Professional Documents
Culture Documents
4.
5.
6.
7.
c.
Selesaikan perhitungan berikut yang terkait dengan garam yang ada di dapur rumah Sdr. :
a. Hitung berapa %berat NaCl yang dibuat denga melarutkan 20g NaCl dalam 55g air.
b. Hitung berapa gram NaCl yang terdapat dalam 500g NaCl 16% berat.
c. Hitung fraksi mol NaCl dan fraksi mol H2O dalam larutan 117 g NaCl dan 3 kg H2O.
d. Seorang mahasiswa mencampurkan 3,5 L NaCl 0,15 M dengan 5,5 L NaCl 0,175 M
dan memperoleh larutan sebanyak 9 liter. Hitung konsentrasi akhir larutan tersebut.
e. Suatu larutan dibuat dengan melarutkan 15,2 g NaCl dalam 197 g air. Larutan ini
mempunyai berat jenis 1,012 g/ml. Hitung fraksi mol, molalitas dan molaritas NaCl.
f. Bagaimana cara membuat membuat larutan 1,2 molar dan 1,2 molal larutan NaCl
dalam air. Coba lakukan di dapur Sdr. Bisa tidak ? Apa yang perlu diasumsikan ?
d.
Kasus berikut terkait dengan satuan konsentrasi yang sering digunakan di lapangan:
a. Berapa gram pupuk natrium fosfat yang diperlukan untuk membuat 20 mL larutan
pupuk 9% mg (9% mg coba search di google.).
b. Hitung konsentrasi Na+ dalam %mg, jika 5 mL darah mengandung 0,14mg Na+.
c. Hitung jumlah miliekivalen ion Ca2+ yg terdapat dlm 100mL darah 0,1% (W/V) Ca2+.
d. Hitung berapa mg ion K+ yg terdapat dalam cuplikan darah yang mengandung 2,5 m
ekuivalen ion K+.
e.
Tekanan uap eter (Mr 74) adalah 442 mmHg pada 293 K. Jika 3 g senyawa A dilarutkan ke
dalam 50 g eter pada temperature ini, tekanan uap menjadi 426 mmHg. Hitung massa
molekul relative (Mr) senyawa A.
f.
Kalau Sdr. pernah tinggal di daerah yang mengalami musim dingin atau musim salju, anda
akan melihat jalanan ditaburi dengan garam. Apa gunanya tindakan tersebut ? Teori apa,
terutama yang ada dalam bab ini, yang bisa membenarkan tindakan tersebut ? Kalau Sdr.
belum pernah tinggal di daerah demikian, coba taburkan garam di freezer kulkas Sdr. Apa
yang terjadi ?
g.
h.
i.
j.
k.
l.
m.
n.
o.
p.
q.
r.
s. Jawaban bab 5
t.
1. Defenisi ada di buku
u.
v. 2.A.
w.
x. Solution
y. From the given volume and concentration you can calculate how many
grams of
z. AgNO3 to weigh out :
aa.Wt. Of AgNO3 needed = (0.2500 liter) (0. 1250 moles AgNO3) A (169.9
g AgNO3)
ab.
1 liter
ac.
mole AgNO3
= 5.039 g AgNO3
ae. 2.b
af. Solution
ag.From the given volume and concentration of CuSO4 , you can calculate the
moles of CuSO4 required. Furthermore. The formula shows that 1 mole of
CuSO4 - 5H2O is required per mole of CuSO4. Thus the weigh(W) of CuSO4
5H2O needed is
ah. W=(0.100 liter) V=(0.2000 moles CuSO4) V=( mole CuSO4 5H2O) V=( g
CuSO4 5H2O)
ai.
1 liter
mole CuSO4
mole
CuSO4 5H2O
aj.
am.2.c
an.Solution
ao. You are given the molality of the solution adn the weight of the solvent.
From which you can find x, the number of moles of C10H8 needed.
ap.
aq.
= 2.00
ar.
0.0500 kg CCl4
as.
at.
au.
(128
mole C10H8
av.
= 12.8 g C10H8
aw.
To prepare the solution, dissolve 12.8 g C10H8 in 50.0 g CCl4. If you
knew that the density of CCl4 is 1.59 g/ml. You could measure out.
ax.
50.0 g
ay.
= 31.4 ml CCl4
1.59
az.
ml
ba. 2.d
bb.Solution
bc. You are given the mole fraction of sucrose and the moles of water
bd.
100 g
be.
18
bf.
