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Introduction
Wear resistance of tool steels is one of the key governing
factors that determines the useful life of a tool and in
turn controls the productivity of the manufacturing
process. One of the approaches to achieve improved
wear resistance of tool steels is the use of deep cryogenic
treatment.110 Deep cryogenic treatment, often simply
referred to as cryotreatment, is applied in between
conventional hardening and tempering treatments
Unlike age old cold treatments (213193 K), cryotreatments are usually carried out between 148 K and 77 K
for a sufficiently long time (1272 h) with controlled
cooling and heating cycles.8,9 The most prevalent claim
regarding the benefit of cryotreatment of tool steels is
the increment in wear resistance,112 apart from the
enhancement of dimensional stability,13 hardness,3,5,7,8,12,14,15 fatigue resistance,14 toughness,16 bend
strength3 and reduction of residual stress.17 The
enhancement of the mechanical properties of tool steels
by cryotreatment has been attributed to the nearly
complete transformation of retained austenite to martensite,4,18 precipitation of ultrafine carbide particles5,6,19 or both.8,15,20
The improvements in wear resistance (IWR), typically
for AISI D2 steel, by cryotreatment reported by
different investigators48,11,16 are compiled in Table 1.
It is obvious from the data in Table 1 that the degree of
1
Experimental procedures
The selected steel for this investigation is a commercial
AISI D2 tool steel containing Fe1?49C0?29Mn
0?42Si11?38Cr0?80Mo0?68V0?028S0?029P (wt.-%).
Sample blanks of the steel were first subjected to
conventional (QT) and cryogenic treatment (QCT) in
separate batches; QT consisted of hardening (Q) and
single tempering (T), whereas QCT incorporated an
additional step of controlled deep cryogenic (C) processing in between hardening and tempering. The details
of the hardening and tempering treatments have
been reported earlier.8 The cryogenic processing was
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a QT; b QCT
1 Typical SEM micrographs of differently treated specimens. PC, primary carbide particles; LSC, large secondary carbide particles; SSC, small secondary carbide
particles
Table 1 Reported improvement in wear resistance of AISI D2 steel by deep cryogenic treatment
Wear test conditions
Description of
Sl no. setup used
1
2
3
4
5
6
7
Counter body
817
108{
Dry
Wet
431
NA
0.41
NA
Barron4
Collins and Dormer5
110600{
Dry
21
0.53.62
Meng et al.6
134
Dry
150
0.21
1602290
Dry
4978
1.50
Das et al.8
180{
138{
Dry
NA
1.4
NA
0.074
NA
Bourne et al.11
Rhyim et al.16
*Ratio of wear rates of conventionally treated to cryotreated specimens as the index of improvement in wear resistance following the
report of Barron.4
{
Approximate values obtained from the graphs.
NA, information not available.
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Results
Microstructure and hardness
Figure 1 depicts typical representative SEM micrographs of the QT and QCT specimens. The microstructures of these specimens exhibit a non-uniform
distribution of large elongated dendritic-type PCs and
uniform distribution of nearly spherical SCs on the
tempered martensitic matrix. In this study, the SCs have
been classified into two different size groups LSCs and
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Retained austenite
PCs
SCs (5SSCszLSCs)
Tempered martensite
Amount (vol.-%)
SSCs
LSCs
SSCs
LSCs
SSCs
LSCs
SSCs
LSCs
QT
QCT
9.800.7
6.990.3
6.570.3
76.64
3.520.2
3.050.7
0.490.01
2.240.05
16112
6.40.5
13.5
71.2
7.440.04
9.030.06
Negligible
6.840.5
9.650.3
83.51
5.470.2
4.180.4
0.360.01
1.640.03
47522
15.60.4
6.1
37.6
7.930.04
10.010.07
PCs, primary carbides; SCs, secondary carbides; SSCs, small secondary carbides; LSCs, large secondary carbides.
Table 3 Estimated wear parameters, features of worn surfaces and wear debris, and the proposed modes and
mechanisms of wear
Normal load (N)
29.43
Parameters/
features
29
58.86
QT
3
WR (610 , m m )
b (5WRQT/WRQCT)
K
Worn surfaces
QCT
117.72
QT
1.04610
0.48610
2.16
1.2961025
2.6361025
Compacted oxide layer
24
QCT
4.96610
53.21
6.2761023
Plastic
deformation of
surface and
subsurface
Subsurface
cracking
24
22
Groove marks
Cracking and putt out of PCs
Wear debris
Oxide granules
Metallic
platelets
Maximum
length
<300 mm
Deformation
induced
delamination
wear
Maximum length
Mechanism of wear
Mode of wear
Comparison of mode
and mechanism of
wear
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<20 mm
<13 mm
Oxidative wear coupled
with cracking and pull out
of PCs
Mild wear
Similar
Mild wear
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Severe wear
Dissimilar
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QT
9.32610
24
1.2661024
Compacted
oxide layer
Groove
marks
Cracking and
pull out of PCs
Oxide
granules
Maximum
length
<17 mm
Oxidative
wear coupled
with cracking
and pull out
of PCs
Mild wear
QCT
0.49
0.31
1.58
3.1061022
2.0961022
Heavy surface and subsurface
plastic deformation
Subsurface cracking
Extrusion of material
Large metallic platelets
Maximum length
<1500 mm
<500 mm
Deformation induced
delamination wear
Severe wear
Similar
Severe wear
Das et al.
