Chapter 14 Questions

1. Which of the following is equal for the forward and reverse reactions at equilibrium?
A) concentration
B) rates
C) rate constants
2. All chemical equilibria are _____ in nature.
A) dynamic
B) equal
C) static
D) kinetic
3. An example of a physical equilibrium is _____.
A)
B)
C)
D)
4. Which of the following is not a physical equilibrium?

A) melting
B) allotropic transformation
C) vaporization
D) rusting
5. An example of heterogeneous equilibrium is _____.
A)
B)
C) Enzyme-catalyzed reactions
6. Which of the following statements is always correct?
A) chemical equilibria are homogeneous
B) physical equilibria are homogeneous
C) physical equilibria are heterogeneous
D) chemical equilibria are heterogeneous
7. The expression for Kp for the reaction
is _____.
A) PCO2
B)
P H 2O
C) PCO2
/ P H2O
D) PCO2
P H2O
8. The expression for Kp for the reaction

is _____.
A)
B)
C)
D)
2P SO2 + P O2
P2 SO2 P O2
P SO2 + P O2
2P SO2 / P O2
9. The equilibrium constant Kp is not applicable for the reaction _____.

A)
B)
C)
D)
10. The equilibrium constant Kc for the reaction

is given by _____.
A)
B)
C)
D)
11. The equation relating Kp and Kc is _____.

A) Kp = Kc (RT)n
B) Kp = Kc RTn
C) Kc = Kp RTn
D) Kc = Kp (RT)n
12. Kp will be equal to Kc if _____.
A) n = 1
B) n = 0
C) RT = 0
D) n =
13. Kp will be less than Kp if _____.

A) H = negative
B) n = positive
C) n = negative
D) n = 0
14. The equilibrium constants for the reactions
and
are x and y, respectively. The equilibrium constant for the reaction
is _____.
A)
B) x + y
C) x y
D) xy
Use the following to answer questions 15-16:
The equilibrium constant for the reaction
is x.
15. The equilibrium constant for the reaction
is _____.
A)
B)
C)
D)
16.
x
x
1/x
2x

A) 2x
B) x
C) x/2
D) x2

is 4.17 10
31
. The equilibrium constant for the reaction

is
A) 4.17 10
B) 4.17 1031
C) 2.40 1030
31
is _____.
D) 2.40 10-33
18. The number of moles of H2, S2, and H2S present at the equilibrium for the reaction
are 2.50, 1.35 10-5 and 8.70 moles respectively in a 12 L flask. The equilibrium
constant, Kc for the reaction is _____.
A) 1.08 107
B) 1.08 10-7
C) 5.6 103
D) 7.2 10-5
19. Kc for the reaction
is 2.24 1022 at 1273 C. Kp for the reaction at the same temperature is _____.
A) 7.16 10-18
B) 1.76 1020
C) 5.12 10-15
D) 3.12 1019
20. The equilibrium partial pressures of N2, O2 and NO in the reaction
are 0.15, 0.33 and 0.050 atm, respectively at 2200C. The value of Kp for the reaction is
_____.
A) 5.1
B) 0.51
C) 51
D) 0.051
21. The equilibrium concentrations of NH3, N2 and H2 are 0.25 M, 0.11 M and 1.91 M,
respectively. The equilibrium constant Kc for the reaction
is _____.
A)
B)
C)
D)
0.082
8.2 10-3
8.2
0.82
22. The equilibrium constant, Kc, for the reaction

is 0.082. What is Ka for
A) 0.164
B) 0.041
C) 0.29
D) 1.64
23. The equilibrium constant, Kc , for the reaction
is 3.8 10-5 at 727C. The value of Kp for the equilibrium
at the same temperature is _____.
A)
B)
C)
D)
648
320
32.0
6.48
24. The equilibrium pressure for the reaction

is 0.105 atm at 350C. Kp for the reaction is
_____.
A) 0.105
B) 0.210
C) 1.05
D) 10.5
25. Kp for the reaction
at 350oC is 0.105. Kc for the reaction at the
same temperature is _____.
A) 4.21 103
B) 0.105
C) 3.05 10-4
D) 2.05 10-3
26. The equilibrium constant, Kp, for the reaction
is 1.05 at 250C. The reaction is started with PCl5, PCl3 and Cl2 at 0.177, 0.223 and
0.111 atm at 250C. When the reaction comes to equilibrium, the pressure of _____.
A) PCl3 must have decreased
B) Cl2 must have decreased
C) PCl5 must have decreased
D) PCl5 must have increased
27. Starting with only the solid, the total pressure of NH3 and CO2 was found to 0.363 atm
for the equilibrium
equilibrium constant, Kp is
A) 7.1 10-3
B) 2.5 10-2
C) 5.3 10-4
D) 3.6 10-6
at 40C. The
28. 1.05 moles of Br2 in a 0.980 L container undergo 1.2% dissociation. The equilibrium
constant, Kc for the reaction
A) 2.5 10-5
B) 1.8 10-3
C) 6.2 10-4
D) 5.9 10-6
is _____.
29. Kp = Kc for the reaction _____.

A)
B)
C)
D)
30. 3.00 10-2 mol of phosgene gas, COCl2, was heated in a 1.50 L container at 800 K. At
equilibrium the pressure of CO was found to be 0.497 atm. The equilibrium constant, Kp
for the reaction
A) 3.30
B) 9.80
C) 2.75
D) 5.61
is _____.
31. The equilibrium constant, Kp for the reaction

at 2200C is 0.051. The equilibrium constant, Kc for the same reaction is _____.
A) 0.102
B) 0.051
C) 2.5 10-3
D) 1.02 104
At equilibrium, nitrosyl bromide in the reaction
is 34% dissociated at 25C and the total pressure is 0.25 atm.
32. The value of Kp for the reaction is _____.
A) 9.6 10-3
B) 1.39 10-5
C) 3.8 10-4
D) 6.7 10-6
33. The value of Kc for the above reaction is _____.

A) 1.6 10-6
B) 2.7 10-5
C) 3.9 10-4
D) 4.5 10-7
34. 2.50 mole of NOCl was heated in a 1.50 L vessel at 400C.At equilibrium it was found
that 28.0% of the NOCl had dissociated. The equilibrium constant, Kc of the reaction
is _____.
A)
B)
C)
D)
0.0353
3.53 102
3.53 10-4
3.53
35. The ionization constants Kc' and Kc for
were found to be 9.5 10-8 and 1.0 10-19 respectively. The equilibrium constant for the
reaction
is _____.
A)
B)
C)
D)
9.5 10-8
1.0 10-19
9.5 10-27
1.05 10-12
36. The equilibrium constant, Kc = 4.0 10-6 for the reaction

.
If the equilibrium constant, Kc= 6.5 10 for the reaction
-2
,
the equilibrium constant for
is _____.
A)
B)
C)
D)
-6
4.0 10
6.1 10-5
1.6 104
6.5 10-2

The following equilibrium constants were measured for the reactions:

is _____.
A)
B)
C)
D)
xy
x+y
xy2
x + y2
38. The equilibrium constants K1 and K2 for the reactions above are
1.3 1014 and 6.0 10-3, respectively. The equilibrium constant for the reaction
A)
B)
C)
D)
is _____.
4.7 109
1.0 1014
1.0 1026
3.6 1018
39. The equilibrium constants K1 K2 and K3 for the reactions below are
K1 = 4.2 1052
K2 = x
K3 = 5.6 1023.
The value of K2 is _____.
A) 9.8 1028
B) 9.8 10128
C) 6.7 1012
D) 2.6 1075
40. The equilibrium constant in terms of rate constants for the forward reaction, kf, and the
reverse reaction, kr, is given as _____.
A)
k
K= r
kf
B) K = kf + kr
C)
k
K f
kr
D) K = kf kr
41. The concentration of H+ in pure water at 25C is _____.

