Biokinetics To Insert

4.2.
1 Biological and Microbiological kinetics of Bio diesel wastewater by using Bio carriers (MBBR media) at an operation
time of 30 min (COD)
days influant Ci effluant Ceff Ci-Ceff

1
1180
1107
73
2
1210
1003
207
3
1166
900
266
4
1195
871
324
5
1239
841
398
6
1225
752
473
7
1187
642
545
8
1224
557
667
9
1127
399
728
10
1236
412
824
11
1190
363
827
12
1089
333
756
13
1248
377
871
14
1132
348
784
ln(Ceff/Ci)
0.0638608
0.1876249
0.2589396
0.3162595
0.3874682
0.4879598
0.6145961
0.7873142
1.0383531
1.0986123
1.1873058
1.1848726
1.1970524
1.1795388
TVS ,X(m.o) accumilated X

50.0307692 50.03076923
102.388571 152.4193407
132.521045 284.9403854
156.420155 441.3605405
177.889326 619.2498667
213.029851 832.2797175
253.198346 1085.478063
302.294222 1387.772286
328.08179 1715.854076
371.087665 2086.941741
356.616794 2443.558534
348.541791 2792.100325
419.284211 3211.384536
406.54375 3617.928286
u
2
1.011
0.606
0.431
0.335
0.294
0.264
0.244
0.211
0.195
0.157
0.133
0.14
0.119
U
2.92
2.04
1.22
0.89
0.75
0.65
0.57
0.54
0.47
0.43
0.37
0.29
0.29
0.23
HRT
0.95
0.98
0.96
1
0.98
1.02
1
1.05
1
1.05
1.02
0.98
1.05
1.05
effluant (MB) 1st order cstr eff

1095.763162
1112.506725
1037.112807
1022.069648
942.6604619
933.8593555
930.3736771
907.8756973
938.6267668
898.0090353
863.9160331
817.9104385
758.6476102
735.1683846
710.1507135
670.0681258
571.9623342
552.8973374
605.2134424
573.9379504
585.5372633
538.2053754
500.4732634
503.8925164
535.2874287
552.9696692
440.9440667
505.6922276
102 | P a g e
Kd
KINETICS COMPARISION
2.5
actual effluant
calculated microbiological
1st order cstr
1200
2
y = 0.6534x - 0.1054
R = 0.9668
1.5
Kd
1
Linear (Kd)
EFFLUANT COD
1000
800
600
400
0.5
200
0
0
0
Plot of specific growth rate () with specific substrate utilization

(U) for Bio carriers (MBBR media) at an operation time of 30
minutes
10
15
TIME
Biological and microbiological kinetics of COD removal in Bio

diesel wastewater by using Bio carriers (MBBR) at an operation
time of 30 minutes
103 | P a g e
4.2.2 Biological and Microbiological kinetics of Bio diesel wastewater by using Bio carriers (MBBR media) at an operation
time of 60 min(COD)
days influant Ci effluant Ceff Ci-Ceff

1
1180
1077
103
2
1210
929
281
3
1166
856
310
4
1195
797
398
5
1239
767
472
6
1225
679
546
7
1187
593
594
8
1224
509
715
9
1127
375
752
10
1236
399
837
11
1190
339
851
12
1089
304
785
13
1248
348
900
ln(Ceff/Ci) TVS,X(m.o) accumilated X u

0.091335 63.87692 63.8769231
2
0.264267 140.5186 204.395495 1.05
0.309064 146.7603 351.155793 0.53
0.405047 195.0643 546.220134 0.43
0.479573 208.1391 754.359271 0.32
0.590075 248.6567 1003.01599 0.28
0.69399 290.0959 1293.11193 0.25
0.877431 332.8969 1626.00882 0.23
1.100388 347.8326 1973.84138 0.19
1.130674 402.4236 2376.26496 0.19
1.255708 380.3145 2756.57947 0.15
1.275987 351.4513 3108.03081 0.12
1.277095 420.9853 3529.01607 0.13
U
HRT effluant (MB) 1st order cstr eff
3.22 0.95 1077.70344
1085.788031
2.09 0.98
966.2136
961.0942977
1.12 0.96 923.256963
899.2046835
0.89
1 881.943385
850.5054866
0.73 0.98
898.27478
842.8676823
0.62 1.02 808.839198
764.7281195
0.52
1 706.991883
700.7125208
0.49 1.05 659.402965
637.0676504
0.42
1 566.170917
536.5674047
0.38 1.05 584.324445
565.1040223
0.33 1.02
567.74218
521.7415746
0.27 0.98 505.396727
483.8994192
0.27 1.05 544.581765
533.1169374
104 | P a g e
Kd
2.5
actual effluant
1st order cstr

2
1200
1.5
Kd
1
Linear (Kd)
0.5
EFFLUANT CONCENTRATION
y = 0.6078x - 0.0793
R = 0.9854
1000
800
600
400
200
0

minutes
10
12
14
TIME

time of 60 minutes
105 | P a g e
time of 90 min(COD)
days
1
2
3
4
5
6
7
8
9
10
11
12
13
influant Ci effluant Ceff Ci-Ceff

