JEE-MAINS 2014 Question Paper & Solutions

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PAPER -1 : PHYSIC, MATHEMATICS & CHEMISTY

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JEE-MAINS 2014 Question Paper & Solutions

PHYSICS
1.

The pressure that has to be applied to the ends of a steel wire of length 10
cm to keep its length constant when its temperature is raised by 100oC is :
(For steel Youngs modulus is 2 1011 N m2 and coefficient of thermal
expansion is 1.1 105 K1)
(1) 2.2 107 Pa
(2) 2.2 106 Pa
(3) 2.2 108 Pa
(4) 2.2 109 Pa
Key. 3
Sol.

P T
= 2 1011 1.1 10 5 100
= 2.2 108 Pa

2.

A conductor lies along the z-axis at 1.5 z < 1.5 m and carries a fixed

current of 10.0 A in a z direction (see figure). For a field B 3.0 104 e 0.2x a yT,
find the power required to move the conductor at constant speed to x =
2.0 m, y = 0 m in 5 103s. Assume parallel motion along the x-axis.

(1) 14.58 W
Key. 4
Sol.

3.

(2) 29.7 W

(3) 1.57 W

(4) 2.97 W

1
iBl dx
t
2
1
10 3.0 104 e 0.2x 3 dx
3 0
5 10

= 2.97 W
A bob of mass m attached to an inextensible string of length l is suspened
from a vertical support. The bob rotates in a horizontal circle with an
angular speed rad/s about the vertical. About the point of suspension:
(1) angular momentum changes in direction but not in magnitude.
(2) angular momentum changes both in direction and magnitude.
(3) angular momentum is conserved.
(4) angular momentum changes in magnitude but not in direction.
2

JEE-MAINS 2014 Question Paper & Solutions

Key. 3
Sol. The torque of all the forces about the point of suspension is zero therefore
angular momentum is conserved.
4.

The current voltage relation of diode is given by I = (e1000V/T 1) mA,

where the applied voltage V is in volts and the temperature T is in degree
Kelvin. If a student makes an error measuring 0.01 V while measuring
the current of 5mA at 300 K, what will be the error in the value of current
in mA?
(1) 0.5 mA
(2) 0.05 A
(3) 0.2 mA
(4) 0.02 mA
Key. 3
Sol.

Ie

1000V
T

I 1 e

1000V
T

1000 1000V
e T .V
T
1000

5 1 0.01
300
I

1000V

T
5 1
e

= 0.2 mA
5.
An open glass tube is immersed in mercury in such a way that a length of 8
cm extends above the mercury level. The open end of the tube is then
closed and sealed and the tube is raised vertically up by additional 46 cm.
what will be length of the air column above mercury in the tube now?
(Atmospheric pressure = 76 cm of Hg)
(1) 38 cm
(2) 6 cm
(3) 16 cm
(4) 22 cm
Key. 3
Sol.
x
8 cm

54 cm

Applying Boyles Law to the air column in the glass tube,

P1V1 = P2V2

76 8 A = {76 (54 x)} . x.A

x = 16 cm
3

JEE-MAINS 2014 Question Paper & Solutions

6.

Match List I (Electromagnetic wave type) with List II (Its

association/application) and select the correct option from the choices
given below the lists:
List I
List- II
(a) Infrared waves
(i)
To treat muscular strain
(b) Radio waves
(ii)
For broadcasting
(c) X-rays
(iii)
To detect fracture of bones
(d) Ultraviolet rays
(iv)
Absorbed by the ozone
layer of the
atmosphere
(a)
(iii)
(i)
(iv)
(i)

(1)
(2)
(3)
(4)
Key. 2
Sol. Conceptual

(b)
(ii)
(ii)
(iii)
(ii)

(c)
(i)
(iii)
(ii)
(iv)

(d)
(iv)
(iv)
(i)
(iii)

7.

A parallel plate capacitor is made of two circular plates separated by a

distance of 5 mm and with a dielectric of dielectric constant 2.2 between
them. When the electric field in the dielectric is 3 104 V/m, the charge
density of the positive plate will be close to :
(1) 3 104 C/m2 (2) 6 104 C/m2 (3) 6 107 C/m2 (4) 3 107 C/m2
Key. 3
Sol.

Q
Charge density
A

K o A
.Ed
d
A

= Ko E
6 10 C/m2
7

JEE-MAINS 2014 Question Paper & Solutions

8.

A student measured the length of a rod and worte it as 3.50 cm. Which
instrument did he use to measure it ?
(1) A screw gauge having 100 divisions in the circular scale and pitch as 1
mm.
(2) A screw gauge having 50 divisions in the circular scale and pitch as 1
mm.
(3) A meter scale.
(4) A vernier caliper where the 10 divisions in vernier scale matches with
9 division in main scale and main scale has 10 divisions in 1 cm.
Key. 4
Sol. The least count of the observation is 0.01 cm which corresponds to option
(4)
9.

Four particles, each of mass M and equidistant from each other, move
along a circle of radius R under the action of their mutual gravitational
attraction. The speed of each particle is
(1)

GM
1 2 2
R

(2)

1 GM
1 2 2
2 R

(3)

GM
R

(4) 2 2

GM
R

Key. (2)
Sol. The centripetal force will be provided by the resultant force i.e.
R

GM 2 1 1 Mv2

R 2 2 4
R

v=

1 GM
1 2 2
2 R

10.

In a large building, there are 15 bulbs of 40 W, 5 bulbs of 100 W, 5 fans of

80 W and 1 heater of 1 kW. The voltage of the electric mains is 220 V. the
minimum capacity of the main fuse of the building will be :
(1) 12 A
(2) 14 A
(3) 8 A
(4) 10 A
Key. 1
Sol.

I 15

40
100
80
1000
5
5
1
P VI
220
220
220
220

= 11.36 A
Minimum capacity of the main fuse = 12 A
5

JEE-MAINS 2014 Question Paper & Solutions

11.

A particle moves with simple harmonic motion in a straight line. In first

s, after starting from rest it travels a distance a, and in next s it travels
2a, in same direction, then
(1) amplitude of motion is 4a
(2) time period of oscillations is 6
(3) amplitude of motion is 3a
(4) time period of oscillations is 8
Key. (2)
t = 0
A

A
O

Sol.

