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AMAL KEBAJIKAN ( BUFFER, TITRATIONS & SOLUBILITY)

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1. Identify which of the following mixed systems could function as a buffer solution. For
each system that can function as a buffer, write the equilibrium equation for the
conjugate acid/base pair in the buffer system;
59.
i.

KF/HF
60.
61.
NH3/NH4Br
62.
63.
KNO3/HNO3
64.
65.
Na2CO3/NaHCO3

ii.
iii.
iv.
66.
67.

2. What is the pH of a buffer solution containing 0.500 M CH 3COONa and 0.800 M

CH3COOH?
68.
(Ka CH3COOH = 1.74 105)?
69.
70.
71.
72.
73.
3. What is the pH of the solution obtained when 41g of CH 3COONa is dissolved in 1L of
0.800 M CH3COOH (pKa CH3COOH = 4.76)?
74.
75.
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77.
78.
79.
4. What is the pH of the buffer solution obtained when 100 cm 3 of 0.100 M CH3COOH is
mixed with 20cm3 of 0.300 M CH3COONa solution? The Ka for acetic acid is 1.7 x 10-5.
80.
81.
82.
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84.
85.
5. A buffer solution was made by dissolving 10.0 grams of CH3COONa in 200.0 mL of 1.00
M CH3COOH. Calculate the pH of the acetic acid/sodium acetate buffer solution.
The Ka for acetic acid is 1.7 x 10-5.
86.
87.
88.
89.
90.
6. 50.0 mL of 0.100 M HCl was added to a buffer consisting of 0.025 moles of CH3COONa
and 0.030 moles of acetic acid. What is the pH of the buffer after the addition of the
acid?
Ka of acetic acid is 1.7 x 10-5.
91.
7.
92.

Calculate the pH of a buffer which is 0.2 M with respect to ammonium sulphate and
0.1 M with respect to ammonia. (Ka of NH4+ = 5.6 x 10-10)

93.
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96.
8.

Methanoic acid, HCOOH, has a Ka value of 1.58 x 10-4 M. What ratio of methanoic acid and
sodium methanoate would give a buffer of pH = 4?

97.
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105.
What is the pH of a 1 L solution containing 0.240 mol HC 2H3O2 and 0.180 mol NaC2H3O2?

9.

Ka(HC2H3O2) = 1.8 x 10-5

106.

107.

108.

i.

Calculate pH if 0.010 mol of HCl were added?

ii.

Calculate pH if 0.010 mol of NaOH were added?

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10.

What would be the ratio of [conjugate base] to [conjugate acid] for a solution of citric
acid, if the pH of the solution was 3.00. Would such a solution act as a buffer?
Ka H3C6H5O7= 6.4 x 10-6

121.
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124.
11. Calculate the pH of 0.12 moldm-3 ethanoic acid (Ka = 1.7 x 10-5).
125.
126.

127.
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129.
i.
Calculate the mass of sodium ethanoate (CH 3COONa) which must be added to 500
cm3 this solution to give a buffer solution of pH = 4.60.
130.
131.
ii.

Calculate the pH of this solution after 0.01 moles of HCl are added.

iii.

Calculate the pH of this solution after 0.01 moles of NaOH are added.
135.
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138.

132.
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12.

Calculate the pH of a buffer solution which is 0.1 M with respect to HCN (K a = 4.9 x 10-10)
and 0.8 M with respect to sodium cyanide.

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145.
i.

Calculate the pH after 0.05 moles of HCl are added to this buffer.

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149.
ii.
Calculate the pH after 0.05 moles of NaOH are added to this buffer.
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13.
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Suppose that you had a solution that was 0.165 M HOCl. Given that K a = 3.0x10-8
i.
What is the pH of the solution?

156.
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ii.

What would be the new value for the pH for the solution if 14.3 grams of Ca(OCl) 2
was added to 1.0 L of the solution?

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162.
Would the value of the [H3O+] increase, decrease or stay the same in the 0.165M
HOCl solution if 0.74 grams of Ca(OH)2 was added to 1.0 L of the solution?
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170.
A buffer contains 0.20 M HCHO2 and 0.3 M NaCHO2. Volume of the solution is 125 mL.
Ka HCHO2= 1.8 x 10-4.
i.
What is the ph of this buffer solutions?
iii.

