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ABSTRACT
In Malaysia, the major consumers of energy are the industrial and transport sectors. The demand is expected
to increase steadily in tandem with the growth of the economy. As such, alternative sources of energy need
to be developed, in particular energy from renewable sources, to meet the energy requirements. Fatty acid
methyl esters, commonly known as biodiesel, derived from oils and fats have long been known as a potential
diesel substitute. Biodiesel is suitable to be used neat or blended with petroleum diesel in any proportion in an
unmodified diesel engine. However, the many concerns related to the emissions from the production and use
of biodiesel have been discussed globally. Thus, this life cycle assessment study was conducted to investigate
the environmental impacts from the production and use of palm biodiesel produced using MPOBs production
technology. The results show that the environmental impact from the production of palm biodiesel is related
to the use of methanol, while the use of palm biodiesel contributes to the impact categories of respiratory
inorganics and acidification/eutrophication. In spite of these, the production and use of palm biodiesel is more
environmental-friendly as compared to petroleum diesel.
INTRODUCTION
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Raw materials
Energy
Auxiliary
materials
Transesterification
Wastewater
Palm biodiesel
Glycerol
Utilization in diesel
engines vehicles
Air emissions
METHODOLOGY
System Boundary
Figure 1 shows the system boundary of LCA
for the production and use of palm biodiesel. The
production energy, raw materials and auxiliary
materials were included as the inputs while the
outputs included the products, by-product and
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LIFE CYCLE ASSESSMENT FOR THE PRODUCTION AND USE OF PALM BIODIESEL (part 5)
Material
Palm oil
Methanol
Palm biodiesel
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Unit
Amount
Raw materials
RBD palm oil
Methanol
Sodium hydroxide
Hydrochloric acid
MJ MJbiodiesel-1
MJ MJbiodiesel-1
kg MJbiodiesel-1
kg MJbiodiesel-1
1.006
0.055
0.0001
0.0004
Utilities
Electricity
Water
Steam
Instrument air
MJ MJbiodiesel-1
kg MJbiodiesel-1
MJ MJbiodiesel-1
kg MJbiodiesel-1
0.0022
0.009
0.0144
0.00008
Products
Biodiesel
Glycerol
Wastewater
MJbiodiesel-1
kg MJbiodiesel-1
kg MJbiodiesel-1
1.00
0.0030
0.009
Assumptions
Replacement
Amount
factor
Item
Unit
Vessels and
tanks
Pumps and
agitators
Pipes
tonne
10%
56.5
tonne
5%
12.3
tonne
5%
16.7
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LIFE CYCLE ASSESSMENT FOR THE PRODUCTION AND USE OF PALM BIODIESEL (part 5)
TABLE 4. TAILPIPE EMISSIONS (per km) FOR ULTRA LOW SULPHUR DIESEL (ULSD) BIODIESEL BLENDS USING
PALM OIL
Impact category
Carbon dioxide
Methane
Nitrous oxide
Carbon monoxide
Nitrogen oxides
Non-methanic hydrocarbon
Particulate matters (PM 10)
BD2
BD5
BD10
BD20
BD100
692
0.01
0.016
679
0.01
0.016
659
0.01
0.016
626
0.01
0.016
560
0.01
0.016
0
0.01
0.015
2.81
8.68
0.72
283
2.78
8.71
0.71
278
2.75
8.76
0.71
271
2.69
8.84
0.71
260
2.57
8.99
0.71
238
1.79
10.33
0.71
119
28
26
24
22
20
18
Pt
16
14
12
10
8
6
4
2
0
Carcinogens
Resp.
Resp.
Climate
Radiation
organics
inorganics
change
Biodiesel revised oil palm and emission (Oct 2010)
Methanol, at plant/GLO U (biodiesel)
NaOH ETH U
Electricity Malaysia
Ozone layer
Ecotoxicity
Acidification/
Land use
Minerals
Fossil fuels
eutrophication
Water, completely softened, at plant/RER U
RPO Sept 2010 (OP to OP, without biogas capture, with capital) reviewer
X5CrNI18 (304)
Steam on Site A
Figure 3. Weighted life cycle impact assessment of cradle to grave for production and use of palm biodiesel based on
continued land use for oil palm plantations with biogas emission at palm oil mills.
28
26
24
22
20
18
mPt
16
14
12
10
8
6
4
2
0
Carcinogens
Resp.
Resp.
Climate
Radiation
organics
inorganics
change
Biodiesel revised oil palm and emission (Oct 2010)
Methanol, at plant/GLO U (biodiesel)
NaOH ETH U
Electricity Malaysia
Ozone layer
Ecotoxicity
Acidification/
Land use
Minerals
Fossil fuels
eutrophication
Water, completely softened, at plant/RER U
RPO Sept 2010 (OP to OP, without biogas capture, with capital) reviewer
X5CrNI18 (304)
Steam on Site A
Figure 4. Weighted life cycle impact assessment of cradle to grave for production and use of palm biodiesel based on
continued land use for oil palm plantations with biogas capture at palm oil mills.
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LIFE CYCLE ASSESSMENT FOR THE PRODUCTION AND USE OF PALM BIODIESEL (part 5)
CONCLUSION
REFERENCES
SAKA, S; DADAN, K and EIJI, M (2006). Noncatalytic biodiesel fuel production with supercritical
methanol technologies. J. Sci. Ind. Res, 65: 420-425.
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