Since it is given that the particle starts from rest

So, the particle starts from an extreme position.
Let the particle start from positive extreme at t = 0.

x = A sin t = A cos t

After t = distance travelled by particle is a

x=Aa
A a = A cos
(1)
After t = 2, distance travelled by particle is a + 2a = 3a x = A 3a
A 3a = A cos (2) = A cos (2)
(2)
2
Using cos 2 = 2cos - 1 and putting cos and cos 2 from equation
(1) and (2),
2

A 3a
Aa
We get,
2
1
A
A
2

2
A 3a 2 A a A

A(A 3a) = 2(A a)2 A2

2
A
A

A2 3aA = 2A2 + 2a2 4aA A2 3aA = 2a2 4aA

2a2 = aA a = A/2
(3)
Putting a = A/2 in equation (1) we get A (A/2) = A cos
(A/2) = A cos cos = (1/2)
= /3 = (/3)
T = 2/ =

2
= 6
/ 3

JEE-MAINS 2014 Question Paper & Solutions

12.

The coercivity of a small magnet where the ferromagnet gets

demagnetized is 3 103 Am-1. The current required to be passed in a
solenoid of length 10 cm and number of turns 100, so that the magnet gets
demagnetized when inside the solenoid is
(1) 3 A
(2) 6 A
(3) 30 mA
(4) 60 mA
Key. (1)
Sol. H = nI = (N/L)I
I = HL/N =
13.

Key.
Sol.
14.

Key.
Sol.

3 103 0.1
3A
100

The forward biased diode connection is

2 V
4 V
+2 V
(1)
(2) 2 V
+2 V
2 V
3 V
(3)
(4) 3 V
(3)
For forward biasing of P-N junction diode, P side potential should be
higher than N side.
During the propagation of electromagnetic waves in a medium
(1) Electric energy density equal to the magnetic energy density
(2) Both electric and magnetic energy densities are zero
(3) Electric energy density is double of the magnetic energy density
(4) Electric energy density is half of the magnetic energy density
(1)
In electromagnetic waves,
U Eavg

1
1 B2
o E 2 and U Bavg
4
4 o

Hence U E U B
avg

avg

15. In the circuit shown here, the point C is kept connected

to point A till the current flowing through the circuit
becomes constant. Afterward, suddenly, point C is
disconnected from point A and connected to point B
at time t = 0. Ratio of the voltage across resistance and
the inductor at t = L/R will be equal to
(1) 1
(3)

e
1 e

(2)

A C
B

R
L

1 e
e

(4) 1
7

JEE-MAINS 2014 Question Paper & Solutions

Key. (1)
Sol. Using KVL, during decay of current in RL circuit at any time, we get
VR + VL = 0
VL/VR = 1
16. A mass m is supported by a
massless string wound around a
uniform hollow cylinder of mass
R
m
m and radius R. If the string does
not slip on the cylinder, with
what acceleration will the mass
fall on release?
(1)
(3)

5g
6
2g
3

(2) g
(4)

g
2

Key. (4)
Sol. F. B. D of block is
T
a
mg

mg T = ma (1)
F. B. D of pulley is
T

mg

from = I, we get
TR = mR2
(2)
Due to no slipping a = R
(3)
Solving (1), (2) and (3), we get a= g/2
8

JEE-MAINS 2014 Question Paper & Solutions

17.

Key.
Sol.

18.

Key.
Sol.

P
One mole of diatomic ideal gas undergoes a cyclic
B800 K
process ABC as shown in figure. The process BC is
adiabatic. The temperatures, at A, B and C are 400 K, 800
C
A
400 K 600 K
K and 600 K respectively. Choose the correct statement
V
(1) The change in internal energy in the process AB is
350 R
(2) The change in internal energy in the process BC is
500R
(3) The change in internal energy in whole cyclic process
is 250 R
(4) The change in internal energy in the process CA is
700R
(2)
In process AB,
U = nCvT = 1. (5R/2) 400 = 1000R
In process BC,
U = nCvT = 1 (5R/2)(200) = 500R
In process CA,
U = nCvT = 1 (5R/2) (200) = 500R
Hence option (2) is correct.
From a tower of height H, a particle is thrown vertically upwards with a
speed u. The time taken by the particle, to hit the ground, is n times that
taken by it to reach the highest point of its path. The relation between H, u
and n is
(1) 2gH = nu2(n 2)
(2) gH = (n 2)u2
(3) 2gH = n2u2
(4) gH = (n 2)2u2
(1)
Let height of tower be H, and time taken to reach
+y
ground be t1

H = ut1

1 2
gt1
2

(1)

And let t2 be the time taken to reach the highest

point
u = gt2 t2 = u/g

JEE-MAINS 2014 Question Paper & Solutions

Since t1 = nt2
From (1), H = unt2

1 2
gn t 2
2

u
g

1
2

H = un gn 2

u2
g2

2gH 2nu 2 n 2 u 2 nu 2 n 2
(1)
19.

A thin convex lens made from crown glass

has focal length f. When

it is measured in two different liquids having refractive indices (4/3) and

(5/3), it has the focal lengths f1 and f2 respectively. The correct relation
between the focal lengths is
(1) f2 > f and f1 becomes negative (2) f1 and f2 both become negative
(3) f1 = f2 < f
(4) f1 > f and f2 becomes negative
Key. (4)
Sol.

1 3 1
1 1 1
1
1

f 2 R1 R 2 2 R1 R 2
1 3 3 1
1 1 1
1

f1 2 4 R 1 R 2 8 R 1 R 2
1 3 3 1
1
1 1
1

f2 2 5 R1 R 2
10 R 1 R 2

f : f1 : f2 :: 2 : 8 : 10
20.

Three rods of Copper, Brass and Steel are welded together to form a Y
shaped structure. Area of cross-section of each rod = 4 cm2. End of copper
rod is maintained at 100oC where as ends of brass and steel are kept at
0oC. Lengths of the copper, brass and steel rods are 46, 13 and 12 cms
respectively. The rods are thermally insulated from surroundings except
at ends. Thermal conductivities of copper, brass and steel are 0.92, 0.26
and 0.12 CGS units respectively. Rate of heat flow through copper rod is
(1) 4.8 cal/s
(2) 6.0 cal/s
(3) 1.2 cal/s
(4) 2.4 cal/s

Key. (1)

10

JEE-MAINS 2014 Question Paper & Solutions

Sol.

