Professional Documents
Culture Documents
1
M
r1
r2
M2
=
M1
Practice Problem
An unknown gas effuses at a rate 1.49 times
faster than Cl2. What is the molecular weight
of the gas?
A.
B.
C.
D.
E.
16.0 g/mol
31.9 g/mol
47.6 g/mol
106 g/mol
157 g/mol
m
d=
V
Practice Problem
Silicon tetrachloride is a starting material for
the production of electronics-grade silicon.
Calculate the density of pure silicon
tetrachloride vapor at 85oC and 758 torr.
A.
B.
C.
D.
E.
0.238 g/L
5.77 g/L
1.00 g/L
24.3 g/L
0.056 g/L
PV = nRT
10
11
High
Pressure
Very High
Pressure
Finite molecular
volume leads to
repulsion and the
appearance of a larger
volume or larger n
Low Pressure
As Temperature
increases the
behavior of
real gases
becomes more ideal
CH110 FA11 SAS
12
13
Actual volume:
Vactual = Vmeasured Vexcluded
To compensate, use:
CH110 FA11 SAS
14
PV = nRT
The Equation of state for REAL gases:
2
n
( P + 2 a )(V nb) = nRT
V
15
Practice Problem
What is the pressure P of 1.0 mol Cl2 in a
2.0 L vessel at 273 K?
Ideal Gas:
L2 atm
mol2
b = 0.0562 L/mol
16
n
( P + 2 a )(V nb) = nRT
V
17
b (L/mol)
0.0171
0.0322
0.0398
0.0510
Size
18
Strength
19
20