A) 10-14 M
B) 10-7 M
C) 10-10 M
D) 10-8 M
42. The equilibrium constant of a reaction is 12.6. If the rate constant of the reverse
reaction is 5.1 10-2, the rate constant for the forward reaction is _____.
A) 0.32
B) 0.16
C) 0.64
D) 0.08
43. Which of the following statements can be correct with respect to reaction quotient, Q
and equilibrium constant, K?
A) Q < K
B) Q = K
C) Q > K
D) all the above
44. The value of Kc for the equilibrium
is 5.6 104 350C. The initial pressures of SO2 and O2 in a mixture are 0.350 atm and
0.762 atm. The total pressure at equilibrium will be _____ atm.
A) less than 0.350
B) less than 0.741
C) less than 1.112
D) equal to 1.112
45.
The value of Kc for the reaction

is 1.2 . The
reaction is started with [H2 ]0 = 0.76 M, [N2]0 = 0.60 M and [NH3]0= 0.48 M. Which of
the following is correct as the reaction comes to equilibrium?
A) The concentration of N2will increase
B) The concentration of H2will decrease
C) The concentration of NH3will decrease
D) The concentration of both N2and H2will increase

For the reaction
Kc = 0.534 at 700C
46. Calculate the number of moles of H2 present at equilibrium if a mixture of 0.300 moles
of CO and 0.300 moles of H2O is heated to 700C in a 10.0 L container.
A) 0.432 mol
B) 0.273 mol
C) 0.577 mol
D) 0.173 mol
47. Which statement is correct with respect to the above equilibrium when 0.30 moles of
CO and 0.30 moles of H2O are heated to 700C and allowed to reach equilibrium.
A) [H2O] = [CO2]
B) [CO2] = [CO]
C) [H2O] = [CO]
D) [H2O] = [H2]
48. Which of the following statements is correct?
A) All concentrations are equal
B) Kp = Kc
C) Kp < Kc
D) Kp > Kc
49. Kp is 158 for the equilibrium
Starting with NO2 (g) only, the partial pressure of O2 at equilibrium is 0.25 atm.
Calculate the partial pressure of NO2 at equilibrium.
A) 0.020 atm
B) 0.20 atm
C) 3.1 atm
D) 0.035atm
50. The partial pressure of NO in the above equilibrium is _____ atm.
A) 0.125
B) 0.50
C) 0.25
D) 0.02
51.
The equilibrium constant Kc for the reaction

is
6
2.18 10 . Starting with 3.20 moles of HBr in a 12.0L container, the concentration of
HBr at equilibrium is _____.
A) 0.167 M
B) 0.0267 M
C) 1.6 M
D) 0.267 M
52.
Kc is 3.8 10-5 at 1000K for the equilibrium

Starting with 0.0456 moles of I2 in a 2.30 L flask, at 1000 K, the equilibrium
concentration of I2 at is:
A) 1.94 M
B) 0.0194 M
C) 0.12 M
D) 0.012 M

Kc for the reaction
is 4.63 10-3 at 527C .
53. Starting with pure phosgene, COCl2, at 0.760 atm, the equilibrium partial pressure of
CO is _____.
A) 0.352 atm
B) 0.0416 atm
C) 0.0352 atm
D) 0.416 atm
54. Starting with pure phosgene, COCl2, at 0.760 atm, the equilibrium partial pressure of
COCl2 is _____.
A) 0.173 atm
B) 0.204 atm
C) 0.302 atm
D) 0.408 atm
55.
What is the value of Kc for the reaction

when the equilibrium concentrations of CO, H2, CO2 and H2O are 0.050 M, 0.045 M,
0.086 M and 0.040 M respectively?
A) 0.074
B) 0.52
C) 0.063
D) 0.24

The equilibrium constant Kp for the reaction
at equilibrium is 4.50 atm.
56. The equilibrium partial pressure of CO is _____ atm.
A) 0.86
B) 1.62
C) 1.96
D) 1.31
is 1.52 and the total pressure
57. The equilibrium partial pressure of CO2 is _____ atm.

A) 2.54 atm
B) 0.98 atm
C) 1.27 atm
D) 0.72 atm
The equilibrium constant, Kc for the reaction
0.80 mole of H2 and 0.80 mole CO2 are placed in a 5.0 L flask.
58. The concentration of H2 at equilibrium is _____.
A) 0.054 M
B) 0.025 M
C) 0.15 M
D) 0.029 M
59. At equilibrium, the concentration of H2 is equal to the concentration of _____.
A) H2O
B) CO
C) CO2
D) H2O + CO2
60. The concentration of CO at equilibrium is _____.
A) 0.22M
B) 0.056M
C) 0.021M
D) 0.11M
61. Le Chtelier's principle can help to predict how to maximize _____.
A) Reaction yield
B) Equilibrium constant
C) Temperature
D) Rate constant
62. Which can alter the value of the equilibrium constant?
A) Catalyst
B) Concentration
C) Pressure
D) Temperature
is 4.2. Initially
63. The equilibrium position of the reaction

can be shifted in the forward direction
by _____.
A) Removing SO2
B) Adding Cl2
C) Removing Cl2
D) Removing SO2 and Cl2
The equilibrium constant Kc for the equilibrium
is x.
is _____.
A)
B)
C)
D)
x/2
x1/2
x2
2x

A) x2
B)
is _____.
C) x2
D) 2x
66. Which of the following equilibria is not affected by pressure?
A)
B)
C)
D)
67. The equilibrium

formation by _____. H = 92.5 kJ.
A) Increasing temperature
B) Increasing pressure
, can be shifted toward more product
C) Decreasing temperature
D) Increasing the concentration PCl3
68. The equilibrium
can shifted to the reactant side by _____. H =
198.2 kJ
A) Decreasing temperature
B) Decreasing volume
C) Decreasing pressure
D) Increasing the concentration of SO2
69. The equilibrium pressure of NO in the equilibrium
2
atm. Its pressure on the addition of a catalyst will be _____.
A) 1.06 atm
B) 0.75 atm
C) 1.56 atm
D) 2.71 atm
70.
71.
The position of the equilibrium

to the left by the addition of _____ at constant pressure.
A) CO
B) He
C) O2
D) KCl
The addition of He to the equilibrium

constant volume _____.
A) Shifts the equilibrium to the left
B) Increases Kc
C) Shifts the equilibrium to the right
D) Has no effect
to the right?
Decrease of temperature
Addition of KCl
Addition of CO2
Addition of NaOH solution
can be shifted
at
72. Which of the following will shift the equilibrium
A)
B)
C)
D)
is 1.56
73.
The equilibrium
by _____.
A) increasing temperature
B) decreasing pressure
C) removing some CO2
D) all of the above
can be shifted to the right

Pure NOCl gas was heated to 240 C in a 1.00-L container. At equilibrium the total pressure was 1.00 atm and
the NOCl pressure was 0.64 atm.
74. The partial pressure of NO at equilibrium in the reaction
is _____ atm.
A)
B)
C)
D)
0.24
0.12
0.34
0.17
75. The partial pressure of Cl2 in the equilibrium

is _____ atm.
A)
B)
C)
D)
0.36
0.09
0.12
0.18
76. Kp for the equilibrium

is _____.
A)
B)
C)
D)
1.7
0.12
0.17
0.017

Kp is 2.9 10-11 at 530C for the reaction
.
77. What is the partial pressure of NO at equilibrium when the equilibrium partial pressures
of N2 and O2 are 3.0 atm and 0.012 atm, respectively?
A) 1.0 106 atm
B) 1.6 103 atm

C) 1.6 102 atm
D) 0.16 atm
78. What is the partial pressure of NO at equilibrium under atmospheric conditions where
the partial pressures of N2 and O2 are 0.78 atm and 0.21 atm at 25C? Kp for the reaction
is 4.010-31 at 25 C.
A) 1.12 10-12 atm
B) 2.6 10-16 atm
C) 1.3 10-8 atm
D) 1.45 10-4 atm
79. The thermal decomposition of NaHCO3(s) is favored by _____.
A) decreasing temperature
B) increasing temperature
C) increasing pressure
D) adding CO2
80. Kp < Kc at 25 C for which of the reactions below?
A)
B)
C)
D)
81. The condition for maximum yield of NOCl2 in the reaction