0.92 A 100 T 0.12A T 0 0.26A T 0

46
12
13
92 100 T 12T 26T

46
12
13

100oC
0oC
Copper

Brass
Steel

2(100 T) = T + 2T
200 = 5T
T = 40
Now in copper rod

0C

dQ 0.92 4 60 24

4.8 cal /s
dt
46
5

21.

A pipe of length 85 cm is closed from one end. Find the number of possible
natural oscillations of air column in the pipe whose frequencies lie below
1250 Hz. The velocity of sound in air is 340 m/s.
(1) 6
(2) 4
(3) 12
(4) 8
Key: (1)
Sol. Given l =85 cm
nv
1250
4
n 12.5

22.

Where n = 1, 3, 5, 7, 9, 11
There is a circular tube in a vertical plane. Two liquids which do not mix
and of densities d1 and d2 are filled in the tube. Each liquid subtends 900
angle at centre. Radius joining their interface makes an angle with
vertical. Ratio

d1
d2

is:

d2

d1

(1)

1 tan
1 tan

(2)

1 sin
1 cos

(3)

1 sin
1 sin

(4)

1 cos
1 cos

Key: (1)
Sol. P0 + d1g(R R sin ) = P0 + d2g (R sin + R cos ) + d1g (R R cos)
11

JEE-MAINS 2014 Question Paper & Solutions

From above
d1 sin cos 1 tan

d 2 cos sin 1 tan

23.

A green light is incident from the water to the air-water interface at the
critical angle(). Select the correct statement.
(1) The spectrum of visible light whose frequency is more than that of
green light will come out to the air medium.
(2) The entire spectrum of visible light will come out of the water at
various angles to the normal
(3) The entire spectrum of visible light will come out of the water at an
angle of 900 to the normal
(4) The spectrum of visible light whose frequency is less than that of
green light will come out to the air medium.
Key: (4)
Sol.

1
sin c

.(i)

By Cauchy relation

(ii)

From both eq. c

24.

Hydrogen (1H1), Deuterium (1H2), singly ionized Helium (2He4)+ and

doubly ionized lithium (3Li6)++ all have one electron around the nucleus.
Consider an electron transition from n = 2 to n = 1. If the wave lengths of
emitted radiation are 1, 2, 3 and 4 respectively then approximately
which one of the following is correct?
(1) 1 = 2 = 43 = 94
(2) 1 = 22 = 33 = 44
(3) 41 = 22 = 23 = 4
(4) 1 = 22 = 23 = 4
Key: (1)
Sol.

hc
3
13.6 Z 2

4
1
2
Z

12

JEE-MAINS 2014 Question Paper & Solutions

25.

The radiation corresponding to 3 2 transition of hydrogen atom falls on

a metal surface to produce photoelectrons. These electrons are made to
enter a magnetic field of 3 104. If the radius of the largest circular path
followed by these electrons is 10.0 mm, the work function of the metal is
close to :
(1) 0.8 eV
(2) 1.6 eV
(3) 1.8 eV
(4) 1.1 eV
Key: (4)
Sol.

5
E 13.6 1 eV 1.88 eV
36
p
r
, p rqB 4.8 10 25
qB

p2
0.79 eV
2m
E K.E 1.09
1.1 eV
K.E

26.

A block of mass m is placed on a surface with a vertical cross section given

by

x3
.
6

If the coefficient of friction is 0.5, the maximum height above the

ground at which the block can be placed without slipping is:

(1)

1
m
3

(2)

1
m
2

(3)

1
m
6

(4)

2
m
3

Key: (3)
Sol. mg sin mg cos
tan

At x = 1; y = 1/6
27.

When a rubber-band is stretched by a distance x, it exerts a restoring

force
of
magnitude
2
F = ax + bx where a and b are constants. The work done in stretching the
unstretched rubber-band by L is:
(1)

aL2 bL3

2
3

(2)

1 aL2 bL3

2 2
3

(3)

aL2 bL3

(4)

1 2
aL bL3
2

Key: (1)
13

JEE-MAINS 2014 Question Paper & Solutions

Sol.
28.

L
aL bL
W F dx

0
3
2

On heating water, bubbles being formed at the bottom of the vessel

detatch and rise. Take the bubbles to be spheres of radius R and making a
circular contact of radius r with the bottom of the vessel. If r << R, and the
surface tension of water is T, value of r just before bubbles detatch is:

(1)

R2

wg
T

(2)

R2

3 w g
T

(3)

R2

wg
3T

(4)

R2

wg
6T

Key: (No Correct Option)

Sol.
FB = buoyant force

4
T sin 2 r R 3 w g
3

r
sin
R
2w g
r R2
3T

29.

O
q
q
T

c
T

Two beams, A and B, of plane polarized light with mutually perpendicular

planes of polarization are seen through a Polaroid. From the position
when the beam A has maximum intensity (and beam B has zero intensity),
a rotation of Polaroid through 300 makes the two beams appear equally
bright. If the initial intensities of the two beams are IA and IB respectively,
then

IA
IB

equals:

(1) 1

(2)

1
3

Key: (2)
Sol. IA cos2 = IBcos2(90 )

(3) 3

(4)

3
2

(I = I0 cos2 ) by malus Eq

IA
1
tan 2
IB
3

Where = 300
14

JEE-MAINS 2014 Question Paper & Solutions

30.

Assume that an electric field E 30x 2 i exists in space. Then the potential
difference
(VA - VO), where VO is the potential at the origin and VA the potential at x =
2 m is:
(1) 80 J
(2) 80 J
(3) 120 J
(4) 120J
Key: (1)
Sol.

VA

2
dV E dx 30x dx

VO

VA V0 80J

MATHEMATICS
31.

The image of the line

x 3

3
x 3
(3)

(1)

y 5

1
y5

z2
5
z2
5

x 1 y 3 z 4

in the plane 2x y z 3 0 is the line

3
1
5
x 3 y 5 z 2
(2)

3
1
5
x 3 y 5 z 2
(4)

3
1
5

Key. (1)
Sol. Any point on the given

x 1 y 3 z 4

will be 3t 1, t 3, 5t 4 its image in

3
1
5

the plane 2x y z 3 0 is given by

x 3t 1 y t 3 z 5t 4
6t 2 t 3 5t 4 3 2

2
2
1
1
6
x 3t 3, y t 5, z 2 5t which is the line
x 3 y 5 z 2

3
1
5

32.