1180
1047
133
1210
900
310
1166
826
340
1195
767
428
1239
738
501
1225
649.5
575.5
1187
569
618
1224
485
739
1127
351.5
775.5
1236
376
860
1190
327
863
1089
290.5
798.5
1248
334
914
ln(Ceff/Ci) TVS,X(m.o) accumilated X u

U
HRT
0.119586 72.27692 72.27692308
2 3.68
0.95 1040.709115
1059.620508
0.295981 148.0029 220.2797802 1.01 2.12
0.98 924.4305042
937.9399565
0.34474 165.1031 385.3829145 0.55 1.12
0.96 847.6892392
876.0659616
0.443415 208.5527 593.9356277 0.43 0.87
1 792.2801863
827.8979219
0.518116 225.0586 818.9942197 0.32 0.71
0.98 804.7525141
821.7522335
0.634493 260.9851 1079.979294 0.27 0.61
1.02 720.6314623
743.6938619
0.735304 290.2093 1370.188618 0.24 0.5
1 626.5995007
684.0300184
0.925731 332.6942
1702.88284 0.22 0.48
1.05 580.283256
620.6842727
1.165105 357.8056 2060.688395 0.19 0.41
1 436.0697097
520.5290749
1.190046
406.881 2467.569388 0.18 0.38
1.05 448.7422403
549.4435103
1.291748
391.691 2859.260381 0.15 0.32
1.02 433.0348237
513.4658837
1.321412 365.6687 3224.929038 0.12 0.26
0.98 383.4473105
474.5132536
1.318157 437.3895 3662.318511 0.13 0.27
1.05 401.7126013
523.4757956
106 | P a g e
Kd
2.5
actual effluant
1st order cstr
1200
y = 0.5393x - 0.0414
R = 0.9958
1000
1.5
Kd
Linear (Kd)
0.5
800
600
400
200
0
0

minutes
10
12
14
TIME

time of 90 minutes
107 | P a g e
time of 30 min (BOD)
days
1
2
3
4
5
6
7
8
9
10
11
12
13
14
influant Ci effluant Ceff bod consumed ln(Ceff/Ci) TVS.X(m.o) accumilated X

708
642.96
65.04 0.096362 50.03077 50.03076923
750.2
606.856
143.344 0.212048 102.3886 152.4193407
687.94
510.3618
177.5782 0.298582
132.521 284.9403854
693.1
491.318
201.782 0.344083 156.4202 441.3605405
669.06
434.0682
234.9918 0.432672 177.8893 619.2498667
686
400.54
285.46 0.538064 213.0299 832.2797175
688.46
351.7062
336.7538 0.671661 253.1983 1085.478063
697.68
289.5828
408.0972 0.879319 302.2942 1387.772286
619.85
194.656
425.194 1.158244 328.0818 1715.854076
667.44
189.108
478.332 1.261131 371.0877 2086.941741
618.8
151.632
467.168 1.406326 356.6168 2443.558534
588.06
121.014
467.046 1.580923 348.5418 2792.100325
698.88
141.232
557.648 1.599075 419.2842 3211.384536
656.56
136.184
520.376 1.573007 406.5438 3617.928286
u
2
1.011
0.606
0.431
0.335
0.294
0.264
0.244
0.211
0.195
0.157
0.133
0.14
0.119
U
2.6
1.416
0.812
0.556
0.443
0.393
0.351
0.33
0.274
0.252
0.206
0.178
0.186
0.152
HRT
0.95
0.98
0.96
1
0.98
1.02
1
1.05
1
1.05
1.02
0.98
1.05
1.05

641.878022
648.6227983
614.868432
621.1255509
512.791469
534.6801113
486.340096
515.6676694
433.935697
469.8393568
404.3952
442.9163269
353.776367
411.841862
298.040505
362.7543043
186.183638
287.2011276
176.854087
287.1712888
147.387189
254.1845044
127.376679
230.6746993
144.577212
260.8706479
119.100376
247.6036188
108 | P a g e
Kd
2.5
actual effluant
1st order cstr
y = 0.7588x - 0.003
R = 0.9986
700
1.5
Kd
Linear (Kd)
0.5
600
500
400
300
200
100
0

minutes
10
15
TIME
Biological and microbiological kinetics of BOD removal in Bio

time of 30 minutes
109 | P a g e
days
1
2
3
4
5
6
7
8
9
10
11
12
13
influant Ci effluant Ceff bod consumed ln(Ceff/Ci) TVS,X(m.o) accumilated X u

U
HRT
708
624.96
83.04 0.124756 63.87692 63.87692308
2
2.6
0.95
750.2
553.474
196.726 0.304125 140.5186 204.3954945 1.0476 1.4666
0.98
687.94
491.2812
196.6588 0.336685 146.7603 351.155793 0.5283 0.708
0.96
693.1
441.467
251.633 0.451071 195.0643 546.2201341 0.4347 0.5608
1
669.06
394.1082
274.9518 0.529248 208.1391 754.3592711 0.3201 0.4228
0.98
686
352.8
333.2 0.664976 248.6567 1003.015988 0.283 0.3792
1.02
688.46
302.6324
385.8276 0.821938 290.0959 1293.111927 0.2527 0.3361
1
697.68
248.2692
449.4108 1.033247 332.8969 1626.008816 0.2281 0.3079
1.05
619.85
169.059
450.791 1.29923 347.8326 1973.841378 0.1932 0.2504
1
667.44
148.716
518.724 1.501411 402.4236 2376.264962 0.185 0.2385
1.05
618.8
120.588
498.212 1.635402 380.3145 2756.579466 0.1482 0.1941
1.02
588.06
117.1152
470.9448 1.613671 351.4513 3108.030809 0.1199 0.1606
0.98
698.88
138.9696
559.9104 1.615224 420.9853 3529.016072 0.1269 0.1687
1.05

