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Abstract
A model of a solar-hydrogen powered residence, in both stand-alone and grid parallel congurations, was developed using
Matlab/Simulink . The model assesses the viability of employing a regenerative fuel cell (RFC) as an energy storage device to
be used with photovoltaic (PV) electrical generation. Other modes of energy storage such as batteries and hybrid storage were
also evaluated. Analyses of various operating conditions, system congurations, and control strategies were performed. Design
requirements investigated included RFC sizing, battery sizing, charge/discharge rates, and state of charge limitations. Dynamic
load demand was found to be challenging to meet, requiring RFC and or battery sizes signicantly larger than those required
to meet average power demand. Employing a RFC with batteries in a hybrid conguration increased PV utilization and both
battery efciency and power density. Grid parallel congurations were found to alleviate many of the difculties associated with
energy storage costs and meeting peak demand.
2005 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
Keywords: Solar hydrogen; Regenerative fuel cell; Electrolyzer; Dynamic modeling; Energy storage; Renewable energy
1. Introduction
Solar photovoltaic (PV) arrays have been used to meet
electrical energy needs at the residential level for many
decades. However, one of the major challenges for PV
systems remains matching their sun dependent power
supply curve with that of the time dependent power demand of the residence. To solve this problem an energy
storage device must be used in conjunction with the PV
array. This device must store excess PV energy and subsequently deliver power at the desired time and rate. The
energy storage device that is most commonly used with
PV systems today is the rechargeable lead acid battery.
Corresponding author. Tel.: +1 949 824 7302;
fax: +1 949 824 7423.
E-mail address: jb@nfcrc.uci.edu (J. Brouwer).
0360-3199/$30.00 2005 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
doi:10.1016/j.ijhydene.2005.10.008
J.D. Maclay et al. / International Journal of Hydrogen Energy 31 (2006) 994 1009
995
US Department of Energy [5], and Giner Electrochemical Systems [6]. Other groups that are more focused
on bi-functional electrode or MEA development include
researchers at AIST in Japan and the Dalian Institute of
Chemical Physics in China [79].
Although few research groups have published analyses pertaining to regenerative fuel cells as applied to
solar photovoltaic energy systems, many have analyzed
analogous systems containing fuel cells and electrolyzers as separate components [1025].
At the residential level, a single-family home in
Switzerland has operated a 5 kW PV array since
1991 to produce electrolytic H2 which is then utilized to power a stove, laundry machine, and minivan
(no fuel cell present in this system) [10]. At the building
level, a study of a solar-hydrogen powered library in
Germany outlines the challenges to systems engineering optimization in a stand-alone conguration [11].
A marine laboratory at Humboldt State University has
been powered successfully by solar-hydrogen for many
years in a stand-alone conguration [12]. A large-scale
study in Germany reiterates the difculties of systems
integration and also refers to the need for more basic
research, more development projects, better component availability, and cost reductions before widespread
hydrogen energy storage becomes practical [13].
Solmecke and Hackstein have shown system efciency and cost reduction gains that have been achieved
by integration of DCDC converters in similar systems [14]. Rahman and Tam showed that oscillations in
PV power output could be effectively smoothed out
by integration with phosphoric acid fuel cells, allowing the PV-fuel cell hybrid to successfully load follow
at the building scale [15]. Vosen and Keller developed
a model of a hybrid energy storage system containing
batteries and hydrogen that estimated the hybrid system cost at 48% of a hydrogen-only system and only
9% of a battery-only system. The minimum cost design
employed batteries for short-term storage and hydrogen
for long-term storage [16].
Many researchers have indicated that an appropriate and advanced control strategy is key to establishing
good performance. Vanhanen, Kauranen, and Lund employed a control strategy utilizing fuels cells to recharge
batteries in the winter that allowed current control of
the fuel cell and optimized fuel cell efciency [17].
PV-fuel cell power plant performance was shown to
be enhanced by using neural network and real/reactive
power controllers [18] and fuzzy logic controllers [19].
