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9701 CHEMISTRY
9701/42
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2013 series for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level components and some Ordinary Level
components.
Page 2
1
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
42
(a)
8 e- around chlorine
1 Helectron (+) on the Cl - ion
3 covalent (ox) and one dative (oo) around N
[1]
[1]
[1]
[3]
[1]
[1]
(iii) CaO absorbs more water or CaO has greater affinity for water
[1]
[3]
[1]
[1]
[1]
[1]
[4]
[Total: 10]
Page 3
2
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
42
[1]
[1]
[2]
[1]
[1]
[1]
[1]
[4]
[Total: 6]
Page 4
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
42
[1]
[1]
[1]
[1]
[4]
[1]
[1]
[2]
[1]
[1]
[1]
[1]
[1]
[5 max 4]
(d) (i) [H+] = (0.5 1.34 10-5) = 2.59 10-3 (mol dm-3)
pH = 2.59/2.6 (min 1 d.p)
[1]
ecf
[1]
[1]
[1]
[1]
ecf
[1]
[6]
(e) G is CH3CH2COCl
H is SOCl2 or PCl5
J is NaCl
(or corresponding Br compounds for G, H and J; CH3CH2COBr, SOBr2, NaBr)
[2]
[Total: 18]
Page 5
4
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
42
[1]
[1]
[2]
[1]
[1]
(ii) (as the bond energy of C-X decreases) the halogenalkanes become more reactive
(answer must imply that it is from F to I)
[1]
[3]
(c) The C-Cl bond is weaker than the C-F and C-H bonds
or C-Cl bond (E = 340) and C-H (E = 410)
[1]
[1]
[1]
[3]
(d) Cl-CH2CH2-CO2H
HO-CH2CH2CH2-Cl
[1]
[1]
OH
Br
[1]
[3]
(e) (i) light/UV/h or 300C
[1]
[1]
[1]
ecf
[1]
[1]
[1]
[1]
[1]
[8]
[Total: 19]
Page 6
5
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
42
[1]
(ii) addition
[1]
(iii) C=C/double/ bond is broken and new C-C single bonds are formed
or double bond breaks and forms single bonds with other monomers
[1]
[3]
[1]
[1]
(c) (i)
[1]
[1]
[1]
[1]
[4]
(d) (i)
Any four:
hydrogen bond labelled
water H-bonded to O through H atom
+/- shown on each end of a H-bond
lone pair shown on O- or C=O or H2O on a correct H-bond
Na+ shown as coordinated to a water molecule
(ii) Solution became paler and Cu(2+) swapped with Na(+)
or darker in colour and polymer absorbs water
[3]
[1]
[4]
Page 7
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
42
[2]
(ii) NH3
[1]
(iii) H2O
[1]
[1]
[5]
[Total: 17]
Page 8
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
42
Section B
6
[1]
(ii)
[1]
[1]
[1]
2 [1]
[6]
[1]
[1]
[1]
(iii)
[1]
[4]
[Total: 10]
Pa
age
e9
7
Ma
ark
k Sch
S hem
me
e
GCE
E A LEV
VEL
L Octo
O ob
ber//No
ove
em
mbe
er 2
201
13
Syllab
bus
s
97
701
1
Pa
ape
er
4
42
(
(a)
pow
p
werr su
upp
ply
y (id
dea
a of
o com
c mpllete
e circ
c uit)
e ctro
elec
oly
yte//bu
uffe
er solu
s utio
on
g /filtter pa
gel/
ape
er/a
abs
sorrbent pa
ape
er
(am
mino
o acid
a d) sam
s mp
ple//miixtu
ure
e [c
cen
ntre
e off plate
e]
4 [1]
4]
[4
( ) a
(b)
anyy tw
wo fro
om::
s e/M
size
Mr (of
( the
ea
amiino
o ac
cid sp
pec
cies
s)
c arge
cha
e (on the a
am
mino
o acid
a d specie
es)
te
em
mpe
eraturre
2 [1]
[2
2]
(
(c)
Rattio of the
R
e con
c nce
entrratiion
n off a so
olutte in e
eac
ch of two
o (immis
sciible
e) ssolvents
s
o e
or
equ
uilib
briu
um
m co
ons
sta
ant rep
pre
ese
enting
g th
he dis
strib
buttion
no
of a so
olu
ute be
etw
wee
en two
t o solv
ven
nts
o P
or
PC = [X]]a/[X
X]b (a
at a consta
ant temp
perratu
ure
e)
[1]
[1]
( ) (i)
(d)
(
Kpc = [Z
Z in e
ether]]/[Z
Z in
n H2O]
O allow
w reve
ers
se rattio
40
0 = (x
x/0.05
5)/(((4
x))/0.5))
= 3.2 g
(ii) Firstt ex
xtrracttion
n
40
0 = (x
x/0.02
25))/((4
4x
x)//0.5
5)
x = 2.6
2 67 g
[1]
e f
ecf
[1]
e f
ecf
[1]
e f
ecf
[1]
(iii) Sec
cond ext
e trac
ctio
on: 1.33
3g rem
r maiin in
i ssolutio
on
Sec
cond ext
e trac
ctio
on
40
0 = (y
y/0.02
25))/((1.3
33
y)/0.5)
y = 0.8
0 887
7g
mas
m ss ext
e traccte
ed = 2.67
2 7 + 0.89
9 = 3..56
6/3..6 g
4]
[4
[To
ota
al: 11]
Ca
amb
brid
dge
e In
nterrnattion
nal Ex
xam
mina
atio
ons
s 20
013
3
Page 10
8
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
42
[1]
[1]
SO4(2-)
[1]
[1]
[4]
[1]
[1]
[1]
[3]
[1]
[1]
[2]
[Total: 9]