623.5131898
632.9800729
564.3242198
577.9471518
493.8209174
519.8993906
435.0544366
477.6471943
393.7367876
440.5584872
357.0361794
408.752833
304.6995965
377.8722806
257.2247188
334.6332702
159.7113152
269.5902838
134.994072
259.0509472
115.6577
231.9244371
123.1656306
227.8068372
141.8751476
259.2299249
110 | P a g e
Kd
2.5
actual effluant
1st order cstr
700
y = 0.7585x - 0.0034
R = 0.9985
600
1.5
Kd
1
Linear (Kd)
0.5
500
400
300
200
100
0
0

minutes
10
12
14
TIME

time of 60 minutes
111 | P a g e
days
1
2
3
4
5
6
7
8
9
10
11
12
13
influant Ci effluant Ceff

708
614.04
750.2
542.996
687.94
466.7018
693.1
424.067
669.06
371.7576
686
336.28
688.46
302.4816
697.68
248.5428
619.85
156.134
667.44
142.9704
618.8
105.6848
588.06
98.064
698.88
117.152
ln(Ceff/Ci)
0.142384
0.3232379
0.3880111
0.4912828
0.5876317
0.7129335
0.8224368
1.0321455
1.3787629
1.5408119
1.767321
1.7912087
1.7860068
TVS,X(m.o) accumilated X
72.27692
72.27692308
148.0029
220.2797802
165.1031
385.3829145
208.5527
593.9356277
225.0586
818.9942197
260.9851
1079.979294
290.2093
1370.188618
332.6942
1702.88284
357.8056
2060.688395
406.881
2467.569388
391.691
2859.260381
365.6687
3224.929038
437.3895
3662.318511
u
2
1.0118
0.5452
0.4259
0.3186
0.2749
0.2369
0.2165
0.1901
0.1797
0.1471
0.1202
0.127
U
2.6
1.417
0.731
0.549
0.421
0.368
0.315
0.292
0.246
0.232
0.193
0.161
0.169
HRT
0.95
0.98
0.96
1
0.98
1.02
1
1.05
1
1.05
1.02
0.98
1.05

612.476523
623.6430369
554.573086
569.7260864
469.726408
501.2347368
417.419296
464.7676399
371.582515
424.5630321
340.984812
397.1764228
304.839431
377.7689363
257.818629
334.8189935
146.875634
260.5766215
129.494885
254.9570711
100.995135
220.7896616
104.727231
213.4221208
120.599041
243.0627275
112 | P a g e
Kd
2.5
actual effluant
1st order cstr

700
y = 0.7593x - 0.0037
R = 0.9986
Axis Title
1.5
Kd
1
Linear (Kd)
0.5
600
500
400
300
200
100
0
0
Axis Title

minutes
10
12
14
TIME

time of 90 minutes
113 | P a g e
4.2.7 Biological and Microbiological kinetics of Bio diesel wastewater by using Pumice stone at an operation time of 30 min
(COD)
days
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15

1180
1136
44
1210
1092
118
1166
1018
148
1195
945
250
1239
870
369
1225
797
428
1187
666
521
1224
581
643
1127
496
631
1236
521
715
1190
479
711
1089
450
639
1248
493
755
1132
450
682
1089
435
654
ln(Ceff/Ci)
0.038001
0.102609
0.135739
0.234717
0.353567
0.429841
0.577895
0.745129
0.820739
0.863886
0.910008
0.883768
0.928788
0.922494
0.917669
TVS ,X(m.o) accumilated X u

U
HRT
36.646154 36.64615385
2 2.401
0.95 1126.262923
1138.88504
68.332857
104.979011 0.965 1.666
0.98 1109.391679
1099.44299
80.565821 185.5448319 0.555 1.019
0.96 1047.70034
1031.575771
128.52171 314.0665373 0.514 1.001
1 1005.264186
967.8334778
160.96987 475.0364086 0.408 0.935
0.98 1001.999687
920.1665734
199.34328 674.3796922 0.347 0.745
1.02 929.9199709
851.618052
247.90857 922.2882636 0.311 0.653
1 821.0140809
752.2681849
297.32889 1219.617153 0.278
0.6
1.05 782.1065756
686.7202668
296.48225 1516.099406 0.217 0.461
1 689.3050495
618.9795767
330.60233 1846.701733 0.197 0.425
1.05 744.6552298
648.1112907
320.01832 2166.720054 0.159 0.354
1.02 716.2894558
617.1532886
314.55806 2481.278113 0.135 0.275
0.98 625.8676264
583.5724549
386.20632 2867.484429 0.144 0.282
1.05 674.0159783
631.8258603
375.71313 3243.197554 0.123 0.223
1.05 573.6110724
575.0225758
370.03256 3613.230112 0.108 0.191
1.1 535.3840045
541.9431121
114 | P a g e
Kd
2.5
actual effluant
1st order cstr

