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Prelim course:
8.2 Chemical Earth:
1) The living and non-living components of the Earth contain mixtures
Biosphere
Definition
Is inhabited by and
sustains living matter.
The lower part of the
atmosphere, the
hydrosphere, and the
lithosphere to a depth
of about 2 kilometres.
Elements
nitrogen
(78%),
oxygen
Hydrospher
e
Compounds=Water,Carbon
Dioxide/Monoxide and Nitrogen exist.
Mixture = Air
Dissolved O2 and N2
Salt
water
is
mixture
of
the
Number of Carbons
Meth
Eth
Prop
Bute
Pent
Hex
Hept
Oct
Non
Dec
1
2
3
4
5
6
7
8
9
10
Suffix
-ane
-ene
-yne
Formula
CnH2n+2
CnH2n
CnH2n-2
2) Although most elements are found in combinations on Earth, some elements are
found uncombined
Metals
Non-Metals
Lustre
Usually
lustrous
High (solids at
room temp)
Usually Dull
Semi
Conductors
Variable
High
Typically
Low( gas/liquid at
room temp)
Low(as they are
usually gas/liquids)
No
No(except Graphite)
Yes
No
Variable
Variable
Variable
Slight
Maximum number of
electrons
2
8
18
32
C12.01
atomic mass
Therefore the number of protons in carbon is 6 and the number of neutrons is 6 (126). The number of neutrons equals the number of electrons. Therefore it has 6 protons,
6 neutrons and 6 electrons.
Group 1 Metals lose 1 electron in ionic reactions and become +1 ions, Group 2 lose 2
electrons and so forth, until you reach group 4 which cannot form ions. Group 5 gains
3 electrons and becomes a -3 ion, whilst group 6 gains 2 forming a -2 ion. Group 8
cannot form ions as it has full shells and is stable.
Cations = positive ions (groups <4)
Anions= negative ions (groups >4)
Industrial Example
Decomposition of
limestone to form lime
Light
Decomposition of silver
bromide in photographic
paper
Production of aluminium
through electrolysis
Electrical
Everyday Example
Decomposition of baking
soda to form carbon
dioxide in baking
Production of sugars and
oxygen during
photosynthesis
Synthesis of nitrogen oxide
by lightning strikes
5. The properties of elements and compounds are determined by their bonding and
structure
Chemical Properties
Does not burn, no reaction
with water and hydrogen
Sodium
Ionic
Network covalent
Crystalline
All
Good
Covalent
molecular
Water (H20)
Variable
Dull if solid
Variable
Low to medium
Varies, but
generally soft
Shapeless
Slightly soluble
Bad
Example
Physical state
Appearance
Colour
Density
Hardness
Salt(NaCl)
Solids
Powder/crystals
Variable
Medium
Hard/brittle
Structure
Solubility in Water
Electrical
conductivity of
solutions
Thermal
conductivity
Melting point
Poor
Poor
Good
High
Generally low
High
Sand(SiO2)
Solids
Shiny
Silvery
Medium
Hard/brittle
Crystalline
Insoluble
n/a
Na + Cl NaCl
Covalent bonding This occurs when the two electrons share their joint electrons to
complete their outer shell, this can be seen with most gases.
O + O O2
Metallic bonding This is the same as covalent bonding, however instead of the
electrons being shared with its immediate neighbours it is shared by ALL of the
atoms. This is why metallic bonded compounds can conduct electricity.
This occurs in a piece of metal, so equations arent necessary.
Example Conductivity
Sodium High(when
Chloride molten/dissolved)
(NaCl)
Reason
When molten
the electrons
are free to
move around,
Hardness
Hard,
Reason
The Strong bonds
between the cations
and Anions mean
that very strong
Covalent
Molecular
Water
(H2O)
Low
Covalent
Lattice
Silicon
Dioxide,
(SiO2)
Low
however when
it is not the
electrons are in
a fixed position
No delocalised
Electrons
No delocalised
Electrons
8.3 Metals
1) Metals have been extracted and used for many thousands of years
Gold: Has been used for jewellery and coinage, due to its lustre and rarity. It has also
been used in circuits for its high conductivity.
Silver: Has been used for Jewellery, due to its malleability and lustre.
Bronze: Used for jewellery, wiring and cooking utensils. This is because it has a high
shine, and high conductivity.
