31 1

2011 6

Modern Chemical Industry

June 2011
416

DNTF

710065
DNTF

DNTF ChemCAD
TZ966
A
0253 4320 2011 S1 0416 04

Simulation and design of synthesis reactor of DNTF

JIN Jian-pingZHOU Yan-shuiZHANG Zhi-zhongCHEN ChaoZHOU Cheng
Xian Modern Chemistry Research InstituteXian 710065China
Abstract The simulation and enlargement design of DNTF synthesis reactor are researched in this article
According to the dynamics character and the transfer behavior of the equipment in reaction systemthe basic parameter of
reactor is calculated and the structural parameter is definedsuch as the capacity of reactoragitator typeagitator speed
heat transfer areaheat exchange mode and so on The reaction kinetics model and the heat transfer of the reactor are
combined The quantity of heat transfer and heat duty are calculated The energy capacity and heat balance of the reactor
are reviewed and analyzed The fluctuation magin and the maximum of heat duty are reaearched The regular pattern of
the heat transfer and mass transfer in the reactor approached Resrarching the rules of mass transfer and heat transfer in
the reactorthe accurate enlargement design basis data of the reactor are got in order to realize the enlargement design of
the reactor and supply the theory model and design basis for the industrial reactor
Key words DNTF reactor model simulation enlargement design ChemCAD

3
4 DNTF

DNTF

DNTF

1 2

4
DNTF DAFF 3
2
3

1. 1

DNTF

Q c = K A LMTD

DNTF

1 K A LMTD

1 / K = 1 / hp + fp + xW / kW + fu + 1 / hu

2 K h p f p
x W f u

1 000 L
DNTF

k W h u

2011 04 28
2371000415
029 88291065goldjppp@ sina com
1956

DNTF

2011 6

417

in
c

out
c

V c c C c dT c / dt = F c C c T T + Q c

A = V V min / V max V min X A max A min + A min

3 V c c C c
in
c

F c T T

out
c

10

10 A max A min
V max V min

CC ReACS 2

V max A max
V min A min 0

2
Seader Tate

1. 2

Nu = f Re a Pr b W /

4 Nu Nusselt Re Pr
Prandtl W
fabc

ij

A j e E j / RT

j =1

kj

a kj

k =1

nj

1 +

k =1

kj

e e k / RT C bk kjj

DNTF

Ramp Controller

PID

nj

nrx

ri =

Chemstaions
ChemCAD 6. 14 CC ReACS

5 r A C A0 N
A E R

DNTF 1

DNTF

r1 = dC DAFF / dt = k1 C aDAFF C bH2O2
r2 = dC DAFF / dt = k2 C

m
DAFF

n
H2 O2

Arhenius n
ChemCAD

DNTF
39
r1 = 2. 2314 10exp 30407 / RT C1.DAFF
C1.H221O2

r2 = 5. 0922 10exp 38906 / RT C

0. 91
DAFF

1. 31
H2 O2

8
9

DNTF

CSTR
Thermal model 5

1. 3

3
1

NRTL Latent Heat

415

ting packed bed HIGEE with split packingJ Ind Eng Chem
Res
2005 44

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M
2007
2 J
2008 4

3 Chandra AGoswami P SRao D P Characteristics of flow in a rota-

4 D
2007

5
2004
D
6 Chen Y HChang C YSu W L Modeling ozone contacting process
2004 43
in a rotating packed bedJ Ind Eng Chem Res

1. 4

31 1

418

C V

C V = Q SG f / P

0. 5

11

Sizing
Control Valve
C V
1

AE

/ m

C V
CV c /

CV

CV

/m

0. 0254

W mK

2
2. 1

/ m

1. 4256

/ m3
/ m

/ m
8. 07

4. 6

8000

/ m

402

0. 02

C V c

0. 0017

9. 0000

1. 17

/ m

J kgK

0. 0155

/ m

/ kgm

DNTF

0. 1728
3

/ m

0. 842

/ m

/ m

0. 214

0. 038
0. 018

/ m

0. 35

/ m

0. 75

/ Hz

/ m

0. 030

5 7

2. 2

1 000 L

Dynamics 270
min 1. 5 min

2
6
1 /

1 000 L
DNTF 200 L
1 000 L

25% CaCl2

ChemCAD the batch

reactor model

2 3
2

ST

0. 67

0. 33

0. 14

0. 33

0. 62

0. 33

0. 14

0. 87

1 2 3

50
45 55
DNTF
2

DNTF

2011 6

1 2

1 2 3

419

2 000 kg / h

1 DNTF

1 2

0 2 000 kg / h
4

2
DNTF
PID

1 2

0 800 kcal / m h
5
1 h

1 3
4
2004
25 2 155
J
158
2 3
4
2005
28 2 43 46
J
3 3
4 4'3'
2007
30 1 54 56
J
4 ChemCAD Version 6 0 User Guide and TutorialM Houston
Chemstations Inc 2007
5 D
2006

6 J 201038

7 M
2003

2 174 176