So (1) is correct.
18
If the coefficients of x3 and x4 in the expansion of 1 ax bx 2 1 2x in
powers of x are both zero, then (a, b) is equal to
251
(1) 16,

251
(2) 14,

272
(3) 14,

272
(4) 16,

Key. (4)
15

JEE-MAINS 2014 Question Paper & Solutions

Sol.

18

1 ax bx 1 2x
1 ax bx 1 C 2x
2

18

18

C2 . 2x 18C3 2x 18C 4 2x ....

Coefficient of x3 = 0

18 C 3 .8 a. 18 C 2 .4 b 18 C1 2 0

. (i)

51a 3b 544 0

Coefficient of x4 = 0

18

C 4 .16 a 18 C 3 8 b 18 C 2 4 0

32a 3b 240 0

. (ii)

Solving (i) & (ii), we get

A = 16, b
33.

272
3

So Answer (4)
2
If a R and the equation 3 x x 2 x x a 2 0 (where [x] denotes the

greatest integer x) has no integral solution, then all possible values of a

lie in the interval
(1) 1,0 0,1 (2) 1, 2
(3) 2, 1
(4) , 2 2,
Key. (1)
Sol. x x x , since x I , so 0 x 1
Let x t
1 1 3a 2 1 3a 2

as t 0
3
3
2
Now 0 < t < 1 0 a 1
a 1,0 0,1

So 3t 2 2t a 2 0, t

34.

Option (1) is correct.

2
If a b b c c a a b c then is equal to

(1) 2
Key. (4)

Sol. a b b c

(2) 3

c a



a b . b c c a


a b . b c a c b c c a

(3) 0

(4) 1

16

JEE-MAINS 2014 Question Paper & Solutions

a b . a b c c
2
a b c
1

35.

Option (4) is correct.

The variance of first 50 even natural numbers is
(1)

833
4

(2) 833

(3) 437

(4)

437
4

Key. (2)
Sol. The first 50 no. are 2, 4,6,8,.....100
Mean
X

2 4 6 ....100
51
50

Variance
2

2
1
2
xi X

1 2
2
2
2 42 62 .... 100 51
50
3434 2601 833

36.

A bird is sitting on the top of a vertical pole 20 m high and its elevation
from a point O on the ground is 45o. It flies off horizontally straight away
from the point O. After one second, the elevation of the bird from O is
reduced to 30o. Then the speed (in m/s) of the bird is
(1) 40 2 1
(2) 40 3 2 (3) 20 2
(4) 20 3 1

Key. (4)
B

Sol.

d
A

BOA 45
COA 30 o

tan tan 45o

h 20

x x
17

JEE-MAINS 2014 Question Paper & Solutions

1

20
x 20
x

Now tan tan 30o

h
xd

1
20

3 20 d
20 d 20 3

d 20

3 1

d
t

So velocity

20

3 1 m
1sec

37.

The integral

1 4sin 2

(1) 4

20

x
x
4sin dx
2
2

2
44 3
3

(2)

3 1 m / s

(3) 4 3 4

(4) 4 3 4

Key. (4)

Sol.

I 1 4sin 2
0

I
0

2sin 2 1 dx

I 2 sin
0
/3

x
x
4sin dx
2
2

x
1 dx
2

x
x

1 2 sin dx 2 sin 1 dx
2
2

/3

x
x 4cos
2

/3

4cos x
2
/3

3
3
4
0 4 0 4

2 3
2

4 34
3

38.

The statement ~ p ~ q is
(1) equivalent to p q
(3) a tautology

(2) equivalent to ~ p q
(4) a fallacy
18

JEE-MAINS 2014 Question Paper & Solutions

Key. (1)
Sol.

39.

~ p

~ q

p ~ q

T
T
F
F

T
F
T
F

F
F
T
T

F
T
F
T

F
T
T
F

~ q
T
F
F
T

~ p q

p q

F
T
T
F

T
F
F
T

Clearly ~ p ~ q equivalent to p q
If A is an 3 3 non-singular matrix such that AA ' A 'A and B A1A ' then
BB'
(1) I B

(2) I

(4) B1

(3) B1

Key. (2)
'
Sol. Now BB ' A1A ' A1A '

A 1A ' A. A 1

A 1 A ' A A '

'

AB B' A '
'

A 1A A '. A '

I.I I

40.

The integral

(1) x 1 e
Key. (2)
Sol.

1
x

1 x 1x

1 x e dx
x

(2) x e

1
x

(3) x 1 e

1
x

(4) x e

1
x

1 x 1x
I 1 x e .dx
x

1
x
1 x 1x

x
I e dx x e dx
x

1
x

1 x 1x
x
I e dx x. 1 2 e dx
x

1 x 1

dx x. 1 2 e x dx 1.
x

1
1
1
x
x
x

1
e x dx x.e x e x dx x
x

I e

I x.e

1
x

1
x

1 x 1x

e dx dx

2
x

t 1 2 dx dt
x

c
19

41.

JEE-MAINS 2014 Question Paper & Solutions

1
If z is a complex number such that z 2 , then the minimum value of z :
2
5
(1) is equal to
(2) lies in the interval (1, 2)
2
5
3
(3) is strictly greater than
(4) is strictly greater than but less
2
2
5
than
2

Key. (2)
Sol.
A
2

42.

1/2

B
+2

1
1
= Distance between z and
2
2
1
3
OA = minimum value of z = .
2
2
z

1
, then g ' (x) is equal to:
1 x5
1
(3)
(4) 1 {g(x)}5
5
1 {g(x)}

If g is the inverse of a function f and

(1) 1 + x5

(2) 5x4

f ' (x)

KEY. (4)
Sol.

f (g(x)) = x
f ' (g(x)) . g ' (x) = 1
(g(x)) =

1
g ' (x)

f'

g ' (x) = 1 + g5(x).

20

JEE-MAINS 2014 Question Paper & Solutions

43.