A group from King Fahd University in Saudi Arabia
has assessed the potential for solar-hydrogen to aid agricultural development by providing remote energy for
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J.D. Maclay et al. / International Journal of Hydrogen Energy 31 (2006) 994 1009
3. Approach
As the Background section suggests there has been
signicant recent attention and interest in application of
electrolyzers and fuel cells (or RFCs) to renewable energy systems. The work contained here expands upon
current understanding and addresses the dynamic performance required by the systems and system components. In addition, a new simulation tool that can account for and address dynamic operation and develop
and test system control strategies was applied to renewable RFC system concepts.
In order to analyze the performance of regenerative
fuel cells as energy storage devices at the residential
level, an empirical model of a PV-RFC powered home
was constructed using MATLAB /Simulink . The
empirical model incorporates experimental data into
Simulink by using look-up tables. The ve lookup tables utilized by the model are PV power output
(kW) vs. time (s), residential power demand (kW) vs.
time (s), fuel cell power density (W/cm2 ) vs. current
density (A/cm2 ), electrolyzer power density (W/cm2 )
vs. current density (A/cm2 ), and battery voltage (V)
vs. state of charge (%) at charge/discharge rates of C/5,
C/10 and C/20. Batteries are typically rated in A-h for
20 h charge/discharge period. For example, a battery
rated for 100 A-h can deliver 5 A for 20 h. Thus, the
20 h charge/discharge rate in amps (i.e., A-h/h) for a
100 A-h battery is denoted as C/20. If the same 100
A-h battery is discharged over a period of 5 h the
C/5 charge/discharge rate would not be 20 A for the
5 h. Typically the C/5 charge/discharge rate would be
less than a C/10 or C/20 charge/discharge rate due to
inefciencies associated with increased current draw.
4. Dynamic data
The dynamic data for PV power output (kW vs. time
(s)) were determined by measurement of a Unisolar
6 kW nominal DC amorphous PV array installed at
the University of California, Irvine (Latitude: 33.6 N,
Longitude: 117.7 W). LabViewTM data acquisition software was used to collect power output data on a time
interval of every 15 min, 24 h/day. One week of data, acquired from 8/2/018/9/01, comprised the primary data
set for the analyses presented herein. These data were
directly used to develop the Simulink PV output table.
The dynamic data for residential power demand (kW
vs. time (s)) data were collected from a 6-person family
home in Irvine California (Latitude: 33.6 N, Longitude: 117.7 W) using a BMI Dranetz power quality
meter (Model 8020 PQ Node). The meter uses inductor clips applied to the 120 and the 240 V legs of the
utility grid power coming into the home as a means of
measuring power usage. BMIs PQ NodeTM data acquisition software was used to collect power usage on a
time interval of every 5 min, 24 h/day. A week of data,
acquired from 8/2/038/9/03, comprised the primary
data set for the analyses presented herein. These data
were directly used to develop the Simulink residential
power demand table. The major electrical devices used
within the residence included a stove and oven, washer
and dryer, refrigerator, coffee maker, microwave, hair
dryer, television, computers and lighting. The oven
was determined to account for some of the largest
peaks observed during evening hours. Air conditioning,
which is common to many of the residences throughout
the Western US, was not furnished in this particular
residence.
5. Model
5.1. Model components
A schematic of the renewable RFC system conguration considered in the current work is presented in
Fig. 1. The model contains eight main components, PV
power supply, residential power demand, power management, battery, RFC, utility grid power supply, and
H2 and O2 storage tanks. The model assumes RFC operation on oxygen not air. The model was run as both
a stand-alone system autonomous of the grid, where all
of the power demand in the residence is met by the PV
Residential
Power
Demand
Power Management
Utility
Grid
Battery
RFC
PV Power
Supply
H2
Storage
J.D. Maclay et al. / International Journal of Hydrogen Energy 31 (2006) 994 1009
5. Electrolyzer
6. Store H2
7. Power to Grid
1. PV Power
2. Battery Power
3. FC Power
L
o
a
d
4. Grid Power
Fig. 2. Control strategy for the Simulink renewable RFC system
model.
3.
4.
5.
6.
5.2. Model control strategy
Various power ow control strategies are under investigation in the current study. The control strategy
presented in this paper consists of a hierarchy of power
ow through the system as presented in Fig. 2.
