.56
-384.03
52.30
54.39
-1266.83
-365.89
-1047.67
-851.86
0
0
-46.44
-216.31
-453.13
230.10
0
16.32
163.43

304.30
219.99

84.10
-68.62
29.86
37.91
79.08
38.70

155.60
146.44

109.87

51.05
60.25
72.80
72.38

28.41

149.49
116.32

127.61
93.05
110.50
87.61
20.79
25.98

135.98
102.09
146.22
30.13
159.41
38.58
79.50
160.95
205.03
110.88
237.65

68.20
49.71

44.35
21.91
29.36
167.40
38.16

Termodinamica bio/6gica

212

LlHo
Sustancia
P
P043PZ074P40IQ
PH3
HP04zHzP04H3P04
H4PZ07
Pb
Pbz+
PbO
PbOz
PbCl2
PbS
PbS04
PI
PICI4zRb
Rb+
S
SOz
S03
S03ZS04ZHzS
HS03HS04-

HzS04
SF6
Se
SeOz
HzSe
HZSe04
Si
SiOz
Sr
Srz+
SrC!z
SrS04
SrC03
W

Estado
sol (blanco)
sol (rajo)
aq
aq
sol
gas
aq
aq
sol
sol
sol
aq
sol (amarillo)
sol
sol
sol
sol
sol
aq
sol
aq
sol (r6mbico)
sol (monoclinico)
gas
gas
aq
aq
gas
aq
aq
1iq
gas
sol
sol
gas
sol
sol
sol (cuarzo)
sol
aq
sol
sol
sol
sol

SO
(J mol-1 OK-I)

LlGO

(kJ mol-I)

(kJ mol-I)
0
-18.40
-1284.07
-2275.68
-3012.48
9.25
-1298.71
-1302.48
-1281.14

0
13.82
-1025.59

18.24
-1094.12
-1135.12

44.00
29.31

Cpo

(J mol-10K-I)
23.22

-217.57

210.04
-35.98
89.12

-2250.99
0
1.63
-217.86
-276.65
-359.20
-94.31
-918.40

0
24.31
-188.49

-516.31

-218.99
-313.97

76.57
136.40
91.21

-92.68
-811.24
-384.51
0

0
-246.44

-282.21

0
0.30
-296.06
-395.18
-624.25
-907.51
-20.15
-627.98
-885.75
-811.32

64.89
21.34
69.45

0
0.10
-300.37
-370.37
-497.06
-741.99
-33.02
-527.31
-752.87

147.28
41.84
175.73
69.45
124.27
31.88
32.55
248.52
256.22
43.51
17.15
205.64
132.38

26.82
48.53
64.43
76.99
49.50
104.18
26.57
30.42
22.59
23.64
39.79
50.63

33.97

126.86

-1096.21
0
-225.35
29.71

42.44

25.36

15.90

218.91

34.73

18.70

19.87
44.43

41.84
54.39
39.33

-530.11
0
-859.30

-805.00
0
-557.31

-545.51
-828.43
-1444.74
-1218.38

-781.15
-1334.28
-1137.63
0

25.10

117.15
121.75

79.08

97.07
33.47

81.42
24.98

213

Apendices

Sustancia

Estado

W03
W04Xe
Zn
Zn2+

sol
aq
gas
sol
aq
sol
sol
sol
sol

ZnO
ZnCl2
ZnS
ZnS04

LiHO
(kJ mol-1)

LiGo
(kJ mol-1)

-840.31
- 1115.45

-763.45

83.26

81.50

0
0
-147.21
-318.19
-369.26
-198.32
-871.57

169.58
41.63
106.48

20.79

43.93
108.37
57.74

40.25
76.57
45.19
117.15

0
0
-152.42
-347.98
-415.89
-202.92
-978.55

SO
mol-1 K-l)

Cpo

o mol-

K-l)

25.06

124.68

Los valores de esta tabla fueron tomados de Selected Values of Chemical Thermodynamics
Properties, por F. D. Rossini y colaboradores,
publicado por la "National Bureau of Standards",
NBS Circular 500, (1952), asi como de NBS Technical Notes 270-3 (1968) Y 270-4 (1969),
editado
material

por D. D. Wagman y colaboradores.

Todos 105 valores estan referidos a 1 mol de
en el estado fisico indicado, a 1 atm de presion y a 298.15 oK de temperatura.
Los

valores para los iones en solucion

acuosa (1 M) estan basad os en la convencion

de que todas

las propiedades
enlistadas para H+(aq) son igual a cera. De donde, con la adicion de valores
para combinaciones
neutras de iones con cargas opuestas, se obtiene los valores correctos
para soluciones de sa!.

