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Lecture 5.
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baos
PV = nRT
where P = absolute pressure of the gas
V = total volume occupied by the gas
n = number of moles of the gas
R = ideal gas constants in appropriate units
T = absolute temperature of the gas
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baos
SLIDE
R = 1.987 cal/(gmol)(K)
= 1.987 Btu/(lbmol)(0R)
= 10.73 (psia)(ft3)/(lbmol)(0R)
= 8.314 (kPa)(m3)/(kmol)(K)
= 8.314 J/(gmol)(K)
= 82.06 (atm)(cm3)/(gmol)(K)
= 0.08206 (atm)(L)/(gmol)(K)
= 21.9 (in. Hg)(ft3)/(lbmol)(0R)
= 0.7302 (atm)(ft3)/(lbmol)(0R)
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baos
SLIDE
TS
PS
VS
nS
SI
273.15 K
101.325 kPa
22.415 m3
1 kmol
Am. Eng.
4920R
1 atm
359.05 ft3
1 lbmol
Natural Gas
Industry
333.15 K
14.696 psia
379.4 ft3
1 lbmol
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baos
SLIDE
PV nRT
V n
or P RT
t
t
t t
P V = n RT
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baos
SLIDE
n RT
V=
P
Obtaining the molar flowrate from mass flowrate:
m
1100 kg / h
n=
19.0 kmol / h
MW 58 kg / kmol
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baos
SLIDE
L atm 1000gmol
L atm
R 0.08206
82.06
gmol K 1kmol
kmol K
The volumetric flowrate is
V=
P
3atm
L 1m3
m3
V =328,978.5
329
h 1000 L
h
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baos
SLIDE
PV
nT
PS VS n STS
Using a basis of 1 hr, then n = 19 kmol
The following standard conditions will be used.
PS = 1 atm
VS = 22.41 m3
nS = 1 kmol
TS = 273 K
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baos
SLIDE
Solving for V:
n T P
V S VS
n S TS P
19.0kmol 633K 1atm
3
V
22.415m
273K 3atm
1kmol
V 329m 3
In terms of volumetric flowrate
m3
V = 329
h
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baos
SLIDE
P1V1 n1T1 T1
P2 V2 n 2T2 T2
Solving for V2:
0
P1 T2
1.00
atm
1070
R
3
3
V2 V1 10.0 ft
8.08
ft
530 0 R
P
T
2.50
atm
2 1
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baos
SLIDE
10
PV
nT
PSVS n STS
Solving for (n/V) and obtaining the density from this :
n S P TS
n
MW MW
V
VS PS T
1kmol 100 kPa 273K
kg
kg
28
1.123 3
3
m
22.41m 101.3kPa 300 K kmol
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baos
SLIDE
11
PiVtotal = niRTtotal
where Pi and ni are the partial pressure and number of
moles of component i.
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baos
SLIDE
12
PtotalVtotal = ntotalRTtotal
Dividing the two equations,
Pi VT n i RTT
PT VT n T RTT
or
Pi
ni
PT yi PT
nT
According to Dalton,
PA + PB + PC + . . . . = Ptotal
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baos
SLIDE
13
Pi (mmHg)
CO2
0.140
0.140(765) = 107.1
O2
0.060
0.060(765) = 45.9
N2
0.800
0.800(765) = 612.0
Total
1.000
765 mmHg
Prof. Manolito E Bambase Jr. Department of Chemical Engineering. University of the Philippines Los Baos
SLIDE
14