0
is _______. ( H f of NOCl = 51.7 kJ/mol,
H 0f of NO = 90.4kJ/mol.)
A)
B)
C)
D)
high pressure, high temperature

low pressure, low temperature
low pressure, high temperature
high pressure, low temperature
82. For the reaction

PA = 0.60 atm and PB = 0.60 atm at equilibrium at some temperature. Kp for the reaction
is _____.
A) 1
B) 0.5
C) 1.7
D) 0.6
83. For the reaction

at equilibrium, the PA=0.60 atm and PB=0.60 atm and the total pressure is 1.2 atm. What
is the PA when the total pressure is increased to 1.5 atm?
A) 0.69 atm
B) 0.81 atm
C) 0.75 atm
D) 0.91 atm
84. The equilibrium mixture in the reaction
consists of 0.020 mole O2, 0.040 mole NO and 0.96 mole NO2. What is Kp for the
reaction at 430C and at a total pressure of 0.20 atm?
A) 1.5 105
B) 7.2 104
C) 8.1 103
D) 5.6 106
85. Ammonium carbamate decomposes at a certain temperature .The equilibrium pressure
of the reaction
is 0.318 atm. Kp for the reaction is _____.
A) 5.92 10-5
B) 1.26 10-4
C) 3.12 10-6
D) 4.76 10-3
A mixture of 0.47 moles of H2 and 3.59 moles of HCl is heated to 2800C and allowed to reach equilibrium.
The total pressure at equilibrium is 2.00 atm.
Kp = 193 at 2800C.
86. The equilibrium pressure of H2 is _____ atm.
A) 0.56 atm
B) 0.28 atm
C) 0.049 atm
D) 1.67 atm
87. The partial pressure of Cl2 in the above equilibrium is _____ atm.
A) 0.28 atm
B) 0.049 atm
C) 0.56 atm
D) 0.49 atm
88. The partial pressure of HCl in the above equilibrium is _____ atm.
A) 1.28 atm
B) 1.01 atm
C) 2.06 atm
D) 1.67 atm
89. Initially 1 mole of N2O4 is placed in a vessel and allowed to reach equilibrium. The
relation between the degree of dissociation , total pressure P and Kp for the reaction
is _____.
A)
4
P
1 2
B)
4 2
Kp
P
(1 ) 2
C)
2
Kp
P
1 2
D)
2 2
Kp
P
2
1
Kp
90. One mole of N2 and three moles of H2 are placed in a flask and allowed to reach
equilibrium. T = 375 C. The mole fraction of NH3 at equilibrium is found to be 0.21.
What is the total pressure of the system at equilibrium?
A)
B)
C)
D)
50 atm
5 atm
500 atm
0.5 atm
91. What is [S2] at equilibrium in the following reaction if [H2S] = 4.84 10-3 M and [H2] =
1.50 10-3 M at equilibrium?
Kc = 2.25 10-4
A)
B)
C)
D)
2.34 10-2
0.234 M
2.34 10-3M
2.34 10-4M
92. 6.75 g of SO2Cl2 was placed in a 2.00L flask. At 648 K 0.0345 moles of SO2 was
present. Kc for the reaction
A) 3.83 10-2
B) 4.71 10-3
C) 1.12 10-2
is _____.
D) 6.12 10-4
Kp for the reaction
at 375C is 4.31 10-4. The reaction is started with
0.373 atm of H2 and 0.862 atm of N2 in a constant volume vessel.
93. The partial pressure of N2 at equilibrium is _____ atm.
A) 0.260
B) 0.760
C) 0.860
D) 0.960
94. The partial pressure of H2 at equilibrium is _____ atm.
A) 0.366
B) 0.166
C) 0.266
D) 0.566
95. The partial pressure of NH3 at equilibrium is _____ atm.
A) 4.40 10-3
B) 1.12 10-2
C) 7.20 10-4
D) 2.70 10-5
A 0.244 M fructose solution was prepared and it was found that at equilibrium the fructose concentration had
decreased to 0.113 M.
96.

A) 2.06
B) 5.16
C) 4.27
D) 1.16
97. The percentage of fructose converted into glucose in the equilibria

is _____.
A)
B)
C)
D)
53.7%
83.1%
21.7%
63.2%
is _____.

The equilibrium pressure of oxygen for the reaction
is 0.49 atm .
98. Kp for the reaction is _____.

A) 0.49
B) 2.5 10-3
C) 0.98
D) 4.9
99. The fraction of CuO that will decompose if 0.16 mole of CuO is placed in a 2.0 L vessel
at 1024C is _____.
A) 0.15
B) 0.71
C) 0.23
D) 0.47
100. 3.9 moles of NO and 0.88 moles of CO2 are allowed to react as
At equilibrium 0.11 moles of CO2 was present. Kc for the reaction is _____.
A) 0.27
B) 1.7
C) 3.14
D) 6.03
For the reaction at 430C,
Kc = 54.3.
Initially 0.714 moles of H2 and 0.984 moles of I2 and 0.886 moles of HI are placed in a 2.40 L vessel.
101. The equilibrium concentration of H2 is _____.
A) 0.070 M
B) 0.182 M
C) 0.152 M
D) 0.012 M
102. The equilibrium concentration of I2 is _____.
A) 0.112
B) 0.082
C) 0.182
D) 0.116
103.
A gaseous compound, A, dissociates as follows:
. A was
heated until equilibrium was reached. The pressure of A at equilibrium was 0.14P,where
P is the total pressure. Kp for the reaction is _____.
A) 0.13P
B) 1.3P
C) 0.013P
D) 13P
For the reaction
Kc = 1.2 at 375C.
104. Kp for the reaction is _____.

A) 4.2 10-2
B) 1.2 102
C) 3.1 10-3
D) 4.2 10-4
105. K for the reaction
c
A) 1.2
B) 0.83
C) 0.38
D) 0.012
is _____.
106. Kc for the formation of one mole of NH3 from H2 and N2 is _____.
A) 0.6
B) 1.1
C) 1.2
D) 2.2
The vapor pressure of water at 20C is 0.0231 atm.
107.
Kp for the process

A) 0.0231
B) 2.31 10-6
C) 2.31
D) 100
is _____.
108. Kc for vaporization of water is_____.

A) 1.8 10-2
B) 2.3 10-5
C) 9.6 10-4
D) 3.6 10-3
The density of a mixture of the gases, NO2 and N2O4, is 2.3 g/L at 74C and 1.3 atm.
109. The partial pressure of NO2 in the mixture is _____ atm.
A) 1.2
B) 0.12
C) 0.012
D) 0.24
110. The partial pressure of N2O4 the mixture is _____ atm.
A) 0.62
B) 0.12
C) 0.062
D) 0.63
111. What is Kp for the reaction
equilibrium is 2.2 atm?
A) 1.1
B) 1.2
C) 2.2
D) 2.1
when the total pressure at