2
1200
1.5
Kd
Linear (Kd)
0.5
y = 0.7825x - 0.1552
R = 0.9386
1000
800
600
400
200
0
0
3
0
-0.5

(U) for Pumice stone at an operation time of 30 minutes
10
15
20
TIME

diesel wastewater by using Pumice stone at an operation time of
30 minutes
115 | P a g e
(COD)
days
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
influant Ci effluant Ceff Ci-Ceff ln(Ceff/Ci) TVS ,X(m.o) accumilated X

1180
1107
73 0.063861 44.584615
44.58461538
1210
1047
163 0.144691 88.261429
132.846044
1166
988
178 0.165652 88.640896
221.4869395
1195
915
280 0.266977 147.38295
368.8698852
1239
826
413 0.405465 194.15064
563.0205287
1225
753
472 0.486631 212.61194
775.632469
1187
642
545 0.614596 253.19835
1028.830815
1224
545
679 0.809094 297.02489
1325.855704
1127
460
667 0.896088 302.19444
1628.050148
1236
484
752 0.937551 351.28068
1979.330831
1190
450
740 0.972461 336.25344
2315.584266
1089
406
683 0.986662 332.2894
2647.873669
1248
450
798 1.02005 399.05684
3046.930511
1132
421
711 0.989108 388.85375
3435.784261
1089
392
697 1.021753 384.96744
3820.751703
u
2
0.995
0.5
0.499
0.417
0.318
0.281
0.252
0.205
0.195
0.157
0.134
0.14
0.12
0.106
U
HRT
3.27
0.95 1102.23521
1112.506725
1.84
0.98 1055.76004
1059.732479
1
0.96
1011.2936
1006.017466
0.95
1 937.116075
943.189674
0.89
0.98
899.71491
886.6746714
0.71
1.02 852.509595
818.6513433
0.6
1 743.965136
735.1683846
0.58
1.05 702.631755
661.7831855
0.45
1 598.234008
594.3816877
0.42
1.05 619.396477
622.8494222
0.34
1.02 600.893019
597.4164829
0.28
0.98
508.31256
553.6550393
0.28
1.05
547.53491
602.5921706
0.22
1.05 449.444414
555.2928853
0.19
1.1 411.130503
512.7290974
116 | P a g e
Kd
2.5
actual effluant
1st order cstr

2
1200
y = 0.6102x - 0.0677
R = 0.9924
1.5
Kd
Linear (Kd)
0.5
1000
800
600
400
200
0
0
0

10
15
20
TIME

60 minutes
117 | P a g e
(COD)
days
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15

1180
1092
88
1210
1033
177
1166
959.5
206.5
1195
886
309
1239
797
442
1225
723
502
1187
618
569
1224
521
703
1127
436
691
1236
461
775
1190
424
766
1089
392
697
1248
435
813
1132
406
726
1089
377
712
ln(Ceff/Ci)
0.077504
0.158153
0.194922
0.299185
0.441205
0.527287
0.652696
0.854129
0.949672
0.986238
1.031975
1.021753
1.053952
1.025388
1.06077
51.507692 51.50769231
94.461429 145.9691209
101.1894 247.1585239
155.04884 402.2073611
200.9405 603.1478607
230.26866 833.4165174
268.8409
1102.25742
322.66222 1424.919642
312.37963 1737.299272
350.56012 2087.859396
346.57405 2434.433441
333.54269 2767.976128
399.06695 3167.043075
390.52125 3557.564325
386.87907 3944.443395
u
2
0.957
0.515
0.478
0.4
0.321
0.278
0.255
0.198
0.183
0.153
0.128
0.134
0.116
0.103
U
3.417 0.95 1087.391594
1099.076756
1.793 0.98 1039.888213
1047.628022
1.051 0.96
983.96817
982.2047667
0.952
1 915.478316
919.807762
0.879 0.98 877.1343371
864.9932627
0.699 1.02 809.4259611
796.575628
0.588
1 702.3342451
718.2204381
0.556 1.05 640.7420724
645.2851324
0.437
1 563.8427284
578.045868
0.405 1.05 602.3126409
607.2070541
0.339 1.02 564.5254867
579.7483758
0.268 0.98 488.3363926
544.1413517
0.274 1.05 526.6296484
592.4100049
0.216 1.05 426.0772137
545.106739
0.19
1.1 387.7866359
502.5735715
118 | P a g e
Kd
2.5
actual effluant
1st order cstr
1200
y = 0.5862x - 0.0568
R = 0.9947
1000
1.5
Kd
1
Linear (Kd)
0.5
800
600
400
200
0
0

10
15
20
TIME

90 minutes
119 | P a g e
(BOD)
days
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
influant Ci effluant Ceff bod consumed

