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Briones
Hope Louis Simbrio
BS in Chemistry III
Experiment No. 9
Distillation of an Azeotropic Mixture
I.
Calibration Curve
1.55
1.50
1.45
benzene
Refraction Index
f(x) = 0.12x
- 0.12x
++
1.37
1.49
R = 0.99
Linear (benzene)
IPA
Linear (IPA)
1.40
1.35
1.30
0.00
0.20
0.40
0.60
0.80
mole Fraction
Sample Calculations:
Calibration Curve:
Data:
density Benzene
(g/ml)
density IPA (g/ml)
MW Benzene
(g/mol)
MW IPA (g/mol)
Mass of benzene =
0.8765
0.786
78.11184
60.09502
1.00
1.20
= 0.0000
Mass of IPA =
= 1.5720 g
Mole of Benzene =
=
mass of benzene
M W of benzene
0.0000 g
78.11184 g /mol
= 0 mols
mass of IPA
MW of IPA
Mole of IPA =
1.5720 g
60.09502 g/ mol
= 0.02616 mols
Mole of benzene
Mol e of benzene+ mole of IPA
X Benzene =
0.0000 mol
0.0000mols +0.02616 mols
=0
X IPA =
Mole of IPA
Mole of benzene +mole of IPA
0.02616 mols
0.0000mols +0.02616 mols
= 1.0000
y = -0.1221x + 1.4938
x = mole fraction = -(y 1.4938)/ 0.1221
Distillation Curve
T
E
M
P
E
R
A
T
U
R
E
355
350
Residue
Distillate
345
Residue 2
Distillate 2
340
335
0.0
0.2
0.4
0.6
0.8
1.0
1.2
ISOPROPYL DISTILLATION
TRIAL
Boiling Temp(K)
1
353.0
2
346.5
3
344.5
4
343.0
5
342.8
6
341.0
Refraction Index
Residue Distillate
1.3764
1.3760
X Benzene
Residue
Distillate
0.03931
0.03604
X benzene (residue) =
X benzene (distillate) =
X Isopropyl Alcohol
Residue
Distillate
0.96151
0.96478
1.37641.3716
= 0.03931
0.1221
distillate ( refractive index )1.3716
0.1221
= 0.03931
1.37641.4938
0.1221
X IPA (distillate) =
=
= 0.03604
X IPA (residue) =
=
1.37601.3716
0.1221
= 0.96151
1.37601.4938
0.1221
= 0.96478
Distillation Curve
T
355
E
M
350
P
E
345
R
A
340
T
U
335
R
-0.2
0.0
E
Residue
Distillate
Residue 2
Distillate 2
0.2
0.4
0.6
0.8
1.0
1.2
BENZENE DISTILLATION
TRIAL
Boiling Temp(K)
1
353
2
345
3
343
Refraction Index
Residue Distillate
X Benzene
Residue
Distillate
X Isopropyl Alcohol
Residue
Distillate
1.4962
1.4564
1.4539
1.4978
1.4764
1.4561
1.02048
0.69451
0.67404
X benzene (residue) =
1.49781.3716
0.1221
1.49621.4938
0.1221
X IPA (distillate) =
II.
= 1.02048
= 1.03358
X IPA (residue) =
-0.03276
0.14251
0.30876
-0.01966
0.30631
0.32678
1.49621.3716
0.1221
X benzene (distillate)
1.03358
0.85831
0.69206
= 0.01966
1.49781.4938
0.1221
= 0.03278
Discussion
Binary mixtures of two volatile liquids exhibit a range of boiling behavior from
ideal, with a simple continuous change in boiling point with composition, to
nonideal, showing the presence of an azeotrope and either a maximum or minimum
boiling point. In this experiment, the properties of a binary mixture of benzene and
isoprpyl wasobserved by studying the change in boiling point with composition. a
boiling point diagram was constructed and any nonidealbehaviour was identified in
the system.
For ideal mixtures of liquids, the composition of the vapor phase is always
richer in the component with the higher vapor pressure. According to Raoult's Law,
the vapor pressure of component A is given by
III.
Conclusion