Chongqing Changyuan Chemical Corporation Limited

(formerly Chongqing Jialing Chemical Products Limited)

Dujiaba Industrial Park, Rongchang County,
Chongqing China 402460
www.changyuancorp.com
Tel: +86-23-67957983
Fax: +86-23-67959523

MATERIAL SAFETY DATA SHEET

SODIUM PERMANGANATE SOLUTION 40%
Section 1 Chemical Product and Company identification

Product Name: Sodium permanganate solution 40%

Description: 40% minimum solution of NaMnO4
Company Name: Chongqing Changyuan Chemical Corporation Limited
Company Address: Dujiaba Industrial Park, Rongchang County, Chongqing, China
Emergency Number: +86 23 46797156
Fax Number: +86 23 67959523
Email Address: liu.qianqian@changyuancorp.com
Web Address: http://en.changyuancorp.com

Section 2 Composition

Chemical name Assay (%) CAS No.

Sodium permanganate 40.0-40.4 10101-50-5

Identification: Sodium permanganate

Section 3 Hazards Identification

Classification: CLASS 5.1: Oxidizing material.

Primary Route of Entry: Inhalation, Ingestion, Skin contact

Potential Acute Health Hazard:
Very hazardous in case of skin contact (irritant), or eye
contact (irritant). Hazardous in case of skin contact, of
ingestion, of inhalation. Prolonged exposure may result in
skin burns and ulcerations.
Over-exposure by inhalation may cause respiratory irritation.
Inflammation of the eye is characterized by redness, watering,
and itching. Skin inflammation is characterized by itching,
scaling, reddening, or, occasionally blistering.

Potential Chronic Health Effects: CARCINOGENIC EFFECTS: Not available.

MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
Repeated or prolonged exposure is not known to aggravate
medical condition.

Environmental Hazard: No data available

Explosive Hazard: May explode upon contact with concentrated sulfuric acid,
ammonium salts, peroxides, glycerol, ethanol, ether, sulfur,
phosphorous, etc. In acidic condition, may react violently and
cause fire upon contact with organic material, sulfur, carbon,
reducing agent, flammables.

Section 4 First Aid Measures

Sodium Permanganate MSDS Page 1/6, Rev 12/09


Eye Contact:
Skin Contact:
Serious Skin Contact:
Inhalation:
Serious Inhalation:
Ingestion:
Serious Ingestion:
Section 5 Fire Fighting Measures
Flammability of the Product:
Auto-Ignition Temperature:
Flash Points:
Products of Combustion:
Fire Hazards:
Special Remarks:
Fire Fighting Precautions:
Fire Fighting Methods/Agents:
Section 6 Accidental spill measures
Spill Treatment:
Sodium Permanganate MSDS
Chongqing Changyuan Chemical Corporation Limited
(formerly Chongqing Jialing Chemical Products Limited)
Dujiaba Industrial Park, Rongchang County,
Chongqing China 402460
www.changyuancorp.com
Tel: +86-23-67957983
Fax: +86-23-67959523
Check for and remove any contact lenses. Immediately flush
eyes with running water for at least 15 minutes, keep eyelids
open. Cold water may be used. Do not use an eye ointment.
Seek medical attention.
After contact with skin, wash immediately with plenty of water.
Gently and thoroughly wash the contaminated skin with
running water and non-abrasive soap. Be particularly careful
to clean folds, crevices, creases and groin.
Cold water may be used. Cover the irritated skin with an
emollient. If irritation persists, seek medical attention. Wash
contaminated clothing before reusing.
Wash with a disinfectant soap and cover the contaminated
skin with an anti-bacterial cream. Seek medical attention.
Allow the victim to rest in a well ventilated area. Seek
immediate medical attention.
Evacuate the victim to a safe area as soon as possible.
Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not
breathing, perform mouth-to-mouth resuscitation. Seek
medical attention.
Do not not induce vomiting. Loosen tight clothing such as a
collar, tie, belt or waistband. If the victim is not breathing,
perform mouth-to-mouth resuscitation. Seek immediate
medical attention.the victim to a safe area as soon as
possible. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, administer oxygen. If the
victim is not breathing, perform mouth-to-mouth resuscitation.
Seek medical attention.
Not available
Non flammable.
Not Applicable.
Not Applicable.
Metallic oxides.
Highly flammable in presence of combustible materials.
When heated to decomposition it emits irrigating fumes.
Wear protective cloth (suit, gloves, goggles, and boots) and a
self contained breathing apparatus.
Apply flooding quantity of water.
Persons not wearing protective equipment and clothing should be
Page 2/6, Rev 12/09
 Chongqing Changyuan Chemical Corporation Limited
(formerly Chongqing Jialing Chemical Products Limited)
Dujiaba Industrial Park, Rongchang County,
Chongqing China 402460
www.changyuancorp.com
Tel: +86-23-67957983
Fax: +86-23-67959523

restricted from spill areas until clean-up has been completed.