For the equilibrium
atm at 25C.
, the equilibrium partial pressures of NO2 and N2O4 are 0.15 and 0.20
112. What is the equilibrium partial pressure of NO2 when the volume is doubled?
A) 1.0atm
B) 0.10atm
C) 10atm
D) 0.01atm
113. The equilibrium partial pressure of N2O4 when the volume is doubled will be _____ atm.
A) 0.88
B) 0.44
C) 0.044
D) 0.088
114. Kp for the equilibrium
A) 1.13
B) 0.113
C) 11.3
D) 1.13 104
at 25C is _____.
115. The vapor pressure of mercury is 0.0020 mmHg at 26C. Kc for the process
, is _____.
A)
B)
C)
D)
1.1 10-7
2.2 104
1.1 10-3
4.4 10-2
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B
C
B
C
D
C
B
D
C
B
A
B
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
61.
62.
63.
64.
65.
66.
67.
68.
69.
70.
71.
72.
73.
74.
75.
76.
77.
78.
79.
80.
81.
82.
83.
84.
85.
86.
87.
88.
89.
90.
91.
92.
93.
94.
95.
96.
97.
98.
99.
100.
101.
102.
D
B
A
D
B
C
A
A
C
D
A
D
B
B
C
A
A
C
C
B
D
D
D
A
C
D
A
B
B
A
D
C
A
A
D
B
B
D
A
A
C
A
C
A
A
D
A
A
C
B
A
C
103.
104.
105.
106.
107.
108.
109.
110.
111.
112.
113.
114.
115.
B
D
B
B
A
C
A
B
B
B
D
B
A
Chapter14ChemicalEquilibrium
Student:___________________________________________________________________________
1.
2.
Whichisthecorrectequilibriumconstantexpressionforthefollowingreaction?
Fe2O3(s)+3H2(g)
2Fe(s)+3H2O(g)
A.
B.
C.
D.
E.
Kc=[Fe2O3][H2]3/[Fe]2[H2O]3
Kc=[H2]/[H2O]
Kc=[H2O]3/[H2]3
Kc=[Fe]2[H2O]3/[Fe2O3][H2]3
Kc=[Fe][H2O]/[Fe2O3][H2]
Theequilibriumconstantexpressionforthereaction2BrF5(g)
A.
B.
C.
D.
E.
Br2(g)+5F2(g)is
Kc=[Br2][F2]/[BrF5]
Kc=[Br2][F2]5/[BrF5]2
Kc=[Br2][F2]2/[BrF5]5
Kc=[BrF5]2/[Br2][F2]5
Kc=2[BrF5]2/([Br2]5[F2]5)
3.
Thefollowingreactionsoccurat500K.Arrangetheminorderofincreasingtendencytoproceedto
completion(leastgreatesttendency).
A.
B.
C.
D.
E.
2<1<3
1<2<3
2<3<1
3<2<1
3<1<2
4.
Considerthetwogaseousequilibria
ThevaluesoftheequilibriumconstantsK1andK2arerelatedby
A.
B.
C.
D.
E.
5.
K2=K12
K22=K1
K2=1/K12
K2=1/K1
noneofthese
Carbontetrachloridereactsathightemperatureswithoxygentoproducetwotoxicgases,phosgeneand
chlorine.
CCl4(g)+(1/2)O2(g)
COCl2(g)+Cl2(g),Kc=4.4109at1,000K
CalculateKcforthereaction2CCl4(g)+O2(g)
A.
B.
C.
D.
E.
2COCl2(g)+2Cl2(g).
4.4109
8.8109
1.91010
1.91019
2.31010
6.
TheequilibriumconstantforthereactionNi(s)+4CO(g)
theequilibriumconstantforthereactionNi(CO)4(g)
A.
B.
C.
D.
E.
Ni(CO)4(g)is5.0104at25C.Whatis
Ni(s)+4CO(g)?
2.0105
2.5109
5.0104
5.0104
2.0103
7.
Whichofthesestatementsistrueaboutchemicalequilibriaingeneral?
A.
B.
C.
D.
E.
Atequilibriumthetotalconcentrationofproductsequalsthetotalconcentrationofreactants,thatis,
[products]=[reactants].
Equilibriumistheresultofthecessationofallchemicalchange.
ThereisonlyonesetofequilibriumconcentrationsthatequalstheKcvalue.
Atequilibrium,therateconstantoftheforwardreactionisequaltotherateconstantforthereverse
reaction.
Atequilibrium,therateoftheforwardreactionisequaltoastherateofthereversereaction.
8.
Thefollowingreactionsoccurat500K.Arrangetheminorderofincreasingtendencytoproceedto
completion(leastcompletiongreatestcompletion).
A.
B.
C.
D.
E.
2<1<3<4
3<1<4<2
3<4<1<2
4<3<2<1
4<3<1<2
9.
Whenthefollowingreactionisatequilibrium,whichoftheserelationshipsisalwaystrue?
2NOCl(g)
2NO(g)+Cl2(g)
A.
B.
C.
D.
E.
[NO][Cl2]=[NOCl]
[NO]2[Cl2]=[NOCl]2
[NOCl]=[NO]
2[NO]=[Cl2]
[NO]2[Cl2]=Kc[NOCl]2
10. CalculateKpforthereaction2NOCl(g)
2NO(g)+Cl2(g)at400CifKcat400Cforthisreactionis
2.1102.
A.
B.
C.
D.
E.
2.1102
1.7103
0.70
1.2
3.8104
11. Onanalysis,anequilibriummixtureforthereaction2H2S(g)
2H2(g)+S2(g)wasfoundtocontain
1.0molH2S,4.0molH2,and0.80molS2ina4.0Lvessel.Calculatetheequilibriumconstant,Kc,forthis
reaction.
A.
B.
C.
D.
E.
1.6
3.2
12.8
0.64
0.8
12. 2.50molNOClwasplacedina2.50Lreactionvesselat400C.Afterequilibriumwasestablished,itwas
foundthat28%oftheNOClhaddissociatedaccordingtotheequation2NOCl(g)
2NO(g)+Cl2(g).
Calculatetheequilibriumconstant,Kc,forthereaction.
A.
B.
C.
D.
E.
0.021
0.039
0.169
26
47
13. 1.25molesofNOClwereplacedina2.50Lreactionchamberat427C.Afterequilibriumwasreached,
1.10molesofNOClremained.Calculatetheequilibriumconstant,Kc,forthereaction2NOCl(g)
2NO(g)+Cl2(g).
A.
B.
C.
D.
E.
3.0104
1.8103
1.4103
5.6104
4.1103
14. ThereactionA(g)+2B(g)
C(g)wasallowedtocometoequilibrium.Theinitialamountsof
reactantsplacedintoa5.00Lvesselwere1.0molAand1.8molB.Afterthereactionreached
equilibrium,1.0molofBwasfound.CalculateKcforthisreaction.
A.
B.
C.
D.
E.
0.060
5.1
17
19
25
15. ThebrowngasNO2andthecolorlessgasN2O4existinequilibrium,2NO2
N2O4.Inanexperiment,
0.625moleofN2O4wasintroducedintoa5.00Lvesselandwasallowedtodecomposeuntilequilibrium
wasreached.TheconcentrationofN2O4atequilibriumwas0.0750M.CalculateKcforthereaction.
A.
B.
C.
D.
E.
7.5
0.125
0.0750
0.10
0.050
16. CalculateKcforthereaction2HI(g)
H2(g)+I2(g)giventhattheconcentrationsofeachspeciesat
equilibriumareasfollows:
[HI]=0.85mol/L,[I2]=0.60mol/L,[H2]=0.27mol/L.
A.
B.
C.
D.
E.
5.25
0.22
4.5
0.19
1.6102
17. Phosgene,COCl2,apoisonousgas,decomposesaccordingtotheequation
COCl2(g)
CO(g)+Cl2(g).CalculateKpforthisreactionifKc=0.083at900C.
A.
B.
C.
D.
E.
0.125
8.0
6.1
0.16
0.083
18. KpforthereactionofSO2(g)withO2toproduceSO3(g)is31024.CalculateKcforthisequilibriumat
25C.(Therelevantreactionis2SO2(g)+O2(g)
2SO3(g).)
A.
B.
C.
D.
E.
31024
51021
21020
51022
71025
19. IfonestartswithpureNO2(g)atapressureof0.500atm,thetotalpressureinsidethereactionvesselwhen
2NO2(g)
2NO(g)+O2(g)reachesequilibriumis0.674atm.Calculatetheequilibriumpartial
pressureofNO2.
A.
B.
C.
D.
E.
0.152atm
0.174atm
0.200atm
0.326atm
ThetotalpressurecannotbecalculatedbecauseKpisnotgiven.
20. Equilibriumisestablishedforthereaction2X(s)+Y(g)
2Z(g)at500K,Kc=100.
DeterminetheconcentrationofZinequilibriumwith0.2molXand0.50MYat500K.
A.
B.
C.
D.
E.
3.2M
3.5M
4.5M
7.1M
noneofthese
21. At250C,theequilibriumconstantKpforthereactionPCl5(g)
PCl3(g)+Cl2(g)is1.80.Sufficient
PCl5isputintoareactionvesseltogiveaninitialpressureof2.74atmat250C.Calculatethepressureof
PCl5afterthesystemhasreachedequilibrium.
A.
B.
C.
D.
E.
1.50atm
1.24atm
4.24atm
0.94atm
1.12atm
22. At35C,theequilibriumconstantforthereaction2NOCl(g)
2NO(g)+Cl2(g)is
Kc=1.6105.AnequilibriummixturewasfoundtohavethefollowingconcentrationsofCl2andNOCl:
[Cl2]=1.2102M;[NOCl]=2.8101M.CalculatetheconcentrationofNO(g)atequilibrium.
A.
B.
C.
D.
E.
1.0104M
1.0102M
2.8101M
2.4102M
1.6103M
23. ForthereactionSO2(g)+NO2(g)
SO3(g)+NO(g),theequilibriumconstantis18.0at1,200C.If1.0