708
660.36
47.64
750.2
654.534
95.666
687.94
579.9818
107.9582
693.1
527.307
165.793
669.06
456.4188
212.6412
686
418.88
267.12
688.46
358.7416
329.7184
697.68
296.286
401.394
619.85
235.609
384.241
667.44
241.2936
426.1464
618.8
199.576
419.224
588.06
166.5522
421.5078
698.88
185.2256
513.6544
656.56
175.6472
480.9128
653.4
176.058
477.342
ln(Ceff/Ci) TVS,X(m.o)
0.069659 36.646154
0.136416 68.332857
0.170705 80.565821
0.273391 128.52171
0.382463 160.96987
0.493293 199.34328
0.651855 247.90857
0.856435 297.32889
0.967304 296.48225
1.017435 330.60233
1.131587 320.01832
1.26152 314.55806
1.327905 386.20632
1.318537 375.71313
1.311376 370.03256
accumilated X
36.64615385
104.979011
185.5448319
314.0665373
475.0364086
674.3796922
922.2882636
1219.617153
1516.099406
1846.701733
2166.720054
2481.278113
2867.484429
3243.197554
3613.230112
u
2
0.96498
0.55462
0.51449
0.40798
0.34686
0.31053
0.27763
0.21675
0.19662
0.15947
0.13535
0.14441
0.12297
0.10794
U
2.6
1.351
0.743
0.664
0.539
0.465
0.413
0.375
0.281
0.253
0.209
0.181
0.192
0.157
0.139
HRT
0.95
0.98
0.96
1
0.98
1.02
1
1.05
1
1.05
1.02
0.98
1.05
1.05
1.1

659.6330086
664.0554623
660.0033263
661.7341046
581.6028704
591.0763546
523.4459367
544.2945647
456.5861248
486.6550373
422.8422068
456.3722111
361.2102461
416.7799567
305.1326985
367.3436298
228.4809408
315.0758823
230.9635716
322.6987405
196.3362304
287.2503093
172.8557796
262.9623399
188.9926236
291.8932784
160.5262176
275.3491534
164.7904867
267.5113032
120 | P a g e
Kd
2.5
actual effluant
1st order cstr
800
y = 0.7599x - 0.0031
R = 0.9986
700
1.5
Kd
1
Linear (Kd)
0.5
600
500
400
300
200
100
0
0

10
15
20
TIME

30 minutes
121 | P a g e
(BOD)
days
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
influant Ci effluant Ceff bod consumed ln(Ceff/Ci) TVS,X(m.o) accumilated X

708
650.04
57.96 0.0854102 44.584615 44.58461538
750.2
626.634
123.566 0.1799772 88.261429
132.846044
687.94
569.1612
118.7788 0.1895379 88.640896 221.4869395
693.1
502.976
190.124 0.3206318 147.38295 368.8698852
669.06
412.587
256.473 0.4834266 194.15064 563.0205287
686
401.1
284.9 0.5366669 212.61194
775.632469
688.46
351.7062
336.7538 0.6716611 253.19835 1028.830815
697.68
296.6964
400.9836 0.8550512 297.02489 1325.855704
619.85
228.206
391.644 0.9992288 302.19444 1628.050148
667.44
214.6392
452.8008 1.134491 351.28068 1979.330831
618.8
178.308
440.492 1.2442697 336.25344 2315.584266
588.06
142.7922
445.2678 1.4154386 332.2894 2647.873669
698.88
168.1344
530.7456 1.4247154 399.05684 3046.930511
656.56
158.8272
497.7328 1.4191973 388.85375 3435.784261
653.4
156.792
496.608 1.4272694 384.96744 3820.751703
u
2
0.9949
0.5003
0.4993
0.4167
0.3177
0.2806
0.2523
0.2046
0.1948
0.1566
0.1339
0.1401
0.12
0.1061
U
2.6
1.393
0.67
0.644
0.55
0.426
0.373
0.341
0.265
0.251
0.205
0.179
0.186
0.154
0.137
HRT
0.95 649.123584
654.864501
0.98 633.636554
637.7203753
0.96 570.881711
582.0350009
1 498.446576
524.8245441
0.98 412.652774
453.9822325
1.02
405.18141
443.3242309
1 354.052754
411.841862
1.05 305.336804
367.6249534
1 220.732021
310.0445557
1.05 203.429774
304.5980546
1.02 174.675294
272.7006163
0.98 149.218271
246.3460527
1.05 171.761759
280.0054785
1.05 142.919128
263.6620769
1.1 144.824137
254.2416058
122 | P a g e
Kd
2.5
actual effluant
1st order cstr
700
y = 0.7592x - 0.0027
R = 0.9986
600
1.5
Kd
1
Linear (Kd)
0.5
500
400
300
200
100
0
0

10
15
20
TIME

60 minutes
123 | P a g e
(BOD)
days
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
influant Ci effluant Ceff bod consumed ln(Ceff/Ci) TVS,X(m.o)