Apendice 4. Datos termodinamicos

bio/6gicas a 298.15 oK y 1 atm.

Compuesto
Acido acetico
Acido acetico

Acido DL-aspartico
Acido L-aspartico
Acido
Acido
Acido
Acido

L-aspartico, ion
L-aspartico, ion dipolar
L-aspartico, ion dipolar
butirico

Acido a-cetoglutarico

Formula
CH3COOH
CH3COOH

C4H704N
C4H704N
C4HB04N+
C4H704N+C4H604N+2C4H302

CSH60S

de compuestos

Estado
liq
liq
aq
buf
sol
sol
buf
aq
aq
aq
liq
aq
buf
sol

LiHO
(KJ/mol)
-484.21
-484.21
-485.26
-485.60
-976.96
-972.53
-943.41
-955.17
-947.43
-943.41
-535.13
-532.62
-535.55
-1026.34

organicos

LiGO
(KJ/mol)
-389.45
-389.45
-404.09
-417.52
-729.27
-729.36
-736.51
-733.87
-718.06
-695.88
-379.07
-399.57
-412.54

y mo/ecu/as

So
cp
OtK mol)OtK mol)
159.83
159.83
205.43
249.37
154.39
170.12
291.63

155.27

229.28
216.31
155.65
226.35
303.76
320.91

179.49

Termodinamica bio/6gica

214

Compue?to

Formula

Acido citrico

C6Ha07

Acido citico, monohidrato

Acido f6rmico
Acido fumarico

C6H100a
HCOOH
C4H404

Acido L-glutamico

CsHg04N

Acido
Acido
Acido
Acido

L-glutamico, ion
L-glutamico, ion dipolar
L-glutamico, ion dipolar
L(+)-Iactico

Acido DL-Iactico
Acido L-malico

Acido DL-malico
Acido oxalacetico

CSH1004N+
CSH904N+CsHa04N+zC3H603

C3H603
C4H60S

C4H6OS
C4H40S

Acido palmitico

C16H3Z0Z

Acido piruvico

C3H403

Acido succinico

C4H604

Acetato
Acetato de etilo
Acetaldehido
Acetona
Acetileno
Adenina
DL-Alanina
L-Alanina

CH3COOC4HaOz
CH3CHO
CH3COCH3
CzHz
CsHsNs
C3H70ZN
C3H70zN

L-Alanina, ion
L-Alanina, ion dipolar
L-Alaninato, ion
L-Arginina

C3HaOzN+
C3H70Z+C3H60zNC6H140ZN4

Estado
sol
buf
sol
liq
sol
aq
buf
sol
buf
aq
aq
aq
sol
aq
buf
liq
sol
aq
buf
sol
sol
aq
buf
sol
aq
buf
liq
aq
buf
sol
aq
buf
aq
liq
gas
liq
gas
sol
sol
sol
buf
aq
aq
aq
sol

ilHo

ilGo

(KJ/mol)

(KJ/mol)

-1543.90
-1515.78
-1838.45
-409.20
-810.65
-774.88
-777.39
-1009.18
-981.98
-981.57
-981.99
-979.89
-694.04
-686.22
-686.64
-673.62
-1103.32

-1288.63
-1473.56
-346.02
-653.25
-645.80
-684.38
-730.95
-721.87
-734.63
-721.87
-697.47
-523.25
-538.77
-557.35
-518.82

So

OrK

mol)OrK

512.54
283.47
128.95
166.11
261.08
381.99
188.20
248.95
293.72
248.95
174.05
143.51
221.75

Cp
mol)

268.15
99.04
142.26

175.23

127.61

192.05

211.29

-315.06
-287.86
-299.16

455.22

460.66

-486.60
-513.38
-747.35
-746.64
-772.99
-376.89
-337.65
-139.08
-153.55
209.20
-300.41
-371.96
-370.20
-371.16
-384.55
-371.16
-314.85
-656.89

179.91

-891.61
-925.08
-1105.41
-984.50
-832.62
-875.71
-890.77

-585.76
-607.52
-596.22
-940.81
-912.20
-908.72
-485.60
-481.99
-246.81
-246.81
226.73
97.07
-563.59
-562.75
-554.80
-557.94
-554.80
-509.61
-621.74

175.73
269.45
369.45
112.97
262.76
264.22
198.74
200.83
151.04
132.21
129.20
158.99
192.05
158.99
121.75
250.62