moleofSO2and2.0molesofNO2areplacedina20.Lcontainer,whatconcentrationofSO3willbe
presentatequilibrium?
A.
B.
C.
D.
E.
0.48mol/L
0.11mol/L
0.95mol/L
2.22mol/L
18mol/L
24. ConsiderthereactionN2(g)+O2(g)
2NO(g),forwhichKc=0.10at2,000C.Startingwithinitial
concentrationsof0.040MofN2and0.040MofO2,determinetheequilibriumconcentrationofNO.
A.
B.
C.
D.
E.
5.4103M
0.0096M
0.011M
0.080M
0.10M
25. Hydrogeniodidedecomposesaccordingtotheequation2HI(g)
H2(g)+I2(g),forwhichKc=0.0156
at400C.0.550molHIwasinjectedintoa2.00Lreactionvesselat400C.Calculatetheconcentrationof
HIatequilibrium.
A.
B.
C.
D.
E.
0.138M
0.220M
0.550M
0.275M
0.0275M
26. Hydrogeniodidedecomposesaccordingtotheequation2HI(g)
H2(g)+I2(g),forwhichKc=0.0156
at400C.0.550molHIwasinjectedintoa2.00Lreactionvesselat400C.Calculatetheconcentrationof
H2atequilibrium.
A.
B.
C.
D.
E.
0.275M
0.138M
0.0275M
0.0550M
0.220M
27. At400C,Kc=64fortheequilibriumH2(g)+I2(g)
2HI(g).If3.00molH2and3.00molI2are
introducedintoanempty4.0Lvessel,findtheequilibriumconcentrationofHIat400C.
A.
B.
C.
D.
E.
0.15M
1.2M
2.4M
4.8M
5.8M
28. Sodiumcarbonate,Na2CO3(s),canbepreparedbyheatingsodiumbicarbonate,NaHCO3(s).
2NaHCO3(s)
Na2CO3(s)+CO2(g)+H2O(g)Kp=0.23at100C
IfasampleofNaHCO3isplacedinanevacuatedflaskandallowedtoachieveequilibriumat100C,what
willthetotalgaspressurebe?
A.
B.
C.
D.
E.
0.46atm
0.96atm
0.23atm
0.48atm
0.11atm
29. At340K,Kp=69forthereactionH2(g)+I2(g)
2HI(g).50.0gofHIisinjectedintoanevacuated
5.00Lrigidcylinderat340K.Whatisthetotalpressureinsidethecylinderwhenthesystemcomesto
equilibrium?
A.
B.
C.
D.
E.
2.60atm
1.76atm
0.424atm
2.18atm
10.9atm
30. 15.00gofsolidammoniumhydrogensulfideisintroducedintoa500.mLflaskat25C,theflaskis
sealed,andthesystemisallowedtoreachequilibrium.Whatisthepartialpressureofammoniainthis
flaskifKp=0.108at25CforNH4HS(s)
NH3(g)+H2S(g)?
A.
B.
C.
D.
E.
0.657atm
1.25atm
0.329atm
14.4atm
2.50atm
31. Forthenitrogenfixationreaction3H2(g)+N2(g)
2NH3(g),Kc=6.0102at500C.If0.250MH2
and0.050MNH3arepresentatequilibrium,whatistheequilibriumconcentrationofN2?
A.
B.
C.
D.
E.
0.750M
2.7M
0.250M
0.025M
1.85M
32. Considerthefollowingreactionsandtheirassociatedequilibriumconstants:
ForthereactionA+2B
A.
B.
C.
D.
E.
D+E,havingequilibriumconstantKc,
Kc=K1+K2
Kc=K1/K2
Kc=K1K2
Kc=(K1)(K2)
Kc=K2/K1
33. Considerthefollowingequilibria:
Calculatetheequilibriumconstantforthereaction
SO2(g)+NO3(g)
SO3(g)+NO2(g).
A.
B.
C.
D.
E.
78
1.3102
1.6104
3.21010
6.1103
34. At700K,thereaction2SO2(g)+O2(g)
2SO3(g)hastheequilibriumconstantKc=4.3106,andthe
followingconcentrationsarepresent:[SO2]=0.10M;[SO3]=10.M;[O2]=0.10M.
Isthemixtureatequilibrium?Ifnotatequilibrium,inwhichdirection(astheequationiswritten),leftto
rightorrighttoleft,willthereactionproceedtoreachequilibrium?
A.
B.
C.
D.
Yes,themixtureisatequilibrium.
No,lefttoright
No,righttoleft
Thereisnotenoughinformationtobeabletopredictthedirection.
35. At700K,thereaction2SO2(g)+O2(g)
2SO3(g)hastheequilibriumconstantKc=4.3106,andthe
followingconcentrationsarepresent:[SO2]=0.010M;[SO3]=10.M;[O2]=0.010M.
Isthemixtureatequilibrium?Ifnotatequilibrium,inwhichdirection(astheequationiswritten),leftto
rightorrighttoleft,willthereactionproceedtoreachequilibrium?
A.
B.
C.
D.
Yes,themixtureisatequilibrium.
No,lefttoright
No,righttoleft
Thereisnotenoughinformationtobeabletopredictthedirection.
36. ForthereactionH2(g)+I2(g)
2HI(g),Kc=50.2at445C.If[H2]=[I2]=[HI]=1.75103Mat
445C,whichoneofthesestatementsistrue?
A.
B.
C.
D.
E.
Thesystemisatequilibrium,thusnoconcentrationchangeswilloccur.
TheconcentrationsofHIandI2willincreaseasthesystemapproachesequilibrium.
TheconcentrationofHIwillincreaseasthesystemapproachesequilibrium.
TheconcentrationsofH2andHIwillfallasthesystemmovestowardequilibrium.
TheconcentrationsofH2andI2willincreaseasthesystemapproachesequilibrium.
37. ForthereactionPCl3(g)+Cl2(g)
PCl5(g)ataparticulartemperature,Kc=24.3.Supposeasystemat
thattemperatureispreparedwith[PCl3]=0.10M,[Cl2]=0.15M,and[PCl5]=0.60M.Whichofthese
statementsistrue?
A.
B.
C.
D.
Thereactionisatequilibrium.
ThereactionwillproceedinthedirectionofformingmorePCl5untilequilibriumisreached.
ThereactionwillproceedinthedirectionofformingmorePCl3andCl2untilequilibriumisreached.
Noneofthesestatementsistrue.
38. Forthefollowingreactionatequilibrium,whichchoicegivesachangethatwillshiftthepositionof
equilibriumtofavorformationofmoreproducts?
2NOBr(g)
A.
B.
C.
D.
E.
2NO(g)+Br2(g),Hrxn=30kJ/mol
Increasethetotalpressurebydecreasingthevolume.
AddmoreNO.
RemoveBr2.
Lowerthetemperature.
RemoveNOBrselectively.
39. Forthefollowingreactionatequilibrium,whichoneofthechangesbelowwouldcausetheequilibriumto
shifttotheleft?
2NOBr(g)
A.
B.
C.
D.
E.
Increasethecontainervolume.
RemovesomeNO.
RemovesomeBr2.
AddmoreNOBr.
Decreasethetemperature.
40. Forthefollowingreactionatequilibriuminareactionvessel,whichoneofthesechangeswouldcausethe
Br2concentrationtodecrease?
2NOBr(g)
A.
B.
C.
D.
Increasethetemperature.
RemovesomeNO.
AddmoreNOBr.
Compressthegasmixtureintoasmallervolume.
41. Forthefollowingreactionatequilibriuminareactionvessel,whichoneofthesechangeswouldcausethe
Br2concentrationtoincrease?
2NOBr(g)
A.
B.
C.
D.
Lowerthetemperature.
RemovesomeNO.
RemovesomeNOBr.
Compressthegasmixtureintoasmallervolume.
42. Fortheequilibriumreaction2SO2(g)+O2(g)
2SO3(g),Hrxn=198kJ/mol.Whichoneofthese
factorswouldcausetheequilibriumconstanttoincrease?
A.
B.
C.
D.
E.
Decreasethetemperature.
AddSO2gas.
RemoveO2gas.
Addacatalyst.
noneofthese
43. Thereaction2SO3(g)
A.
B.
C.
D.
E.
2SO2(g)+O2(g)isendothermic.Ifthetemperatureisincreased,
moreSO3willbeproduced.
Kcwilldecrease.
nochangewilloccurinKc.
Kcwillincrease.
thepressurewilldecrease.
44. Forthereactionatequilibrium2SO3
2SO2+O2(Hrxn=198kJ/mol),ifweincreasethereaction
temperature,theequilibriumwill
A.
B.
C.
D.
shifttotheright.
shifttotheleft.
notshift.
Thequestioncannotbeansweredbecausetheequilibriumconstantisnotgiven.
45. WhichofthesesituationswillresultifsomeCH4(g)isremovedfromthereaction
CO(g)+3H2(g)
CH4(g)+H2O(g)atequilibrium?
A.
B.
C.
D.
E.
H2Owillbeconsumed.
MoreCH4andH2Owillbeproduced.
Kpwilldecrease.
MoreCOwillbeproduced.
Nochangewilloccur.
46. Forthecommonallotropesofcarbon(graphiteanddiamond),C(gr)
C(dia)withequilibrium
constantK=0.32.Themolarvolumesofgraphiteanddiamondare,respectively,5.30cm3/moland3.42
cm3/mol;Hfofdiamondis1.90kJ/mol.Thesedatasuggestthattheformationofdiamondisfavoredat