708
641.04
66.96 0.099352 51.50769
750.2
617.954
132.246 0.193926 94.46143
687.94
552.3462
135.5938 0.219527 101.1894
693.1
493.087
200.013 0.340489 155.0488
669.06
403.6176
265.4424 0.505406 200.9405
686
377.44
308.56 0.597466 230.2687
688.46
330.9016
357.5584 0.732636 268.8409
697.68
262.086
435.594 0.979088 322.6622
619.85
215.006
404.844 1.058812 312.3796
667.44
215.568
451.872 1.130173 350.5601
618.8
164.788
454.012 1.323122 346.574
588.06
141.1128
446.9472 1.427269 333.5427
698.88 168.12096
530.75904 1.424795 399.0669
656.56
156.6928
499.8672 1.432727 390.5213
653.4
154.326
499.074 1.443122 386.8791
accumilated X
51.50769231
145.9691209
247.1585239
402.2073611
603.1478607
833.4165174
1102.25742
1424.919642
1737.299272
2087.859396
2434.433441
2767.976128
3167.043075
3557.564325
3944.443395
u
2
0.957
0.515
0.478
0.4
0.321
0.278
0.255
0.198
0.183
0.153
0.128
0.134
0.116
0.103
U
2.6
1.339
0.69
0.616
0.528
0.43
0.369
0.345
0.256
0.236
0.201
0.172
0.179
0.149
0.133
HRT
0.95
0.98
0.96
1
0.98
1.02
1
1.05
1
1.05
1.02
0.98
1.05
1.05
1.1

640.0335668 646.9389136
625.54323
630.395111
554.4125941
568.195363
488.4763372 517.0502525
403.8872833 447.4426641
382.087791
426.2417452
333.6607566 397.3482791
271.7870944 344.0165028
207.5910941 301.0717476
204.7236993 305.2296021
161.3861021 263.3656844
147.8977604 245.1553384
172.1378839 279.9960626
141.0976422 262.1664433
142.6687228
252.528134
124 | P a g e
Kd
2.5
actual effluant
1st order cstr
700
y = 0.76x - 0.003
R = 0.9987
600
1.5
Kd
1
Linear (Kd)
0.5
500
400
300
200
100
0
0
0

10
12
14
16
TIME

90 minutes
125 | P a g e
4.2.13 Biological and Microbiological kinetics of Bio diesel wastewater by using Foam at an operation time of 30 min (COD)
days
1
2
3
4
5
6
7
8
9
10

1180
1077
103
1210
856
354
1166
723
443
1195
605
590
1239
458
781
1225
369
856
1187
280
907
1224
272
952
1127
221
906
1236
280
956
ln(Ceff/Ci) TVS,X(m.o)
0.091335 69.230769
0.346105 156.77143
0.477925 220.72164
0.680673 265.27132
0.995191 309.12854
1.199899 373.08955
1.444395 421.41579
1.504077 438.13156
1.629152 403.62191
1.484846 436.74228
accumilated X
69.3208
226.0922286
446.8138704
712.0851882
1021.213727
1394.303279
1815.719069
2253.850624
2657.472538
3094.214819
u
2
1.061
0.656
0.458
0.357
0.309
0.263
0.215
0.164
0.152
U
2.972 0.95 1055.496188
1085.788031
2.397 0.98 927.1393706
903.5358558
1.317 0.96 768.6227873
799.2826259
1.018
1 715.3313157
711.024688
0.901 0.98 681.2434374
627.2506593
0.709 1.02 548.9052117
550.8347473
0.565
1 424.9878875
485.6007729
0.468 1.05 427.4549431
474.5508045
0.369
1 397.1631152
428.6553537
0.332 1.05 441.9807139
482.9844997
126 | P a g e
Kd
2.5
actual effluant
calculated microiological
1st order cstr

2
1200
y = 0.6205x - 0.122
R = 0.9357
1.5
Kd
Linear (Kd)
0.5
1000
800
600
400
200
0
0

(U) for Foam at an operation time of 30 minutes
6
TIME
10
12

diesel wastewater by using Foam at an operation time of 30
minutes
127 | P a g e
days
1
2
3
4
5
6
7
8
9
10
influant Ci effluant Ceff Ci-Ceff ln(Ceff/Ci) TVS,X(m.o) accumilated X

1180
1047
133
46.98 72.27692 72.27692308
1210
826
384
126.542 180.7743 253.0512088
1166
693
473 153.2938 228.7967 481.8479252
1195
576
619
186.441 289.0558 770.9037392
1239
413
826 226.3653 342.7181 1113.621832
1225
310
915
263.06 392.6269 1506.248697
1187
251
936 285.2092
428.886 1935.134712
1224
261
963 298.8738
442.776 2377.910712
1127
228
899 265.8205 410.2168 2788.127533
1236
251
985 285.9732 443.7133 3231.840799
u
2
1.111
0.623
0.461
0.364
0.3
0.249
0.205
0.159
0.147
U
3.68
2.361
1.287
0.988
0.877
0.699
0.544
0.447
0.348
0.327
HRT
0.2788 1038.29898
1059.620508
0.2788
854.9585
880.5473817
0.2788
717.17231
777.5965793
0.2788 626.623412
690.8337846
0.2788 565.900145
596.6368626
0.2788 452.059814
510.0752771
0.2788 343.672318
464.8100322
0.2788 350.795584
466.7076165
0.2788
320.38195
433.8004225
0.2788 360.947189
462.247569
128 | P a g e
Kd
2.5
y = 0.5404x - 0.0626
R = 0.9929
actual effluant
1st order cstr
1200
2
1.5
Kd
1
Linear (Kd)
0.5
1000
800
600
400
200
0
0
0