Iron: Used for buildings. Iron is very strong, and malleable (at high heats)
Alloy
Industrial
Steel
Brass
Made up of
Iron, carbon
Uses
Building
Copper, Zinc
Lead Solder
60% Tin,
40% Lead
Iron, Nickel
Instruments, coins,
decorative
Electrical circuits, joining
metal piping
Cutlery
Stainless
Steel
Properties
Extremely strong and
hard, cheap
Very Malleable, cheap,
non corrosive
High conductivity, low
M.P. ,soft
Non corrosive, high M.P.,
hard, strong
- Identify why there are more metals available for people to use now
than there were 200 years ago
200 years ago, technology was a lot less sophisticated than what it is today. This
means that they would not have been able to produce such high amounts of energy, to
help separate metals. As metals are stronger and stronger bonded, more energy is
required meaning that it is less likely that there was enough technology for the
minimum amount of energy to be produced.
The Bronze alloy is relatively easier to produce (through heating copper and tin) than
extracting iron from its ore (puddling a molten mixture of iron ore/slag Therefore
more metals and alloys were/are produced today due to the increase in quality and
quantity of technological developments and scientific understanding. There are also
sophisticated methods of extracting ores, such as extracting titanium, which is done
by reacting titanium tetrachloride with sodium, inside a heated steel bomb.
2. Metals differ in their reactivity with other chemicals and this influences their uses.
- Describe and justify the criteria used to place metals into an order
of activity based on their ease of reaction with oxygen, water and
dilute acids
The more violent the reaction, the more reactive and thus the higher the position of
the metal in the electrochemical series
The degree of reaction with oxygen can be used to identify the most reactive metals
(less reactive metals do not react)
Metals of moderate reactivity can be determined by their reactivity with water (less
reactive metals do not react)
Metals that are relatively unreactive can be determined by their reactivity with dilute
acids (less reactive metals do not react)
4. For efficient resource use, industrial chemical reactions must use measured amounts
of each reactant.
C2H8 Ethane
CH4 empirical Formula (the ratio cannot get any simpler)
C2H8 Molecular Formula (The ratio that the particles in the molecule)
5. The relative abundance and ease of extraction of metals influences their value and
breadth of use in the community
- Define the terms mineral and ore with reference to economic and
non-economic deposits of natural resources
Mineral: A naturally occurring substance which has been formed through geological
processes and has characteristics of a chemical composition
Ore: An economically viable rock which contains minerals.
Recycle
Sorted
Heated
Cast
Rolled
Moulded
8.4 Water:
1. Water is distributed on Earth as a solid, liquid and gas
Description of
Sphere
State of Abundance
Water
of Water
Lithosphere
Liquid,
solid
<10%
% of
Earths
water
0.6%
Liquid,
solid
Gas,
Liquid,
solid
Gas,
Liquid,
solid
>95%
>99%
0.5%-5%
0.0001%
60-90%
0.0001%
Distribution
Found as
ground water
and ice(on
mountain tops)
In the oceans,
glaciers
Found as rain,
water vapour
and hail
Within
organisms, in
habitats( such
as lakes, water
vapour and
glaciers)
Water is a versatile substance used for recreation, irrigation, electricity generation and
drinking.
2. The wide distribution and importance of water on Earth is a consequence of its
molecular structure and hydrogen bonding
A polar molecule is a molecule which has a net dipole. That means that
one side of the molecule will have stronger dispersion forces applied to
it than another side. This can be seen in water (as seen in diagram).
Viscosity is the ability for a liquid to flow. Viscosity is determined by 2 things. Molecular
size and complexity, (the larger the molecule the higher its viscosity) and strength of
intermolecular forces (The stronger the intermolecular forces the higher the viscosity).Since
water is an extremely small molecule, and when compared to other molecules its size the
intermolecular forces are high, this means that water is relatively high.
-Boiling and melting points
Boiling and melting points are determined by the intermolecular forces of the molecules.
Because water has 2 hydrogen bonds and a relatively high polarity it means that it has a high
M.P. and B.P. for its molecular size.
3. Water is an important solvent
4.The concentration of salts in water will vary according to their solubility, and
precipitation can occur when the ions of an insoluble salt are in solution together.
Exceptions
Compounds that
are insoluble
Carbonates
Exceptions
Phosphates
Ag+ Pb+2
Hydroxides
Oxides
Nitrates
Chlorides ,
Bromides and
Iodides
Sulphates
Sr+2, Ca+2
Common Precipitates:
AgCl
PbSO4
Using the Change in Enthalpy we can find how many degrees a substance has
increased by. This can then tell you how many joules the reaction has created.