5.3. Model control strategy & component operational
limitations
The control strategy employed for this paper, together
with various model component limitations is dened as
follows:
1. PV power is rst sent to meet residential load
demands.
2. PV power is sent next to the battery.
(a) If excess PV power is available, then charge the
battery. (However, the state of charge limitation
must be met as well as the charge rate limitation,
see #3).
997
7.
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J.D. Maclay et al. / International Journal of Hydrogen Energy 31 (2006) 994 1009
(1)
(2)
J.D. Maclay et al. / International Journal of Hydrogen Energy 31 (2006) 994 1009
Electrochemical electrolyzer efciency is also commonly dened using the 1st law of thermodynamics [29]
as
ez =
(3)
Wout
H + T S(theoretical)
Wout
,
G(theoretical)
ez =
Energy required(theoretical)
Actual useful energy in
H T S(theoretical)
Win
G(theoretical)
,
Win
(4)
(6)
(5)
999
(7)
kWh(load + H2 + to grid)
, (8)
kWh(P V + (Bi Bf ) + f rom grid)
1000
J.D. Maclay et al. / International Journal of Hydrogen Energy 31 (2006) 994 1009
Table 1
Gibbs free energy and enthalpy values for hydrogen used in fuel cell and electrolyzer efciency calculations along with equivalent higher
heating values (HHV) and cell voltages
Energy values
G(theoretical)H2 (J/mol)
HHV (kJ/kg)
Voltage (V)
Temperature ( C)
Pressure (kPa)
Fuel cell
Electrolyzer
229,800
227,705
113,988
112,949
1.19
1.18
80
80
207
101
Fuel cell
Electrolyzer
H (theoretical)H2
287,965
285,869
142,840
141,800
NA
NA
80
80
207
101
J.D. Maclay et al. / International Journal of Hydrogen Energy 31 (2006) 994 1009
1001
9
8
7
6
5
4
3
2
1
0
8/2/03
8/3/03
8/4/03
8/5/03
8/6/03
8/7/03
8/8/03
8/9/03
Fig. 3. Electrical load demand for a six-person family home in Irvine, California.
5
4.5
4
PV Power (kW)
3.5
3
2.5
2
1.5
1
0.5
0
8/2/01
8/3/01
8/4/01
8/5/01
8/6/01
8/7/01
8/8/01
8/9/01
Fig. 4. Photovoltaic electrical power supply from a Unisolar 6 kW DC nominal amorphous silicon array.
density conditions. This lower power density operation results in higher efciency for both the fuel cell
and the electrolyzer. For the system conguration
containing a 2 kW fuel cell and 7.3 kW electrolyzer
there is a decit of H2 to keep the fuel cell running. In
1002
J.D. Maclay et al. / International Journal of Hydrogen Energy 31 (2006) 994 1009
Table 2
Summary results from the dynamic analyses of stand-alone (not grid-connected) RFC systems as applied to a dynamic residential load
Without
battery
With battery
500 A-h
Without
battery
With battery
500 A-h
2 kW
1.95 W/cm2
0 W/cm2
7.3 kW
1.04 W/cm2
0 W/cm2
(36.9%)
(93%)
46.25%
74.09%
34.27%
41.70%
66.42%
0%
33.58%
0%
0%
14.32 kWh
2 kW
1.67 W/cm2
0 W/cm2
7.3 kW
1.04 W/cm2
0 W/cm2
(34%)
(93.4%)
41.02%
74.44%
30.54%
58.40%
35.24%
0%
33.58%
31.21%
0%
24.64 kWh
5.9 kW
0.65 W/cm2
0 W/cm2
22 kW
0.35 W/cm2
0 W/cm2
(51.4%)
(99.2%)
64.41%
78.88%
50.88%
65.33%
66.42%
0%
33.58%
0%
0%
38.79 kWh
5.9 kW
0.56 W/cm2
0 W/cm2
22 kW
0.35 W/cm2
0 W/cm2
(50.7%)
(99.4%)
63.47%
79.16%
50.24%
73.63%
38.60%
0%
33.58%
27.85%
0%
59.24 kWh
System Effciency
Electrolyzer Efficency
H2 Storage (kWh)
100
90
80
70
60
50
40
30
20
10
0
80
60
40
20
H2 Storage (kWh)
is unreasonable. For the system conguration containing a 5.9 kW fuel cell the maximum power density of
0.65 W/cm2 , at 1.44 A/cm2 and 0.45 V is much more
reasonable and correspondingly leads to higher fuel cell
efciency. If the fuel cell is restricted to an operational
power density limit of 0.47 W/cm2 , at 1 A/cm2 and
0.47 V, as is done in the grid parallel scenario, then one
would need a 8.1 kW maximum fuel cell to fully meet
the 8.1 kW peak. Therefore, at the scale of the fuel cell
studied here, the power system would either have to
be grid parallel or rely on a secondary energy storage
device. The system conguration could use a RFC
together with batteries in a hybrid energy storage
system.