10
12
TIME

minutes
129 | P a g e
days
1
2
3
4
5
6
7
8
9
10

ln(Ceff/Ci)
1180
1033
147 0.133047
1210
797
413 0.417521
1166
664
502 0.563052
1195
546
649 0.783282
1239
369
870 1.211263
1225
292
933 1.433942
1187
238
949 1.606914
1224
261
963 1.545359
1127
221
906 1.629152
1236
251
985 1.594183
TVS,X(m.o)
84.18461538
198.9757143
236.4314925
313.2899225
370.8340651
400.1492537
429.378797
447.944
417.9702932
448.8912335
accumilated X u
U
HRT
84.18461538
2 3.492
0.95 1021.015466
1047.589984
283.1603297 1.0833 2.249
0.98 833.4161481
858.6611522
519.5918222 0.5891 1.251
0.96 719.1715117
756.8823084
832.8817447 0.4633
0.96
1 601.2095137
670.1125636
1203.71581 0.3642 0.854
0.98 537.1549475
566.519656
1603.865064 0.285 0.665
1.02 465.4906733
497.4374526
2033.243861 0.2361 0.522
1 373.1817876
455.327689
2481.187861 0.1984 0.427
1.05 371.9411733
466.7076165
2899.158154 0.1554 0.337
1 334.8047653
428.6553537
3348.049387 0.1437 0.315
1.05 382.1393885
462.247569
130 | P a g e
y = 0.5685x - 0.0775
R = 0.9897
Kd
2.5
actual effluant
1200
1st order cstr
1000
800
1.5
Kd
1
Linear (Kd)
600
400
0.5
200
0
0

0
0
10
12
TIME

minutes
131 | P a g e
4.2.16 Biological and Microbiological kinetics of Bio diesel wastewater by using Foam at an operation time of 30 min (BOD)
days
1
2
3
4
5
6
7
8
9
10
influant Ci effluant Ceff BOD consumed ln(Ceff/Ci) TVS,X(m.o) accumilated X u

U
HRT
708
617.88
90
0.13615 69.323077
69.3208
2 2.597
0.95 616.3020287
626.9135372
750.2
530.72
219.48 0.346105 156.77143 226.0922286 1.061 1.486
0.98 542.7958155
560.1922306
687.94
392.173
295.767 0.561999 220.72164 446.8138704 0.656 0.879
0.96 395.9622776
446.8539671
693.1
350.9
342.2 0.680673 265.27132 712.0851882 0.458 0.591
1 342.1165099
412.3943191
669.06
260.7012
408.3588 0.942499 309.12854 1021.213727 0.357 0.471
0.98 260.0916496
347.8077627
686
186.06
499.94 1.304808 373.08955 1394.303279 0.309 0.414
1.02 192.3089308
294.30634
688.46
127.977
560.483 1.682607 421.41579 1815.719069 0.263 0.349
1 130.8799879
256.6384444
697.68
106.2024
591.4776 1.882414 438.13156 2253.850624 0.215 0.291
1.05 117.8303584
234.3933837
619.85
96.756
523.094 1.857285 403.62191 2657.472538 0.164 0.213
1 85.81326701
216.9366947
667.44
104.4792
562.9608 1.854461 436.74228 3094.214819 0.152 0.196
1.05 89.42900812
226.4669841
132 | P a g e
Kd
2.5
y = 0.7598x - 0.0053
R = 0.9982
actual effluant
1st order cstr
700
1.5
Kd
1
Linear (Kd)
0.5
600
500
400
300
200
100
0
0
0

10
12
TIME

minutes
133 | P a g e
days
1
2
3
4
5
6
7
8
9
10
influant Ci effluant Ceff BOD consumed ln(Ceff/Ci) TVS,X(m.o) accumilated X u

U
HRT
708
614.04
93.96 0.142384 72.27692 72.27692308
2
2.6
0.95
750.2
497.116
253.084 0.411516 180.7743 253.0512088 1.111 1.556
0.98
687.94
381.3524
306.5876 0.589978 228.7967 481.8479252 0.623 0.834
0.96
693.1
320.218
372.882 0.772172 289.0558 770.9037392 0.461 0.595
1
669.06
216.3294
452.7306 1.129071 342.7181 1113.621832 0.364 0.48
0.98
686
159.88
526.12 1.456454 392.6269 1506.248697
0.3 0.402
1.02
688.46
118.0416
570.4184 1.76342 428.886 1935.134712 0.249 0.332
1
697.68
99.9324
597.7476 1.943267 442.776 2377.910712 0.205 0.277
1.05
619.85
88.209
531.641 1.949769 410.2168 2788.127533 0.159 0.206
1
667.44
95.4936
571.9464 1.94439 443.7133 3231.840799 0.147 0.19
1.05

612.216859
623.6430369
510.603442
534.602313
384.720326
439.1913842
309.956061
391.1019317
214.824625
317.6183979
165.528935
275.9915688
119.970908
249.13331
110.656977
229.4675487
76.106954
210.1351333
79.1743696
219.4364326
134 | P a g e
Kd
2.5
calculated microbiologial
y = 0.7576x - 0.0042
R = 0.9982
actual effluant
1st order cstr