a worn surface of QT; b worn surface of QCT; c typical micrograph of the region marked as 1 in a and b; d typical
micrograph of the region marked as 2 in a and b; e wear debris of QT; f wear debris of QCT
3 Typical backscatter electron (a, b and c) and secondary electron (d) SEM micrographs of worn surfaces; and secondary electron (e and f) SEM micrographs of wear debris tested at FN529?43 N
Discussion
Mode and mechanism of wear
One of the simple ways to ascertain the operative mode
of wear is through the estimation of the specific wear
coefficient K,22,28,29 which is expressed as
K~WR
HV
FN
(1)
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a worn surface of QT; b worn surface of QCT; c wear debris QT, d wear debris of QCT, inset at higher magnification of
same; e EDX profile of the area marked as 1 in wear debris of QT in c; f EDX profile of the area marked as 2 in wear
debris of QCT in d
4 Typical secondary electron SEM micrographs and EDX proles of worn surfaces and wear debris tested at
FN558?86 N
than that for the QCT specimen (Table 3); so the mode of
wear is different for QT and QCT specimens at this
intermediate load.28,29 The mode of wear changes from
mild to severe at a characteristic FN value, popularly
termed the T1 transition, in the dry sliding wear of steel at
a constant sliding velocity.21,22 The results in Table 3
suggest that the FN529?43 and 117?72 N are lower and
higher than the characteristics T1 transition values for
both QT and QCT specimens, whereas FN558?86 N is
higher than the T1 transition for the QT specimen, but
lower than that for the QCT specimen.
At FN529?43 N, the worn surfaces of both QT
(Fig. 3a) and QCT (Fig. 3b) specimens are almost
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covered by a compact oxide layer (Fig. 3d). A representative micrograph (Fig. 3c) of the oxide depleted
regions of the worn surfaces (Figs. 3a and 3b) reveals the
presence of groove marks, cracking and pull out of PCs.
The wear debris of these QT and QCT specimens in
Figs. 3e and 3f exhibit fine granular oxide particles.
These observations suggest that the mechanism of wear
at FN529?43 N for both QT and QCT specimens is
predominantly oxidative coupled with cracking and pull
out of PCs and are similar in nature.30 However, the
fraction of area of worn surface covered by the compact
oxide layer is higher (Fig. 3) and the generated debris is
finer (Table 3) for the QCT specimens than that for the
Das et al.
a macrograph of worn surface of QT; b macrograph of worn surface of QCT; c micrograph of worn surface of QT, d
micrograph of worn surface of QCT; e wear debris of QT; f wear debris of QCT
5 Typical secondary electron SEM macro- and micrographs of worn surface, and micrographs of wear debris tested at
FN5117?72 N
respectively. These observations suggest that the operative wear mechanisms are different for the QT and the
QCT specimens at FN558?86 N. These are oxidative30
wear for the QCT specimens and delaminative31 wear
for the QT specimens. Under this test condition, the WR
and K for the QT specimen compared with the QCT
specimen is higher by an order of magnitude and the
estimated value of b is 53?2 times.
Examinations of the morphology of the worn surfaces
and the generated debris of both QT and QCT specimens at FN5117?72 N reveal: (i) extrusion of subsurfaces in the sliding direction (Figs. 5a and b), (ii) a rough
metallic nature (Figs. 5c and d) and (iii) large metallic
platelets (Figs. 5e and f). These observations indicate
that the operative wear mechanism for both QT and
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Conclusions
The experimental results and their pertinent analyses
result in the following major conclusions:
1. Incorporation of deep cryogenic processing in
between conventional hardening and tempering treatments (QCT) improves the wear resistance of D2 steel
compared with that of conventionally treated (QT)
specimens. However, the degree of improvement in wear
resistance (b) by cryotreatment is strongly dependent on
the applied load, which determines whether the operative mode and mechanism of wear for both QT and QCT
specimens would be similar or dissimilar.
2. At the sliding velocity of 2 m s1, the operative
modes and mechanisms of wear for both the QT and
QCT specimens are mild and oxidative at normal loads
(FN) of 29?43 N, whereas at FN5117?72 N these are
severe and delaminative. The values of b at these test
conditions are 2?2 and 1?6 times, respectively. When the
wear tests have been carried out at FN558?86 N, QCT
specimens exhibited mild and oxidative wear in contrast
to severe and delaminative wear illustrated by the QT
specimens; the corresponding value of b is 53?2 times.
3. Correlation of wear resistance with the corresponding microstructures indicates that the improvement in
wear resistance by cryotreatment is due to the nearly
complete removal of soft retained austenite with a
concurrent increase in the amount of hard secondary
carbides and tough tempered martensite.
Acknowledgement
The financial assistance received from the University
Grants Commission, Government of India [Grant no. F.
No. 31-48/2005(SR)] to carry out a part of this research
is gratefully acknowledged.
References
1. V. Firouzdor, E. Nejati and F. Khomamizadeh: J. Mater. Proc.
Tech., 2007, 186, 298303.
2. A. J. Vimal, A. Bensely, D. Mohan Lal and K. Srinivasan: Mater.
Manuf. Process, 2008, 23, 369376.
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