A.
B.
C.
D.
lowtemperaturesandlowpressures.
hightemperaturesandlowpressures.
lowtemperaturesandhighpressures.
hightemperaturesandhighpressures.
47. Inwhichofthesegasphaseequilibriaistheyieldofproductsincreasedbyincreasingthetotalpressureon
thereactionmixture?
A.
CO(g)+H2O(g)
CO2(g)+H2(g)
B.
2NO(g)+Cl2(g)
2NOCl(g)
C.
2SO3(g)
2SO2(g)+O2(g)
D.
PCl5(g)
PCl3(g)+Cl2(g)
48. Considerthisgasphaseequilibriumsystem:
PCl5(g)
PCl3(g)+Cl2(g)Hrxn=+87.8kJ/mol.
Whichofthesestatementsisfalse?
A.
B.
C.
D.
E.
Increasingthesystemvolumeshiftstheequilibriumtotheright.
Increasingthetemperatureshiftstheequilibriumtotheright.
Acatalystspeedsuptheapproachtoequilibriumandshiftsthepositionofequilibriumtotheright.
Decreasingthetotalpressureofthesystemshiftstheequilibriumtotheright.
Increasingthetemperaturecausestheequilibriumconstanttoincrease.
49. Thereaction2NO(g)
N2(g)+O2(g)isexothermic,Hrxn=180kJ/mol.
Whichoneofthesestatementsistrue?
A.
B.
C.
D.
Kpat1,000KislessthanKpat2,000K.
Kpat1,000KislargerthanKpat2,000K.
TheKp'sat1000Kand2000Karethesame.
Kpdependsontotalpressureaswellastemperature.
50. Considerthisreactionatequilibrium:
2SO2(g)+O2(g)
2SO3(g),Hrxn=198kJ/mol
Ifthevolumeofthesystemiscompressedatconstanttemperature,whatchangewilloccurintheposition
oftheequilibrium?
A.
B.
C.
D.
ashifttoproducemoreSO2
ashifttoproducemoreO2
nochange
ashifttoproducemoreSO3
51. ConsiderthisreactionatequilibriumatatotalpressureP1:
2SO2(g)+O2(g)
2SO3(g)
Supposethevolumeofthissystemiscompressedtoonehalfitsinitialvolumeandthenequilibriumis
reestablished.Thenewequilibriumtotalpressurewillbe
A.
B.
C.
D.
E.
twiceP1.
threetimesP1.
3.5P1.
lessthantwiceP1.
unchanged.
52. Forthereaction2NOCl(g)
2NO(g)+Cl2(g),Kc=8.0atacertaintemperature.
WhatconcentrationofNOClmustbeputintoanempty4.00Lreactionvesselinorderthattheequilibrium
concentrationofNOClbe1.00M?
A.
B.
C.
D.
E.
1.26M
2.25M
2.50M
3.52M
11.0M
53. Theequilibriumconstants(expressedinatm)forthechemicalreaction
N2(g)+O2(g)
2NO(g)areKp=1.1103and3.6103at2,200Kand2,500K,respectively.Which
oneofthesestatementsistrue?
A.
B.
C.
D.
E.
Thereactionisexothermic,H<0.
ThepartialpressureofNO(g)islessat2,200Kthanat2,500K.
KpislessthanKcbyafactorof(RT).
Thetotalpressureat2,200Kisthesameasat2,500K.
Highertotalpressureshiftstheequilibriumtotheleft.
54. Whenthesubstancesintheequationbelowareatequilibrium,atpressurePandtemperatureT,the
equilibriumcanbeshiftedtofavortheproductsby
CuO(s)+H2(g)
A.
B.
C.
D.
E.
H2O(g)+Cu(s)Hrxn=2.0kJ/mol
increasingthepressurebymeansofamovingpistonatconstantT.
increasingthepressurebyaddinganinertgassuchasnitrogen.
decreasingthetemperature.
allowingsomegasestoescapeatconstantPandT.
addingacatalyst.
55. 50.0gofN2O4isintroducedintoanevacuated2.00Lvesselandallowedtocometoequilibriumwithits
decompositionproduct,N2O4(g)
2NO2(g).ForthisreactionKc=0.133.Oncethesystemhasreached
equilibrium,5.00gofNO2isinjectedintothevessel,andthesystemisallowedtoequilibrateonceagain.
CalculatethemassofNO2inthefinalequilibriummixture.
A.
B.
C.
D.
E.
17.8g
12.4g
14.7g
19.7g
15.5g
56. 50.0gofN2O4isintroducedintoanevacuated2.00Lvesselandallowedtocometoequilibriumwithits
decompositionproduct,N2O4(g)
2NO2(g).ForthisreactionKc=0.133.Oncethesystemhasreached
equilibrium,5.00gofNO2isinjectedintothevessel,andthesystemisallowedtoequilibrateonceagain.
CalculatethemassofN2O4inthefinalequilibriummixture.
A.
B.
C.
D.
E.
39.5g
35.3g
30.3g
25.2g
43.7g
57. 75.0gofPCl5(g)isintroducedintoanevacuated3.00Lvesselandallowedtoreachequilibriumat250C.
PCl5(g)
PCl3(g)+Cl2(g)
IfKp=1.80forthisreaction,whatisthetotalpressureinsidethevesselatequilibrium?
A.
B.
C.
D.
E.
2.88atm
2.27atm
4.54atm
7.42atm
9.69atm
58. 75.0gofPCl5(g)isintroducedintoa3.00Lvesselcontaining10.0gofCl2(g),andthesystemisallowed
toreachequilibriumat250C.
PCl5(g)
PCl3(g)+Cl2(g)
IfKp=1.80forthisreaction,whatisthetotalpressureinsidethevesselatequilibrium?
A.
B.
C.
D.
E.
6.83atm
8.85atm
5.38atm
3.47atm
7.42atm
59. 25.0gofHI(g)isinjectedintoa4.00Lreactionvesselthatcontains20.0gofI2(g).Whenthesystem
comestoequilibriumat400C,whatwillbethetotalpressureinsidethereactionvessel?
2HI(g)
H2(g)+I2(g),Kc=0.0156at400C
A.
B.
C.
D.
E.
2.70atm
13.0atm
2.43atm
0.815atm
3.79atm
60. Solidammoniumhydrogensulfideisintroducedintoa2.00Lflask,andtheflaskissealed.Ifthissolid
decomposesaccordingtotheequation
NH4HS(s)
NH3(g)+H2S(g),Kp=0.108at25C,
whatistheminimummassofammoniumhydrogensulfidethatmustbepresentintheflaskinitiallyif
equilibriumistobeestablishedat25C?
A.
B.
C.
D.
E.
0.917g
1.37g
2.74g
0.581g
0.452g
61. Whenthereaction2H2S(g)
2H2(g)+S2(g)iscarriedoutat1065C,Kp=0.012.Startingwithpure
H2Sat1065,whatmusttheinitialpressureofH2Sbeiftheequilibratedmixtureatthistemperatureisto
contain0.250atmofH2(g)?
A.
B.
C.
D.
E.
1.06atm
1.86atm
0.94atm
0.90atm
1.52atm
62. Ifthereaction2H2S(g)
2H2(g)+S2(g)iscarriedoutat1065C,Kp=0.0120.StartingfrompureH2S
introducedintoanevacuatedvesselat1065C,whatwillthetotalpressureinthevesselbeatequilibrium
iftheequilibratedmixturecontains0.300atmofH2(g)?
A.
B.
C.
D.
E.
1.06atm
1.36atm
2.39atm
4.20atm
1.51atm
63. Aquantityofliquidmethanol,CH3OH,isintroducedintoarigid3.00Lvessel,thevesselissealed,and
thetemperatureisraisedto500K.Atthistemperature,themethanolvaporizesanddecomposesaccording
tothereaction
CH3OH(g)
CO(g)+2H2(g),Kc=6.90102.
IftheconcentrationofH2intheequilibriummixtureis0.426M,whatmassofmethanolwasinitially
introducedintothevessel?
A.
B.
C.
D.
E.
147g
74.3g
33.9g
49.0g
24.8g
64. Describewhyadditionofacatalystdoesnotaffecttheequilibriumconstantforareaction.
65. ConsiderthereactionN2(g)+3H2(g)
2NH3(g).Ifhydrogengasisaddedtothissystemat
equilibrium,whichdirectionwillthereactionshift?
2NH3(g).Ifnitrogenisaddedtothesystematequilibrium,
whatwillhappentotheammoniaconcentration?
2NH3(g).Ifnitrogenisremovedfromthesystemat
equilibrium,whatwillhappentothehydrogen(H2)concentration?
2NH3(g).Theproductionofammoniaisanendothermic
reaction.Willheatingtheequilibriumsystemincreaseordecreasetheamountofammoniaproduced?
shift?
2NH3(g).Ifweuseacatalyst,whichwaywillthereaction
70. 5.00molofammoniaareintroducedintoa5.00Lreactorvesselinwhichitpartiallydissociatesathigh
temperatures.
2NH3(g)
3H2(g)+N2(g)
Atequilibriumataparticulartemperature,1.00moleofammoniaremains.CalculateKcforthereaction.
71. 4.2molofoxygenand4.0molofNOareintroducedtoanevacuated0.50Lreactionvessel.Ataspecific
temperature,theequilibrium2NO(g)+O2(g)
