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H 2O
+
CO
Equilibrium values
.2M
.3M
.55M
.55M
at 1727 C
Change occurring
b/c of lower temp +0.165 M
+0.165 M
-.165M
-.165 M
(changing by 30% of
Equilibrium values
.365 M
.465M
.385M
.385M
at lower temp
[CO] = 0.55 - 0.16 =0.385 mol/L
Kc =
(0.385)(0.385) = 0.873
(0.465)(0.365)
H2
+
.167M
-x
.167 - x
.167M
-x
.167 - x
Kc = [H2O] [ CO] = [ x ] [ x ]
= 5.0
[H2] [CO2]
[.167 - x] [.167 - x]
H 2O
0M
+x
x
CO
0M
+x
x
[x] [x]
=
[.167 - x] [.167 - x]
5.0
____x
= 2.236
[.167 - x]
2.236(.167 x) = x
0.373 2.236x = x
0.373 = 3.236x
0.373 = x
3.236
x = .115 M
Now solve for equilibrium concentrations using x = .115 M
Equilibrium .167 - x
.167 - x
x
x
.167 - .115 = .052 M .167 - .115 = .052 M .115 M
.115 M
Now check by putting equilibrium values in the K expression and see if you get close to the real value for K:
Kc = [H2O] [ CO] = [ .115 ] [ .115 ]
[H2] [CO2]
[.052] [.052]
(Initial)
(3.4g/34.1 g/mol)/1.25L
Initial
0.0798 M
Change
- 2x
Equilibrium
2H2
0M
+2x
0.0798 M 2x
S2
0M
+x
2x
x
3.72x10-2 mol/1.25L
0.0798 M 2x = 0.0798 M 2(.02976)
= 0.02976 M
2x = 2(.02976) = .05952
= .02028M
Since [S2] is .02976M, then
x = .02976
2 HI (g)
1.0 M
-2x
1-2x
Since [HI] is0.80 M,
then 2x must be = .20M,
H2 (g) +
0
+x
x
I2(g)
0
+x
x
so 1x = 0.10M
0.10 M
0.10 M
(d) Curve should start at 0 M, increase to 0.1 M and reach equilibrium at the same time [HI] reaches equilibrium
(e) i.) Kc = [0.10] [0.10] = 0.016
[0.80]2
ii.) Kp = Kc (RT) n = (0.016) [(0.0821L*atm/mol*K)(700K)](2-2) = (0.016) (1) = 0.016
(anything to the zero power is 1)
(f) Q = (0.10) (0.50) = 8.9x10-2
Kc = 2.6x10-2
2
(0.75)
Q > Kc therefore the reaction will shift to the left towards the reactants, so [HI] will be greater
than the initial concentration of HI.
5.) The equilibrium concentrations for this reaction at 425C are [SO3] = 0.50 M; [SO2] = 0.80 M; [O2] = 0.15M
2SO2(g) + O2(g)
a. Write the Kc expression for the reaction
Kc =
2SO3(g)
[SO3]2
[SO2]2[O2]
b. Calculate Kc
Kc =
(0.50)2
(0.80)2(0.15)
2.6
2NO2(g)
Kc = ?
H2(g) + Cl2(g)
2HCl(g)
Kc = 2.3 x 102
If the concentrations of [H2] = .60 M; [Cl2] = .80 M; and [HCl] = .25 M at 430C , is the reaction at
equilibrium? If not, which way will it shift to reach equilibrium (towards reactants or toward products)?