If , , and f (n) = and

n

1 f (1) 1 f (2)

1 f (1) 1 f (2) 1 f (3)

1 f (2) 1 f (3) 1 f (4)

= 2 (1 2 ( 2 , then K is equal to:

(1)

(2)

(3) 1

(4) 1

Key. (3)
3

Sol.

1 +

1 2 + 2

1 + 1 2 + 2 1 3 + 3 = 1
1 2 + 2 1 3 + 3 1 4 + 4
1 2 2

= 2 2 2
Hence, K = 1.
44.

Let fk (x) =

1
(sink x + cosk x) where x R and k 1. Then f4(x) f6(x)
k

equals:
(1)

1
6

(2)

1
3

(3)

1
4

(4)

1
12

Key. (4)
1
sin k x cos k x

k
1
1

f4(x) f6(x) = sin 4 x cos4 x sin 6 x cos 6 x

4
6
1
1
1
= 1 2 sin 2 x cos 2 x 1 3sin 2 x cos 2 x = .
4
6
12
2
Let and be the roots of equation px + qx + r = 0, p 0. If p, q, r are in A.

Sol. fk(x) =

45.

P.
1 1
+ =4, then the value of is:

61
2 17
34
(1)
(2)
(3)
9
9
9

and

(4)

2 13
9

Key. (4)
21

JEE-MAINS 2014 Question Paper & Solutions

Sol. Let , are the rots of px2 + qx + r = 0

1 1
4

q
4
r

q = 4r

p, q, r are in A. P.
p = 9r
Hence the given equation becomes
9x2 + 4x 1 =0

46.

| |

16 4
52 2 13

81 9
81
9

1
6

Let A and B be two events such that P(A B) , P(A B)

1
1
and P(A) ,
4
4

where A stands for the complement of the event A. Then the events A and
B are:
(1) mutually exclusive and independent.
(2) equally likely but not independent.
(3) Independent but not equally likely.
(4) Independent and equally likely.
Key. (3)
Sol. P(A B) P(A) P(B) P(A B)

5 3
1
x where P(B) = x
6 4
4
1
x
3
P(A B) P(A).P(B)

Hence A and B are independent but not equally likely.

47.

If f and g are differentiable functions in [0, 1] satisfying f(0) = 2 = g(1), g(0)

= 0 and f(1) = 6, then for some c ]0,1[ :
(1) 2f(c) = g(c) (2) 2f(c) = 3g(c) (3) f(c) = g(c) (4) f(c) = 2g(c)
Key. (4)
Sol. Let h(x) = f(x) 2g(x)
h(x) is continuous and differentiable in [0, 1].
h(0) = f(0) 2g(0) = 2 0 = 2
h(1) = f(1) 2g(1) = 6 4 = 2
22

JEE-MAINS 2014 Question Paper & Solutions

h(0) = h(1)
h(x) verify all conditions of Rolles theorem.

Hence, at least one c (0, 1) such that

h '(c) 0
f '(c) 2g'(c)

48.

Let the population of rabbits surviving at a time t be governed by the

differential equation

dP(t) 1
p(t) 200.
dt
2

If p(0) = 100, then p(t) equals:

(1) 400 300 et/2 (2) 300 200 et/2 (3) 600 500 et/2
300 et/2
Key. (1)
Sol. I.F e t / 2
So solution is P t e t / 2 200.e t / 2dt 400e t /2 k

(4)

400

k = 300
P(t) = 400 300 et/2

P 0 100

49.

Let C be the circle with centre at (1, 1) and radius = 1. If T is the circle
centre at (0, y), passing through origin and touching the circle C
externally, then the radius of T is equal to:
(1)

3
2

(2)

3
2

(3)

1
2

(4)

1
4

Key. (4)
B
A

Sol.

A = (0, y)
Since

y=

Hence,

B = (1, 1)
AB 1 y

1
4

2 3
23

JEE-MAINS 2014 Question Paper & Solutions

50.

The area of the region described by A = {(x, y) : x2 + y2 1 and y2 1 x}

is:
(1)

2 3

(2)

2 3

(3)

2 3

(4)

2 3

Key. (1)

Sol.
1

Required area = 20 (

1 x 2 1 x )dx
1

x 1 x 2 1 1

2
2 4
2
sin x (1 x)3/ 2 2
2
2
3
4 3 2 3

51.

Let a, b, c and d be non-zero numbers. If the point of intersection of the

lines 4ax 2ay c 0 and 5bx 2by d 0 lies in the fourth quadrant and is
equidistant from the two axes then:
(1) 2bc 3ad 0 (2) 2bc 3ad 0 (3) 3bc 2ad 0 (4) 3bc 2ad 0
Key: (3)
Sol.
Point (k, -k) satisfies both lines
4ak 2ak c 0 . . . . . (1)
5bk 2bk d 0 . . . . . (2)
c = -2ak and d = -3bk

c
d

2a 3b

2ad - 3bc = 0
3bc 2ad = 0
52.

Let PS be the median of the triangle with vertices P(2, 2), Q(6, - 1) and R(7,
3). The equation of the line passing through (1, -1) and parallel to PS is:
(1) 4 x 7 y 11 0 (2) 2 x 9 y 7 0 (3) 4 x 7 y 3 0 (4) 2 x 9 y 11 0
Key: (2)

24

JEE-MAINS 2014 Question Paper & Solutions

Sol.
1
2

13 9
2
2
2
y 1
x 1
9
9 y 2x 7 0
m ps

53.

sin( cos 2 x)
is equal to :
x 0
x2

(1)
(2) 1
2
lim

(3)

(4)

Key : (4)
Sol.
lim

sin cos 2 x

x2
sin sin 2 x sin 2 x
= lim
x 0
sin 2 x x2
x0

=
54.

If X 4 n 3n 1 : n N and Y 9 n 1 : n N , where N is the set of natural

numbers, then XY is equal to :

(1) N
(2) Y X
Key : (4)
Sol.

(3) X

(4) Y

4n 3n 1
n
= 1 3 3n 1

= n C2 32 n C3 33 ........
= 9 n C2 3 nC3 .......
Set X contains numbers which are multiples of 9 but not all multiples of 9
XY = Y

25

JEE-MAINS 2014 Question Paper & Solutions

55.