2NO2(g)isreachedwhen[NO]=1.6M.CalculateKc
forthereactionatthistemperature?
72. 4.21molesofS2Cl4areintroducedintoa2.0Lvessel.
S2Cl4(g)
2SCl2(g)
Atequilibrium,1.25molesofS2Cl4arefoundtoremaininthecontainer.CalculateKcforthisreaction.
73. Thedatabelowrefertothefollowingreaction:
FindtheconcentrationofBr2whenthesystemreachesequilibrium.
FindtheconcentrationofNOBrwhenthesystemreachesequilibrium.
CalculateKc.
76. Considerthechemicalreaction2NH3(g)
N2(g)+3H2(g).Theequilibriumistobeestablishedina1.0
Lcontainerat1,000K,whereKc=4.0102.Initially,1,220molesofNH3(g)arepresent.
EstimatetheequilibriumconcentrationofH2(g).
EstimatetheequilibriumconcentrationofN2(g).
CalculateKpforthereaction.
79. Hydrogeniodidedecomposesaccordingtotheequation:
2HI(g)
H2(g)+I2(g),Kc=0.0156at400C
A0.660molsampleofHIwasinjectedintoa2.00Lreactionvesselheldat400C.
CalculatetheconcentrationofH2equilibrium.
80. Hydrogeniodidedecomposesaccordingtotheequation:
2HI(g)
H2(g)+I2(g),Kc=0.0156at400C
A0.660molsampleofHIwasinjectedintoa2.00Lreactionvesselheldat400C.
CalculatetheconcentrationofHIatequilibrium.
81. WhatconditionsareusedintheHaberprocesstoenhancetheyieldofammonia?Explainwhyeach
conditionaffectstheyieldintermsoftheLeChtelierprinciple.
82. Thedissociationofsolidsilverchlorideinwatertoproducesilverionsandchlorideionshasan
equilibriumconstantof1.8x1018.Basedonthemagnitudeoftheequilibriumconstant,issilverchloride
verysolubleinwater?Why?
83. ConsidertheequilibriumequationC(s)+H2O(g)+2296J
CO(g)+H2(g).Whatwillhappentothe
concentrationofcarbonmonoxideifthetemperatureofthissystemisraised?
CO(g)+H2(g).Ifadditionalgaseous
waterisaddedtothisreactionmixture,whatwillhappentothetemperatureofthemixture?
massofcarbonifweaddwatertothesystem?
CO(g)+H2(g).Whatwillhappentothe
CO(g)+H2(g).Whichwaywillthe
reactionshiftifthepressureonthesystemisincreased?
87. Ethanolandaceticacidreacttoformethylacetateandwateraccordingtotheequation
C2H5OH+CH3COOH
CH3COOC2H5+H2O
Whentwomoleseachofethanolandaceticacidareallowedtoreactat100Cinasealedtube,equilibrium
isestablishedwhentwothirdsofamoleofeachofthereactantsremains.Calculatetheequilibrium
constantforthisreaction.
88. 5.00moleachofaceticacidandethanolareallowedtoreactina1.00Lsealedcontainerat100Cuntil
equilibriumisestablished.Howmanymolesoftheesterandwaterareproducedinthisreaction?The
equilibriumconstantis4.00forthereaction
C2H5OH+CH3COOH
CH3COOC2H5+H2O.
89. 5.00moleachofaceticacidandethanolareallowedtoreactina1.00Lsealedcontainerat100Cuntil
equilibriumisestablished.Howmanymolesofethanolandacidremainfollowingequilibration?The
equilibriumconstantis4.00forthereaction,
C2H5OH+CH3COOH
CH3COOC2H5+H2O.
90. Whatisthecorrectequilibriumconstantexpressionforthisreaction?
2HI(g)
H2(g)+I2(g)
91. Considerthefollowingequilibrium,
4NH3+3O2
2N2+6H2O+1531kJ
Statewhethertheconcentrationofeachofthereactantswouldincrease,decrease,orremainconstant
whenthetemperatureisincreased.
4NH3+3O2
2N2+6H2O+1531kJ
Statewhethertheconcentrationofeachoftheproductswouldincrease,decrease,orremainconstant
whenthetemperatureisincreased.
4NH3+3O2
2N2+6H2O+1531kJ
Statewhethertheconcentrationofeachofthereactantswouldincrease,decrease,orremainconstant
followingtheadditionof2molofammoniatothesystem.
4NH3+3O2
2N2+6H2O+1531kJ
Statewhethertheconcentrationofeachofthereactionproductswouldincrease,decrease,orremain
constantfollowingtheadditionof2molofammoniatothesystem.
95. KcforthereactionCO2(g)+H2(g)
H2O(g)+CO(g)is1.6atabout990C.Calculatethenumberof
molesofcarbondioxideinthefinalequilibriumsystemobtainedbyinitiallyadding1.00molofH2,2.00
molofCO2,0.750molofH2O,and1.00molofCOtoa5.00Lreactorat990C.
molesofhydrogengasinthefinalequilibriumsystemobtainedbyinitiallyadding1.00molofH2,2.00
molesofwaterinthefinalequilibriumsystemobtainedbyinitiallyadding1.00molofH2,2.00molof
CO2,0.750molofH2O,and1.00molofCOtoa5.00Lreactorat990C.
molesofcarbonmonoxideinthefinalequilibriumsystemobtainedbyinitiallyadding1.00molofH2,2.00
99. TwomolesofPCl5areplacedina5.0Lcontainer.DissociationtakesplaceaccordingtotheequationPCl5
(g)
PCl3(g)+Cl2(g).Atequilibrium,0.40molofCl2arepresent.Calculatetheequilibriumconstant
(Kc)forthisreactionundertheconditionsofthisexperiment.
100. Theequilibriumconstantexpressionforthereaction
CuO(s)+H2(g)
Cu(s)+H2O(g)isKc=[H2]/[H2O].
TrueFalse
101. Whenthereaction2O3(g)
3O2(g),forwhichKp=3.01026at773C,isatequilibrium,themixture
willcontainverylittleO2ascomparedtoO3.
TrueFalse
102. Ifthesystem3H2(g)+N2(g)
2NH3(g)isatequilibriumandmoreN2isadded,anetreactionthat
consumessomeoftheaddedN2willoccuruntilanewequilibriumisreached.
TrueFalse
103. Equilibriumconstantsareknownforthefollowingreactions:
Thus,forthereactionS(s)+O2(g)
TrueFalse
SO2(g),Kc=4.41020.
104. ForthereactionH2(g)+I2(g)
TrueFalse
2HI(g),Kp=Kc.
Chapter14ChemicalEquilibriumKey
1.C
2.B
3.C
4.C
5.D
6.A
7.E
8.C
9.E
10.D
11.B
12.A
13.D
14.C
15.A
16.B
17.B
18.E
19.A
20.D
21.B
22.B
23.A
24.C
25.B
Page 1
26.C
27.B
28.B
29.D
30.C
31.B
32.D
33.A
34.B
35.C
36.C
37.C
38.C
39.E
40.D
41.B
42.A
43.D
44.A
45.B
46.D
47.B
48.C
49.B
50.D
51.D
52.D
53.B
54.C
Page 2
55.E
56.A
57.D
58.B
59.E
60.B
61.A
62.E
63.B
64.Acatalystaffectsboththeforwardandreverserateofthereaction.Therefore,theequilibriumconstantisnotaffected.
65.Thereactionwillshifttowardtheproducts.
66.[NH3]willincrease.
67.[H2]willincrease.
68.TheamountofNH3producedwillincrease.
69.Additionofacatalystwillhavenoeffectonthepositionoftheequilibrium.
70.Kc=17.3
71.Kc=3.1
72.Kc=14.0
73.4.75M
74.1.5M
75.0.12
76.20M
77.6.8M
78.270
79.0.033M
80.0.264M
81.Highpressure,lowtemperature,useofacatalyst.Pressureiskepthighbecausehighpressureconcentratesthereactantstoa
greaterextentthanitdoestheproducts.Temperatureiskeptlowbecausethereactionisexothermic,anduseofacatalyst
facilitatesthereactionprogress.
82.Kcherewillbe[Ag+(aq)][Cl(aq)].IfKeqisverysmall,thentheconcentrationsofthedissolvedionsmustalsobesmall,
implyingthatAgClisnotverysoluble.
Page 3
83.Itwillincrease.
84.Thetemperaturewilldecrease.
85.Themassofcarbonwilldecrease.
86.towardthereactants
87.4
88.1.67moleseachofacidandethanol
89.3.33moleseachofesterandwater
90.Kc=[H2][I2]/[HI]2
91.increase
92.decrease
93.decrease
94.increase
95.1.6mol
96.0.62mol
97.1.1mol
98.1.4mol
99.0.020
100.FALSE
101.FALSE
102.TRUE
103.TRUE
104.TRUE
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1. Which of the following is equal for the forward and reverse reactions at equilibrium?