Wear splash goggles, full protective suit, boots and gloves. A self
contained breathing apparatus should be used to avoid inhalation of
the product. Suggested protective clothing might not be sufficient;
consult a specialist BEFORE handling this product Oxidizing material.

(1) Ventilate the spill area. Confine spill in a pit or behind a holding dam
of sand or soil.
(2) Dilute to approximately 6.0% with water then reduce with sodium
thiosulfate, a bisulfite or a ferrous salt solution. Bisulfite or ferrous salt
may require dilute sulfuric acid (10%), to promote reduction.
(3) Adjust pH to neutral with Sodium Carbonate if required. (4) Decant
or filter solution and deposit sludge in an approved landfill.
(5) To clean contaminated floors, flush with an abundant quantity of
water and treat collected water as described above.
(6) Dispose of all waste according to all federal, state and local
regulations. Unused material is a hazardous waste: D001- Ignitable.
Do not wash or pour sodium permanganate aqueous solution into any
surface waters or streams or directly into sewers.

Eliminate all ignition sources. Call for assistance on disposal. Be

careful that the product is not present at a concentration level above
TLV. Check TLV on the MSDS and with local authorities.

Section 7 Handling and Storage

Precautions: Keep away from heat. Keep away from sources of ignition. Keep away
from combustible material. Empty containers pose a fire risk; evaporate
the residue under a fume hood. Ground all equipment containing
material.
In case of insufficient ventilation, wear suitable respiratory equipment.
If ingested, seek medical advice immediately and show the container or
the label. Avoid contact with skin and eyes. Keep away from
incompatibles such as reducing agents, organic materials, metals,
acids, moisture.

Storage: Keep in a cool, dry, ventilated area. Ground all equipment containing
material. Containers should be closed. Avoid mixing with impurities like
organic material, flammables, etc. Store in separate safety cabinet or
room away from acids, organic material, flammables, reducing agent,
reactive metal powders, autoflammables, etc. Storage facilities should
be equipped with suitable material to absorb the spills.

Section 8 Exposure control/Personal Protection

Maximum Exposure: (China) MAC 0.2mg[MnO2]/m3.

(United States) TLV-TWA:ACGIH 5mg[Mn]/m3
(Russian Federation) 5mg/m3

Monitoring Method: Phosphoric acid – sodium permanganate colorimetry,

cold vapor atomic absorption spectrometry

Engineering Controls: Use process enclosures, local exhaust ventilation, provide eyewash in
working area or other engineering controls to keep airborne levels

Sodium Permanganate MSDS Page 3/6, Rev 12/09

 Chongqing Changyuan Chemical Corporation Limited
(formerly Chongqing Jialing Chemical Products Limited)
Dujiaba Industrial Park, Rongchang County,
Chongqing China 402460
www.changyuancorp.com
Tel: +86-23-67957983
Fax: +86-23-67959523

below permitted exposure level.

Respiratory Protection: Use mist respiratory mask. In case of emergency evacuation, wear air
supplied respirator.

Eye Protection: Wear splash goggles or face shield.

Personal Protection: Wear chemical resistant, protective clothing.

Hand Protection: Wear protective gloves (for example, neoprene gloves)

Other Protection: No smoking, eating or drinking in working area. Shower and change
cloths after use.

Section 9 Physical and Chemical Properties

Physical state and appearance: Dark purple liquid

pH value: 6~8
Boiling point(oC): 110oC
Flash point(oC): Not available
Density (g/cm3): 1.375
Vapour Pressure(kPa): Not available
Vapor Density: Not available
Critical Temperature: Not available
Soluibility: Miscible with water, ethanol, ethane, liquid chlorine
Oxidizing properties: Strong oxidizer
Explosive properties: May explode upon contact with concentrated sulfuric acid,
ammonium salts, peroxides, glycerol, ethanol, ether, sulfur,
phosphorous, etc.

Section 10 Stability and Reactivity Data

Stability: Stable under normal condition.

