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is the average enthalpy required to break or make one mole of a bond (e.g. CH, C
C etc.). This is taken as an average from many (but not all) molecules containing the
bond. 11. Mean bond enthalpies can be used to estimate enthalpy changes by
calculating the enthalpy needed to break existing bonds (endothermic), and that
when new bonds are made (exothermic). 12. Mean bond enthalpies can be
calculated using the bond dissociation enthalpy for a species.
Reaction Kinetics And Equilibria 1. The rate of a reaction can be explained using
collision theory: a. The molecules must have a minimum amount of energy to start
the reaction the activation energy (EA). b. The molecules must approach each
other at the correct angle and alignment. c. Molecules can only react if they collide,
and not all collisions lead to a reaction. d. Increasing the frequency of collisions will
increase the rate of reaction. 2. There are four main ways of increasing the rate of a
reaction: a. Increasing the concentration of reactants (liquids) or the pressure
(gases). b. Increasing the temperature. c. Increasing the surface area of reactants
(in solids). d. Using a catalyst (this lowers EA). 3. The Maxwell-Boltzman distribution
of molecular energies (Emp is the most probable (modal) energy
What other isomer is formed in the nitration step a? Rationalise the
regioselectivity of the mono-debenzylation reaction carried out in step b. Suggest
a structure for compound 6 and give reasons for carrying out the reaction in a
reductive environment. What is the mechanism of the hydrolysis of compound
ced in nuclear reactors and is used in the production of the hydrogen bomb.
Hydrogen is the primary component of Jupiter and the other gas giant planets. At
some depth in the planet's interior the pressure is so great that solid molecular
hydrogen is converted to solid metallic hydrogen.
In 1973, a group of Russian experimenters may have produced metallic hydrogen at
a pressure of 2.8 Mbar. At the transition the density changed from 1.08 to 1.3
g/cm3. Earlier, in 1972, at Livermore, California, a group also reported on a similar
experiment in which they observed a pressure-volume point centered at 2 Mbar.
Predictions say that metallic hydrogen may be metastable; others have predicted it
would be a superconductor at room temperature.
Compounds
Although pure Hydrogen is a gas we find very little of it in our atmosphere.
Hydrogen gas is so light that uncombined Hydrogen will gain enough velocity from
collisions with other gases