The next step of the study involved simulating such
a hybrid conguration by adding a battery to the
RFC system. Typically, battery operation is limited
to charge/discharge rates that range from C/5 to C/20
(as dened in the Section 3). The model restricts the
batterys state of charge to values between 20% and
85%. This SOC limit restricts battery charge/discharge
to within the bulk phase range, allowing the use of fast
charge/discharge rates. For this reason, a charge rate of
C/5 was chosen for the current analyses.
Fig. 5 explores the effect of battery size on the
stand alone system using a 2 kW fuel cell and 7.3 kW
electrolyzer. Initially, as battery size increases fuel cell
efciency decreases. This is due to a control hierarchy
that uses the battery before the fuel cell to meet load
demand resulting in battery power meeting more of
Efficiency
Stand-alone analyses
0
-20
0
500
1000
1500
2000
2500
3000
3500
System Effciency
Electrolyzer Efficency
H2 Storage (kWh)
90
80
70
60
50
40
30
20
10
0
90
80
70
60
50
40
30
20
10
0
0
500
1000
1500
2000
2500
3000
H2 Storage (kWh)
Efficiency
J.D. Maclay et al. / International Journal of Hydrogen Energy 31 (2006) 994 1009
3500
1003
1004
J.D. Maclay et al. / International Journal of Hydrogen Energy 31 (2006) 994 1009
Table 3
Summary results from the dynamic analyses of grid-connected RFC systems as applied to a dynamic residential load for system conguration
containing a 2 kW fuel cell and 7.3 kW electrolyzer
Grid-parallel analyses
With
lower limit
Without
lower limit
2 kW
0.47 W/cm2
0.047 W/cm2
7.3 kW
1.75 W/cm2
0.071 W/cm2
(49.5%)
(93%)
62.06%
74.05%
45.96%
67.33%
48.78%
17.66%
33.58%
0%
0.37%
55.33 kWh
2 kW
0.47 W/cm2
0 W/cm2
7.3 kW
1.75 W/cm2
0 W/cm2
(49.9%)
(93.0%)
62.55%
74.09%
46.34%
66.78%
50.63%
15.81%
33.58%
0%
0%
53.48 kWh
2 kW
0.47 W/cm2
0.047 W/cm2
7.3 kW
1.75 W/cm2
0.071 W/cm2
(47.5%)
(93.4%)
59.55%
74.41%
44.31%
73.85%
26.58%
12.02%
33.58%
27.85%
0.19%
68.91 kWh
Table 4
Summary results from the dynamic analyses of grid-connected RFC systems as applied to a dynamic residential load for system conguration
containing a 5.9 kW fuel cell and 22 kW electrolyzer
Grid-parallel analyses
With
lower limit
Without
lower limit
5.9 kW
0.47 W/cm2
0.047 W/cm2
22 kW
1.75 W/cm2
0.071 W/cm2
(48.1%)
(99%)
78.88%
47.51%
73.02%
42.36%
24.09%
33.58%
0%
2.26%
70.01 kWh
5.9 kW
0.47 W/cm2
0 W/cm2
22 kW
1.75 W/cm2
0 W/cm2
(52.5%)
(98.6%)
78.99%
51.93%
66.68%
65.59%
0.85%
33.58%
0%
0%
42.44 kWh
5.9 kW
0.47 W/cm2
0.047 W/cm2
22 kW
1.75 W/cm2
0.071 W/cm2
(47.5%)
(99.3%)
79.09%
46.87%
78.25%
26.43%
8.82%
33.58%
31.21%
1.18%
74.54 kWh
J.D. Maclay et al. / International Journal of Hydrogen Energy 31 (2006) 994 1009
1005
7
6
5
4
3
2
1
0
0
100000
200000
300000
400000
500000
600000
Time (s)
Fig. 7. Residential power demand supplied by the grid when using a 2 kW fuel cell and 7.3 kW electrolyzer and no battery.