Instability Temperature:
Conditions of Instability:
Incompatible substances:
Conditions to avoid:
Decomposition products:
Polymerization:
Not available.
Not available.
Strong reducing agents, organic materials, reactive metal powders,
inflammables, combustibles, sulfur, phosphorous.
Fire, high temperature
Manganese oxide, oxygen
Not known to occur.

Section 11 Toxicological Information

Routes of Entry: Dermal contact. Eye contact. Inhalation. Ingestion.

Toxicity to Animals: Acute oral toxicity (LD50): 1090 mg/kg [Rat].

Intravenous (LD50): 55mg/kg [Rabbit]

Chronic Effects on Humans: No data available.

Other Toxic Effects on Humans: Very hazardous in case of skin contact (irritant).

Sodium Permanganate MSDS Page 4/6, Rev 12/09

 Chongqing Changyuan Chemical Corporation Limited
(formerly Chongqing Jialing Chemical Products Limited)
Dujiaba Industrial Park, Rongchang County,
Chongqing China 402460
www.changyuancorp.com
Tel: +86-23-67957983
Fax: +86-23-67959523

Hazardous in case of skin contact (permeator), of ingestion, of

inhalation.

Special Remarks on Toxicity to Animals: No data available.

Special Remarks on Chronic Effects on Humans: No data available.
Special Remarks on other Toxic Effects on Humans: Exposure can cause nausea, headache and
vomiting. Material is corrosive to the mucous membranes.

Section 12 Ecological information

Ecotoxicity: No data available.

Products of Biodegradation: Possibly hazardous short term degradation

products are not likely. However, long term
degradation products may arise.

Toxicity of the Biodegradation Products: The product itself and its products of
degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.

Section 13 Disposal considerations

Waste Disposal: D001 Hazardous waste

Disposal Method: Please follow procedures in section 6

Section 14 Transportation information

UN number: 3214
Packing group: II
Hazard Class: Oxidizer
DOT shipping Name: Permanganates, inorganic, aqueous solution n.o.s. (Sodium
Permanganate)

Section 15 Regulatory information

Chinese Regulations
“Dangerous Chemical Goods Safety Management Regulation”, State Council Order No 344 issued
at 26 January 2002, stated the safety requirement of production, usage, transportation, loading and
unloading of hazardous chemicals.

“Common Hazardous Chemicals Classification and Labelling” (GB13690-1992), classified sodium

permanganate as a class 5.1 oxidizing material

“New Edition of Dangerous Chemical Safety Manual”, specified the safety requirement of production,
usage, storage, transportation, destruction and fire safety of inflammable and explosive chemicals.

“Common Hazard Chemicals Storage General Principle” (GB15603-1995) specified the requirement
of warehousing, storage and conservation of hazardous chemicals.

US Regulations
Toxic Substances Control Act: All components of this product are listed in the Toxic
Substance Control Act inventory

Sodium Permanganate MSDS Page 5/6, Rev 12/09

 Chongqing Changyuan Chemical Corporation Limited
(formerly Chongqing Jialing Chemical Products Limited)
Dujiaba Industrial Park, Rongchang County,
Chongqing China 402460
www.changyuancorp.com
Tel: +86-23-67957983
Fax: +86-23-67959523

Comprehensive Environmental Response Compensation

and Liability Act: Not Listed

Hazardous Materials Identification System -

Health: 3
Flammability: 0
Reactivity: 0
Protective Equipment: Gloves. Dust respirator. Be sure to use an approved/certified respirator or
equivalent. Wear appropriate respirator when ventilation is inadequate.
Splash goggles.

Section 16 Other information

Other Special Considerations: Not available.

The Chongqing Changyuan Chemical Corporation Limited (“Changyuan Chemical”) urges each customer or recipient of this
(M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand
the data contained in this MSDS and any hazards associated with the product. The information herein is provided in good faith and
believed to be accurate. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and
may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state,
provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the
product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe
use of this product.

The information herein is supplied upon the condition that the persons receiving same will make their own determination as to its
suitability for their purposes prior to use. In no event will Changyuan Chemical be responsible for damages of any nature
whatsoever resulting from the use of or reliance upon the information herein or the product to which that information refers.
Nothing contained herein is to be construed as a recommendation to use any product, process, equipment or formulation in conflict
with any patent, and Changyuan Chemical makes no representation or warranty, express or implied, that the use thereof will not
infringe any patent. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY,
FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT.

Sodium Permanganate MSDS Page 6/6, Rev 12/09