= 5 55 moles
Mole
X moles sucrose
bj. Therefore,
bk.
bm.
bn.
mole sucrose
= 68 4 g sucrose
bq.
Cluster 3 : Equilibrium (Kesetimbangan)
br.
bs.Soal bahan diskusi kelas
bt. Bab VI. Kesetimbangan
bu.
bv.
1. Berikan contoh reaksi yang memenuhi hubungan berikut: Kp = Kc ; Kp = Kc
(RT) ; Kp = Kc (RT)-3; Kp = Kc (RT)5 .
bw.
bx.
2. (Prinsip umum) Suatu campuran gas H2 dan N2 pada suhu 450 C memiliki
ratio 3:1. Pada keadaan kesetimbangan campuran gas menjadi NH 3 9,6%, N2
22,6% dan H2 67,8% volume. Tekanan total adalah 50 atm. Hitung nilai Kp
dan Kc. Reaksi yang berlangsung adalah N 2 + 3H2 2 NH3.
by.
bz.
3. (Pengarus perubahan tekanan total pada Kp dan posisi kesetimbangan)
Nilai Kp untuk reaksi H2 + I2 2 HI adalah 54,4 pada 355 C. Berapa persen I 2
yang akan berubah menjadi HI, jika 0,2 mol H 2 dan I2 dicampurkan dan
dibiarkan mencapai kesetimbangan pada suhu 355 C dengan tekanan total
0,5 atm?
ca.
cb.
4. Dengan kasus yang sama dengan soal No. 3, berapa persen I 2 yang akan
berubah menjadi HI, jika 2 mol H2 dan 0,2 mol I2 dicampurkan dan dibiarkan
mencapai kesetimbangan pada suhu 355 C dengan tekanan total 0,5 atm?
cc.
cd.
5. (Persen dekomposisi gas) Nilai Kp pada suhu 250 C untuk reaksi PCl5
PCl3 + Cl2 adalah 1,78. Hitung persen PCl5 yang terdisosiasi jika 0,5 mol gas
tersebut dimasukkan dalam wadah tertutup pada suhu 250 C dan tekanan
total 2 atm.
ce.
cf.
cg.
ch.
ci.
cj.
ck.
cl.
cm.
cn.Jawaban no 2:
co.
cp. According to Daltons law of partial pressure, the partial pressure of a gas in a
mixture is given by the product of its volume fraction and the total pressure.
Therefore the equilibrium pressure of each gas is
cq.
cr. PNH3 = (0.096) (50.0 atm) = 4.8 atm
cs. PX
= (0.226) (50.0 atm) = 11.3 atm
ct. PHz = (0.678) (50.0 atm) = 33.9 atm
cu. Total pressure = 50.0 atm
cv. By subsitution in
cw.
cx. Use Equation below to calculate Kc, noting that An = (2 - 4) = -2.
cy. Note that the starting composition does not enter into the calculations, only the
cz. equilibrium composition.
da.
db.
Jawaban No 3
dc. Assume that X moles each of H2 and I2 are used up in reaching equilibrium
dd. to give 2X moles of HI, in accordance with the chemical equation, leaving
de. 0.20 - X moles each of H2 and I2. The partial pressure of each gas is given by the
df. product of its mole fraction and the total pressure (see p 163).
dg. Moles of H2 at equilibrium = 0.20 - X
dh. Moles of I2 at equilibrium = 0.20 X
di. Moles of HI at equilibrium = 2X
dj. Total moles at equilibrium = 0.40 - 2X + 2X = 0.4
dk.
dl. Taking the square root of each side, we obtain
dm.
dn.
X = 1.48 = 0. 157 = moles of H2 and I2 used up
do.
9.4
dp. Percentage conversion (yield) = 0.157 = 78.5%
dq.
0.200
dr. Jawaban No 4
ds. In this problem, it is advantageous first to assume that the large excess of H2 will
dt. use almost the entire amount of I2, leaving only A' moles of it unused. In general, it
du. is always advantageous to let X represent the smallest unknown entity because it
dv. often simplifies the mathematical solution. If A' moles of I2 are not used, then 0.20
dw.- X moles are used. For every mole of I2 used up, one of H2 is used up, and two of
dx. HI are formed. Proceeding as in the last problem, the number of moles of each
dy. component at equilibrium is
dz. moles of H2 = 2.00 - (0.20 - X) = 1.80 + X
ea. moles of I2 = X = X
eb. moles of HI = 2(0.20 - X) = 0.40 - 2X
94.3% dissociated. If Kp is very large (or very small), it means that the
equilibrium position lies far to the right (or to the left). In either of these cases
it is possible to choose X so that it will be very small and amenable to a
simplified mathsolution. The value of Kp for the PCl5 equilibrium is neither
very large nor very small, and hence it never will be possible to neglect X.
fi.
fj.
fk.
fl.
fm.