Q = [HCl]2 =
(0.25)2
[H2] [Cl2]
(0.60) (0.80)
= 0.130
**Not at equilibrium, Q < K therefore the reaction will shift towards the products
8.) Calculate the equilibrium concentrations of the reactants and products for the following reaction at 430C if
initially you started with [H2] = .50 M; [Cl2] = .50 M and if the equilibrium constant, Kc = 2.3 x 102
R
I
C
E
H2(g)
0.5M
Cl2(g)
2HCl(g)
0.5M
0M
Kc = [HCl]2
[H2] [Cl2]
2.3 x 102
-x
0.5 x
0.5M - .442M
.058M
0.5 x
0.5M - .442M
.058M
= (2x)2
+2x
(.5 x)2
15.166 = 2x
2x
(.5 x)
15.166(.5-x) = 2x
7.583 15.166x = 2x
2(.442M)
7.583 = 17.166x
.884M
x = .442M
[HCl] = __0.88 M
9)
Answers to 15.22 a) 13.3 b) 0.274 c) 0.0349
Given:
Kp = (PHCl)4(PO2)
= 0.0752
(PCl2)2(PH2O)2
a) compare Kp expression to the one given:
Kp = (PCl2)2(PH2O)2
= ? Since this Kp expression is the inverse of the given Kp expression,
4
the Kp value is the value is the inverse of the given Kp value
(PHCl) (PO2)
1
.0752
=13.3
Kc = .0349
Answers to 15.48 a) [PH3] = [BCl3] = 0.0432 M b) a little bit more than 3.27 g PH3BCl3
a) Will have to do a RICE box:
Reaction
Initial
Change
Equilibrium
Kc =
PH3BCl3
Some solid
-------------------
[PH3] [BCl3]
[x] [x]
x2
x
[PH3]eq
[BCl3]eq
PH3
0M
+x
x
BCl3
0M
+x
x
= 0.00187
= 0.00187
=.00187
= .0432 M
= .0432 M
= .0432 M
b) This is just a stoichiometry problemin order to have 0.0432 M of either PH3 or BCl3 in a 0.500 L
container, you have to have a minimum of PH3BCl3 to make it. Remember, in the original problem, you
started with some solid PH3BCl3.
0.500 L PH3
0.0432 mol PH3
1 mol PH3BCl3
151.3 g PH3BCl3
=3.27 g PH3BCl3
1L
1 mol PH3
1 mol PH3BCl3
Keep in mind, you need not all of the PH3BCl3 to be used up, need a little left to be in equilibrium, so you
need a little more than 3.27 g PH3BCl3
10)
SrSO4(s) <===> Sr(aq)2+ + SO42(aq)
x
x
x
Ksp = (x) (x) = x2 = 7.6 x 10-7
(x) = 8.7 x 104 M = solubility of SrSO4
b)
SrF2(s) <===> Sr(aq)2+ + 2 F(aq)
x
x
2x
2+
at equilibrium: [Sr ] = x, [F] = 2x
Ksp = [Sr2+] [F]2 = (x) (2x)2 = 4x3 = 7.9 x 10-10
x = 5.8 x 104 M = solubility of SrF2
c)
Solve for [Sr+] required for precipitation of each salt.
Ksp = [Sr2+][F]2 = 7.9 x 10 10
= (x) (0.020 M)2 = 7.9 x 1010
2+
[Sr ]= x = 2.0 x 10-6 M
Ksp = [Sr2+][SO42] = 7.6 x 10-7
= (x) (0.10 M) = 7.6 x 10-7
[Sr2+]= x = 7.6 x 10-6 M
Since 2.0 x 10-6 M < 7.6 x 10-6 M, SrF2 must precipitate first.
When SrF2 precipitates, [Sr2+] = 2.0 x 10-6 M
d) The second precipitate to form is SrSO4, which appears when [Sr2+] = 7.6 x 10-6 M (Based on calculation in
Part c.)
When [Sr2+] = 7.6 x 10-6M, [F] that will still be in solution is determined as follows:
Ksp = [Sr2+][F]2 = 7.9 x 10-10
= (7.6 x 106) (x)2 = 7.9 x 10-10
[F-] = x = 1.0 x 10-2 M
%F still in solution = 1.0 x 10-2 / 2.0 x 10-2 x 100 = 50.% (not a very good separation technique