153.97
230.12

105.44
56.07
126.78
43.93
143.09
121.75
122.26
288.70
141.00
71.55
233.47

Apendices

Compuesto

Formula

Estado

L-Arginina, ion dipolar

L-Aspartato, ion
L-Asparagina
L-Asparagina, ion dipolar
L-Asparagina, monohidrato
Benceno
Butirato, ion
a-Cetoglutarato, ion
L-Cistefna

C6H1402N4+C4Hs04N2C4H803N2
C4H803N2+C4H1004N2
C6H6

L-Cisteina, ion
L-Cisteina, ion dipolar
L-Cisteinato, ion monovalente
L-Cisteinato, ion divalente
L-Cistina

C3H80zNS+
C3H70zNS+C3H60zNSC3HsOzNSzC6H lZ04NzSz

aq
aq
sol
aq
sol
1iq
aq
aq
sol
buf
aq
aq
aq
aq
sol
buf
aq
aq
aq
aq
aq
aq
aq
sol
aq
sol
aq
buf
aq
aq
sol
gas
liq
gas
aq
aq
aq
liq
sol
buf
aq
aq
aq
sol
buf
aq

L-Cistina, ion
L-Cistina, ion dipolar
L-Cistina, ion dipolar
L-Cistinato, ion
Citra to, ion monovalente
Citra to, ion divalente
Citra to, ion trivalente
Creatinina
Creatinina, ion
Creatina

C4HzOzCsH4OzC3H70zNS

C6H1404Nzsi+
C6H1304NzSz+C6H lZ04NzS2+2C6H 1004NzS2C6H707C6H707ZC6Hs073C4H70N3
C4HaON3+
C4H90zN3

Creatina, cation
Creatina, anion
Creatina, monohidrato
Etano
Etanol
Etileno
Formato, ion
Fumarato, ion monovalente
Fumarato, ion divalente
Glicerol
Glicina

C4H100zN3+
C4H80ZN3C4Hl103N3
CZH6
C2HSOH
CZH4
HCOOC4H304-

Glicina, ion
Glicina, ion dipolar
Glicinato, ion
Glicilglicina

C2H60zN+
C2HSOzN+C2H4OzNC4H803NZ

Glicilglicina, ion

C4H903Nz+

C4Hz04zC3H803
CZHS02N

215
ilHO

ilGO

(KJ/mol)

(KJ/mol)

-615.47
-905.84
-790.36
-766.09
-1085.75
49.04
-535.55
-532.02

-638.69
-530.95
-525.93
-767.35
172.80
-372.04
-793.41
-342.67
338.95

So

Cp
OrK mol) OrK mol)

89.96
174.47
238.91
209.62
124.52
201.67

160.67
207.95

169.87

173.22

280.58

261.92

286.19
203.34
92.05
167.36

187.86
0.84
-254.81
138.91

189.54

171.96

234.30
229.49
161.04
219.45
91.63
203.34
105.44
204.60
103.51
158.57
189.54
158.57
120.50
189.95
232.21
286.60

213.38
52.66
111.96
43.56

-349.36

-1044.33

-1520.88
-1518.46
-1515.11
-237.65
-536.47

-833.03
-84.68
-276.98
52.30
-410.03
-774.46
'-777.39
-670.70
-537.23
-523.00
-527.18
':'523.00
-478.65
-746.01
-734.25
-735.72

-338.82
-290.99
-229.58
-685.76
-668.19
684.50
-678.23
-666.51
-562.33
-1226.33
-1199.18
-1162.69
-28.45
4.14
-264.01
-259.20
-259.20
-274.39
-177.82
-504.59
-32.89
-174.18
68.12
-334.72
-628.14
-601.87
-479.49
-377.69
-379.91
-393.30
-379.91
-324.09
-491.50
-493.08
-510.87

216.73
99.20
171.54
36.82
54.81
163.59
288.70

216

Compuesto
Glicilglicina, ion dipolar
Glicilglicinato, ion
a-D-Glucosa

Termodinamica

Formula

Estado

C4H803N2+C4H703N2C6H1206

aq
aq
sol
aq
sol
aq
aq
sol
aq
buf
aq
aq
aq
aq
aq
aq
sol
buf
aq
aq
sol
aq
sol
aq
sol
sol
buf
aq
aq
aq
aq
aq
aq
aq
aq
sol
gas
liq
aq
sol
aq
aq
aq
aq
aq