The locus of the foot of perpendicular drawn from the centre of the ellipse
x 2 3 y 2 6 on any tangent to it is :
2
2
(1) x 2 y 2 6 x 2 2 y 2
(2) x 2 y 2 6 x 2 2 y 2
2

(3) x 2 y 2 6 x 2 2 y 2

(4) x 2 y 2 6 x 2 2 y 2

Key : (3)
Sol.
K mh 6m 2 2 . . . . . (1)
K
. . . . . . (2)
m 1
h

Eliminating m from (1) and (2)

Locus is

y 2 6 x2 2 y 2

56.

Three positive numbers form an increasing G.P. If the middle term in this
G.P. is doubled, the new numbers are in A.P. Then the common ratio of the
G.P is :
(1) 2 3
(2) 3 2
(3) 2 3
(4) 2 3
Key : (4)
Sol.
a
ar
r
r 2 3

4a =

(r > 1)

but as r > 1
r 2 3

57.

If 10 2 11 10 3 11 10 .... 10 11 k 10 , then k is equal to :

(1)

121
10

(2)

441
100

(3) 100

(4) 110

Key : (3)
Sol. S = 109 + 2(11) (10)8 + . . . . . . + 10(11)9
S

11
= (11.108) + . . . . . + . . . + (11)10
10
26

JEE-MAINS 2014 Question Paper & Solutions

10

11

109 1
10

(11)10

10
11
1
10

S = 1011
= (100) 109
K = 100
58.

The angle between the lines whose direction cosines satisfy the equations
l m n 0 and l 2 m2 n 2 is :
(1)

(2)

(3)

(4)

Key : (1)
Sol. Solving two equation
l = -(m + n) then (m + n)2 = m2 + n2
mn = 0
If m = 0 , If n = 0
l = -n
l = -m
hence dr are 1, 0, -1 and 1, -1, 0
cos

=
59.

1
1

2 2 2

The slope of the line touching both the parabolas y 2 4 x and x 2 32 y is :

(1)

1
2

(2)

3
2

(3)

1
8

(4)

2
3

Key : (1)
Sol. Eq. of tangent at t & t respectively are yt x t 2 and xt ' y 8t '2
1 t
t2

t2
t ' 1 8t '2
1
Hence slope =
2

Comparing

27

60.

JEE-MAINS 2014 Question Paper & Solutions

If x 1 and x 2 are extreme points of f ( x) log | x | x 2 x then :
1
1
1
1
(1) 6,
(2) 6, (3) 2,
(4) 2,
2
2
2
2

Key: (3)
Sol. Differentiating

2 x 1 0 2 x 2 x 0
x
Put x 2 and -1 gives
2 1 0 and 8 2 0
1
Solving 2,
2
f ' x

CHEMISTRY
61.

Which one of the following properties is not shown by NO?

(1) It combines with oxygen to form nitrogen dioxide
(2) Its bond order is 2.5
(3) It is diamagnetic in gaseous state
(4) it is a neutral oxide
Key. (3)
Sol. Nitric Oxide, NO is paramagnetic.
62. If Z is a compressibility factor, van der Waals equation at low pressure can
be written as:
Pb
RT
RT
(3) Z 1
PB

(1) Z 1

Pb
RT
a
(4) Z 1
VRT

(2) Z 1

Key (4)
Sol. As pressure is low so volume must be large.
i.e., V b V
So Van der Waals equation reduces into
a
RT
V
a
Z 1
RTV
PV

28

JEE-MAINS 2014 Question Paper & Solutions

63.

The metal that cannot be obtained by electrolysis of an aqueous solution

of its salts is :
(1) Cu
(2) Cr
(3) Ag
(4) Ca
Key. (4)
Sol. In case of aqueous solution of calcium salt hydrogen gas will
preferentially evolve due to selective electrolysis. H has higher reduction
potential than that of Ca 2
64.

Resistance of 0.2 M solution of an electrolyte is 50 . The specific

conductance of the solution is 1.4 S m1. The resistance of 0.5 M solution of
the same electrolyte is 280 . The molar conductivity of 0.5 M solution of
the electrolyte in Sm2 mol1 is :
(1) 5 103
(2) 5 102
(3) 5 104
(4) 5 103
Key. 3
Sol.

1
1
.
R
/A
1
1
1.4.
50
/A
1
1
.
280
/A

Solving we get
0.25Sm 1

C
0.25

5 104 S m 2 mol1
0.5 1000

65.

CsCl crystallizes in body centred cubic lattice. If a is its edge length then
which of the following expression is correct?
(1) rCs rCl

3
a
2

(3) rCs rCl 3a

(2) rCs rCl 3a

(4) rCs rCl

3a
2
29

JEE-MAINS 2014 Question Paper & Solutions

Key. (1)
Sol. In CsCl lattice, centrally placed Cs remains in contact with all eight Cl
ions present at the vertices of the cube.
Body diagnonal = 3a
3a 2 Cs Cl

.
66. Consider separate solutions of 0.500 M C2H5OH(aq), 0.100 M Mg3(PO4)2
(aq), 0.25 M KBr(aq) and 0.125 M Na3PO4(aq) at 25oC. Which statement is
true about these solutions, assuming all salts to be strong electrolytes?
(1) 0.125 M Na3PO4(aq) has the highest osmotic pressure.
(2) 0.500 M C2H5OH(aq) has the highest osmotic pressure.
(3) The all have the same osmotic pressure.
(4) 0.100 M Mg3(PO4)2(aq) has the highest osmotic pressure.
Key. (3)
Sol. Considering complete dissociation of electrolytes, the effective
concentration of solute particles is same (0.5 M) in all the solution.
67. In which of the following reaction H2O2 acts as a reducing agent?
(a) H 2 O 2 2H 2e 2H 2 O
(b) H 2 O 2 2e O 2 2H
(c) H 2 O 2 2e 2OH
(d) H 2 O 2 2OH 2e O 2 2H 2 O
(1) (a), (c)
(2) (b), (d)
(3) (a), (b)
(4) (c), (d)
Key. (2)
1

Sol. H 2 O 2
O 2 2e
68. In SN2 reactions, the correct order of reactivity for the following
compounds:
CH3Cl,CH3CH2Cl, CH3 2 CHCl and CH3 3 CCl

(1) CH3CH2Cl CH3Cl CH3 2 CHCl CH3 3 CCl

(2) CH3 2 CHCl CH3CH2Cl CH3Cl CH3 3 CCl
(3) CH3Cl CH3 2 CHCl CH3CH2Cl CH3 3 CCl
(4) CH3Cl CH3CH2 Cl CH3 2 CHCl CH3 3 CCl
Key. (4)
Sol. In S N 2 reactivity order is CH 3 X 1o R X 2 o R X 3o R X

30

JEE-MAINS 2014 Question Paper & Solutions

69.