4. Which of the following is not a physical equilibrium?

8. The expression for Kp for the reaction

9. The equilibrium constant Kp is not applicable for the reaction _____.

10. The equilibrium constant Kc for the reaction

11. The equation relating Kp and Kc is _____.

13. Kp will be less than Kp if _____.

The equilibrium constant for the reaction

17. The equilibrium constant for the reaction

. The equilibrium constant for the reaction

22. The equilibrium constant, Kc, for the reaction

24. The equilibrium pressure for the reaction

29. Kp = Kc for the reaction _____.

31. The equilibrium constant, Kp for the reaction

33. The value of Kc for the above reaction is _____.

35. The ionization constants Kc' and Kc for

36. The equilibrium constant, Kc = 4.0 10-6 for the reaction

Use the following to answer questions 37-38:

37. The equilibrium constant for the reaction

41. The concentration of H+ in pure water at 25C is _____.

The value of Kc for the reaction

Use the following to answer questions 46-48:

The equilibrium constant Kc for the reaction

Kc is 3.8 10-5 at 1000K for the equilibrium

Use the following to answer questions 53-54:

is 4.63 10-3 at 527C .

What is the value of Kc for the reaction

Use the following to answer questions 56-57:

is 1.52 and the total pressure

57. The equilibrium partial pressure of CO2 is _____ atm.

63. The equilibrium position of the reaction

65. The equilibrium constant for the reaction

67. The equilibrium

, can be shifted toward more product

The position of the equilibrium

The addition of He to the equilibrium

72. Which of the following will shift the equilibrium

can be shifted to the right

Use the following to answer questions 74-76:

75. The partial pressure of Cl2 in the equilibrium

76. Kp for the equilibrium

Use the following to answer questions 77-78:

B) 1.6 103 atm

81. The condition for maximum yield of NOCl2 in the reaction

high pressure, high temperature

82. For the reaction

83. For the reaction

The equilibrium constant for the reaction

97. The percentage of fructose converted into glucose in the equilibria

Use the following to answer questions 98-99:

98. Kp for the reaction is _____.

104. Kp for the reaction is _____.

Kp for the process

108. Kc for vaporization of water is_____.

when the total pressure at

Use the following to answer questions 112-114:

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