700
1.5
Kd
1
Linear (Kd)
0.5
600
500
400
300
200
100
0
0

10
12
TIME

minutes
135 | P a g e
days
1
2
3
4
5
6
7
8
9
10
influant Ci effluant Ceff BOD consumed ln(Ceff/Ci)

708
598.56
109.44 0.167917
750.2
471.634
278.566 0.464137
687.94
371.1218
316.8182 0.617171
693.1
288.956
404.144
0.8749
669.06
179.1882
489.8718 1.317437
686
149.8
536.2 1.521577
688.46
117.3862
571.0738 1.768988
697.68
92.9556
604.7244 2.015639
619.85
78.1605
541.6895 2.070713
667.44
88.8192
578.6208 2.016847
84.184615 84.18461538
198.97571 283.1603297
236.43149 519.5918222
313.28992 832.8817447
370.83407
1203.71581
400.14925 1603.865064
429.3788 2033.243861
447.944 2481.187861
417.97029 2899.158154
448.89123 3348.049387
u
2
1.083
0.589
0.463
0.364
0.285
0.236
0.198
0.155
0.144
U
2.6
1.517
0.789
0.598
0.481
0.382
0.314
0.268
0.201
0.185
HRT
0.95
0.98
0.96
1
0.98
1.02
1
1.05
1
1.05
effluant (MB)1st order cstr eff

596.533087
610.5967214
486.7062
515.653172
374.872781
431.9916562
278.189137
369.6730765
177.982598
292.0271494
156.009067
268.8079255
119.804853
248.6323644
104.307767
223.8722267
66.3038997
201.8586492
72.8130076
214.0816491
136 | P a g e
Kd
y = 0.7584x - 0.0044
R = 0.9982
2.5
actual effluant
1st order CSTR

2
1.5
Kd
1
Linear (Kd)
0.5
700
600
500
400
300
200
100
0

10
12
TIME

minutes
137 | P a g e

Biokinetics To Insert

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4.2.

days influant Ci effluant Ceff Ci-Ceff

TVS ,X(m.o) accumilated X

effluant (MB) 1st order cstr eff

1st order cstr

Plot of specific growth rate () with specific substrate utilization

Biological and microbiological kinetics of COD removal in Bio

days influant Ci effluant Ceff Ci-Ceff

ln(Ceff/Ci) TVS,X(m.o) accumilated X u

1st order cstr

Plot of specific growth rate () with specific substrate utilization

Biological and microbiological kinetics of COD removal in Bio

influant Ci effluant Ceff Ci-Ceff

ln(Ceff/Ci) TVS,X(m.o) accumilated X u

1st order cstr

Plot of specific growth rate () with specific substrate utilization

Biological and microbiological kinetics of COD removal in Bio

influant Ci effluant Ceff bod consumed ln(Ceff/Ci) TVS.X(m.o) accumilated X

effluant (MB) 1st order cstr eff

1st order cstr

Plot of specific growth rate () with specific substrate utilization

Biological and microbiological kinetics of BOD removal in Bio

influant Ci effluant Ceff bod consumed ln(Ceff/Ci) TVS,X(m.o) accumilated X u

effluant (MB) 1st order cstr eff

1st order cstr

Plot of specific growth rate () with specific substrate utilization

Biological and microbiological kinetics of BOD removal in Bio

influant Ci effluant Ceff

effluant (MB) 1st order cstr eff

1st order cstr

Plot of specific growth rate () with specific substrate utilization

Biological and microbiological kinetics of BOD removal in Bio

influant Ci effluant Ceff Ci-Ceff

TVS ,X(m.o) accumilated X u

1st order cstr

Plot of specific growth rate () with specific substrate utilization

Biological and microbiological kinetics of COD removal in Bio

influant Ci effluant Ceff Ci-Ceff ln(Ceff/Ci) TVS ,X(m.o) accumilated X

1st order cstr

Plot of specific growth rate () with specific substrate utilization

Biological and microbiological kinetics of COD removal in Bio

influant Ci effluant Ceff Ci-Ceff

1st order cstr

Plot of specific growth rate () with specific substrate utilization

Biological and microbiological kinetics of COD removal in Bio

influant Ci effluant Ceff bod consumed

effluant (MB) 1st order cstr eff

1st order cstr

Plot of specific growth rate () with specific substrate utilization

Biological and microbiological kinetics of BOD removal in Bio

influant Ci effluant Ceff bod consumed ln(Ceff/Ci) TVS,X(m.o) accumilated X

1st order cstr

Plot of specific growth rate () with specific substrate utilization

Biological and microbiological kinetics of BOD removal in Bio

influant Ci effluant Ceff bod consumed ln(Ceff/Ci) TVS,X(m.o)

effluant (MB) 1st order cstr eff

1st order cstr

Plot of specific growth rate () with specific substrate utilization

Biological and microbiological kinetics of BOD removal in Bio

influant Ci effluant Ceff Ci-Ceff

1st order cstr

Plot of specific growth rate () with specific substrate utilization

Biological and microbiological kinetics of COD removal in Bio