The octahedral complex of a metal ion M3+ with four monodentate ligands
L1, L2, L3 and L4 absorb wavelengths in the region of red, green, yellow and
blue, respectively. The increasing order of ligand strength of the four
ligands is :
(1) L3 < L2 < L4 < L1
(2) L1 < L2 < L4 < L3
(3) L4 < L3 < L2 < L1
(4) L1 < L3 < L2 < L4
Key. (4)
Sol. As the order of wavelength
red yellow green blue & Energy

70.

For the estimation of nitrogen, 1.4 g of an organic compound was digested

by Kjeldahl method and the evolved ammonia was absorbed in 60 mL of
M
M
sulphuric acid. The unreacted acid required 20 mL of
sodium
10
10

hydroxide for complete neutralization. The percentage of nitrogen in the

compound is:
(1) 3 %
(2) 5 %
(3) 6 %
(4) 10 %
Key. (4)
Sol. Eq.H 2SO 4 Eq.NH 3 Eq.NaOH
60
1
20
1
2 Eq.NH 3

1000 10
1000 10
100
Eq.NH 3
0.01
10000
Mole NH 3 0.01
0.01 14
Weight percent of N 2
100 10%
1.4

71.

The equivalent conductance of NaCl at concentration C and at infinite

dilution are C and , respectively. The correct relationship between C
and is given as
(1) C (B) C
(2) C (B) C
(3) C (B) C
(4) C (B) C
Key. (1)
Sol. It is Debye Huckel onsager equation i.e.
C B C
31

JEE-MAINS 2014 Question Paper & Solutions

72.

1
2

SO3(g) , if KP = KC(RT)x where the symbols

For the reaction SO 2(g ) O 2(g)

have usual meaning, then the value of x is (assuming ideality)

(1)

1
2

(2) 1

Key. (4)
Sol. K P K C (RT) n
x or n g
73.

(3) 1

(4)

1
2

1
2

In the reaction,
LiAlH 4
PCl5
Alc. KOH
CH 3COOH
A
B
C ,

the product C is
(1) Ethylene
Key. (1)

(2) Acetyl chloride (3) Acetaldehyde (4) Acetylene

PCl5
LAH
CH3 COOH
CH 3CH 2OH
CH 3CH 2Cl

(B)

(A)

alc. KOH

CH 2 CH 2
(C)
Sol.
74. Sodium phenoxide when heated with CO2 under pressure at 125C yields a
product which on acetylation produces C.
ONa
125
B
+ CO2
5 Atm

H
C
Ac2 O

The product C would be

OH

O COCH3
COOCH3

(1)

(2)
COOH
O COCH3

OH

COOH

(3)

COCH3

(4)
COCH 3

Key. (3)

32

JEE-MAINS 2014 Question Paper & Solutions

OH
ONa

OH
COONa

+ CO2

COOH
+

125
5 atm

H
5 atm

OCOCH3
COOH

Sol.

(AC)2O
Acetylation

Aspirin

75.

On heating an aliphatic primary amine with chloroform and ethanolic

potassium hydroxide, the organic compound formed is
(1) an alkyl cyanide
(2)an alkyl isocyanide
(3) an alkanol
(4) an alkanediol
Key. (2)
Sol. Carbylamine reaction
(CHCl3 KOH )
RCH 2 NH 2
R N C
C 2 H5 OH

76.

The correct statement for the molecule, CsI3, is

(1) it contains Cs3+ and I ions
(2) it contains Cs+, I and lattice I2 molecule
(3) it is a covalent molecule
(4)it contains Cs+ and I 3 ions
Key. (4)
Sol. CsI3
Cs I3
77. The equation which is balanced and represents the correct product(s) is
excess NaOH
(1) [Mg(H 2 O)6 ]2 (EDTA) 4
[Mg(EDTA) 2 6H 2 O
(2) CuSO4 4KCN K 2 [Cu(CN)4 ] K 2SO4
(3) Li2O 2KCl 2LiCl K2O
(4) [CoCl(NH 3 )5 ] 5H Co 2 5NH 4 Cl
Key. (3)
Sol. No proof available.
78. For which of the following molecule significant 0 ?
Cl

(A)

CN

(B)
Cl

(1) only (C)

OH

(C)
CN

(2) (C) and (D)

SH

(D)
OH

(3) only (A)

SH

(4) (A) and (B)

33

JEE-MAINS 2014 Question Paper & Solutions

Key. (2)
Sol.
N

79.

For the non-stoichiometre reaction 2A B C D , the following kinetic

data were obtained in three separate experiments, all at 298 K.
Initial
Concentration
(A)
0.1 M
0.1 M
0.2 M

Initial
Concentration
(B)
0.1 M
0.2 M
0.1 M

Initial rate of
formation of C
(mol LS)
1.2 103
1.2 103
2.4 103

The rate law for formation of C is

(A)

dc
k[A][B]2
dt

dc
k[A]
dt

(B)

(C)

dc
k[A][B]
dt

(D)

dc
k[A]2 [B]
dt

Key. (2)
Sol. Rate reaction,
d(c)
n
m
A B
dt
=

1.2 103
0.1

1.2 103
0.2

m=0
n

3
0.1 1.2 10

2.4 103
0.2
n

1 1
n=1

2=
2

rate equation
80.

dc
k[A]
dt

Which series of reactions correctly represents chemical relations related

to iron and its compound?
Cl , heat
heat , air
Zn
(A) Fe
FeCl3
FeCl 2
Fe
O , heat
CO, 600 C
CO, 700 C
(B) Fe
Fe 3O 4
FeO
Fe
dil. H SO
H SO , O
heat
(C) Fe
FeSO 4
Fe 2 (SO 4 ) 3
Fe
O , heat
dil. H SO
heat
(D) Fe FeO FeSO 4
Fe
2

34

JEE-MAINS 2014 Question Paper & Solutions

Key. (2)
Sol.
81.