Cluster 3 : Equilibrium
fn.
fo.Soal bahan diskusi kelas
fp.Bab VII. Kesetimbangan Asam Basa
fq.
fz.
8. (Buffer-lanjutan) Berapa gram natrium asetat yang
mesti ditambahkan ke dalam 250 mL asam asetat 0,2 M
untuk membuat larutan penyanggah dengan pH = 5 ?
ga.
9. (Hidrolisis) (a) Hitung pH larutan garam natrium asetat
0,05 M ? Mengapa ada pH, padahal larutan garam ? Dari
mana ion H+ muncul di larutan tersebut ? (b) Berapa nilai
pH untuk larutan 0,1 M KHCO3 ?
gb.
gc.
gd.
ge.
gf.
gg.
gh.
gi.
gj. Solution
gk. Write the chemical equation, and above each term of the equation write the
equilibnum molar concertration. Because we are not given the H+ and C2H3O2gl.
gm.
Concertrations, and because the two are the same, we represent
this value by X This gives a concentration of (0 0500 X) mole/liter of
undissociated HC2H3O2 molecules, because 0 0500 mole of acid is put
into solution and v moles dissociate
gn.Substitute the molar concertrations into the K equation
go.To solve an equation of this type, we usually first assume v to be so small
that 0 0500 X may be considered as 0 0500 does not appreciably change
the value) This gives, as the simplified equation.
gp.You can see that X is much smaller than the original concertration of 0
0500 M, and that we were justified in neglecting it compared to 0 0500 In
general, we shall say that, if the calculated value of X is less than 10 0% of
the number from Which it is subtracted or to which it is added, it is
permissible to make the approximation as we did in this problem
gq.
gr. Solution
gs. For the reasons just given, the proper chemical equilibrium to consider is
gt. With equal small unknown concentration of H+ and HS- of X moles/liter.
Leaving (0.100 X) moles/liter of undissociated H2S. Substituting these
values into the K1 expression. We obtain
gv.
gw.
gx. solution
gy.
gz. first, write the chemical equation
ha. secound, write the K, expression based on the chemical equation, obtaining the
needed value of K1, from table 23-1
hb.
hc. Third, write what you know and do not know. You are asked for the pH of a basic
solution, so you will first have to find the [OH-] . Let [OH-] = X . Because NH4+ and
OH- ions are formed in equal amounts, [NH4+] also equals X. Of the original 0.100
mole/liter will dissociate and leave (0.100 X) mole/liter at equilibrium. Associate
these concertrations with the chemical equation, and substitute them into the K,
expression.
hd.
he. We try to simplify the solution by neglecting X compared to 0.100, obtaining
hf. We see that the assumption about neglecting X was sound
hg.
hh.
hu.
hv.
hw.Solution
hx.
hy. K1 [acid]
hz.
[salt]
ia.
id. Solution
ie.
if. The 0.10 mole of HCl (strong acid) reacts with the salt
ig.
ih. To give 0.10 mole more HC2H3O2 for a total of 1.10 mole/liter. And 0.10 mole less
C2H3O2- for a total of 0.90 mole/liter. If we substitute these new acid and salt
concentrations into our expression for [H=], we get
ii.
ij. You see that the pH changes only 0.90 units. Whereas 0.10 mole HCl added to one
liter of water would have given a solution whose pH = 1.00 an enormous change in
pH without the buffer.
ik.
jp. Solution
jq.
jr. Write the chemical equation, showing the equilibrium concentration above the
symbols
js.
jt. As in previous problems. We represent the small unknown concentration of OH- by
X. Because HC2H3O2 is formed simultaneously wiyh OH- and in equimolar
amounts. Its concentration also is X. The unhydrolyzed concentration of C2H3O2- is
0.500 X. Substitution of these values into the Kh expression gives
ju.
jv. Neglecting X compared to 0.0500. we have
jw.
jx.
kq.
kr. Solution
ks.The two possible reactions of the HCO3- ion and the associated
equilibrium constants are the following
kt. Because Kh K1, the hydrolysis reaction predominates, and the
solution will be basic. Letting X = [OH-] = [H2CO3], and [HCO3-] =
0.100 X = 0.100 M. We have
ku.
kv.
kw.
kz.
la.
lb.
lc.
ld.
le.
lf.