19.

171.
172.
173.
ii.

If 50.0 mL of 0.10 M NaOH added to the buffer solution, what is the pH?

iii.

If 50.0 mL of 0.10 M NaOH added to the buffer solution, what is the pH?

174.
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178.
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14.
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182.

What is the pH of a 1 L solution containing 0.240 mol HC 2H3O2 and 0.180 mol NaC2H3O2?
Ka(HC2H3O2) = 1.8 x 10-5.

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198.

i.

What would be the pH if 0.010 mol of HCl were added to this buffer?

ii.

What would be the pH if 0.010 mol NaOH were added to this buffer?

199.
20.

What is the pH of 50.00 mL buffer solution which is 2.00M in HC 2H3O2 and 2.00M in
NaC2H3O2

200.
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205.

i.

What is the new pH after 2.00 mL of 6.00M HCl is added to this buffer ?

ii.
212.

What is the new pH after 2.00 mL of 6.00M NaOH is added to this buffer?

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15.

Calculate the pH of a buffer solution which contains the weak monoprotic acid,
propanoic acid (CH3CH2COOH), in concentration 0.1 M and sodium propanoate in
concentration 0.05 M.
Ka of propanoic acid is 1.26 x 10-5.

215.
i.

Calculate the pH of the solution after 0.01 moles of NaOH are added to 500 cm 3
of the solution.

ii.

Calculate the pH of the solution after 0.01 moles of HCl are added to 500 cm 3 of
the solution.

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1. Write the solubility product expression for the following:
a. PbI2(cr)

Pb2+(aq)
+
2I-(aq)
223.
b.
Cu3(PO4)2(cr)

3Cu2+(aq)
+
2PO432. The solubility product constant for silver iodide is 8.32 x 10 -17. What is the silver ion
concentration?
224.
3. If [D+] is 2.00 x 10-5M at equilibrium, what is the Ksp for D2A?
225.
4. What is the concentration of beryllium ions in a saturated solution of beryllium
hydroxide? Ksp = 1.58 x 10-22
226.
5. A saturated solution of lead iodide has a lead ion concentration of 1.21 x 10 -3M. What is
the Ksp for lead iodide?
227.
6. What is the solubility (M) of AgBr if the Ksp is 5.0 x 10 -13?
228.
7. If the solubility of Li2CO3 is 0.15M, what is its Ksp at this temperature?
229.
8. What is the solubility (M) of PbI2 is the Ksp is 8.5 x 10-9?
230.
9. If the solubility of Ag2CrO4 is 7.2 x 10-5M, what is the Ksp?
231.
10.How many moles of AgCl will dissolve in 500.ml of water if the Ksp =0.7 x 10 -10?
232.
11.The solubility product constant for lead iodide is 7.08 x 10 -9. What is the lead ion
concentration?
233.
12.If [Ag+] is 1.33 x 10-5M at equilibrium, what is the Ksp for AgCl?
234.
13.What is the concentration of aluminum ions in a saturated solution of aluminum
hydroxide? Ksp = 1.26 x 10-33
235.
14.A saturated solution of lead iodide has a lead ion concentration of 1.21 x 10 -3M. What is
the Ksp for lead iodide?
236.
15.Find the Ksp of BaCl2 if 0.095 grams can be recovered from 1.0 liter of a saturated
solution.
237.
16.If the Ksp of CuCO3 is 1.7 x 10-7, how many grams could be recovered from 2.0 liters of a
saturated solution?
238.
17.You add 1.0 g of Na2CO3 is added to 1.0 liters of a saturated solution of barium
carbonatecalculate the [Ba+2] when equilibrium is re-established.
239.
18. You add 2.2 g Na2CO3 is added to 2.0 liters of a saturated solution of magnesium
carbonatecalculate the [Mg+2] when equilibrium is re-established
(Ksp for magnesium carbonate is 6.82 x 10-6)
240.
19. If 1.00 liter of 0.0200M NaCl is added to 1.00 liter of 0.0100M AgNO 3. Will a precipitate
of AgCl form?
241.
20. 0.0216 grams of silver nitrate is added to 1.0 liter of 2.0 x 10 -3M Na2Cr2O7 solution.
Does Ag2Cr2O7 precipitate form?
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