~-D-Glucosa

C6H1206

a-~-D-Glucosa
a-D-Glucosa, monohidrato
Glucosa- 1-fosfato

C&H1206
C&H1407
C&H1309P

Glucosa- 1-fosfato, ion monovalente

Glucosa- 1-fosfato, ion divalente
Glucosa-6-fosfato
Glucosa-6-fosfato, ion monovalente
Glucosa-6-fosfato, ion divalente
L-Glutamato
L-Glutamina
L-Glutamina, ion dipolar
L(+)-Lactato, ion
a-Lactosa
~-Lactosa
a, ~- Lactosa
DL-Leucina
L-Leucina

bi%gica

C3H1209PC3H1209P2C6H1309P
C6H1209PC6Hl109p2CSH704N2CSHlOO3N2
CSHlOO3N2+C3HS03C12Hn011
C12HnOIl
C12HnOI1
C6H1302N
C6H1302N

L-Leucina, ion
L-Leucina, ion dipolar
L-Leucinato, ion
Malato, ion monovalente
Malato, ion divalente
a-Maltosa
~-Maltosa
a,~-Maltosa
~-Maltosa, monohidrato
Metano
Metanol

C6H1402N+
C6H1302N+C6H1202NC4HsOSC4H40S2C12Hn011
C12HnOll
C12HnOll
C12H24012
CH4
CH30H

L-Metionina
L-Metionina, ion
L-Metionina, ion dipolar
Oxaloacetato, ion monovalente
Oxaloacetato, ion divalente
Palmitato, ion

CSH1I02NS
CSH1202NS+
CsH 1102NS+C4H30SC4H20s2Cl&H3102-

tJ.HO

tJ.Go

(Kl/mol)

(Kl/mol)

-734.25
-689.90
-1274.45
-1263.06
-1268.05
-1264.24
-1263.78
-1571.09

-939.73
-825.92
-805.00
-805.00
-686.64
-2221.70
-2232.37
-2236.77
-2233.09
-649.78
-646.85
-643.37
-645.01
-643.37
-600.61
-842.66
-2238.27
-2237.73
-2238.06
-2539.27
-74.85
-238.66
-245.89
-761.07
-744.75
-744.33
-818.39
-793.29

-492.08
-445.76
-910.56
-914.54
-908.89
-915.79
-916.97
-1149.55
-1789.50
-1828.83
-1783.22
-1746.11
-1797.45
-1789.08
-1753.51
-643.50
-532.21
-528.02
-528.02
-516.72

So
Cp
(JrK mol) (JrK mol)
231.38
222.17
212.13
264.01
228.03
264.01
269.45
252.30

127.61
195.10
251.04
251.04
146.44

-1564.90
-1566.91
-1567.33
-358.57
-356.48
-352.25
-365.56
-352.25
-296.60
-871.95

394.13
386.18
399.57
207.11
209.62
206.69
246.44
207.53
164.43

-1573.60
-1572.18
-1574.69
-1809.58
-50.79
-166.31
-175.23
-508.36

403.34
400.41
407.94
417.56
186.19
126.78
132.34
231.46

-259.41

158.99
218.87

305.43

183.80

410.45
195.39
208.36
-660.24
506.26
447.69

453.96
35.73
81.59
290.20

217

Apendices

Compuesto

Formula

Estado

Piruvato, ion
2-Propanol

C3H303C3H70H

aq
liq
aq
aq
aq
sol
aq
sol
buf
aq
aq
aq

Succinato, ion monovalente

Succinato, ion divalente
Sacarosa

C6HS04C6H4042C12H22011

DL-Valina

CSH1102N

L-Valina, ion
L- Valina, ion dipolar
L-Valinato, ion

CSHI202N+
CSH1102N+CSH1002N-

~HO

~GO

(KJ/mol)

(KJ/mol)

-596.22
-317.86
-330.83
-908.89
-908.68
-2221.70
-2215.85
-617.98
-617.98
-612.24
-611.99
-567.43

-472.37
-180.29
-185.23
-722.62
-690.44
-1544.31
-1551.43
-359.82
-358.65
-371.71
-358.65
-307.40

SO

OrK

mol)

171.54
180.58
153.55
199.99
92.88
360.24
403.76
181.17
176.98
240.16
176.98
174.89

Cp
mol)

OtK

154.22
96.23
122.59
425.51
633.04

547.27
389.11
333.88

Los datos de esta tabla fueron obtenidos de R.C. Wilhoit "Thermodynamic properties of biochemical
substances" publicados en Biochemical Microcalorimetry, editado por HD. Brown, capitulo 2,
Academic Press Inc., New York, 1969.
EI simbolo buf significa los valores en el equilibrio de una soluci6n amortiguadora 0 tamp6n a pH 7. Las
concentraciones de las soluciones acuosas son todas de 1 M.