Endothermic reactions ABSORB heat, this is because the bonds that are broken are not as
strong as the bonds that are created, this means that energy is needed from the environment to
help the reaction work. An example of this would be ammonium nitrate and potassium
chloride.
8.5 Energy:
1. Living organisms make compounds which are important sources of energy
Photosynthesis is one of the most important chemical reactions. This is because this is
the only way that light energy is converted into chemical energy and stored as
glucose. The formula for photosynthesis is represented by 6CO2 + 6H2O C6H12O6 +
6O2. This formula shows that photosynthesis is endothermic and also shows that it
forms a Carbohydrate.
-
Photosynthesis is used to change light energy (from the sun) into chemical potential
energy (carbohydrates). Photosynthesis uses the suns energy to change carbon
dioxide and water to glucose and oxygen. Using high energy carbohydrates also
means that you are able to store energy much more efficiently. It also means that it is
going to be a long term fuel storage system.
-
The three main fossil fuels are coal, petroleum and natural gas. Coal is made up of
plants that have been buried in swamps and compressed into pure carbon. Petroleum
and Natural gas are both originated from marine plankton and bacteria, which is then
heated under high temperatures and pressure. Fossil fuels contain large amounts of
chemical energy. This means that all the energy found in fossil fuels is derived from
plants. Plants get there energy from the sun thus all energy in fossil fuels is derived
from the sun.
2. There is a wide variety of carbon compounds.
Carbon is the 6th element on the periodic table. It is in Group 4 and Period 2. Its electron
configuration is 2, 4.
Allotrope: a structural variant of an element. It has different bonding patterns which lead to
different physical and chemical properties.
Diamond
Graphite
Conducts Electricity
Soft
Layers (held by dispersion forces)
Hydrocarbons are a great example. Alkanes form carbon-carbon single bonds, alkenes
form carbon-carbon double bonds and alkynes form carbon-carbon triple bonds.
-
Carbon atoms have four valence electrons capable of forming four covalent bonds and
can form single, double or triple bonds with itself. Carbon-carbon bonds are strong
and not easily broken. There are numerous compounds containing carbon-carbon
bonds e.g. hydrocarbons, allotropes of carbon. There are several million organic:
carbon-based molecules have been discovered.
-
The M.P. and boiling points of hydrocarbons goes up as there overall mass increases.
All forms of hydrocarbons except the ynes are non polar. Alkanes have a higher
boiling point than Alkenes (this is because of the higher Molar mass). Alkenes are
more reactive because they contain a double bond.
-
Because Alkanes are extremely flammable it is suggested that they should be kept
well away from naked flames or cigarette butts. It is also recommended that they are
kept under high pressure (to remove the problems of flash point).
4. Combustion provides another opportunity to examine the conditions under which
chemical reactions occur
Complete combustion produces both carbon dioxide and water vapour. CO2 is a
greenhouse gas. Incomplete combustion produces carbon monoxide, carbon dioxide,
particulate carbon and water vapour. CO is harmful to humans and the environment.
When hydrocarbon fuels burn they produce many pollutants, some of which assist in
the formation of photochemical smog. Catalytic converters in car exhaust systems
break down CO and hydrocarbons into CO2 and H2O.
5. The rate of energy release is affected by factors such as types of reactants
Slow: not enough air/oxygen to combust substance quickly. E.g. rust. Spontaneous: A
slow build up to the combustion of a substance. E.g. Liquid ethanol. Explosive: fast,
uncontrolled combustion reactions. E.g. Methane leaking from a gas tap.
-
For a reaction to occur, particles must collide. The more successful collisions i.e.
where a chemical reaction takes place, the faster the rate of chemical reaction. The
rate of reaction is directly proportional to the concentration of reactant particles.
Average energy of collision and orientation of collision are two important factors
in the rate of chemical reactions.
-
Vanadium (V) oxide. It is a very important chemical, used as a catalyst in the manufacture of
sulphuric acid, which is produced in massive quantities around the world for various chemical
and industrial purposes.
When the particles get hotter, it means that they move faster, increasing the possibility of a
productive collision.
Catalysts are used to lower the activation rate. This means that it is more likely of chemical
reactions to occur. Catalysts lower the activation energy by increasing the number of
particles that collide with favourable orientation, attract reactant particles to its
surface thus increasing reactant concentration, increase the reactivity of reactant
molecules and provide a series of low activation energy reactions to form products.