Fe3O 4 4CO
3Fe 4CO2
500 800 K
Fe 2O3 CO
2FeO CO2
FeO CO
Fe CO 2
900 1500 K

Considering the basic strength of amines in aqueous solution, which one

has the smallest pKb values
(A) (CH3)3N
(2) C6H5H2
(3) (CH3)2NH
(4) CH3NH2

Key. (3)
Sol. The base which has maximum Kb will have smallest pKb
82. Which one of the following bases is not present in DNA?
(1) Cytosine
(2) Thymine
(3) Quinoline
(4) Adenine
Key . (3)
Sol. In DNA, Nitrogenous base
(i) Cytosine
(ii) Thymine
(iii) Adenine
(iv) Guanine
83. The correct set of four quantum numbers for the valence electrons of
rubidium atom (Z = 37) is
(1) 5, 1, 1, +

1
2

(2) 5, 0, 1, +

1
2

(3) 5, 0, 0, +

1
2

(4) 5, 1, 0, +

1
2

Key . (3)
Sol.
Configuration : Ar 4s2 3d10 4p6 5s1
Its quantum numbers n, l, m and s will be 5, 0, 0, +
84.

1
respectively.
2

The major organic compound formed by the reaction of 1, 1, 1

trichloroethane with silver powder is
(1) 2-butyne
(2) 2- butane
(3) acetylene
(4) ethane

Key . (1)
Sol.
Cl

Cl
H 3C

Cl
Cl

6Ag

Cl

CH3
Cl

- 6AgCl

H3C

CH3

2-butyne
35

JEE-MAINS 2014 Question Paper & Solutions

85.

Given below are the half-cell reactions :

Mn2+ + 2e- Mn;
E0 = -1.18 V
2(Mn3+ + e- Mn2+); E0 = +1.51 V
The E0 for 3Mn2+ Mn + 2Mn3+ will be
(1) -0.33 V; the reaction will not occur
(2) -0.33V; the reaction will occur
(3) -2.69 V; the reaction will not occur
(4) -2.69V; the reaction will occur
Key . (3)
Sol. Mn2+ + 2e- Mn;
G10 = 2 F (1.18)
2(Mn3+ + e- Mn2+); G20 = 2 F (+1.51) . . . . .(ii)
for
3Mn2+ Mn + 2Mn3+
G30 = G10 G20
2FE30 = 2F (1.18) + 2F(1.51)
E30 = 2.69 V
E30 = 2.69 V
Reaction will not occur

. . . . .(i)

86.

The ratio of masses of oxygen and nitrogen in a particular gaseous

mixture is 1 : 4. The ratio of number of their molecule is :
(1) 1 : 8
(2) 3 : 16
(3) 1 : 4
(4) 7 : 32
Key . (4)
Sol.

n O2
n N2

w O2 / M O2
w N 2 / M N2

x / 32
28

7 : 32
4x / 28 4 32

87.

Which one is classified as a condensation polymer ?

(1) Teflon
(2) Acrylonitrile
(3) Dacron
(4) Neoprene
Key . (3)
Sol. Dacron is condensed polymer of tere-phthalic acid and glycol.
88. Among the following oxoacids, the correct decreasing order of acid
strength is :
(1) HClO4 > HClO3 > HClO2 > HOCl
(2) HClO2 > HClO4 > HClO3 > HOCl
(3) HOCl > HClO2 > HClO3 > HClO4
(4) HClO4 > HOCl > HClO2 > HClO3
36

JEE-MAINS 2014 Question Paper & Solutions

Key. (1)
Sol.

HClO 4 HClO3 HClO 2 HOCl

Higher is the oxidation state, more will be the acidic strength of these
oxoacids.
Order of resonance stability of conjugate bases ClO 4 ClO 3 ClO 2
89. For complete combustion of ethanol,
C2H5OH(l) + 3O2(g) 2CO2(g) + 3H2O(l)
the amount of heat produced as measured in bomb calorimeter, is
1364.47 kJ mol-1 at 250C. Assuming ideality the Enthalpy of combustion,
CH, for the reaction will be:
(R = 8.314 kJ mol-1)
(1) -1460.50kJ mol-1
(2) -1350.50 kJ mol-1
(3) -1366.95 kJ mol-1
(4) -1361.95 kJ mol-1
Key . (3)
Sol. C2H5OH(l) + 3O2(g) 2CO2(g) + 3H2O(l)
H = E + nRT
qp = qv + nRT
= 1364.47

1 8.31 298
1000

= -1364.47 2.47638
= - 1366.95 kJ mol-1
90.

The most suitable reagent for the conversion of R CH2 OH R CHO is :

(1) CrO3
(2) PCC (Pyridinium Chlorochromate)
(3) KMnO4
(4) K2Cr2O7
Key. (2)
O
||

Sol. R CH2OH
R C H , other oxidizing agents may convest RCHO to
RCOOH.
PCC

37

JEE-MAINS 2014 Question Paper & Solutions

IITJEE MAINS-2014
Answer Key (CODE-H)
Q.N.
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.

PHYSICS
Code -H
3
4
3
3
3
2
3
4
2
1
2
1
3
1
1
4
2
1
4
1
1
1
4
1
4
3
1
No answer
2
1

MATHEMATICS
Q.N.
Code-H
31.
1
32.
4
33.
1
34.
4
35.
2
36.
4
37.
4
38.
1
39.
2
40.
2
41.
2
42.
4
43.
3
44.
4
45.
4
46.
3
47.
4
48.
1
49.
4
50.
1
51.
3
52.
2
53.
4
54.
4
55.
3
56.
4
57.
3
58.
1
59.
1
60.
3

Q.N.
61.
62.
63.
64.
65.
66.
67.
68.
69.
70.
71.
72.
73.
74.
75.
76.
77.
78.
79.
80.
81.
82.
83.
84.
85.
86.
87.
88.
89.
90.

CHEMISTRY
Code-H

3
4
4
3
1
3
2
4
4
4
1
4
1
3
2
4
3(Not confirmed)
2
2
2
3
3
3
1
3
4
3
1
3
2
38