2.5
1.5
0.5
0
0
100000
200000
300000
400000
500000
600000
Time (s)
Fig. 8. Residential power demand supplied by the grid when using a 5.9 kW fuel cell and 22 kW electrolyzer and no battery.
System Effciency
Electrolyzer Efficency
H2 Storage (kWh)
90
80
70
60
50
40
30
20
10
90
80
70
60
50
40
30
20
10
H2 Storage (kWh)
J.D. Maclay et al. / International Journal of Hydrogen Energy 31 (2006) 994 1009
Efficiency
1006
0
0
500
1000
1500
2000
2500
3000
3500
% From Grid
% Fuel Cell
% To Grid
% Battery
70
60
50
40
30
20
10
0
0
500
1000
1500
2000
2500
3000
3500
Fig. 10. Percent of total energy demand provided from the grid, fuel
cell or battery as well as energy fed to the grid vs. battery size for a
grid parallel system using a 2 kW fuel cell and 7.3 kW electrolyzer.
J.D. Maclay et al. / International Journal of Hydrogen Energy 31 (2006) 994 1009
PV Power
Battery Power
1007
Grid Power
8
7
Power (kW)
6
5
4
3
2
1
0
0
86564
173126
259688
346251
432814
519376
Time (s)
Fig. 11. Fraction of total load demand met by each power source (PV, battery, fuel cell and grid) for the week when using a 2 kW fuel cell,
7.3 kW electrolyzer and 500 A-h battery.
When energy storage demand is met by a combination of both RFC and batteries, it becomes clear that
control strategy is very important.
7.2. Grid parallel
7. Discussion
7.1. Stand-alone
The average daily PV energy supply over the week
analyzed was 32.0 kWh/day and average daily residential energy demand was 15.4 kWh/day.
Peak load demand was found to typically exist during morning and evening hours, a time when PV
power supply is often low if not zero. As a result,
stand-alone systems must incorporate energy storage
devices sized to handle the majority of peak load
demand.
Energy storage devices must possess a mixture of
both high energy density to meet energy needs over
long durations and high power density to handle
transient peaks and provide power that can meet the
highly dynamic load prole of a residence.
The model shows that when a RFC is employed as the
sole energy storage device in a stand-alone scenario,
it must operate at very high power densities which
will most likely cause irreversible damage to the cells
or at the least result in poor operational efciency.
The RFC is uncontrolled in the stand-alone analyses
which is unrealistic but instructional.
Many of the residences that utilize PV to meet electrical power needs, size the PV and batteries to minimize cost and then use the utility grid in parallel
to provide power demand in excess of what the system can provide. We modeled this conguration by
adding operational control limits to the RFC.
Only the maximum control limit should be applied
to the fuel cell.
We observed numerous advantages when operating
the 2 kW fuel cell as grid parallel verses stand-alone.
Using maximum and minimum operational power
density limits, there was a 16% increase in fuel cell
efciency, 26% increase in system efciency, and
an increase in H2 energy storage of 70 kWh, when
employing the grid parallel verses the stand-alone
conguration.
The vast improvement in fuel cell efciency is a
result of sending the major power spikes present at
peak demand to the grid.
System efciency improvements are a combination
of higher fuel cell efciency, greater H2 production
capabilities, and more reliance on the grid.
There is virtually no change in efciency for the
7.3 kW electrolyzer when comparing grid parallel
and stand alone analyses.
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J.D. Maclay et al. / International Journal of Hydrogen Energy 31 (2006) 994 1009
Acknowledgements
J.D. Maclay et al. / International Journal of Hydrogen Energy 31 (2006) 994 1009
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